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    • 8. 发明授权
    • Method of coating a substrate with a polymer having a combination of crown ether and carbon nanotubes having guanidine groups
    • 用具有冠醚和具有胍基的碳纳米管的组合的聚合物涂覆基材的方法
    • US07261924B2
    • 2007-08-28
    • US11126375
    • 2005-05-11
    • Hai Sung Lee
    • Hai Sung Lee
    • B05D1/00C01B31/02
    • B82Y30/00D01F11/12D01F11/14Y10S977/745Y10S977/746Y10S977/847
    • Disclosed herein is a method of forming a guanidine group on carbon nanotubes to improve the dispersibility of carbon nanotubes, a method of attaching carbon nanotubes having guanidine groups to a substrate, and carbon nanotubes and a substrate manufactured by the above methods. The method of forming the guanidine group on the carbon nanotubes includes forming a carboxyl group on the carbon nanotubes, and forming the guanidine group on the carboxyl group of the carbon nanotubes. In addition, the method of attaching the carbon nanotubes having guanidine groups to the substrate includes coating a substrate with a polymer having crown ether attached thereto, drying the polymer layer having crown ether attached thereto formed on the substrate to be semi-dried, and coating the semi-dried polymer layer with a solution including carbon nanotubes having guanidine groups dispersed therein. The carbon nanotubes having guanidine groups, which are manufactured by the method of the current invention, are hydrogen bonded with the solvent molecule capable of reacting with the guanidine group to form the hydrogen bond, and thus, are uniformly dispersed in the solvent. Further, by using the properties of the guanidine group capable of being selectively combined with crown ether, the carbon nanotubes having guanidine groups are aligned perpendicularly to the substrate at regular intervals thereon.
    • 本文公开了一种在碳纳米管上形成胍基以提高碳纳米管的分散性的方法,将具有胍基的碳纳米管连接到基材上的方法,以及通过上述方法制造的基材。 在碳纳米管上形成胍基的方法包括在碳纳米管上形成羧基,并在碳纳米管的羧基上形成胍基。 此外,将具有胍基的碳纳米管附着在基板上的方法包括用附着有冠醚的聚合物涂布基板,干燥其上附着有冠醚的聚合物层,形成在待半干燥的基板上,涂布 该半干燥聚合物层具有包含其中分散有胍基的碳纳米管的溶液。 通过本发明的方法制造的具有胍基的碳纳米管与能够与胍基反应形成氢键的溶剂分子氢键合,从而均匀地分散在溶剂中。 此外,通过使用能够与冠醚选择性组合的胍基的性质,具有胍基的碳纳米管在其上以规则的间隔垂直于基底排列。
    • 9. 发明申请
    • Method of coating a substrate with a polymer having a combination of crown ether and carbon nanotubes having guanidine groups
    • 用具有冠醚和具有胍基的碳纳米管的组合的聚合物涂覆基材的方法
    • US20080193656A1
    • 2008-08-14
    • US11822468
    • 2007-07-06
    • Hai Sung Lee
    • Hai Sung Lee
    • C07C277/08B05D3/02C07C279/14C25D9/06
    • B82Y30/00D01F11/12D01F11/14Y10S977/745Y10S977/746Y10S977/847
    • Disclosed herein is a method of forming a guanidine group on carbon nanotubes to improve the dispersibility of carbon nanotubes, a method of attaching carbon nanotubes having guanidine groups to a substrate, and carbon nanotubes and a substrate manufactured by the above methods. The method of forming the guanidine group on the carbon nanotubes includes forming a carboxyl group on the carbon nanotubes, and forming the guanidine group on the carboxyl group of the carbon nanotubes. In addition, the method of attaching the carbon nanotubes having guanidine groups to the substrate includes coating a substrate with a polymer having crown ether attached thereto, drying the polymer layer having crown ether attached thereto formed on the substrate to be semi-dried, and coating the semi-dried polymer layer with a solution including carbon nanotubes having guanidine groups dispersed therein. The carbon nanotubes having guanidine groups, which are manufactured by the method of the current invention, are hydrogen bonded with the solvent molecule capable of reacting with the guanidine group to form the hydrogen bond, and thus, are uniformly dispersed in the solvent. Further, by using the properties of the guanidine group capable of being selectively combined with crown ether, the carbon nanotubes having guanidine groups are aligned perpendicularly to the substrate at regular intervals thereon.
