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1. 发明授权

US08067332B2 Methanation catalyst, and carbon monoxide removing system, fuel processor, and fuel cell including the same 有权
标题翻译：甲烷化催化剂和一氧化碳去除系统，燃料处理器和包括其的燃料电池
公开(公告)号：US08067332B2
公开(公告)日：2011-11-29
申请号：US11743763
申请日：2007-05-03
申请人： Hyun-chul Lee , Soon-ho Kim , Kang-hee Lee , Doo-hwan Lee , Eun-duck Park , Eun-yong Ko
发明人： Hyun-chul Lee , Soon-ho Kim , Kang-hee Lee , Doo-hwan Lee , Eun-duck Park , Eun-yong Ko
IPC分类号： B01J23/00 , B01J23/40 , B01J23/42 , B01J23/44 , H01M8/00 , H01M4/02 , H01M4/36 , H01M4/92
CPC分类号： H01M8/0668 , B01J23/75 , B01J23/755 , B01J35/0006 , B01J35/023 , B01J37/031 , B01J37/033 , B01J37/036 , B01J37/16 , C01B3/586 , C01B2203/0233 , C01B2203/0283 , C01B2203/044 , C01B2203/0445 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0894 , C01B2203/127 , C01B2203/1294 , H01M8/0675
摘要： A methanation catalyst, a carbon monoxide removing system, a fuel processor, and a fuel cell including the same, and more particularly a non-supported methanation catalyst including the catalytically active non-precious metal particles and the metal oxide particles, and a carbon monoxide removing system, a fuel processor, and a fuel cell including the same. The methanation catalyst has high selectivity for the methanation of carbon monoxide instead of the methanation of carbon dioxide and the reverse water gas shift reaction of carbon dioxide, which are side reactions of the methanation of carbon monoxide, maintains high concentration of generated hydrogen as small amounts of hydrogen and carbon dioxide are consumed, and effectively removes carbon monoxide at low operating temperatures of 200° C. or less.
摘要翻译：甲烷化催化剂，一氧化碳去除系统，燃料处理器和包含该甲烷化催化剂的燃料电池，更具体地，包括催化活性非贵金属颗粒和金属氧化物颗粒的非负载型甲烷化催化剂和一氧化碳燃料处理器和包括该系统的燃料电池。甲烷化催化剂对于一氧化碳的甲烷化代替二氧化碳的甲烷化和二氧化碳的反向水煤气变换反应具有高选择性，二氧化碳是一氧化碳甲烷化的副反应，维持生成氢的高浓度少量的氢和二氧化碳被消耗，并且在200℃或更低的低操作温度下有效地除去一氧化碳。

