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1. 发明授权

US4683334A Modified 8-ring zeolites as catalysts for conversion of methanol and ammonia to dimethylamine 失效
标题翻译：改性的8-环沸石作为甲醇和氨转化为二甲胺的催化剂
公开(公告)号：US4683334A
公开(公告)日：1987-07-28
申请号：US729161
申请日：1985-04-30
申请人： Horacio E. Bergna , David R. Corbin , George Sonnichsen
发明人： Horacio E. Bergna , David R. Corbin , George Sonnichsen
IPC分类号： C01B39/06 , B01J29/50 , B01J29/70 , C01B39/30 , C07B61/00 , C07C67/00 , C07C209/00 , C07C209/16 , C07C211/04 , C07C85/02 , C07C85/06
CPC分类号： B01J29/7015 , B01J29/50 , B01J29/70 , B01J2229/36
摘要： A process for producing dimethylamine is provided, comprising reacting methanol and/or dimethylether and ammonia, in amounts sufficient to provide a carbon/nitrogen (C/N) ratio from about 0.2 to about 1.5, and at a temperature from about 250.degree. C. to about 450.degree. C., in the presence of a catalytic amount of a modified acidic zeolite selected from the group consisting of chabazite, erionite, ZK-5, and rho, the zeolite having been modified by treatment with one or more compounds containing at least one element selected from the group consisting of silicon, aluminum, phosphorus, and boron, to deposit thereon at least 0.05 weight percent of the element.
摘要翻译：提供了一种生产二甲胺的方法，包括使甲醇和/或二甲醚与氨反应，其量足以提供约0.2至约1.5的碳/氮（C / N）比和约250℃的温度。至约450℃，在催化量的选自菱沸石，毛沸石，ZK-5和rho的改性酸性沸石存在下，该沸石已被一种或多种含有选自由硅，铝，磷和硼组成的组中的至少一种元素，以沉积至少0.05重量％的元素。

2. 发明授权

US4752596A Modified 8-ring zeolites as catalysts 失效
标题翻译：改性的8-环沸石作为催化剂
公开(公告)号：US4752596A
公开(公告)日：1988-06-21
申请号：US32375
申请日：1987-03-31
申请人： Horacio E. Bergna , David R. Corbin , George C. Sonnichsen
发明人： Horacio E. Bergna , David R. Corbin , George C. Sonnichsen
IPC分类号： B01J29/50 , B01J29/70 , B01J29/06
CPC分类号： B01J29/7015 , B01J29/50 , B01J29/70 , B01J2229/36
摘要： A process for producing dimethylamine is provided, comprising reacting methanol and/or dimethylether and ammonia, in amounts sufficient to provide a carbon/nitrogen (C/N) ratio from about 0.2 to about 1.5, and at a temperature from about 250.degree. C. to about 450.degree. C., in the presence of a catalytic amount of a modified acidic zeolite selected from the group consisting of chabazite, erionite, ZK-5, and rho, the zeolite having been modified by treatment with one or more compounds containing at least one element selected from the group consisting of silicon, aluminum, phosphorus, and boron, to deposit thereon at least 0.05 weight percent of the element.
摘要翻译：提供了一种生产二甲胺的方法，包括使甲醇和/或二甲醚与氨反应，其量足以提供约0.2至约1.5的碳/氮（C / N）比和约250℃的温度。至约450℃，在催化量的选自菱沸石，毛沸石，ZK-5和rho的改性酸性沸石存在下，该沸石已被一种或多种含有选自由硅，铝，磷和硼组成的组中的至少一种元素，以沉积至少0.05重量％的元素。

3. 发明授权

US5569785A Attrition resistant zeolite catalysts for production of methylamines in fluidized bed reactors 失效
公开(公告)号：US5569785A
公开(公告)日：1996-10-29
申请号：US454470
申请日：1995-05-30
申请人： Konstantinos Kourtakis , Horacio E. Bergna , George C. Sonnichsen , David R. Corbin , Loren D. Brake
发明人： Konstantinos Kourtakis , Horacio E. Bergna , George C. Sonnichsen , David R. Corbin , Loren D. Brake
IPC分类号： B01J29/06 , B01J29/70 , B01J37/00 , C07B61/00 , C07C209/16 , C07C211/04
CPC分类号： B01J29/7015 , B01J29/70 , B01J37/0009 , B01J37/0045 , C07C209/16 , B01J21/04 , B01J21/063 , B01J2229/26 , B01J2229/42
摘要： This invention provides an attrition resistant catalyst composition and method for producing such composition. The catalyst is comprised of an acidic zeolite, rho or chabazite, and a particulate binder, kaolin, bentonite, alpha-alumina, or titania, which can be optionally modified by treatment with a compound containing Si, Al, P or B.This invention further provides a process for producing methylamines, preferably dimethylamine, comprising reacting methanol and/or dimethyl ether and ammonia in the presence of a catalytic amount of an attrition resistant catalyst of the invention.

