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1. 发明授权

US08559003B2 Electrically driven devices for surface enhanced raman spectroscopy 有权
标题翻译：用于表面增强拉曼光谱的电驱动装置
公开(公告)号：US08559003B2
公开(公告)日：2013-10-15
申请号：US13384456
申请日：2009-09-17
申请人： Huei Pei Kuo , Shih-Yuan Wang , Min Hu , Zhiyong Li , Alexandre M. Bratkovski
发明人： Huei Pei Kuo , Shih-Yuan Wang , Min Hu , Zhiyong Li , Alexandre M. Bratkovski
IPC分类号： G01J3/44
CPC分类号： G01N21/658 , B82Y15/00 , B82Y30/00
摘要： An electrically driven device for surface enhanced Raman spectroscopy includes a first electrode, a substrate positioned proximate to the first electrode, a plurality of cone shaped protrusions formed integrally with or on a substrate surface, a Raman signal-enhancing material coated on each protrusion, and a second electrode positioned relative to the first electrode at a predetermined distance. Each of the protrusions has a tip with a radius of curvature ranging from about 0.1 nm to about 100 nm. The second electrode is positioned relative to the first electrode such that the electrodes together produce an electric field when a voltage bias is applied therebetween. The electric field has a field distribution that creates a stronger field gradient at a region proximate to the tips than at other portions of the substrate.
摘要翻译：用于表面增强拉曼光谱的电驱动装置包括第一电极，靠近第一电极定位的基板，与基底表面一体地形成的多个锥形突起，涂覆在每个突起上的拉曼信号增强材料，以及相对于第一电极以预定距离定位的第二电极。每个突起具有具有约0.1nm至约100nm范围的曲率半径的尖端。第二电极相对于第一电极定位，使得当在其之间施加电压偏置时，电极一起产生电场。电场具有场分布，其在靠近尖端的区域处产生比在衬底的其它部分更强的场梯度。

2. 发明授权

US08208137B2 Molecule detection using Raman light detection 失效
标题翻译：使用拉曼光检测的分子检测
公开(公告)号：US08208137B2
公开(公告)日：2012-06-26
申请号：US12696853
申请日：2010-01-29
申请人： Min Hu , Alexandre M. Bratkovski , Jingjing Li , Huei Pei Kuo , Zhiyong Li , Fung Suong Ou , Michael Josef Stuke , Michael Renne Ty Tan , Shih-Yuan Wang , Wei Wu
发明人： Min Hu , Alexandre M. Bratkovski , Jingjing Li , Huei Pei Kuo , Zhiyong Li , Fung Suong Ou , Michael Josef Stuke , Michael Renne Ty Tan , Shih-Yuan Wang , Wei Wu
IPC分类号： G01J3/44
CPC分类号： G01J3/44
摘要： An apparatus for detecting at least one molecule using Raman light detection includes a substrate for supporting a sample containing the at least one molecule, a laser source for emitting a laser beam to cause Raman light emission from the at least one molecule, a modulating element for modulating a spatial relationship between the laser beam and the substrate at an identified frequency to cause the Raman light to be emitted from the at least one molecule at the identified frequency, at least one detector for detecting the Raman light emitted from the at least one molecule, and a post-signal processing unit configured to process the detected Raman light emission at the identified frequency to detect the at least one molecule.
摘要翻译：用于使用拉曼光检测检测至少一个分子的装置包括用于支撑含有至少一个分子的样品的基底，用于发射激光束以产生来自至少一个分子的拉曼光发射的激光源，以识别的频率调制激光束和衬底之间的空间关系，以使所述拉曼光以所识别的频率从所述至少一个分子发射;至少一个检测器，用于检测从所述至少一个分子发射的拉曼光以及后信号处理单元，被配置为处理所识别的频率处的所检测的拉曼光发射以检测所述至少一个分子。

