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1. 发明授权

US07008673B2 Hardenable mixture of substances, production method and use thereof 失效
标题翻译：物质的可硬化混合物，其制备方法和用途
公开(公告)号：US07008673B2
公开(公告)日：2006-03-07
申请号：US10490344
申请日：2002-10-16
申请人： Hubert Baumgart , Sandra Hasse , Helmut Kleine Beckmann , Vincent Cook
发明人： Hubert Baumgart , Sandra Hasse , Helmut Kleine Beckmann , Vincent Cook
IPC分类号： C09D133/14 , C09D161/20
CPC分类号： C09D133/06 , C08G18/6237 , C08G18/6254 , C08G18/73 , C08G18/7837 , C08G18/792 , C08G18/8016 , C08G18/8064 , C08G18/807 , C08G18/8093 , C08G73/0655 , C08L33/06 , C08L75/04 , C08L2666/20 , C09D175/04 , C09J133/06 , Y10T428/31551 , Y10T428/31601 , Y10T428/31605
摘要： A curable composition comprising (A) constituents containing carbamate groups I: —O—C(O)—NHR (I) in which R=a hydrogen atom or an alkyl, cycloalkyl or aryl group, (B) constituents containing carbamate-reactive groups, the equivalents ratio of carbamate-reactive groups in (B) to carbamate groups in (A) being >0.2, (C) adducts preparable from (c1) polyisocyanates and (c2) compounds II containing isocyanate-reactive functional groups: in which R1 and R2: independently of one another are hydrogen atoms or alkyl radicals; X and Y: oxygen atom, sulfur atom or a radical >N—R6, in which R6=aliphatic radical; R3: is an alkylene radical; R4 and R5: are hydrogen atoms, isocyanate-reactive functional groups or R6; with the proviso that one group R4, R5 or R6 contains an isocyanate-reactive functional group or R4 or R5 is an isocyanate-reactive functional group and the other radicals R4, R5 or R6—where present—contain no isocyanate-reactive groups; the molar ratio of (c1) to (c2) being chosen such that the adducts (C) contain in the molecule isocyanate groups; process for its preparation, and its use.
摘要翻译：包含（A）含有氨基甲酸酯基团的组分的可固化组合物I：<？in-line-formula description =“In-line formula”end =“lead”→OC（O）-NHR（I）式中：R =氢原子或烷基，环烷基或芳基，（B）含有氨基甲酸酯反应性基团的组分，氨基甲酸酯反应性的当量比例为“In-line Formulas”end =“tail” （A）中的（B）氨基甲酸酯基团中的基团> 0.2，（C）可从（c1）多异氰酸酯制备的加合物和（c2）含有异氰酸酯反应性官能团的化合物II：其中R 1，和R 2彼此独立地是氢原子或烷基; X和Y：氧原子，硫原子或基团> N-R 6，其中R 6 =脂族基; R 3是亚烷基; R 4和R 5是氢原子，异氰酸酯反应性官能团或R 6; 条件是一个R 4，R 5或R 6基团含有异氰酸酯反应性官能团或R 4， SUP>或R 5是异氰酸酯反应性官能团，而其它基团R 4，R 5或R 6， SUP> - 其中含有不含异氰酸酯反应性基团; 选择（c1）至（c2）的摩尔比使得加合物（C）在分子中含有异氰酸酯基; 其准备过程及其使用。

