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1. 发明授权

US5241096A Fluorine-containing organosilicon compound 失效
标题翻译：含氟有机硅化合物
公开(公告)号：US5241096A
公开(公告)日：1993-08-31
申请号：US961369
申请日：1992-10-15
申请人： Hitoshi Kinami , Kouichi Yamaguchi , Hideki Fujii , Shuji Suganuma , Yoshikazu Saito
发明人： Hitoshi Kinami , Kouichi Yamaguchi , Hideki Fujii , Shuji Suganuma , Yoshikazu Saito
IPC分类号： C07F7/18 , C08G77/22 , C08G77/24 , C08K5/5419 , C08L83/04
CPC分类号： C07F7/1896
摘要： A fluorine-containing organosilicon compound according to the present invention is expressed by the general formula: ##STR1## wherein Rf is a perfluoropolyether group having 3 to 17 carbon atoms, R is an alkylene group having 1 to 6 carbon atoms or an ether group expressed by the general formula:--R.sup.1 --O--R.sup.2 --wherein R.sup.1 and R.sup.2 may be the same or different and are each alkylene groups having 1 to 6 carbon atoms. The fluorine-containing organosilicon compound is highly useful as a curing agent for organopolysiloxane compositions that are condensation curable at room temperature.
摘要翻译：根据本发明的含氟有机硅化合物由以下通式表示：其中Rf是具有3至17个碳原子的全氟聚醚基团，R是具有1至6个碳原子的亚烷基或表示的醚基团通式为：-R 1 -O-R 2 - ，其中R 1和R 2可以相同或不同，并且各自是具有1至6个碳原子的亚烷基。含氟有机硅化合物作为在室温下可缩合固化的有机聚硅氧烷组合物的固化剂是非常有用的。

2. 发明授权

US5210253A Fluorine-containing organosilicon compound 失效
标题翻译：含氟有机硅化合物
公开(公告)号：US5210253A
公开(公告)日：1993-05-11
申请号：US961361
申请日：1992-10-15
申请人： Hitoshi Kinami , Kouichi Yamaguchi , Hideki Fujii , Shuji Suganuma
发明人： Hitoshi Kinami , Kouichi Yamaguchi , Hideki Fujii , Shuji Suganuma
IPC分类号： B01J27/122 , C07B61/00 , C07F7/12 , C07F7/18 , C08G77/08 , C09K3/00 , C09K3/18
CPC分类号： C07F7/12 , C07F7/1836
摘要： Fluorine-containing organosilicon compound according to the present invention is expressed by the general formula: ##STR1## wherein Rf is a perfluoropolyether group having 3 to 17 carbon atoms, R is an alkylene group having 1 to 6 carbon atoms or a group of the general formula, --R.sup.2 --O--R.sup.3 --, wherein R.sup.2 and R.sup.3 may be the same or different and are each alkylene groups having 1 to 6 carbon atoms. The present compound is useful as a curing catalyst for organo-polysiloxane compounds that are condensation curable at room temperature. The compositions added with the fluorine-containing organosilicon compound have excellent characteristics such as water and oil repellencies, chemical resistance and contamination resistance and offer a variety of uses such as high performance sealing, coating and electric insulating materials.
摘要翻译：根据本发明的含氟有机硅化合物由以下通式表示：其中Rf是具有3至17个碳原子的全氟聚醚基团，R是具有1至6个碳原子的亚烷基或一般的基团 R 2 -O-R 3 - ，其中R 2和R 3可以相同或不同，并且各自是具有1至6个碳原子的亚烷基。本发明化合物可用作在室温下可缩合固化的有机聚硅氧烷化合物的固化催化剂。加入含氟有机硅化合物的组合物具有防水拒油性，耐化学性和耐污染性等优异特性，并提供高性能密封，涂层和电绝缘材料等各种用途。

3. 发明授权

US5118828A Fluorine-containing organosilicon compound 失效
标题翻译：含氟的有机硅化合物
公开(公告)号：US5118828A
公开(公告)日：1992-06-02
申请号：US723317
申请日：1991-06-28
申请人： Toshio Takago , Hirofumi Kishita , Shinichi Sato , Hitoshi Kinami , Shuji Suganuma , Koichi Yamaguchi , Kenichi Fukuda , Hirokazu Yamada
发明人： Toshio Takago , Hirofumi Kishita , Shinichi Sato , Hitoshi Kinami , Shuji Suganuma , Koichi Yamaguchi , Kenichi Fukuda , Hirokazu Yamada
IPC分类号： C07F7/08
CPC分类号： C07F7/0841
摘要： The fluorine-containing organosilicon compound of the present invention is represented by the following formula: ##STR1## wherein Rf is a perfluoroalkyl group. This compound is quite useful as a raw material for the production of polysilethylenesiloxanes excellent in solvent resistance.

4. 发明授权

US5117025A Polysilethylenesiloxane 失效
标题翻译：聚硅氧烷硅氧烷
公开(公告)号：US5117025A
公开(公告)日：1992-05-26
申请号：US726334
申请日：1991-07-05
申请人： Toshio Takago , Hirofumi Kishita , Hitoshi Kinami , Kenichi Fukuda , Shinich Sato , Koichi Yamaguchi , Shuji Suganuma
发明人： Toshio Takago , Hirofumi Kishita , Hitoshi Kinami , Kenichi Fukuda , Shinich Sato , Koichi Yamaguchi , Shuji Suganuma
IPC分类号： C08G77/48 , C08G77/50
CPC分类号： C08G77/485 , C08G77/50
摘要： The present polysilethylenesiloxane is a liquid polymer represented by the following general formula: ##STR1## wherein R.sup.1 and R.sup.2 each represent a lower alkyl group and R.sup.3 and R.sup.4 each represent a perfluoroalkylethyl group, and n is an integer of 10 to 1,000. This polymer is quite useful as a major component of elastomer compositions having chemical resistance, electrical properties, and high strength.