2. 发明授权

US08142529B2 Fuel processor having carbon monoxide removing unit and method of operating the same 有权
标题翻译：具有一氧化碳去除单元的燃料处理器及其操作方法
公开(公告)号：US08142529B2
公开(公告)日：2012-03-27
申请号：US11740535
申请日：2007-04-26
申请人： Hyun-chul Lee , Soon-ho Kim , Doo-hwan Lee , Kang-hee Lee
发明人： Hyun-chul Lee , Soon-ho Kim , Doo-hwan Lee , Kang-hee Lee
IPC分类号： B01J7/00 , H01M8/06 , C01B3/36 , C01B6/24 , C01B3/02
CPC分类号： H01M8/0668 , C01B3/34 , C01B3/48 , C01B2203/0216 , C01B2203/0233 , C01B2203/0283 , C01B2203/047 , C01B2203/0816 , C01B2203/0822 , C01B2203/0827 , C01B2203/0894 , C01B2203/1241 , C01B2203/1258 , C01B2203/1294 , C01B2203/1604 , H01M8/04022 , H01M8/0612 , Y02P20/128
摘要： A fuel processor having a CO removal unit including an apparatus for warming a CO shifter, is provided. A method of using the fuel processor is also provided. The fuel processor includes a reformer that extracts hydrogen gas from a raw fuel by reacting the raw fuel with water. A burner heats up the reformer to a temperature suitable for extracting the hydrogen gas. A CO shifter removes CO produced during the extraction reaction from the hydrogen gas, and a medium path line in which a heat exchange medium disposed therein absorbs heat from the reformer and passes the heat to the CO shifter. A fuel processor having the above structure can greatly reduce the time required to increases the temperature of the CO shifter to an appropriate operating temperature at an early stage of start up, since a rapid heating of the CO shifter is possible using the heat exchange of steam.
摘要翻译：提供了一种具有CO去除单元的燃料处理器，其包括用于加热CO移位器的装置。还提供了使用燃料处理器的方法。燃料处理机包括通过使原料燃料与水反应从原料燃料中提取氢气的重整器。燃烧器将重整器加热至适于提取氢气的温度。 CO移动器从氢气中除去在提取反应期间产生的CO，并且其中设置在其中的热交换介质吸收来自重整器的热并将热量传递给CO移位器的介质路径线。具有上述结构的燃料处理器可以在启动的早期将CO移动器的温度升高到适当的工作温度所需的时间大大减少，因为CO移动器的快速加热可以通过使用蒸汽的热交换。

3. 发明申请

US20080044699A1 FUEL PROCESSOR HAVING CARBON MONOXIDE REMOVING UNIT AND METHOD OF OPERATING THE SAME 有权
标题翻译：具有一氧化碳去除单元的燃料处理器及其操作方法
公开(公告)号：US20080044699A1
公开(公告)日：2008-02-21
申请号：US11740535
申请日：2007-04-26
申请人： Hyun-chul LEE , Soon-ho Kim , Doo-hwan Lee , Kang-hee Lee
发明人： Hyun-chul LEE , Soon-ho Kim , Doo-hwan Lee , Kang-hee Lee
IPC分类号： H01M8/04 , B01D19/00 , B01D47/02
CPC分类号： H01M8/0668 , C01B3/34 , C01B3/48 , C01B2203/0216 , C01B2203/0233 , C01B2203/0283 , C01B2203/047 , C01B2203/0816 , C01B2203/0822 , C01B2203/0827 , C01B2203/0894 , C01B2203/1241 , C01B2203/1258 , C01B2203/1294 , C01B2203/1604 , H01M8/04022 , H01M8/0612 , Y02P20/128
摘要： A fuel processor having a CO removal unit including an apparatus for warming a CO shifter, is provided. A method of using the fuel processor is also provided. The fuel processor includes a reformer that extracts hydrogen gas from a raw fuel by reacting the raw fuel with water. A burner heats up the reformer to a temperature suitable for extracting the hydrogen gas. A CO shifter removes CO produced during the extraction reaction from the hydrogen gas, and a medium path line in which a heat exchange medium disposed therein absorbs heat from the reformer and passes the heat to the CO shifter. A fuel processor having the above structure can greatly reduce the time required to increases the temperature of the CO shifter to an appropriate operating temperature at an early stage of start up, since a rapid heating of the CO shifter is possible using the heat exchange of steam.
摘要翻译：提供了一种具有CO去除单元的燃料处理器，其包括用于加热CO移位器的装置。还提供了使用燃料处理器的方法。燃料处理机包括通过使原料燃料与水反应从原料燃料中提取氢气的重整器。燃烧器将重整器加热至适于提取氢气的温度。 CO移动器从氢气中除去在提取反应期间产生的CO，并且其中设置在其中的热交换介质吸收来自重整器的热并将热量传递给CO移位器的介质路径线。具有上述结构的燃料处理器可以在启动的早期将CO移动器的温度升高到适当的工作温度所需的时间大大减少，因为CO移动器的快速加热可以通过使用蒸汽的热交换。