3. 发明申请

US20110188033A1 MOLECULE DETECTION USING RAMAN LIGHT DETECTION 失效
标题翻译：使用拉曼光检测的分子检测
公开(公告)号：US20110188033A1
公开(公告)日：2011-08-04
申请号：US12696853
申请日：2010-01-29
申请人： Min Hu , Alexandre M. Bratkovski , Jingjing Li , Huei Pei Kuo , Zhiyong Li , Fung Suong Ou , Michael Josef Stuke , Michael Renne Ty Tan , Shih-Yuan Wang , Wei Wu
发明人： Min Hu , Alexandre M. Bratkovski , Jingjing Li , Huei Pei Kuo , Zhiyong Li , Fung Suong Ou , Michael Josef Stuke , Michael Renne Ty Tan , Shih-Yuan Wang , Wei Wu
IPC分类号： G01J3/44
CPC分类号： G01J3/44
摘要： An apparatus for detecting at least one molecule using Raman light detection includes a substrate for supporting a sample containing the at least one molecule, a laser source for emitting a laser beam to cause Raman light emission from the at least one molecule, a modulating element for modulating a spatial relationship between the laser beam and the substrate at an identified frequency to cause the Raman light to be emitted from the at least one molecule at the identified frequency, at least one detector for detecting the Raman light emitted from the at least one molecule, and a post-signal processing unit configured to process the detected Raman light emission at the identified frequency to detect the at least one molecule.
摘要翻译：用于使用拉曼光检测检测至少一个分子的装置包括用于支撑含有至少一个分子的样品的基底，用于发射激光束以产生来自至少一个分子的拉曼光发射的激光源，以识别的频率调制激光束和衬底之间的空间关系，以使所述拉曼光以所识别的频率从所述至少一个分子发射;至少一个检测器，用于检测从所述至少一个分子发射的拉曼光以及后信号处理单元，被配置为处理所识别的频率处的所检测的拉曼光发射以检测所述至少一个分子。

4. 发明授权

US08472018B2 Grating for multiple discrete wavelengths of Raman scattering 有权
标题翻译：用于多个离散波长的拉曼散射的光栅
公开(公告)号：US08472018B2
公开(公告)日：2013-06-25
申请号：US12847982
申请日：2010-07-30
申请人： Michael J. Stuke , Michael R. T. Tan , Alexandre M. Bratkovski , Min Hu , Huei Pei Kuo , Jingjing Li , Zhiyong Li , Fung Suong Ou , Shih-Yuan Wang , Wei Wu
发明人： Michael J. Stuke , Michael R. T. Tan , Alexandre M. Bratkovski , Min Hu , Huei Pei Kuo , Jingjing Li , Zhiyong Li , Fung Suong Ou , Shih-Yuan Wang , Wei Wu
IPC分类号： G01J3/44
CPC分类号： G01N21/65 , G01N21/658
摘要： Systems and methods employ a layer having a pattern that provides multiple discrete guided mode resonances for respective couplings of separated wavelengths into the layer. Further, a structure including features shaped to enhance Raman scattering to produce light of the resonant wavelengths can be employed with the patterned layer.
摘要翻译：系统和方法采用具有图案的层，该图案为分离的波长的各个耦合提供到层中提供多个离散的引导模式谐振。此外，可以使用包括成形为增强拉曼散射以产生谐振波长的光的特征的结构与图案化层。

5. 发明申请

US20120026493A1 GRATING FOR MULTIPLE DISCRETE WAVELENGTHS OF RAMAN SCATTERING 有权
标题翻译：用于拉曼散射的多个分辨波长的光刻
公开(公告)号：US20120026493A1
公开(公告)日：2012-02-02
申请号：US12847982
申请日：2010-07-30
申请人： Michael J. Stuke , Michael R.T. Tan , Alexandre M. Bratkovski , Min Hu , Huei Pei Kuo , Jingjing Li , Zhiyong Li , Fung Suong Ou , Shih-Yuan Wang , Wei Wu
发明人： Michael J. Stuke , Michael R.T. Tan , Alexandre M. Bratkovski , Min Hu , Huei Pei Kuo , Jingjing Li , Zhiyong Li , Fung Suong Ou , Shih-Yuan Wang , Wei Wu
IPC分类号： G01J3/44
CPC分类号： G01N21/65 , G01N21/658
摘要： Systems and methods employ a layer having a pattern that provides multiple discrete guided mode resonances for respective couplings of separated wavelengths into the layer. Further, a structure including features shaped to enhance Raman scattering to produce light of the resonant wavelengths can be employed with the patterned layer.
摘要翻译：系统和方法采用具有图案的层，该图案为分离的波长的各个耦合提供到层中提供多个离散的引导模式谐振。此外，可以使用包括成形为增强拉曼散射以产生谐振波长的光的特征的结构与图案化层。