4. 发明授权

US4257874A Petroleum refinery processes using catalyst of aluminosilicate sols and powders 失效
标题翻译：使用硅铝酸盐溶胶和粉末的催化剂的石油炼厂工艺
公开(公告)号：US4257874A
公开(公告)日：1981-03-24
申请号：US84404
申请日：1979-10-12
申请人： Horacio E. Bergna
发明人： Horacio E. Bergna
IPC分类号： B01J35/10 , B01J37/02 , C10G11/05 , B01J29/28
CPC分类号： C10G11/05 , B01J35/10 , B01J37/024 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1061 , B01J35/1085
摘要： An amorphous aluminosilicate sol with uniform size particles and a porous amorphous aluminosilicate powder are useful as catalyst in petroleum cracking. Water is removed from the sol without gelling so that the particles become uniformly packed into aggregates having pores of substantially uniform size and coating said powder with a surface layer 0 to 15% by weight of a metal or metal oxide, said powder having a specific surface area of 30 to 750 m.sup.2 /g, a bulk density of 0.5 g/cc or more and substantially uniform size pore diameters of from 20 A to 250 A, with pore diameters of 20 A to 45 A having a uniformity such that at least 90% of the pore volume is made up of pores of from 0.6D to 1.4D and pore diameters of 45 A to 250 A having a uniformity such that at least 80% of the pore volume is made up of pores of from 0.6D to 1.4D, where D is the median pore diameter.
摘要翻译：具有均匀粒度的无定形硅铝酸盐溶胶和多孔无定形硅铝酸盐粉末可用作石油开裂中的催化剂。从溶胶中除去水分而不凝胶化，使得颗粒均匀地填充到具有基本均匀尺寸的孔的聚集体中，并用0至15重量％的金属或金属氧化物的表面层涂覆所述粉末，所述粉末具有比表面积 30至750m 2 / g的面积，体积密度为0.5g / cc或更大，孔径大致均匀的尺寸为20A至250A，孔径为20A至45A，均匀度为至少90 孔体积的％由0.6D至1.4D的孔隙和45A至250A的孔径组成，具有使孔至少80％的孔体积为0.6D至1.4的孔的均匀性 D，其中D是中值孔径。

5. 发明授权

US4849539A Method of making acrylonitrile 失效
标题翻译：制备丙烯腈的方法
公开(公告)号：US4849539A
公开(公告)日：1989-07-18
申请号：US179557
申请日：1988-04-08
申请人： Horacio E. Bergna
发明人： Horacio E. Bergna
IPC分类号： B01J27/198 , B01J33/00 , B01J37/00 , B01J37/08 , C07B61/00 , C07C67/00 , C07C253/00 , C07C255/08 , C07D307/60 , G11B15/26
CPC分类号： B01J23/002 , B01J27/198 , B01J37/0045 , B01J37/08 , B01J2523/00
摘要： This invention relates to highly attrition resistant catalysts, catalyst precursors and catalyst supports and to processes for making and using them.
摘要翻译：本发明涉及高耐磨性催化剂，催化剂前体和催化剂载体以及制备和使用它们的方法。

6. 发明授权

US4316744A High ratio silicate foundry sand binders 失效
标题翻译：高比例硅酸盐铸造砂粘合剂
公开(公告)号：US4316744A
公开(公告)日：1982-02-23
申请号：US197747
申请日：1980-10-16
申请人： Horacio E. Bergna
发明人： Horacio E. Bergna
IPC分类号： B22C1/02 , B22C1/16 , B22C1/18 , B28B7/34
CPC分类号： C04B35/6316 , B22C1/02 , B22C1/167 , B22C1/188 , B82Y30/00 , C04B33/1305 , C04B33/131 , C04B33/1315 , C04B33/14 , C04B33/16 , C04B35/632 , C04B35/63416 , C04B35/63496 , C04B35/636 , C04B2235/3203 , C04B2235/3418 , C04B2235/3427 , C04B2235/349 , C04B2235/5445 , C04B2235/5454 , C04B2235/9676
摘要： Binder solution for preparing sand cores of initial high strength but with essentially no strength after casting metals above 700.degree. C., said binder solution comprising an aqueous solution of sodium, potassium or lithium silicate having an overall molar ratio of SiO.sub.2 /alkali metal oxide from 3.5:1 to 10:1, and containing sufficient amorphous silica so that the fraction of the total silica in the binder solution which is present as amorphous silica is from 2 to 75%, the amorphous silica having a particle size in the range from about 2 nanometers to 500 nanometers.
摘要翻译：用于制备初始高强度的砂芯的粘结剂溶液，但是在铸造金属高于700℃时基本上没有强度，所述粘合剂溶液包含钠，钾或硅酸锂的水溶液，其具有SiO 2 /碱金属氧化物的总摩尔比 3.5:1至10:1，并且含有足够的无定形二氧化硅，使作为无定形二氧化硅存在的粘合剂溶液中的总二氧化硅的分数为2〜75％，无定形二氧化硅的粒径为约 2纳米至500纳米。

