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1. 发明授权

US4539009A Dyestuff mixture 失效
标题翻译：染料混合物
公开(公告)号：US4539009A
公开(公告)日：1985-09-03
申请号：US667525
申请日：1984-11-02
申请人： Horst Nickel , Hans-Gunter Otten
发明人： Horst Nickel , Hans-Gunter Otten
IPC分类号： C09B31/062 , C09B67/22 , D06P1/06
CPC分类号： C09B31/062 , C09B67/0055 , Y10S534/01 , Y10S8/917 , Y10S8/924
摘要： Mixtures of dyestuffs of the formula I ##STR1## and of the formula II ##STR2## wherein R=alkyl,R.sub.1 =H or R andR.sub.2 /R.sub.3 =R.sub.1 or alkoxy,are distinguished by being readily soluble in hard water and produce satisfactory golden yellow dyeings on polyamide fibres.
摘要翻译：其中R =烷基，R 1 = H或R和R 2 / R 3 = R 1或烷氧基的式I化合物（I）和式II的化合物（II）的染料的混合物的特征在于容易溶于硬水，并在聚酰胺纤维上产生令人满意的金黄色染色。

2. 发明授权

US4478681A Forgery-proof paper 失效
标题翻译：防伪纸
公开(公告)号：US4478681A
公开(公告)日：1984-10-23
申请号：US400834
申请日：1982-07-22
申请人： Friedhelm Muller , Horst Nickel
发明人： Friedhelm Muller , Horst Nickel
IPC分类号： D21H19/10 , B44F1/12 , D21H21/28 , D21H21/40 , D21H21/46 , D21H5/10
CPC分类号： D21H21/46 , Y10S428/916
摘要： Forgery-proof paper, which exhibits a distinct coloration when treated with an oxidizing agent and, if appropriate, a reducing agent, contains, as the reagent, a compound of the formula ##STR1## wherein A represents N or C,B represents NR, O or S,R represents hydrogen or alkyl,X and Y represent hydrogen or customary substituents andn and m represent the numbers 1 or 2.
摘要翻译：当用氧化剂和如果合适的话还原剂时，显示出明显的着色的防伪纸含有作为试剂的式Ⅰ化合物，其中A代表N或C，B代表NR ，O或S，R表示氢或烷基，X和Y表示氢或常规取代基，n和m表示数字1或2。

3. 发明授权

US3966703A Asymmetrical frisazo dyestuffs derived from diazotized 2,7-diamino-carbazole 失效
标题翻译：衍生自重氮化的2,7-二氨基咔唑的不对称弗里索沙染料
公开(公告)号：US3966703A
公开(公告)日：1976-06-29
申请号：US381167
申请日：1973-07-20
申请人： Wolf-Eckhard Bleck , Horst Nickel , Karl-Heinz Schundehutte
发明人： Wolf-Eckhard Bleck , Horst Nickel , Karl-Heinz Schundehutte
IPC分类号： C09B35/00 , C09B35/34 , C09B35/376 , C09B35/46 , C09B45/24
CPC分类号： C09B45/24 , C09B35/00 , C09B35/34 , C09B35/376 , C09B35/469
摘要： Azo dyestuffs of the formula ##SPC1##Wherein A and B are different radicals of an aromatic coupling component are described. The new dyestuffs are outstandingly suitable for dyeing and printing natural or synthetic fibre materials containing hydroxyl groups and nitrogen like wool, wool-cotton union, silk, high molecular polyamide as well as paper pulp and paper materials and leather to give dyeings havings good fastness properties.
摘要翻译：描述了式A和B的芳族偶联组分的不同基团的偶氮染料。新型染料非常适用于染色和印刷含有羟基和氮的天然或合成纤维材料，如羊毛，羊毛棉纱，丝绸，高分子聚酰胺以及纸浆和纸材料和皮革，以提供具有良好牢度的染色。

