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1. 发明授权

US07939199B1 Method of controlling voltage delay and RDC growth in an electrochemical cell using low basis weight cathode material 失效
标题翻译：使用低基重阴极材料控制电化学电池中的电压延迟和RDC生长的方法
公开(公告)号：US07939199B1
公开(公告)日：2011-05-10
申请号：US11736039
申请日：2007-04-17
申请人： Hong Gan , Joseph M. Lehnes , Esther S. Takeuchi
发明人： Hong Gan , Joseph M. Lehnes , Esther S. Takeuchi
IPC分类号： H01M10/32
CPC分类号： H01M4/131 , H01M4/366 , H01M4/38 , H01M4/382 , H01M4/485 , H01M4/505 , H01M4/5815 , H01M4/583 , H01M4/623 , H01M6/16 , H01M10/052 , H01M2004/021 , H01M2300/0037
摘要： An electrochemical cell comprising a lithium anode, a silver vanadium oxide cathode having a relatively lower basis weight, and an electrolyte activating the anode and the cathode is described. By limiting the amount of cathode active material per unit area (i.e. basis weight) facing the anode in the Li/SVO cell, the magnitude of the passivating film growth at the solid-electrolyte interphase (SEI) and its relative impermeability to lithium ion diffusion is reduced. Therefore, by using a cathode of a relatively low basis weight active material, it is possible to eliminate or significantly reduce undesirable irreversible Rdc growth and voltage delay in the cell and to extend its useful life in an implantable medical device.
摘要翻译：描述了包含锂阳极，具有相对较低基重的银钒氧化物阴极和激活阳极和阴极的电解质的电化学电池。通过限制在Li / SVO电池中面向阳极的每单位面积（即单位面积重量）的阴极活性材料的量，固体 - 电解质间相（SEI）的钝化膜生长的大小及其对锂离子扩散的相对不渗透性降低了。因此，通过使用相对低的基重量的活性材料的阴极，可以消除或显着减少电池中不期望的不可逆的Rdc生长和电压延迟并延长其在可植入医疗装置中的使用寿命。

2. 发明申请

US20120308861A1 METHOD OF MAKING ELECTRODES WITH DISTRIBUTED MATERIAL LOADING USED IN ELECTROCHEMICAL CELLS 审中-公开
标题翻译：在电化学电池中使用分布式材料加载电极的方法
公开(公告)号：US20120308861A1
公开(公告)日：2012-12-06
申请号：US12169038
申请日：2008-07-08
申请人： WEIBING XING , Hong Gan , Esther S. Takeuchi
发明人： WEIBING XING , Hong Gan , Esther S. Takeuchi
IPC分类号： H01M4/04 , H01M4/02
CPC分类号： H01M4/1391 , H01M4/131 , H01M4/133 , H01M4/1393 , H01M4/661 , H01M10/0431 , Y10T29/49115
摘要： A method of making electrodes with distributed material loadings used in rechargeable electrochemical cells and batteries is described. This method controls electrode material loading (mass per unit area) along the electrode's length while maintaining uniform compaction throughout the electrode. Such prepared electrode maintain sufficient mechanical flexibility for winding and are compact and robust to have high energy density and long cycle life in rechargeable cells and batteries.
摘要翻译：描述了在可充电电化学电池和电池中使用分散材料负载的电极的制造方法。该方法控制沿着电极长度的电极材料负载（每单位面积的质量），同时保持整个电极的均匀压实。这种制备的电极保持足够的机械灵活性用于卷绕，并且紧凑且牢固，以在可再充电电池和电池中具有高能量密度和长循环寿命。

