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1. 发明专利

DE60224512T2 未知
公开(公告)号：DE60224512T2
公开(公告)日：2008-05-21
申请号：DE60224512
申请日：2002-03-12
申请人： IDEMITSU KOSAN CO
发明人： MACHIDA SHUJI , SHINOHARA MASAYUKI , HOUSAKI TATSUYA
IPC分类号： C08F210/16 , C08F2/00 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/06 , C08F110/06 , C08F210/06 , C08F212/08 , C08F255/00 , C08F257/02 , C08F297/06 , C08F297/08 , C08L23/02 , C08L23/10 , C08L23/16 , C08L51/06

2. 发明专利

DE69425429D1 未知
公开(公告)号：DE69425429D1
公开(公告)日：2000-09-07
申请号：DE69425429
申请日：1994-02-24
申请人： IDEMITSU KOSAN CO
发明人： TAZAKI TOSHINORI , MACHIDA SHUJI
IPC分类号： C08F4/62 , C08F8/04 , C08F297/06 , C08F297/08 , C08F210/16 , C08F8/00
摘要： A propylene block copolymer composed of 50-95 wt.% of a specified propylene polymer block (A) comprising either propylene units only or a combination of propylene units with at most 4 wt.% of C2-C8 olefin units and 50-5 wt.% of an ethylene-propylene copolymer block (B) containing 20-90 wt.% of ethylene units, wherein at least either block (A) or block (B) contains 0.001-15.0 wt.% of diolefinic units and which has a reduced viscosity of 0.01-30 dl/g in 0.05 g/dl of decalin at 135 DEG C; a process for producing the same; and a product of hydrogenation thereof and a modified copolymer produced by introducing functional groups into at least 5 mole % of the unsaturations of the above block copolymer. The above block copolymer is suppressed in gel formation, has an excellent balance between rigidity and impact resistance and a good moldability, and contains unsaturations available for modification. The above modified copolymer is rich in adhesion, printability, hydrophilicity, capability of polymer modification, antistatic effect, and flame retardancy.

3. 发明专利

DE69220272T2 未知
公开(公告)号：DE69220272T2
公开(公告)日：1997-09-25
申请号：DE69220272
申请日：1992-03-24
申请人： IDEMITSU KOSAN CO
发明人： TAZAKI TOSHINORI , MACHIDA SHUJI , WATANABE MASAMI , TOMOTSU NORIO , KURAMOTO MASAHIKO
IPC分类号： C08F4/60 , C08F212/04 , C08F4/602 , C08F297/06
摘要： There is disclosed a process for efficiently producing a styrenic copolymer comprising a styrenic monomer and a monomer containing a polar group an internally olefic monomer by the use of a specific highly active catalyst. Specifically the present invention provides a process for producing a styrenic copolymer which comprise copolymerizing (a) styrenic monomer and (b) a monomer containing a polar group or an internally olefinic monomer in the presence of a catalyst comprising as primary ingredients (A) a transition metal compound and (B) a coordination complex compound comprising a cation and an anion in which a plurality of radicals are bonded to a metal and optionally (C) an organoaluminum compound. The styrenic copolymer thus obtained forms a resin excellent in heat resistance and mechanical strength and finds effective use as a raw material of a variety of molded products.

4. 发明专利

AT155800T 未知
公开(公告)号：AT155800T
公开(公告)日：1997-08-15
申请号：AT93108144
申请日：1993-05-19
申请人： IDEMITSU KOSAN CO
发明人： MACHIDA SHUJI , TAZAKI TOSHINORI , TANI NORIYUKI
IPC分类号： B32B27/06 , C08F297/06 , C08L25/06 , C08L53/00 , C08L53/02 , C08L101/00 , C08L25/18 , B32B27/30
摘要： There are disclosed a styrenic block copolymer having a reduced viscosity of 0.01 to 20 dl/g (0.05 g/l in 1,2,4-trichlorobenzene at 135 DEG C) which comprises highly syndiotactic styrenic-polymer segments and 10 to 10 mol% of heteroatom-containing styrenic polymer segments; a resin composition comprising the above styrenic block copolymer and a thermoplastic resin, an inorganic filler or an organic filler; a multi-layer material comprising at least one layer composed of the above styrenic block copolymer or the above resin composition; and a process for producing the above styrenic block copolymer which comprises polymerizing a styrenic monomer in the presence of a specific catalyst and adding a heteroatom-containing styrenic monomer to successively proceed with copolymerizaiton reaction. The above-disclosed styrenic block copolymer and the resin composition exhibit excellent compatibiity and adhesivenesss, and the multi-layer material is expected to find a wide range of applications in automobile parts, electrical and electronic parts as well as film, sheet, etc.