6. 发明申请

US20110188034A1 SURFACE ENHANCED RAMAN SPECTROSCOPY EMPLOYING VIBRATING NANORODS 有权
标题翻译：表面增强拉曼光谱仪采用振动纳米级
公开(公告)号：US20110188034A1
公开(公告)日：2011-08-04
申请号：US12697136
申请日：2010-01-29
申请人： Michael J. Stuke , Alexandre M. Bratkovski , Min Hu , Huei Pei Kuo , Jingjing Li , Zhiyong Li , Fung Suong Ou , Shih-Yuan (Sy) Wang , Wei Wu
发明人： Michael J. Stuke , Alexandre M. Bratkovski , Min Hu , Huei Pei Kuo , Jingjing Li , Zhiyong Li , Fung Suong Ou , Shih-Yuan (Sy) Wang , Wei Wu
IPC分类号： G01J3/44
CPC分类号： G01J3/44 , G01N21/658
摘要： A surface enhanced Raman spectroscopy (SERS) apparatus, system and method employ a plurality of nanorods configured to vibrate. The apparatus includes the nanorods having tips at free ends opposite an end attached to a substrate. The tips are configured to adsorb an analyte and to vibrate at a vibration frequency. The apparatus further includes a vibration source configured to vibrate the free ends of the nanorods at the vibration frequency in a back-and-forth motion. Vibration of the nanorods is configured to facilitate detection of a Raman scattering signal emitted by the analyte adsorbed on the nanorod tips. The system further includes a synchronous detector configured to receive the Raman signal and to be gated cooperatively with the vibration of the nanorods. The method includes inducing a vibration of the nanorods, illuminating the vibrating tips to produce a Raman signal, and detecting the Raman signal using the detector.
摘要翻译：表面增强拉曼光谱（SERS）装置，系统和方法采用配置成振动的多个纳米棒。该装置包括纳米棒，其具有与连接到基底的端部相对的自由端处的尖端。尖端被配置为吸附分析物并以振动频率振动。该装置还包括一个振动源，其构造成以往复运动的振动频率使纳米棒的自由端振动。纳米棒的振动被配置为便于检测由吸附在纳米棒尖端上的分析物发射的拉曼散射信号。该系统还包括一个同步检测器，其被配置为接收拉曼信号并与纳米棒的振动协同地门控。该方法包括诱导纳米棒的振动，照亮振动尖端以产生拉曼信号，以及使用检测器检测拉曼信号。