4. 发明授权

US4521217A Phthalocyanine and azo dyestuff mixtures and their use for dyeing paper 失效
标题翻译：酞菁和偶氮染料混合物及其用于染色纸的用途
公开(公告)号：US4521217A
公开(公告)日：1985-06-04
申请号：US568854
申请日：1984-01-06
申请人： Ulrich Beck , Frank-Michael Stohr , Horst Nickel
发明人： Ulrich Beck , Frank-Michael Stohr , Horst Nickel
IPC分类号： C09B29/01 , C09B29/30 , C09B31/08 , C09B35/28 , C09B43/16 , C09B47/24 , C09B47/32 , C09B67/22 , D21H21/28 , C09B47/04 , D21H1/46
CPC分类号： C09B29/0011 , C09B29/0007 , C09B29/30 , C09B31/08 , C09B35/28 , C09B43/16 , C09B47/24 , C09B47/32 , C09B67/0041 , D21H21/28 , Y10S534/01 , Y10S8/919
摘要： Mixtures of a phthalocyanine dyestuff and a substantive azo dyestuff which preferably has cationic or basic groups are suitable for dyeing paper.
摘要翻译：优选具有阳离子或碱性基团的酞菁染料和实质偶氮染料的混合物适用于染色纸。

5. 发明授权

US4337195A Azo dyestuffs 失效
标题翻译：偶氮染料
公开(公告)号：US4337195A
公开(公告)日：1982-06-29
申请号：US86189
申请日：1979-10-17
申请人： Hans-Joachim Vater , Horst Nickel , Hermann Henk
发明人： Hans-Joachim Vater , Horst Nickel , Hermann Henk
IPC分类号： C09B43/16 , C09B45/28 , C09B45/48 , C09B45/00
CPC分类号： C09B45/28 , C09B43/16 , C09B45/485
摘要： Azo dyestuffs of the formula ##STR1## wherein A, R.sub.1, m and n have the meaning given in the description. The dyestuffs are suitable for dyeing cellulose-containing materials, especially cotton, which may be natural or regenerated, as well as union fabrics containing cotton, and paper. The dyestuffs in general give red to violet, as well as reddish brown, color shades.The dyestuffs are distinguished by good light-fastness, substantivity and wet-fastness. Their great suitability for high temperature dyeing processes and for subsequent creaseproof finishing deserves particular mention.
摘要翻译：其中A，R1，m和n具有在说明书中给出的含义的式“IMAGE”的偶氮染料。该染料适用于染色含纤维素的材料，特别是可能是天然或再生的棉，以及含有棉花和纸的联合织物。染料一般给红色到紫色，以及红棕色的色调。染料具有良好的耐光性，亲和性和耐湿性。它们对于高温染色工艺的极大适应性和随后的抗皱整理值得特别提及。

6. 发明授权

US4077767A Process for the preparation of concentrated solutions of urea compounds 失效
标题翻译：制备尿素化合物浓缩液的方法
公开(公告)号：US4077767A
公开(公告)日：1978-03-07
申请号：US621799
申请日：1975-10-14
申请人： Wolf-Eckhard Bleck , Horst Nickel , Erich Kramer
发明人： Wolf-Eckhard Bleck , Horst Nickel , Erich Kramer
IPC分类号： C09B67/24 , C09B43/14 , C09B67/26 , C09B69/04 , C09B67/00 , D06P1/645
CPC分类号： C09B67/0073 , C09B43/14 , C09B69/04 , Y10S8/937 , Y10S8/938
摘要： The invention relates to the preparation of storage-stable, concentrated solutions of urea compounds of the formulaF.sub.1 --HN--CO--NH--F.sub.2wherein F.sub.1 and F.sub.2 denote radicals of dyestuffs or dyestuff intermediates containing acid groups by reacting 2 equivalents of amines of the formulaF.sub.1,2 --NH.sub.2with one equivalent of a compound of the formulaCl--CO--Xwherein X is chlorine or an aryloxy radical in the presence of alkaline earth metal ions in the pH range of 4.0 to 8.0, separating off the sparingly soluble alkaline earth metal salt of the resulting urea compounds, adding -- for example -- a salt of lithium of which the anion forms a salt, which is sparingly soluble in the reaction medium, with the alkaline earth metal cation of the urea compound to the suspension of these urea compounds and separating off the alkaline earth metal salt which has precipitated.
摘要翻译：本发明涉及式F1-HN-CO-NH-F2的脲化合物的储存稳定浓缩溶液的制备，其中F1和F2表示含有酸基团的染料或染料中间体的基团，通过使2当量的式F1-2-NH2与1当量的式Cl-CO-X化合物（其中X是氯或芳氧基）在碱土金属离子存在下，pH范围为4.0-8.0，分离出微溶于所得的脲化合物的碱土金属盐，例如 - 将该盐形成盐的锂盐，该盐的盐可以微溶于反应介质中，与尿素化合物的碱土金属阳离子相连，这些脲化合物并分离析出的碱土金属盐。