4. 发明申请

US20080118794A1 FUEL PROCESSOR HAVING IMPROVED STRUCTURE FOR RAPID HEATING UP OF CARBON MONOXIDE REMOVING UNIT AND METHOD OF OPERATING THE FUEL PROCESSOR 审中-公开
标题翻译：具有改进的一氧化碳去除单元快速加热结构的燃油加工机和操作燃料加工器的方法
公开(公告)号：US20080118794A1
公开(公告)日：2008-05-22
申请号：US11837121
申请日：2007-08-10
申请人： Hyun-chul LEE , Soon-ho Kim , Doo-hwan Lee , Kang-hee Lee
发明人： Hyun-chul LEE , Soon-ho Kim , Doo-hwan Lee , Kang-hee Lee
IPC分类号： H01M8/06 , H01M8/18
CPC分类号： H01M8/0612 , H01M8/0668
摘要： A fuel processor having an improved structure to rapidly increase a temperature of a CO removing unit to an operation temperature, and a method of operating the fuel processor, includes a reformer that produces hydrogen gas by reacting a fuel and water; a CO removing unit that removes CO from the hydrogen produced in the reformer. The CO removing unit comprises a CO shift reactor including a first catalyst that catalyzes a reaction between steam and CO and a second catalyst that catalyzes a reaction between oxygen and CO and between hydrogen and oxygen, and a CO remover including a third catalyst that catalyzes a reaction between oxygen and CO; and an air supply unit that supplies air to the CO shift reactor and the CO remover. The use of the fuel processor can greatly reduce a warming up time required to reach a normal operation of the fuel processor since the CO shift reactor can be rapidly heated using a direct reaction between oxygen and CO and between oxygen and hydrogen during an initial start up operation.
摘要翻译：一种具有改进的结构以快速将CO除去单元的温度升高到操作温度的燃料处理器，以及操作燃料处理器的方法包括通过使燃料和水反应而产生氢气的重整器; CO除去单元，其从重整器中产生的氢中除去CO。 CO去除单元包括CO转化反应器，其包括催化蒸汽和CO之间的反应的第一催化剂和催化氧和CO之间以及氢和氧之间的反应的第二催化剂，以及包含第三催化剂的CO去除剂，氧和CO之间的反应; 以及向CO变换反应器和CO去除器供给空气的空气供给单元。燃料处理器的使用可以大大减少达到燃料处理器的正常操作所需的预热时间，因为CO转化反应器可以在初始启动期间使用氧和CO之间以及氧和氢之间的直接反应进行快速加热操作。

5. 发明申请

US20070259975A1 METHANATION CATALYST, AND CARBON MONOXIDE REMOVING SYSTEM, FUEL PROCESSOR, AND FUEL CELL INCLUDING THE SAME 有权
标题翻译：甲烷催化剂和一氧化碳去除系统，燃料处理器和包含其的燃料电池
公开(公告)号：US20070259975A1
公开(公告)日：2007-11-08
申请号：US11743763
申请日：2007-05-03
申请人： Hyun-chul Lee , Soon-ho Kim , Kang-hee Lee , Doo-hwan Lee , Eun-duck Park , Eun-yong Ko
发明人： Hyun-chul Lee , Soon-ho Kim , Kang-hee Lee , Doo-hwan Lee , Eun-duck Park , Eun-yong Ko
IPC分类号： C07C27/06
CPC分类号： H01M8/0668 , B01J23/75 , B01J23/755 , B01J35/0006 , B01J35/023 , B01J37/031 , B01J37/033 , B01J37/036 , B01J37/16 , C01B3/586 , C01B2203/0233 , C01B2203/0283 , C01B2203/044 , C01B2203/0445 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0894 , C01B2203/127 , C01B2203/1294 , H01M8/0675
摘要： A methanation catalyst, a carbon monoxide removing system, a fuel processor, and a fuel cell including the same, and more particularly a non-supported methanation catalyst including the catalytically active non-precious metal particles and the metal oxide particles, and a carbon monoxide removing system, a fuel processor, and a fuel cell including the same. The methanation catalyst has high selectivity for the methanation of carbon monoxide instead of the methanation of carbon dioxide and the reverse water gas shift reaction of carbon dioxide, which are side reactions of the methanation of carbon monoxide, maintains high concentration of generated hydrogen as small amounts of hydrogen and carbon dioxide are consumed, and effectively removes carbon monoxide at low operating temperatures of 200° C. or less.
摘要翻译：甲烷化催化剂，一氧化碳去除系统，燃料处理器和包含该甲烷化催化剂的燃料电池，更具体地，包括催化活性非贵金属颗粒和金属氧化物颗粒的非负载型甲烷化催化剂和一氧化碳燃料处理器和包括该系统的燃料电池。甲烷化催化剂对于一氧化碳的甲烷化代替二氧化碳的甲烷化和二氧化碳的反向水煤气变换反应具有高选择性，二氧化碳是一氧化碳甲烷化的副反应，维持生成氢的高浓度少量的氢和二氧化碳被消耗，并且在200℃或更低的低操作温度下有效地除去一氧化碳。