3. 发明申请

US20120133341A1 Control of Silver Vanadium Oxide Surface Areas as a Means of Controlling Voltage Delay and RDC Growth in an Electrochemical Cell 审中-公开
标题翻译：控制银钒氧化物表面区域作为控制电化学电池中电压延迟和RDC生长的手段
公开(公告)号：US20120133341A1
公开(公告)日：2012-05-31
申请号：US13368387
申请日：2012-02-08
申请人： Hong Gan , Joseph Lehnes , Robert S. Rubino , Esther S. Takeuchi
发明人： Hong Gan , Joseph Lehnes , Robert S. Rubino , Esther S. Takeuchi
IPC分类号： H02J7/00 , H01B13/00
CPC分类号： H01M4/54 , H01M4/06 , H01M4/382 , H01M4/5835 , H01M4/623 , H01M4/661 , H01M6/16 , H01M6/164 , H01M6/166 , H01M2300/0037 , Y10T29/49108
摘要： An electrochemical cell comprising a lithium anode, a cathode comprising a blank cut from a free-standing sheet of a silver vanadium oxide mixture contacted to a current collector. The active material has having a relatively lower surface area and an electrolyte activating the anode and the cathode is described. By optimizing the cathode active material surface area in a SVO-containing cell, the magnitude of the passivating film growth at the solid-electrolyte interphase (SEI) and its relative impermeability to lithium ion diffusion is reduced. Therefore, by using a cathode of an active material, in a range of from about 0.2 m2/gram to about 2.6 m2/gram, and preferably from about 1.6 m2/gram to about 2.4 m2/gram, it is possible to eliminate or significantly reduce undesirable irreversible Rdc growth and voltage delay in the cell and to extend its useful life in an implantable medical device.
摘要翻译：一种电化学电池，包括锂阳极，阴极，包括从与集电器接触的银钒氧化物混合物的独立片材切割的坯料。活性材料具有相对较低的表面积，并描述了活化阳极和阴极的电解质。通过优化含SVO的电池中的正极活性材料表面积，固体 - 电解质间相（SEI）上的钝化膜生长的大小以及其对锂离子扩散的相对不渗透性降低。因此，通过使用活性物质的阴极，在约0.2m 2 / g至约2.6m 2 / g，优选约1.6m 2 / g至约2.4m 2 / g的范围内，可以消除或显着地减少细胞中不希望的不可逆的Rdc生长和电压延迟，并延长其在可植入医疗装置中的使用寿命。

4. 发明授权

US06984468B2 Hermetically sealed coin cell 有权
标题翻译：密封纽扣电池
公开(公告)号：US06984468B2
公开(公告)日：2006-01-10
申请号：US10761037
申请日：2004-01-20
申请人： Robert S. Rubino , Hong Gan , Joseph Prinzbach , Esther S. Takeuchi
发明人： Robert S. Rubino , Hong Gan , Joseph Prinzbach , Esther S. Takeuchi
IPC分类号： H01M2/08
CPC分类号： H01M2/023 , H01M2/0426 , H01M2/065 , H01M2/08 , Y10T29/4911 , Y10T29/49114
摘要： A hermetically sealed coin cell is described. The coin cell has the opposite polarity terminals isolated from one another by a glass-to-metal seal. Glassing a conductive disc inside a ring of greater diameter and height forms this seal. The height of the ring is equivalent to the desired height of the cell. The disc acts as one cell terminal, which can be positive or negative, and the ring serves as the other terminal. In plan view, both terminals are on the same side of the cell. This allows for easy mounting and connection to an electric circuit board, and the like.
摘要翻译：描述了密封的纽扣电池。纽扣电池具有相反的极性端子，通过玻璃对金属密封件相互隔离。在更大直径和高度的环内玻璃导电盘形成这种密封。环的高度等于电池的所需高度。盘作为一个单元端子，其可以是正的或负的，并且该环用作另一个端子。在平面图中，两个终端位于单元的同一侧。这允许容易地安装和连接到电路板等。