7. 发明授权

US4769477A Method of making maleic anhydride 失效
标题翻译：制备马来酸酐的方法
公开(公告)号：US4769477A
公开(公告)日：1988-09-06
申请号：US34247
申请日：1987-04-06
申请人： Horacio E. Bergna
发明人： Horacio E. Bergna
IPC分类号： B01J27/198 , B01J33/00 , B01J37/00 , B01J37/08 , C07B61/00 , C07C67/00 , C07C253/00 , C07C255/08 , C07D307/60 , G11B15/26
CPC分类号： B01J23/002 , B01J27/198 , B01J37/0045 , B01J37/08 , B01J2523/00
摘要： This invention relates to highly attrition resistant catalysts, catalyst precursors and catalyst supports and to processes for making and using them.
摘要翻译：本发明涉及高耐磨性催化剂，催化剂前体和催化剂载体以及制备和使用它们的方法。

8. 发明授权

US4677084A Attrition resistant catalysts, catalyst precursors and catalyst supports and process for preparing same 失效
标题翻译：耐磨性催化剂，催化剂前体和催化剂载体及其制备方法
公开(公告)号：US4677084A
公开(公告)日：1987-06-30
申请号：US802304
申请日：1985-11-27
申请人： Horacio E. Bergna
发明人： Horacio E. Bergna
IPC分类号： B01J27/198 , B01J33/00 , B01J37/00 , B01J37/08 , C07B61/00 , C07C67/00 , C07C253/00 , C07C255/08 , C07D307/60 , G11B15/26 , B01J35/08
CPC分类号： B01J23/002 , B01J27/198 , B01J37/0045 , B01J37/08 , B01J2523/00
摘要： This invention relates to highly attrition resistant catalysts, catalyst precursors and catalyst supports and to processes for making and using them.
摘要翻译：本发明涉及高耐磨性催化剂，催化剂前体和催化剂载体以及制备和使用它们的方法。

9. 发明授权

US5011804A Ceramic dielectric compositions and method for improving sinterability 失效
标题翻译：陶瓷电介质组合物和改善烧结性的方法
公开(公告)号：US5011804A
公开(公告)日：1991-04-30
申请号：US506964
申请日：1990-02-28
申请人： Horacio E. Bergna , Ian Burn
发明人： Horacio E. Bergna , Ian Burn
IPC分类号： C04B35/628 , C04B35/00 , C04B35/46 , C04B35/468 , C04B35/472 , H01B3/00 , H01G4/12
CPC分类号： C04B35/4682 , C04B35/472 , H01G4/129
摘要： An improved ceramic dielectric composition for preparing multilayer ceramic structures for electronic devices and a method of enhancing the sinterability of such compositions at low firing temperatures by improving the distribution of zinc borate based sintering flux uniformly throughout the composition.
摘要翻译：一种用于制备用于电子器件的多层陶瓷结构的改进的陶瓷电介质组合物，以及通过在整个组合物中均匀地改善硼酸锌基烧结助熔剂的分布，以及在低焙烧温度下提高这些组合物的可烧结性的方法。

10. 发明授权

US4477492A Process for preparing superficially porous supports for chromatography and catalysts 失效
标题翻译：制备色谱和催化剂的表面多孔载体的方法
公开(公告)号：US4477492A
公开(公告)日：1984-10-16
申请号：US487894
申请日：1983-04-22
申请人： Horacio E. Bergna , Joseph J. Kirkland
发明人： Horacio E. Bergna , Joseph J. Kirkland
IPC分类号： B01J20/281 , B01J13/02 , B01J13/04 , B01J20/02 , B01J20/32 , B01J35/02 , B01J37/02 , G01N30/88 , B05D7/00 , C02F1/68
CPC分类号： B01J20/282 , B01J20/286 , B01J20/3289 , B01J20/3295 , B01J35/026 , B01J37/0221 , Y10T428/2991 , Y10T428/2996
摘要： There is disclosed a process for preparing superficially porous macroparticles comprising spray drying a specified well-mixed slurry of core macroparticles, colloidal inorganic microparticles and a liquid and sintering the resulting product to cause a 5%-30% decrease in surface area.
摘要翻译：公开了一种表面多孔大颗粒的制备方法，其包括将核心颗粒，胶体无机微粒和液体的特定的良好混合的浆料喷雾干燥，并烧结所得到的产物，使表面积减少5％-30％。

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