7. 发明授权

US4540776A Reactive fluorotriazinylaminonaphthotriazolyphenylazopyridone or pyrimidone dyestuffs 失效
标题翻译：反应性氟代三嗪基氨基萘并三唑基苯基偶氮吡啶酮或嘧啶酮染料
公开(公告)号：US4540776A
公开(公告)日：1985-09-10
申请号：US608587
申请日：1984-05-09
申请人： Hermann Henk , Erich Kramer , Karl H. Schundehutte , Horst Nickel
发明人： Hermann Henk , Erich Kramer , Karl H. Schundehutte , Horst Nickel
IPC分类号： C09B62/085 , C09B62/08 , C09B62/095 , D06P1/382
CPC分类号： C09B62/085
摘要： A metal free azo dyestuff of the formula ##STR1## in which K is the radical of a coupling component of pyridone, andR.sub.3 and R.sub.4 each independently is hydrogen; C.sub.1 -C.sub.6 -alkyl; C.sub.1 -C.sub.6 -alkyl substituted by OH, SO.sub.3 H, COOH or OSO.sub.3 H; phenyl; naphthyl; or phenyl or naphthyl substituted by SO.sub.3 H or COOH.
摘要翻译：一种不含金属的偶氮染料，其中K是吡啶酮的偶联组分，R3和R4各自独立地为氢; C 1 -C 6 - 烷基; 被OH，SO 3 H，COOH或OSO 3 H取代的C 1 -C 6烷基; 苯基; 萘基; 或被SO 3 H或COOH取代的苯基或萘基。

8. 发明授权

US4354968A Azo reactive dyestuffs having an aryl-triazinyl-aryl diazo component 失效
标题翻译：具有芳基 - 三嗪基 - 芳基重氮组分的偶氮活性染料
公开(公告)号：US4354968A
公开(公告)日：1982-10-19
申请号：US23750
申请日：1979-03-26
申请人： Erich Kramer , Horst Nickel , Karl-Heinz Schundehutte
发明人： Erich Kramer , Horst Nickel , Karl-Heinz Schundehutte
IPC分类号： C09B62/006 , C09B62/008 , C09B45/00 , C09B29/22 , C09B45/24
CPC分类号： C09B62/008 , C09B62/006
摘要： Optionally metallized azo dyestuffs which in the form of the free acid correspond to the formula ##STR1## wherein K is the radical of a benzene, naphthalene, pyrazolone, pyridone, pyrimidone, acetoacetic acid arylide or aminopyrazole coupling component;A is a non-ionic substituent;X is ##STR2## wherein W is a direct bond or a bridge member to a C atom of the benzene or naphthalene nucleus or the coupling component K;R is hydrogen or C.sub.1 -C.sub.4 -alkyl;B is a direct bond or a bridge member, especially -CO- or -SO.sub.2 -, to a C atom of Q;Q is a reactive radical;m is 0, 1 or 2;n is 0, 1 or 2;p is 0 or 1;q is 0, 1 or 2; andr is 0 or 1;and their use for the dyeing and printing of natural and regenerated cellulose fibre materials such as cotton and rayon, as well as natural and synthetic polyamide fibre materials, for example those of wool, silk, poly-.epsilon.-caprolactam or polycondensate of hexamethylene-diamine and adipic acid. The dyeings obtained, espeically those on cotton and rayon, are distinguished by good fastness properties, especially fastness to wet processing and to light.
摘要翻译：任选的以游离酸形式的金属化偶氮染料对应于下式：其中K是苯，萘，吡唑啉酮，吡啶酮，嘧啶酮，乙酰乙酸芳基化物或氨基吡唑偶联组分的基团; A是非离子取代基; X是其中W是苯或萘核的C原子或偶联组分K的直接键或桥键元素; R是氢或C 1 -C 4 - 烷基; B是Q的C原子的直接键或桥结构，特别是-CO-或-SO 2 - ; Q是反应性基团; m为0,1或2; n为0,1或2; p为0或1; q是0,1或2; r为0或1; 以及它们用于天然和再生纤维素纤维材料如棉和人造丝的染色和印花，以及天然和合成的聚酰胺纤维材料，例如羊毛，丝绸，聚ε-己内酰胺或六亚甲基二胺的缩聚物和己二酸。获得的染色，特别是在棉和人造丝上的染色，具有良好的牢度特性，特别是湿法加工和光照牢度的区别。