5. 发明授权

US06930468B2 Discharge methodologies for optimizing the performance of lithium/silver vanadium oxide cells 失效
标题翻译：用于优化锂/银氧化钒电池性能的放电方法
公开(公告)号：US06930468B2
公开(公告)日：2005-08-16
申请号：US10658731
申请日：2003-09-09
申请人： Kenneth Syracuse , Noelle Waite , Hong Gan , Esther S. Takeuchi
发明人： Kenneth Syracuse , Noelle Waite , Hong Gan , Esther S. Takeuchi
IPC分类号： H01M4/48 , H01M4/485 , H01M4/54 , H01M4/58 , H01M6/16 , H01M6/50 , H01M10/42 , H01M10/44 , H01M10/48 , H02J7/00
CPC分类号： H01M6/50 , H01M4/485 , H01M4/54 , H01M4/5825 , H01M6/16 , H01M6/5033 , H01M10/4264 , H01M10/44
摘要： It is known that reforming implantable defibrillator capacitors at least partially restores and preserves their charging efficiency. An industry-recognized standard is to reform implantable capacitors by pulse discharging the connected electrochemical cell about once every three months throughout the useful life of the medical device. A Li/SVO cell typically powers such devices. The present invention relates to methodologies for significantly minimizing, if not entirely eliminating, the occurrence of voltage delay and irreversible Rdc growth in the about 25% to 70% DOD region by subjecting Li/SVO cells to novel discharge regimes. At the same time, the connected capacitors in the cardiac defibrillator are reformed to maintain them at their rated breakdown voltages.
摘要翻译：众所周知，重组可植入除颤器电容器至少部分恢复并保持其充电效率。行业公认的标准是通过在医疗设备的整个使用寿命期间每三个月大约一次脉冲地排放连接的电化学电池来重建可植入电容器。 Li / SVO单元通常为这些设备供电。本发明涉及通过使Li / SVO细胞经受新颖的放电方式，在大约25％至70％的DOD区域中显着地最小化（如果不是完全消除）电压延迟和不可逆Rdc生长的方法。同时，将心脏除颤器中连接的电容器进行重整，以将其维持在额定击穿电压。

6. 发明授权

US06926991B2 SVO/CFx parallel cell design within the same casing 失效
标题翻译： SVO / CFx并联电池设计在同一套管内
公开(公告)号：US06926991B2
公开(公告)日：2005-08-09
申请号：US10328391
申请日：2002-12-23
申请人： Hong Gan , Esther S. Takeuchi
发明人： Hong Gan , Esther S. Takeuchi
IPC分类号： H01M4/66 , A61N1/378 , A61N1/39 , H01M4/02 , H01M4/04 , H01M4/06 , H01M4/08 , H01M4/24 , H01M4/34 , H01M4/36 , H01M4/38 , H01M4/40 , H01M4/50 , H01M4/505 , H01M4/52 , H01M4/525 , H01M4/54 , H01M4/58 , H01M4/583 , H01M6/16 , H01M6/50 , H01M10/052 , H01M10/24 , H01M10/26 , H01M10/36 , H01M10/44 , H01M4/48
CPC分类号： H01M10/052 , H01M4/02 , H01M4/04 , H01M4/0404 , H01M4/0428 , H01M4/043 , H01M4/0471 , H01M4/049 , H01M4/08 , H01M4/36 , H01M4/381 , H01M4/40 , H01M4/505 , H01M4/525 , H01M4/54 , H01M4/583 , H01M4/661 , H01M4/667 , H01M6/16 , H01M2006/5094
摘要： A new cathode design has a first cathode active material of a relatively low energy density but of a relatively high rate capability contacted to a first cathode current collector and a second cathode active material having a relatively high energy density but of a relatively low rate capability in contact with a second cathode current collector, is described. The first and second cathode current collectors are connected to a common terminal lead. The present cathode design is useful for powering an implantable medical device requiring a high rate discharge application.
摘要翻译：新的阴极设计具有第一阴极活性材料，其具有相对低的能量密度但是具有与第一阴极集电器相接触的相对较高的速率能力和具有相对较高能量密度但具有相对较低速率能力的第二阴极活性材料与第二阴极集电体接触。第一和第二阴极集电器连接到公共端子引线。本阴极设计对于需要高速率放电应用的可植入医疗器械的供电是有用的。