2. 发明申请

US20060173120A1 Coating materials, method for the production thereof, and use thereof 审中-公开
标题翻译：涂料，其制造方法及其用途
公开(公告)号：US20060173120A1
公开(公告)日：2006-08-03
申请号：US10543330
申请日：2004-01-20
申请人： Hubert Baumgart , Annette Roters , Vincent Cook , Thomas Farwick , Sandra Hasse , Cornelia Ketteler , Ulrike Rockrath
发明人： Hubert Baumgart , Annette Roters , Vincent Cook , Thomas Farwick , Sandra Hasse , Cornelia Ketteler , Ulrike Rockrath
IPC分类号： C09B67/00
CPC分类号： C08G18/80 , C09D133/14 , C08L2666/20
摘要： Coating materials including at least one hydroxyl-containing (meth)acrylate (co)polymer, at least one carbamate- and hydroxyl-containing compound and at least one amino resin, where at least 10 equivalent % of the hydroxyl groups present in the (meth)acrylate (co)polymers and/or the carbamate and hydroxyl containing compound are primary hydroxyl groups. The coating materials after curing have a storage modulus E′ in the rubber-elastic range of at least 1.5*107 Pa, the storage modulus E′ having been measured by dynamic mechanical thermoanalysis (DMTA) on homogeneous free films with a thickness of 40±10 μm. Also included is a processes for preparing the coating materials and applications therefor.
摘要翻译：包含至少一种含羟基的（甲基）丙烯酸酯（共）聚合物，至少一种含氨基甲酸酯和羟基的化合物和至少一种氨基树脂的涂料，其中至少10当量的羟基存在于（甲基））丙烯酸酯（共）聚合物和/或含氨基甲酸酯和羟基的化合物是伯羟基。固化后的涂料在橡胶弹性范围内具有至少1.5×10 7 Pa的储能模量E'，储能模量E'通过动态机械热分析（DMTA）在均相上测量厚度为40±10um的自由膜。还包括制备涂料及其应用的方法。

3. 发明申请

US20060116488A1 Multi-component system and the use thereof for producing a triple cure mixture which can be hardened thermally and by means of actinic radiation 审中-公开
标题翻译：多组分体系及其用于生产三元固化混合物的方法，其可以通过光化辐射热固化
公开(公告)号：US20060116488A1
公开(公告)日：2006-06-01
申请号：US10541530
申请日：2003-11-19
申请人： Hubert Baumgart , Vincent Cook , Thomas Farwick , Sandra Hasse , Peter Mayenfels , Guido Schulze-Finkenbrink
发明人： Hubert Baumgart , Vincent Cook , Thomas Farwick , Sandra Hasse , Peter Mayenfels , Guido Schulze-Finkenbrink
IPC分类号： C08G18/06 , C08G18/00
CPC分类号： C08G18/792 , C08G18/6254 , C08G18/6283 , C08L61/28 , C09D175/04 , C08L2666/16
摘要： A multicomponent system comprising (I) a component comprising (A) an oligomer and/or polymer containing allophanate groups and/or carbamate groups, (B) an oligomer and/or polymer containing isocyanate-reactive functional groups, (C) a partly or fully alkylated amino resin, and (D) a compound containing groups which can be activated with actinic radiation; and (II) a component comprising (E) a polyisocyanate, with the proviso that the equivalents ratio of isocyanate groups in component (II) to isocyanate-reactive functional groups in component (I) is from 0.2:1 to 1:0.2 and the equivalents ratio of allophanate groups and/or carbamate groups in the oligomer and/or polymer (A) to the N-methylol ether groups or the N-methylol and N-methylol ether groups in the amino resin (C) is from 0.2:1 to 1:0.2; and its use to produce mixtures curable thermally and with actinic radiation.
摘要翻译：一种多组分体系，其包含（I）包含（A）含有脲基甲酸酯基和/或氨基甲酸酯基团的低聚物和/或聚合物的组分，（B）含异氰酸酯反应性官能团的低聚物和/或聚合物，（C）部分或完全烷基化的氨基树脂，和（D）可以用光化辐射活化的基团的化合物; 和（II）包含（E）多异氰酸酯的组分，条件是组分（II）中异氰酸酯基团与组分（I）中异氰酸酯反应性官能团的当量比为0.2:1至1:0.2，低聚物和/或聚合物（A）中氨基甲酸酯基和/或氨基甲酸酯基与氨基树脂（C）中的N-羟甲基醚基或N-羟甲基和N-羟甲基醚基的当量比为0.2:1 至1:0.2; 以及其用于产生可热固化和与光化辐射固化的混合物的用途。