9. 发明授权

US4297278A Pentakis-and heptakis-azoxy dyestuffs 失效
标题翻译：五羟甲基和七烷基偶氮染料
公开(公告)号：US4297278A
公开(公告)日：1981-10-27
申请号：US128201
申请日：1980-03-07
申请人： Horst Nickel
发明人： Horst Nickel
IPC分类号： C09B35/52 , C09B29/30 , C09B33/10 , C09B35/215 , C09B35/35 , C09B35/64 , C09B43/10 , C09B57/00 , C07C105/00 , D06P3/24 , D06P3/32
CPC分类号： C09B35/64 , C09B29/30 , C09B33/10 , C09B35/215 , C09B35/35 , C09B43/10
摘要： Polyazo dyestuffs of the formula ##STR1## wherein D denotes the radical of a diazo component andn denotes the number 1 or 2,and their use for dyeing and printing fibre materials containing amino groups or hydroxyl groups, and leather. The resulting dyeings have good properties under wet conditions and when in use.
摘要翻译：式（I）的多偶唑染料其中D表示重氮组分的基团，n表示数字1或2，以及它们用于染色和印刷含有氨基或羟基的纤维材料和皮革的用途。所得染色在湿条件下和使用时具有良好的性能。

10. 发明授权

US4248771A Metal complex reactive dyestuffs 失效
标题翻译：金属络合活性染料
公开(公告)号：US4248771A
公开(公告)日：1981-02-03
申请号：US957074
申请日：1978-11-02
申请人： Walter Scholl , Horst Nickel
发明人： Walter Scholl , Horst Nickel
IPC分类号： C09B62/24 , C09B62/032 , D06P3/66 , C09B45/00
CPC分类号： C09B62/032
摘要： 1:1 and 1:2 metal complex reactive dyestuffs based on at least one metallizable dyestuff of the formula ##STR1## wherein D=the radical of a metallizable diazo component with an OH group or COOH group in the o-position relative to the azo bridge,K=the radical of a coupling component which couples in the o-position relative to a phenolic or enolic OH group,W= ##STR2## R, R.sub.1 and R.sub.2 =H or a substituent Y=a group which can be split off, in particular halogen andZ=a divalent organic radical,and whereinthe group ##STR3## is bonded, directly or via a bridge member, to an aromatic ring C atom of D or K,and their use for dyeing and printing materials containing hydroxyl groups and N-containing materials, such as cotton, wool and the like.
摘要翻译： 1：1和1：2金属络合物活性染料，其基于至少一种下式的可金属化染料：其中D =相对于偶氮位置的位置上具有OH基团或COOH基团的金属化重氮组分的基团桥，K =在o位置相对于酚或烯醇OH基团偶联的偶合组分的基团，W =（R），（II）R，R 1和R 2 = H或取代基Y =可以分离，特别是卤素，Z =二价有机基团，其中基团“直接”或通过桥接元件键合到D或K的芳香环C原子上，以及它们用于染色和印刷的用途含有羟基和含N材料的材料，如棉，羊毛等。

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