5. 发明专利

DE69117457D1 未知
公开(公告)号：DE69117457D1
公开(公告)日：1996-04-04
申请号：DE69117457
申请日：1991-12-05
申请人： IDEMITSU KOSAN CO
发明人： TANI NORIYUKI , MACHIDA SHUJI , TAZAKI TOSHINORI
IPC分类号： B32B27/06 , C08F257/02
摘要： There is provided a process for producing a styrenic graft copolymer which comprises coplymerizing a styrenic monomer and a styrenic monomer having a hydrocarbon radical with an unsaturated bond in the presence of a catalyst comprising as primary ingredient (A) a transition metal compound and (B) a contact product of an organoaluminum compound and a condensation agent or (C) a compound which produces an ionic complex by reacting with the above-mentioned transition metal compound and subsequently graft polymerizing an ethylenically unsaturated monomer onto the resultant styrenic copolymer. The above-described styrenic graft copolymer is greatly improved in terms of compatibility, adhesivity, coatability and wettability while preserving heat resistance and chemical resistance thereof, and thus effective as a variety of constructional materials and compatibilizing agents. Furthermore, the composition or multi-layer material comprising the above-mentioned styrenic graft copolymer is widely utilized in a variety of application field including film, sheet, especially stampable sheet, container, packaging material, automobile parts, electrical and electronic parts, etc.

6. 发明专利

DE3886820D1 未知
公开(公告)号：DE3886820D1
公开(公告)日：1994-02-17
申请号：DE3886820
申请日：1988-04-26
申请人： IDEMITSU KOSAN CO
发明人： TANAKA MASATO , MACHIDA SHUJI
IPC分类号： C08F8/12 , C08F4/60 , C08F4/70 , C08F8/44 , C08F210/00 , C08F210/02 , C08F220/00 , C08F220/06 , C08F220/04 , C08F220/12
摘要： An ionomer resin having a weight-average molecular weight of at least 5,000 and containing three specific repeating units as the primary components, said units being arranged randomly and linearly with the total proportion of the two units being 0.001 to 45 mol%, is obtained by copolymerizing ethylene with an unsaturated carboxylic acid in the presence of a Lewis acid, using as a catalyst a chromium compound and a compound of a metal of Groups I to V in the periodic table and permitting a compound of a metal of Group I, II, III, IVA or VIII in the periodic table to react with the resulting copolymer. When an unsaturated carboxylic ester is used, the resulting copolymer is hydrolyzed or thermally decomposed.

7. 发明专利

AT97920T 未知
公开(公告)号：AT97920T
公开(公告)日：1993-12-15
申请号：AT89113395
申请日：1989-07-21
申请人： IDEMITSU KOSAN CO
发明人： TANAKA MASATO , AMANO JUNICHI , MACHIDA SHUJI , ASAHI SATOSHI
IPC分类号： C08F4/622 , C08F210/02

