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    • 8. 发明申请
    • NEUTRAL METALLIC DENDRIMER COMPLEXES
    • 中性金属DENDRIMER复合材料
    • WO2004020448A1
    • 2004-03-11
    • PCT/GB2003/003725
    • 2003-08-28
    • ISIS INNOVATION LIMITEDTHE UNIVERSITY COURT OF THE UNIVERSTIY OF ST ANDREWSSAMUEL, Ifor, David, WilliamBURN, Paul, LeslieLO, Shih-Chun
    • SAMUEL, Ifor, David, WilliamBURN, Paul, LeslieLO, Shih-Chun
    • C07F15/00
    • C07F15/0033C09K2211/1007C09K2211/185H01L51/0037H01L51/0085H01L51/5016Y02E10/549Y10S428/917
    • A charge-neutral organometallic dendrimer is described, said dendrimer having the formula (I): CORE-[DENDRITE(-Q) a ] n in which CORE represents a group of formula Mx x Y z , in which M represents a metal cation, x represents an integer of 1 or more, each X which may be the same or different represents a mono-, bi- or tri-dentate coordinating group, z represents 0 or an integer of 1 or more, and each Y which may be the same or different represents a coordinating group, the total of (b.x) + (c.z) being equal to the number of coordination sites on M, wherein b is the number of coordination sites on X and c is the number of coordination sites on Y; n represents an integer of 2 or more; each DENDRITE which may be the same or different represents a dendritic molecular structure bonded to a group X; a represents 0 or an integer of 1 or more; and each Q which may be the same or different represents a surface group; CORE terminating in the first single bond which is connected to a branching group or branching atom of DENDRITE; which dendrimer has a structure in which no hemisphere of a notional sphere centred on M and containing the dendrimer is devoid of a said first single bond.
    • 描述了电荷中性有机金属树枝状聚合物,所述树枝状聚合物具有式(I):CORE- [DENDRITE(-Q)a] n,其中CORE表示式MxxYz的基团,其中M表示金属阳离子,x表示 1或更大的整数,每个X可以相同或不同,表示单,双或三齿配位基团,z表示0或1或更大的整数,每个Y可以相同或不同 代表协调组,(bx)+(cz)的总和等于M上的协调位点数,其中b是X上的协调位点数,c是Y上的协调位点数; n表示2以上的整数, 每个DENDRITE可以相同或不同,表示与X基团键合的树枝状分子结构; a表示0或1或更大的整数; 并且每个可以相同或不同的Q表示表面基团; CORE终止于连接到DENDRITE的支化基团或支化原子的第一单键; 该树枝状聚合物具有这样的结构,其中以M为中心并且含有树枝状大分子的名义球的半球没有所述第一单键。