7. 发明申请

US20110188035A1 VIBRATING TIP SURFACE ENHANCED RAMAN SPECTROSCOPY 有权
标题翻译：振动提示表面增强拉曼光谱
公开(公告)号：US20110188035A1
公开(公告)日：2011-08-04
申请号：US12697156
申请日：2010-01-29
申请人： Huei Pei Kuo , Michael J. Stuke , Min Hu , Fung Suong Ou , Shih-Yuan (SY) Wang , Alexandre M. Bratkovski , Wei Wu , Zhiyong Li
发明人： Huei Pei Kuo , Michael J. Stuke , Min Hu , Fung Suong Ou , Shih-Yuan (SY) Wang , Alexandre M. Bratkovski , Wei Wu , Zhiyong Li
IPC分类号： G01J3/44
CPC分类号： G01J3/44
摘要： A vibrating tip surface enhanced Raman spectroscopy (SERS) apparatus, system and method employ a nano-needle configured to vibrate. The apparatus includes the nano-needle with a substantially sharp tip at a free end opposite an end attached to a substrate. The tip is configured to adsorb an analyte. The apparatus further includes a vibration source configured to provide an alternating current (AC) electric field that induces a vibration of the free end and the tip of the nano-needle. Vibration of the nano-needle under the influence of the AC electric field facilitates detection of a Raman scattering signal from the analyte adsorbed on the nano-needle tip. The system further includes a synchronous detector configured to be gated cooperatively with the vibration of the nano-needle. The method includes inducing the vibration, illuminating the vibrating tip to produce a Raman signal, and detecting the Raman signal using the detector.
摘要翻译：振动尖端表面增强拉曼光谱（SERS）装置，系统和方法采用配置为振动的纳米针。该装置包括在与连接到基底的端相对的自由端处具有基本尖锐的尖端的纳米针。尖端构造成吸附分析物。该装置还包括一个被配置为提供交流（AC）电场的振动源，其引起自由端和纳米针的尖端的振动。在AC电场的影响下，纳米针的振动有助于检测吸附在纳米针尖上的分析物的拉曼散射信号。该系统还包括配置为与纳米针的振动协同地选通的同步检测器。该方法包括引起振动，照亮振动尖端以产生拉曼信号，并使用检测器检测拉曼信号。

8. 发明授权

US08390804B2 Surface enhanced Raman spectroscopy employing vibrating nanorods 有权
标题翻译：使用振动纳米棒的表面增强拉曼光谱
公开(公告)号：US08390804B2
公开(公告)日：2013-03-05
申请号：US12697136
申请日：2010-01-29
申请人： Michael J. Stuke , Alexandre M. Bratkovski , Min Hu , Huei Pei Kuo , Jingjing Li , Zhiyong Li , Fung Suong Ou , Shih-Yuan (Sy) Wang , Wei Wu
发明人： Michael J. Stuke , Alexandre M. Bratkovski , Min Hu , Huei Pei Kuo , Jingjing Li , Zhiyong Li , Fung Suong Ou , Shih-Yuan (Sy) Wang , Wei Wu
IPC分类号： G01J3/44
CPC分类号： G01J3/44 , G01N21/658
摘要： A surface enhanced Raman spectroscopy (SERS) apparatus, system and method employ a plurality of nanorods configured to vibrate. The apparatus includes the nanorods having tips at free ends opposite an end attached to a substrate. The tips are configured to adsorb an analyte and to vibrate at a vibration frequency. The apparatus further includes a vibration source configured to vibrate the free ends of the nanorods at the vibration frequency in a back-and-forth motion. Vibration of the nanorods is configured to facilitate detection of a Raman scattering signal emitted by the analyte adsorbed on the nanorod tips. The system further includes a synchronous detector configured to receive the Raman signal and to be gated cooperatively with the vibration of the nanorods. The method includes inducing a vibration of the nanorods, illuminating the vibrating tips to produce a Raman signal, and detecting the Raman signal using the detector.
摘要翻译：表面增强拉曼光谱（SERS）装置，系统和方法采用配置成振动的多个纳米棒。该装置包括纳米棒，其具有与连接到基底的端部相对的自由端处的尖端。尖端被配置为吸附分析物并以振动频率振动。该装置还包括一个振动源，其构造成以往复运动的振动频率使纳米棒的自由端振动。纳米棒的振动被配置为便于检测由吸附在纳米棒尖端上的分析物发射的拉曼散射信号。该系统还包括一个同步检测器，其被配置为接收拉曼信号并与纳米棒的振动协同地门控。该方法包括诱导纳米棒的振动，照亮振动尖端以产生拉曼信号，以及使用检测器检测拉曼信号。