8. 发明专利

DE60113701D1 PROPYLEN HOMO-UND COPOLYMER 未知
公开(公告)号：DE60113701D1
公开(公告)日：2006-02-09
申请号：DE60113701
申请日：2001-07-19
申请人： IDEMITSU KOSAN CO
发明人： MACHIDA SHUJI , SAEKI TAKASHI , TATSUMI TOMIO
IPC分类号： C08F10/06 , C08F110/06 , C08F210/06 , C08J5/00 , C08L23/02 , C08L23/10 , C08L23/12 , C08L23/14
摘要： Provided are a propylene homopolymer in which a melt tension (MT), a Z average molecular weight (Mz) and a melt index (MI) (g/10 minutes) are specifically related and in which a difference in eluting temperatures and a maximum eluting temperature in programmed temperature fractional chromatography and a propylene copolymer in which a comonomer is specific alpha-olefin and a content thereof falls in a specific range and in which a melt tension (MT), a Z average molecular weight (Mz) and a melt index (MI) (g/10 minutes) are specifically related. The propylene homopolymer or the propylene copolymer of the present invention has physical properties equivalent to or not lower than those of conventional propylene polymers, and it can be controlled in a melt tension and is suited to foaming molding, sheet molding and blow molding. Further, it is excellent in melt-processing characteristics, molding stability and a recycling property and can be applied to molding methods which are restricted in use in conventional propylene polymers, for example, large size blow molding and extrusion foaming molding.

9. 发明专利

DE69430795D1 未知
公开(公告)号：DE69430795D1
公开(公告)日：2002-07-18
申请号：DE69430795
申请日：1994-02-04
申请人： IDEMITSU KOSAN CO
发明人： MACHIDA SHUJI , SHIKUMA HARUO , HOSHINO AYAMI , TAKAKURA YUTAKA
IPC分类号： C08F4/62 , C08F4/639 , C08F4/6392 , C08F8/04 , C08F10/02 , C08F110/02 , C08F210/16 , C08L23/04 , C08L23/06
摘要： Polymers derived from ethylene monomers, which do not contain quaternary carbon in the main chain and have an activation energy (Ea) of melt flow of 8-20 kcal/mol, and wherein (1) the Huggins constant (k) and the limiting viscosity [ eta ] satisfy the relationship of the formula: k >/= 0.2 + 0.0743 x [ eta ], or (2) the mold ratio of the methyl groups to the methylene groups in the molecular chain, [CH3/CH2], is 0.005 to 0.1 and satisfies the relationship of the formula: Tm >/= 131 - 1340 [CH3/CH2], or (3) the Mw and the die swell ratio (DR) satisfy the ralationship of the formula: DR > 0.5 + 0.125 x log Mw, or (4) a beta -dispersion peak is present in a temperature range of 0 to - 100 DEG C in the loss modulus measurement. These polyethylenes are different from ordinary HDPE, L-LDPE and LDPE, and are characterized in that they are excellent in processability and capable of the control of various properties, such as density, melting point and crystallinity, mainly by polyethylene itself.

10. 发明专利

DE69425900T2 未知
公开(公告)号：DE69425900T2
公开(公告)日：2001-02-01
申请号：DE69425900
申请日：1994-10-26
申请人： IDEMITSU KOSAN CO
发明人： MACHIDA SHUJI , MITANI MASAHIRO , WATANABE MASAMI , YABUNOUCHI NOBUHIRO
IPC分类号： C08F4/659 , C08F4/6592 , C08F8/04 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/02 , C08F210/16 , C08F290/00
摘要： There are herein disclosed a branched ethylenic macromonomer which can function as a comonomer to provide a copolymer having excellent molding and working properties and which can be hydrogenated to provide a hydrogenated product as a wax useful in various uses, a copolymer having the excellent molding and working properties obtainable by using this macromonomer as a comonomer, and a branched ethylenic polymer having a low-molecular weight obtainable by hydrogenating the macromonomer. The branched ethylenic macromonomer of the present invention is derivable from ethylene singly or derivable from ethylene and another olefin, (a) a molar ratio of a terminal methyl group/a vinyl group in the macromonomer being in the range of 1 to 100, the macromonomer having a branch other than the branch directly derived from the other olefin, (b) a ratio of vinyl groups to the total unsaturated groups in the macromonomer being 70 mol% or more, (c) a weight-average molecular weight of the macromonomer in terms of a polyethylene measured by a GPC being in the range of 100 to 20,000.

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