6. 发明申请

US20080311446A1 FUEL PROCESSOR HAVING TEMPERATURE CONTROL FUNCTION FOR CO SHIFT REACTOR AND METHOD OF OPERATING THE FUEL PROCESSOR 失效
标题翻译：具有CO转换反应器的温度控制功能的燃油加热器和操作燃料加工器的方法
公开(公告)号：US20080311446A1
公开(公告)日：2008-12-18
申请号：US11835563
申请日：2007-08-08
申请人： Kang-hee Lee , Soon-ho Kim , Doo-hwan Lee , Hyun-chul Lee
发明人： Kang-hee Lee , Soon-ho Kim , Doo-hwan Lee , Hyun-chul Lee
IPC分类号： H01M8/18 , C10J1/20
CPC分类号： H01M8/0668 , C01B3/34 , C01B3/48 , C01B2203/0216 , C01B2203/0233 , C01B2203/0283 , C01B2203/0435 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0894 , C01B2203/1258 , H01M8/04007 , H01M8/0612 , Y02P20/128
摘要： A fuel processor includes a reformer that generates hydrogen gas by reacting a fuel source and water; a burner that heats the reformer to a temperature suitable for a hydrogen generation reaction; a CO shift reactor that removes CO generated during the hydrogen generation reaction in the reformer; a heating element for heating the CO shift reactor; and a cooling element for cooling the CO shift reactor, wherein the cooling element comprises at least one of a cooling water flow line for heat exchange with the CO shift reactor when cooling water flows through the cooling water flow line and a cooling gas flow line for heat exchange with the CO shift reactor when a cooling gas, which is a burner exhaust gas that has heat exchanged with cooling water, flows through the cooling gas flow line. When the fuel processor is operated, a stable CO removal performance can be maintained since the temperature of the CO shift reactor can be actively controlled.
摘要翻译：燃料处理机包括通过燃料源和水反应产生氢气的重整器; 将重整器加热到适合于氢气产生反应的温度的燃烧器; CO转化反应器，其去除在重整器中的氢气产生反应期间产生的CO; 用于加热CO转化反应器的加热元件; 以及用于冷却CO变换反应器的冷却元件，其中当冷却水流过冷却水流动管线时，冷却元件包括用于与CO变换反应器进行热交换的冷却水流动管线和用于当与冷却水进行热交换的燃烧器废气的冷却气体流过冷却气体流路时，与CO转化反应器进行热交换。当燃料处理器运行时，可以保持稳定的CO去除性能，因为可以主动控制CO转化反应器的温度。