    • 本文公开了一种在碳纳米管上形成胍基以提高碳纳米管的分散性的方法,将具有胍基的碳纳米管连接到基材上的方法,以及通过上述方法制造的基材。 在碳纳米管上形成胍基的方法包括在碳纳米管上形成羧基,并在碳纳米管的羧基上形成胍基。 此外,将具有胍基的碳纳米管附着在基板上的方法包括用附着有冠醚的聚合物涂布基板,干燥其上附着有冠醚的聚合物层,形成在待半干燥的基板上,涂布 该半干燥聚合物层具有包含其中分散有胍基的碳纳米管的溶液。 通过本发明的方法制造的具有胍基的碳纳米管与能够与胍基反应形成氢键的溶剂分子氢键合,从而均匀地分散在溶剂中。 此外,通过使用能够与冠醚选择性组合的胍基的性质,具有胍基的碳纳米管在其上以规则的间隔垂直于基底排列。
    • 10. 发明授权
    • Method of coating a substrate with a polymer having a combination of crown ether and carbon nanotubes having guanidine groups
    • 用具有冠醚和具有胍基的碳纳米管的组合的聚合物涂覆基材的方法
    • US07829056B2
    • 2010-11-09
    • US11822468
    • 2007-07-06
    • Hai Sung Lee
    • Hai Sung Lee
    • D01F9/12B32B9/00
    • B82Y30/00D01F11/12D01F11/14Y10S977/745Y10S977/746Y10S977/847
    • Disclosed herein is a method of forming a guanidine group on carbon nanotubes to improve the dispersibility of carbon nanotubes, a method of attaching carbon nanotubes having guanidine groups to a substrate, and carbon nanotubes and a substrate manufactured by the above methods. The method of forming the guanidine group on the carbon nanotubes includes forming a carboxyl group on the carbon nanotubes, and forming the guanidine group on the carboxyl group of the carbon nanotubes. In addition, the method of attaching the carbon nanotubes having guanidine groups to the substrate includes coating a substrate with a polymer having crown ether attached thereto, drying the polymer layer having crown ether attached thereto formed on the substrate to be semi-dried, and coating the semi-dried polymer layer with a solution including carbon nanotubes having guanidine groups dispersed therein. The carbon nanotubes having guanidine groups, which are manufactured by the method of the current invention, are hydrogen bonded with the solvent molecule capable of reacting with the guanidine group to form the hydrogen bond, and thus, are uniformly dispersed in the solvent. Further, by using the properties of the guanidine group capable of being selectively combined with crown ether, the carbon nanotubes having guanidine groups are aligned perpendicularly to the substrate at regular intervals thereon.
    • 本文公开了一种在碳纳米管上形成胍基以提高碳纳米管的分散性的方法,将具有胍基的碳纳米管连接到基材上的方法,以及通过上述方法制造的基材。 在碳纳米管上形成胍基的方法包括在碳纳米管上形成羧基,并在碳纳米管的羧基上形成胍基。 此外,将具有胍基的碳纳米管附着在基板上的方法包括用附着有冠醚的聚合物涂布基板,干燥其上附着有冠醚的聚合物层,形成在待半干燥的基板上,涂布 该半干燥聚合物层具有包含其中分散有胍基的碳纳米管的溶液。 通过本发明的方法制造的具有胍基的碳纳米管与能够与胍基反应形成氢键的溶剂分子氢键合,从而均匀地分散在溶剂中。 此外,通过使用能够与冠醚选择性组合的胍基的性质,具有胍基的碳纳米管在其上以规则的间隔垂直于基底排列。