4. 发明申请

US20050119422A1 Thermally curable, thixotropic mixtures containing carbamate and/or allophanate groups 审中-公开
标题翻译：含有氨基甲酸酯和/或脲基甲酸酯基的热固化触变混合物
公开(公告)号：US20050119422A1
公开(公告)日：2005-06-02
申请号：US10511057
申请日：2002-04-24
申请人： Hubert Baumgart , Sandra Hasse , Vincent Cook
发明人： Hubert Baumgart , Sandra Hasse , Vincent Cook
IPC分类号： C08G18/32 , C08G18/62 , C08G18/80 , C08G71/04 , C09D5/04 , C09D175/04 , C09D201/02 , C08L75/00
CPC分类号： C09D5/04 , C08G18/3212 , C08G18/6254 , C08G18/8093 , C08G71/04 , C09D175/04 , C09D201/025
摘要： Heat-curable thixotropic mixtures containing carbamate and/or allophanate groups, comprising (A) at least one oligomer and/or polymer selected from the group consisting of oligomers and polymers containing allophanate groups, carbamate groups, and carbamate and allophanate groups, and (B) at least one thixotropic agent selected from the group consisting of urea or urea derivatives preparable by reacting at least one amine and/or water with at least one polyisocyanate, with the proviso that the mixture in question, based on its solids, further comprises at least one silica as thixotropic agent (C), and contains the thixotropic agent (B) in an amount of from 0.1 to 5% by weight if the oligomers and polymers (A) contain no allophanate groups; processes for preparing the mixtures, and their use as coating materials, adhesives and sealing compounds.
摘要翻译：含有氨基甲酸酯和/或脲基甲酸酯基团的可热固化触变性混合物，包含（A）至少一种低聚物和/或聚合物，其选自含有脲基甲酸酯基团的低聚物和聚合物，氨基甲酸酯基团和氨基甲酸酯和脲基甲酸酯基团，和（B ）至少一种触变剂，其选自可通过使至少一种胺和/或水与至少一种多异氰酸酯反应制备的脲或脲衍生物，条件是所述混合物基于其固体，还包含在至少一种二氧化硅作为触变剂（C），并且如果低聚物和聚合物（A）不含脲基甲酸酯基团，则含有0.1至5重量％的触变剂（B）制备混合物的方法及其作为涂料，粘合剂和密封剂的用途。

5. 发明授权

US07129280B2 Mixtures which contain carbamate groups and/or allophanate groups and can be cured thermally and by using actinic radiation 有权
标题翻译：含有氨基甲酸酯基和/或脲基甲酸酯基团的混合物可以热和通过光化辐射固化
公开(公告)号：US07129280B2
公开(公告)日：2006-10-31
申请号：US10473728
申请日：2002-06-18
申请人： Hubert Baumgart , Sandra Hasse , Uwe Meisenburg , Vincent Cook
发明人： Hubert Baumgart , Sandra Hasse , Uwe Meisenburg , Vincent Cook
IPC分类号： C08K5/205 , C08K5/21 , C08J3/28
CPC分类号： C09D201/025 , C08G18/6229 , C08G71/04 , C09D175/04 , C08L2666/16
摘要： Mixtures curable thermally and with actinic radiation and containing carbamate and/or allophanate groups, comprising (A) at least one of (A1) low molecular mass compounds, oligomers and polymers containing allophanate groups, carbamate groups, and carbamate and allophanate groups, and (A2) low molecular mass compounds, oligomers and polymers containing allophanate groups, carbamate groups, and carbamate and allophanate groups, and additionally allophanate- and/or carbamate-reactive functional groups, which are substantially or entirely free from reactive functional groups which contain at least one bond which can be activated with actinic radiation, and (C) at least one constituent containing on average per molecule at least one reactive functional group having at least one bond which can be activated with actinic radiation; with the proviso that if only (A1) is used, the mixtures further comprise (B) at least one of low molecular mass compounds, oligomers and polymers containing allophanate- and/or carbamate-reactive functional groups.
摘要翻译：包含（A）至少一种（A1）低分子量化合物，低聚物和包含脲基甲酸酯基团的聚合物，氨基甲酸酯基和氨基甲酸酯和脲基甲酸酯基团中的至少一种，和（A）含有氨基甲酸酯和/或脲基甲酸酯基团的混合物， A2）低分子量化合物，含有脲基甲酸酯基团的低聚物和聚合物，氨基甲酸酯基团和氨基甲酸酯和脲基甲酸酯基团，以及基本上或完全不含至少含有反应性官能团的脲基甲酸酯和/或氨基甲酸酯反应性官能团，可以用光化辐射活化的一个键，和（C）每分子平均含有至少一个具有至少一个可以用光化辐射活化的键的反应性官能团的至少一种组分; 条件是如果仅使用（A1），混合物还包含（B）低分子量化合物，低聚物和含有脲基甲酸酯和/或氨基甲酸酯反应性官能团的聚合物中的至少一种。

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