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    • 7. 发明授权
    • Method for the colorimetric determination of the cyanide concentration
of aqueous solutions
    • 水溶液氰化物浓度的比色测定方法
    • US4871681A
    • 1989-10-03
    • US126095
    • 1987-11-30
    • Edgar BilgerHubert Wolf
    • Edgar BilgerHubert Wolf
    • G01N31/00G01N21/78G01N31/22G01N33/18G01N35/08
    • G01N21/78G01N31/22G01N33/182Y10T436/172307
    • According to the invention, cyanide concentrations of approximately 0.001 to 5 mg cyanide/1 are colorimetrically determined in a continuous manner by means of the known cyanidepicric acid color reaction. The solution containing free cyanide and/or cyanide releasable from cyanocomplexes is converted in a system enclosed in a gas-tight manner in the presence of chelate complexing agents, picric acid and alkaline buffer systems in 1-60 minutes at 50.degree.-120.degree. C. to the color complex and the absorbency is measured spectrophotometrically. The method avoids the extraction step which was previously necessary under 0.2 mg CN/1, avoids errors due to HCN gas evolution losses, is easy to manage, not prone to trouble and suitable for the continuous monitoring of waste-water streams or for controlling cyanide detoxification methods.
    • 根据本发明,氰化物浓度约为0.001至5mg氰化物/ 1,通过已知的氰尿酸显色反应以连续方式进行比色测定。 在螯合络合剂苦味酸和碱性缓冲体系的存在下,在50-120℃下在1-60分钟内将含有可从氰络合物中释放的游离氰化物和/或氰化物的溶液转化为气密封闭的体系 对颜色复合物和吸光度进行分光光度法测量。 该方法避免了0.2 mg CN / 1以前必需的萃取步骤,避免了HCN气体放出损失导致的误差,易于管理,不容易出现故障,适合连续监测废水流或控制氰化物 解毒方法