7. 发明授权

US06919141B2 Phosphate additives for nonaqueous electrolyte rechargeable electrochemical cells 有权
标题翻译：磷酸添加剂用于非水电解质可充电电化学电池
公开(公告)号：US06919141B2
公开(公告)日：2005-07-19
申请号：US10251137
申请日：2002-09-20
申请人： Hong Gan , Esther S. Takeuchi , Robert Rubino
发明人： Hong Gan , Esther S. Takeuchi , Robert Rubino
IPC分类号： H01M4/485 , H01M4/505 , H01M4/525 , H01M4/58 , H01M4/587 , H01M4/60 , H01M6/04 , H01M10/0525 , H01M10/0567 , H01M10/0568 , H01M10/0569
CPC分类号： H01M10/0525 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/581 , H01M4/587 , H01M4/623 , H01M4/625 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M2300/004 , H01M2300/0042
摘要： A lithium ion electrochemical cell having high charge/discharge capacity, long cycle life and exhibiting a reduced first cycle irreversible capacity, is described. The stated benefits are realized by the addition of at least one phosphate additive having the formula: (R1O)P(═O) (OR2) (OR3) and wherein R1, R2 and R3 are the same or different, wherein at least one, but not all three, of the R groups is hydrogen, or at least one of the R groups has at least 3 carbon atoms and contains an sp or sp2 hybridized carbon atom bonded to an sp3 hybridized carbon atom bonded to the oxygen atom bonded to the phosphorous atom.
摘要翻译：描述了具有高充电/放电容量，长循环寿命并且显示出降低的第一周期不可逆容量的锂离子电化学电池。所述优点通过加入至少一种具有下式的磷酸酯添加剂来实现：（R 1）O（O）（OR 2）（OR 2） > 3），并且其中R 1，R 2和R 3相同或不同，其中至少一个，但是不是所有三个R基团都是氢，或者至少一个R基团具有至少3个碳原子并且含有与sp 3连接的sp或sp2-2杂交的碳原子与键合到磷原子的氧原子键合的杂原子碳原子。

8. 发明授权

US06844115B2 Highly conductive and stable nonaqueous electrolyte for lithium electrochemical cells 有权
标题翻译：用于锂电化学电池的高导电和稳定的非水电解质
公开(公告)号：US06844115B2
公开(公告)日：2005-01-18
申请号：US10287395
申请日：2002-11-04
申请人： Hong Gan , Esther S. Takeuchi
发明人： Hong Gan , Esther S. Takeuchi
IPC分类号： A61N1/378 , A61N1/39 , H01M4/131 , H01M4/133 , H01M4/48 , H01M4/485 , H01M4/50 , H01M4/505 , H01M4/52 , H01M4/525 , H01M4/54 , H01M4/58 , H01M4/587 , H01M4/62 , H01M6/14 , H01M6/16 , H01M10/0525 , H01M10/0569 , H01M10/08 , H01M10/36
CPC分类号： H01M10/0569 , H01M4/131 , H01M4/133 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/54 , H01M4/5815 , H01M4/587 , H01M6/164 , H01M10/0525 , H01M2300/0042
摘要： The present invention is directed to at least partially replacing PC and/or DME with a linear carbonate, preferably dimethyl carbonate, and a linear mono-ether, the most preferred being diisopropyl ether, in electrolytes useful for activating alkali metal-containing cells. This electrolyte has improved conductivity and provides electrochemical cells with enhanced discharge performance. A most preferred electrolyte comprises 1,2-dimethoxyethane, propylene carbonate, dimethyl carbonate and diisopropyl ether.
摘要翻译：本发明涉及在用于活化含碱金属的电池的电解质中至少部分地用直链碳酸酯，优选碳酸二甲酯和直链单醚（最优选的是二异丙醚）来代替PC和/或DME。该电解质具有改善的导电性，并提供具有增强的放电性能的电化学电池。最优选的电解质包括1,2-二甲氧基乙烷，碳酸亚丙酯，碳酸二甲酯和二异丙醚。

