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    • 2. 发明申请
    • HIGH STRENGTH SAPO-34 MICROSPHERE CATALYST, METHOD FOR PREPARING SAME, AND METHOD FOR PREPARING LIGHT OLEFINS USING SAME
    • 高强度SAPO-34微球催化剂,其制备方法以及使用其制备光油的方法
    • US20120203046A1
    • 2012-08-09
    • US13502496
    • 2010-10-04
    • Ho Jeong ChaeSoon Yong JeongChul Ung KimKwang Eun JeongTae Wan Kim
    • Ho Jeong ChaeSoon Yong JeongChul Ung KimKwang Eun JeongTae Wan Kim
    • B01J35/08C07C1/20B01J27/182
    • B01J29/85B01J37/0045B01J2229/42C07C1/20C10G3/00C10G11/02C10G11/18C10G2400/20
    • The present invention relates to a high-strength silicoaluminophasphate-34 (SAPO-34) microsphere catalyst, a method for preparing the same, and a method for preparing light olefins by using the same, and when described in more detail, the present invention relates to a method for preparing a SAPO-34 microsphere catalyst, including: spray drying a mixed slurry including a matrix, a binder, an additive, and the like to a SAPO-34 slurry prepared by a hydrothermal synthesizing method using various organic templates such as tetraethylammonium hydroxide (TEAOH), and the like alone or in mixtures to prepare microspheres, and firing the microspheres, and to a SAPO-34 microsphere catalyst for a circulating-fluidized bed reactor, prepared by the preparation method. The SAPO-34 microsphere catalyst of the present invention has excellent reaction activity while having high strength, and thus is appropriate for use in a circulating-fluidized bed reactor requiring high strength of the catalyst. Further, the SAPO-34 microsphere catalyst has a long life-span and excellent conversion rate of C1 to C4 oxygen-including compounds (oxygenates), and thus is appropriate for use in the preparation of light olefins such as ethylene, propylene, butene, and the like.
    • 本发明涉及一种高强度硅铝硅酸盐-S34(SAPO-34)微球体催化剂及其制备方法,以及使用该微球体催化剂的轻质烯烃的制备方法,更详细地说明本发明涉及 涉及一种制备SAPO-34微球催化剂的方法,包括:将包含基质,粘合剂,添加剂等的混合浆料喷雾干燥至通过水热合成法制备的SAPO-34浆料,使用各种有机模板如 四乙基氢氧化铵(TEAOH)等单独或以混合物形式制备微球,并烧制微球,以及通过制备方法制备的循环流化床反应器的SAPO-34微球催化剂。 本发明的SAPO-34微球催化剂具有优异的反应活性,同时具有高强度,因此适用于需要高强度催化剂的循环流化床反应器。 此外,SAPO-34微球催化剂具有长寿命和优异的C1至C4含氧化合物(含氧化合物)的转化率,因此适用于制备轻质烯烃如乙烯,丙烯,丁烯, 等等。