7. 发明申请

US20080038603A1 FUEL PROCESSOR HAVING DESULFURIZER WITH SULFER SENSOR, FUEL CELL SYSTEM INCLUDING THE FUEL PROCESSOR, AND METHOD OF OPERATING THE FUEL CELL SYSTEM 失效
标题翻译：具有硫磺传感器，包括燃料处理器的燃料电池系统的燃料处理器，以及操作燃料电池系统的方法
公开(公告)号：US20080038603A1
公开(公告)日：2008-02-14
申请号：US11675339
申请日：2007-02-15
申请人： Hyun-chul LEE , Soon-ho Kim , Doo-hwan Lee , Do-young Seung , Kang-hee Lee
发明人： Hyun-chul LEE , Soon-ho Kim , Doo-hwan Lee , Do-young Seung , Kang-hee Lee
IPC分类号： B01D46/00
CPC分类号： H01M8/0631 , H01M8/04022 , H01M8/0668 , H01M8/0675 , H01M2008/1095
摘要： A fuel processor and a fuel cell system which have a desulfurizer with multiple sensors, and a method of measuring an adsorbent state in of an adsorbent the desulfurizer The desulfurizer determines the saturation state of the adsorbent using a signal difference between at least two sensors installed adjacent to an inlet and an outlet of the desulfurizer. The desulfurizer provides an accurate determination of the saturation of the adsorbent, and can be used to determine when the adsorbent should be changed. Two desulfurizers can be alternatively used to allow for a consistent fuel flow.
摘要翻译：具有多个传感器的脱硫器的燃料处理器和燃料电池系统以及测定吸附剂中脱硫剂的吸附剂状态的方法脱硫器使用相邻的至少两个传感器之间的信号差确定吸附剂的饱和状态到脱硫器的入口和出口。脱硫剂提供了吸附剂饱和度的精确测定，可用于确定何时更换吸附剂。可以替代地使用两种脱硫剂来允许一致的燃料流。

8. 发明授权

US08328886B2 Fuel processor having temperature control function for co shift reactor and method of operating the fuel processor 失效
标题翻译：具有用于共变换反应器的温度控制功能的燃料处理器和操作燃料处理器的方法
公开(公告)号：US08328886B2
公开(公告)日：2012-12-11
申请号：US11835563
申请日：2007-08-08
申请人： Kang-hee Lee , Soon-ho Kim , Doo-hwan Lee , Hyun-chul Lee
发明人： Kang-hee Lee , Soon-ho Kim , Doo-hwan Lee , Hyun-chul Lee
IPC分类号： B01J8/00
CPC分类号： H01M8/0668 , C01B3/34 , C01B3/48 , C01B2203/0216 , C01B2203/0233 , C01B2203/0283 , C01B2203/0435 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0894 , C01B2203/1258 , H01M8/04007 , H01M8/0612 , Y02P20/128
摘要： A fuel processor includes a reformer that generates hydrogen gas by reacting a fuel source and water; a burner that heats the reformer to a temperature suitable for a hydrogen generation reaction; a CO shift reactor that removes CO generated during the hydrogen generation reaction in the reformer; a heating element for heating the CO shift reactor; and a cooling element for cooling the CO shift reactor, wherein the cooling element comprises at least one of a cooling water flow line for heat exchange with the CO shift reactor when cooling water flows through the cooling water flow line and a cooling gas flow line for heat exchange with the CO shift reactor when a cooling gas, which is a burner exhaust gas that has heat exchanged with cooling water, flows through the cooling gas flow line. When the fuel processor is operated, a stable CO removal performance can be maintained since the temperature of the CO shift reactor can be actively controlled.
摘要翻译：燃料处理机包括通过燃料源和水反应产生氢气的重整器; 将重整器加热到适合于氢气产生反应的温度的燃烧器; CO转化反应器，其去除在重整器中的氢气产生反应期间产生的CO; 用于加热CO转化反应器的加热元件; 以及用于冷却CO变换反应器的冷却元件，其中当冷却水流过冷却水流动管线时，冷却元件包括用于与CO变换反应器进行热交换的冷却水流动管线和用于当与冷却水进行热交换的燃烧器废气的冷却气体流过冷却气体流路时，与CO转化反应器进行热交换。当燃料处理器运行时，可以保持稳定的CO去除性能，因为可以主动控制CO转化反应器的温度。