9. 发明授权

US08243270B2 Vibrating tip surface enhanced Raman spectroscopy 有权
标题翻译：振动尖端表面增强拉曼光谱
公开(公告)号：US08243270B2
公开(公告)日：2012-08-14
申请号：US12697156
申请日：2010-01-29
申请人： Huei Pei Kuo , Michael J. Stuke , Min Hu , Fung Suong Ou , Shih-Yuan (SY) Wang , Alexandre M. Bratkovski , Wei Wu , Zhiyong Li
发明人： Huei Pei Kuo , Michael J. Stuke , Min Hu , Fung Suong Ou , Shih-Yuan (SY) Wang , Alexandre M. Bratkovski , Wei Wu , Zhiyong Li
IPC分类号： G01J3/44
CPC分类号： G01J3/44
摘要： A vibrating tip surface enhanced Raman spectroscopy (SERS) apparatus, system and method employ a nano-needle configured to vibrate. The apparatus includes the nano-needle with a substantially sharp tip at a free end opposite an end attached to a substrate. The tip is configured to adsorb an analyte. The apparatus further includes a vibration source configured to provide an alternating current (AC) electric field that induces a vibration of the free end and the tip of the nano-needle. Vibration of the nano-needle under the influence of the AC electric field facilitates detection of a Raman scattering signal from the analyte adsorbed on the nano-needle tip. The system further includes a synchronous detector configured to be gated cooperatively with the vibration of the nano-needle. The method includes inducing the vibration, illuminating the vibrating tip to produce a Raman signal, and detecting the Raman signal using the detector.
摘要翻译：振动尖端表面增强拉曼光谱（SERS）装置，系统和方法采用配置为振动的纳米针。该装置包括在与连接到基底的端相对的自由端处具有基本尖锐的尖端的纳米针。尖端构造成吸附分析物。该装置还包括一个被配置为提供交流（AC）电场的振动源，其引起自由端和纳米针的尖端的振动。在AC电场的影响下，纳米针的振动有助于检测吸附在纳米针尖上的分析物的拉曼散射信号。该系统还包括配置为与纳米针的振动协同地选通的同步检测器。该方法包括引起振动，照亮振动尖端以产生拉曼信号，并使用检测器检测拉曼信号。

10. 发明申请

US20120113420A1 ELECTRICALLY DRIVEN DEVICES FOR SURFACE ENHANCED RAMAN SPECTROSCOPY 有权
标题翻译：用于表面增强拉曼光谱的电驱动装置
公开(公告)号：US20120113420A1
公开(公告)日：2012-05-10
申请号：US13384456
申请日：2009-09-17
申请人： Huei Pei Kuo , Shih-Yuan Wang , Min Hu , Zhiyong Li , Alexander M. Bratkovski
发明人： Huei Pei Kuo , Shih-Yuan Wang , Min Hu , Zhiyong Li , Alexander M. Bratkovski
IPC分类号： G01J3/44
CPC分类号： G01N21/658 , B82Y15/00 , B82Y30/00
摘要： An electrically driven device (10) for surface enhanced Raman spectroscopy includes a first electrode (16), a substrate (12) positioned proximate to the first electrode (16), a plurality of cone shaped protrusions (12′) formed integrally with or on a substrate surface (S), a Raman signal-enhancing material (14) coated on each protrusion (12′), and a second electrode (18) positioned relative to the first electrode (16) at a predetermined distance, D. Each of the protrusions (12′) has a tip (22) with a radius of curvature, r, ranging from about 0.1 nm to about 100 nm. The second electrode (18) is positioned relative to the first electrode (16) such that the electrodes (16, 18) together produce an electric field (EF) when a voltage bias is applied therebetween. The electric field (EF) has a field distribution that creates a stronger field gradient at a region proximate to the tips (22) than at other portions of the substrate (12).
摘要翻译：用于表面增强拉曼光谱的电驱动装置（10）包括第一电极（16），靠近第一电极（16）定位的基板（12），与该第一电极（16）一体形成的多个锥形突起涂覆在每个突起（12'）上的衬底表面（S），拉曼信号增强材料（14）和相对于第一电极（16）以预定距离D定位的第二电极（D）。突起（12'）具有从约0.1nm至约100nm范围内的具有曲率半径r的尖端（22）。第二电极（18）相对于第一电极（16）定位，使得当施加电压时，电极（16,18）一起产生电场（EF）。电场（EF）具有在靠近尖端（22）的区域处比在衬底（12）的其它部分处产生更强的场梯度的场分布。

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