9. 发明授权

US06746804B2 Nonaqueous organic electrolytes for low temperature discharge of rechargeable electrochemical cells 有权
标题翻译：用于可再充电电化学电池的低温放电的非水有机电解质
公开(公告)号：US06746804B2
公开(公告)日：2004-06-08
申请号：US10232166
申请日：2002-08-30
申请人： Hong Gan , Esther S. Takeuchi , Robert Rubino
发明人： Hong Gan , Esther S. Takeuchi , Robert Rubino
IPC分类号： H01M616
CPC分类号： H01M10/0525 , H01M4/525 , H01M4/587 , H01M10/0569 , Y10T29/49108
摘要： An alkali metal secondary electrochemical cell, and preferably a lithium ion cell, activated with an equilibrated quaternary solvent system, is described. The solvent system comprises a mixture of dialkyl carbonates and cyclic carbonates, and preferably a quaternary mixture of dimethyl carbonate, diethyl carbonate, ethylmethyl carbonate and ethylene carbonate with dimethyl carbonate, diethyl carbonate and ethylmethyl carbonate in an equilibrated molar mixture. Lithium ion cells activated with this electrolyte have good room temperature cycling characteristics and excellent low temperature discharge behavior.
摘要翻译：描述了用平衡的四元溶剂体系活化的碱金属二次电化学电池，优选锂离子电池。溶剂系统包括碳酸二烷基酯和环状碳酸酯的混合物，并且优选在平衡的摩尔混合物中碳酸二甲酯，碳酸二乙酯，碳酸甲乙酯和碳酸亚乙酯与碳酸二甲酯，碳酸二乙酯和碳酸甲乙酯的季混合物。用该电解液活化的锂离子电池具有良好的室温循环特性和优异的低温放电特性。

10. 发明授权

US06692865B2 Double current collector cathode design using mixtures of two active materials for alkali metal or ion electrochemical cells 有权
标题翻译：双集电极阴极设计使用两种活性材料的混合物用于碱金属或离子电化学电池
公开(公告)号：US06692865B2
公开(公告)日：2004-02-17
申请号：US10008823
申请日：2001-10-24
申请人： Hong Gan , Esther S. Takeuchi
发明人： Hong Gan , Esther S. Takeuchi
IPC分类号： H01M400
CPC分类号： H01M4/13 , A61N1/378 , H01M4/06 , H01M4/08 , H01M4/34 , H01M4/366 , H01M4/48 , H01M4/581 , H01M4/582 , H01M4/5825 , H01M4/5835 , H01M4/661 , H01M4/667 , H01M6/16 , H01M6/5055 , H01M2004/028 , H01M2300/0037
摘要： A new sandwich cathode design is provided having a first cathode structure of a first cathode active material of a relatively low energy density but of a relatively high rate capability, for example SVO, mixed with a second cathode active material having a relatively high energy density but a relatively low rate capability, for example CFx, with the percentage of SVO being less than that of CFx and sandwiched between two current collectors. Then, a second cathode mixture of SVO and CFx active materials is contacted to the outside of the current collectors. However, the percentage of SVO to CFx is greater in the second structure than in the first. Such an exemplary cathode design might look like: (100−y)% SVO+y% CFx, wherein 0≦y≦100/current collector/(100−x)% SVO+x% CFx, wherein 0≦x≦100/current collector/(100−y)% SVO+y% CFx, wherein 0≦y≦100, and wherein the ratio of x to y is selected from the group consisting of y
摘要翻译：提供了一种新的夹层阴极设计，其具有第一阴极结构的第一阴极活性材料，该第一阴极活性材料具有相对低的能量密度但具有相对较高速率的能力，例如SVO，与具有较高能量密度的第二阴极活性材料混合，但是相对较低的速率能力，例如CFx，SVO的百分比小于CFx的百分比，夹在两个集电器之间。然后，SVO和CF x活性物质的第二阴极混合物与集电体的外部接触。然而，在第二个结构中，SVO对CFx的比例大于第一个结构。这种示例性阴极设计可能看起来像：（100-y）％SVO + y％CFx，其中0 <= y <= 100 /集电器/（100-x）％SVO + x％CFx，其中0 <= x <= 100 /集电体/（100-y）％SVO + y％CFx，其中0 <= y <= 100，并且其中x与y的比率选自y

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