9. 发明授权

US08226736B2 Fuel processor having desulfurizer with sulfer sensor, fuel cell system including the fuel processor, and method of operating the fuel cell system 失效
标题翻译：具有硫磺传感器的脱硫器，包括燃料处理器的燃料电池系统以及操作燃料电池系统的方法的燃料处理器
公开(公告)号：US08226736B2
公开(公告)日：2012-07-24
申请号：US11675339
申请日：2007-02-15
申请人： Hyun-chul Lee , Soon-ho Kim , Doo-hwan Lee , Do-young Seung , Kang-hee Lee
发明人： Hyun-chul Lee , Soon-ho Kim , Doo-hwan Lee , Do-young Seung , Kang-hee Lee
IPC分类号： B01J7/00 , C01B3/36 , G01N5/02 , G01R27/08
CPC分类号： H01M8/0631 , H01M8/04022 , H01M8/0668 , H01M8/0675 , H01M2008/1095
摘要： A fuel processor and a fuel cell system which have a desulfurizer with multiple sensors, and a method of measuring an adsorbent state in of an adsorbent the desulfurizer. The desulfurizer determines the saturation state of the adsorbent using a signal difference between at least two sensors installed adjacent to an inlet and an outlet of the desulfurizer. The desulfurizer provides an accurate determination of the saturation of the adsorbent, and can be used to determine when the adsorbent should be changed. Two desulfurizers can be alternatively used to allow for a consistent fuel flow.
摘要翻译：具有多个传感器的脱硫器的燃料处理器和燃料电池系统以及测定吸附剂中脱硫剂的吸附剂状态的方法。脱硫剂使用安装在脱硫器的入口和出口附近的至少两个传感器之间的信号差来确定吸附剂的饱和状态。脱硫剂提供了吸附剂饱和度的精确测定，可用于确定何时更换吸附剂。可以替代地使用两种脱硫剂来允许一致的燃料流。

10. 发明授权

US08057560B2 Fuel processor having movable burner, method of operating the same, and fuel cell system having the same 有权
标题翻译：具有可移动燃烧器的燃料处理器，其操作方法以及具有该燃烧器的燃料电池系统
公开(公告)号：US08057560B2
公开(公告)日：2011-11-15
申请号：US11657085
申请日：2007-01-24
申请人： Hyun-chul Lee , Soon-ho Kim , Doo-hwan Lee , Kang-hee Lee
发明人： Hyun-chul Lee , Soon-ho Kim , Doo-hwan Lee , Kang-hee Lee
IPC分类号： B01J8/00
CPC分类号： H01M8/0618 , H01M8/0631 , Y02E60/324
摘要： A fuel processor having a movable burner, a method of operating the fuel processor, and a fuel cell system having the fuel processor. The fuel processor includes a combustion chamber, a reformer burner, a portion of which is partially disposed inside the combustion chamber, a reformer which is heated by heat transfer from the combustion chamber, and a burner-moving apparatus that moves the reformer burner with respect to the combustion chamber. The method of operating the fuel processor includes determining the load on and a plurality of temperatures within the fuel processor and moving the reformer burner depending upon such information.
摘要翻译：具有可移动燃烧器的燃料处理器，操作燃料处理器的方法以及具有燃料处理器的燃料电池系统。燃料处理机包括燃烧室，重整器燃烧器，其一部分部分地设置在燃烧室的内部，通过从燃烧室传热而被加热的重整器，以及使重整器燃烧器相对运动的燃烧器移动装置到燃烧室。操作燃料处理器的方法包括确定燃料处理器内的负载和多个温度，并根据这些信息移动重整器燃烧器。

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