5. 发明授权

US5194647A Organic silicon compounds and method for making 失效
标题翻译：有机硅化合物及其制备方法
公开(公告)号：US5194647A
公开(公告)日：1993-03-16
申请号：US889698
申请日：1992-05-29
申请人： Shinichi Sato , Hirofumi Kishita , Hitoshi Kinami , Hideki Fujii
发明人： Shinichi Sato , Hirofumi Kishita , Hitoshi Kinami , Hideki Fujii
IPC分类号： C07F7/08 , C07F7/21
CPC分类号： C07F7/0887 , C07F7/21
摘要： Organic silicon compounds of formula (1) are novel. ##STR1## In the formula, wherein R.sup.1 and R.sup.2 are monovalent C.sub.1-8 hydrocarbon group, R.sup.3 is a C.sub.2-6 alkylene group or a C.sub.2-6 alkylene group containing at least one --C--O--C-- linkage, R.sup.4 is a C.sub.1-6 alkyl group, Rf is a C.sub.1-15 perfluoroalkyl or perfluorocycloalkyl group or a C.sub.1-20 perfluoroalkyl or perfluorocycloalkyl group containing at least one --C--O--C-- linkage, and n=0, 1 or 2, m=1 or 2, and k=2, 3 or 4. The organic silicon compounds are useful source materials for the manufacture of fluorinated polysiloxanes having solvent resistance, chemical resistance and release property.
摘要翻译：式（1）的有机硅化合物是新颖的。（1）式中，R 1和R 2为一价C 1-8烃基，R 3为C 2-6亚烷基或含有至少一个-COC-键的C 2-6亚烷基，R 4为C 1 -6-烷基，Rf为C1-15全氟烷基或全氟环烷基或含有至少一个-COC-键的C1-20全氟烷基或全氟环烷基，n = 0,1或2，m = 1或2，k = 2,3或4.有机硅化合物是用于制造具有耐溶剂性，耐化学性和脱模性的氟化聚硅氧烷的有用的源材料。

6. 发明授权

US5214177A Fluorinated organic silicon compounds and method for making 失效
标题翻译：氟化有机硅化合物及其制备方法
公开(公告)号：US5214177A
公开(公告)日：1993-05-25
申请号：US769483
申请日：1991-10-01
申请人： Masayuki Oyama , Toshio Takago , Hideki Fujii , Hitoshi Kinami
发明人： Masayuki Oyama , Toshio Takago , Hideki Fujii , Hitoshi Kinami
IPC分类号： C07F7/12
CPC分类号： C07F7/12
摘要： Fluorinated organic silicon compound of the general formula: ##STR1## wherein R is an alkyl group having 1 to 6 carbon atoms, n is an integer of from 1 to 6, and m is equal to 1, 2 or 3 are novel and useful as treating agents and intermediates for the synthesis of fluorinated cyclic organic silicon compounds. The fluorinated organic silicon compounds are prepared by reacting a chlorosilane with a fluorinated olefin.
摘要翻译：具有以下通式的氟化有机硅化合物：其中R是具有1至6个碳原子的烷基，n是1至6的整数，m等于1,2或3是新的并且可用作合成氟化环状有机硅化合物的处理剂和中间体。氟化有机硅化合物通过氯硅烷与氟化烯烃反应制备。

7. 发明授权

US5420189A Organopolysiloxane compositions 失效
标题翻译：有机聚硅氧烷组合物
公开(公告)号：US5420189A
公开(公告)日：1995-05-30
申请号：US205115
申请日：1994-03-03
申请人： Hirofumi Kishita , Kouichi Yamaguchi , Takashi Matsuda , Kenichi Fukuda , Nobuyuki Kobayashi , Shinichi Sato , Hitoshi Kinami
发明人： Hirofumi Kishita , Kouichi Yamaguchi , Takashi Matsuda , Kenichi Fukuda , Nobuyuki Kobayashi , Shinichi Sato , Hitoshi Kinami
IPC分类号： C08L83/05 , C08K5/549 , C08L83/04 , C08L83/07 , C08L83/08 , C08L83/12 , C09D183/04 , C09D183/08 , C09J183/00 , C09J183/08 , C08G77/08
CPC分类号： C08L83/08 , C09D183/08
摘要： An organopolysiloxane composition comprising (A) a linear, alkenyl-containing, fluorinated organopolysiloxane, (B) a cyclic fluorinated organosiloxane as a tackifier, (C) an organohydrogenpolysiloxane having at least two hydrogen atoms attached to a silicon atom in a molecule, and (D) a platinum group metal catalyst has excellent properties inherent to fluorinated silicone rubber, and cures into products having adhesion and close contact to various materials including metals, glass and resins.
摘要翻译：一种有机聚硅氧烷组合物，其包含（A）直链，含链烯基的氟化有机聚硅氧烷，（B）作为增粘剂的环状氟化有机硅氧烷，（C）分子中具有至少两个氢原子的有机氢聚硅氧烷，和 D）铂族金属催化剂具有氟化硅橡胶固有的优异性能，并固化成与各种材料（包括金属，玻璃和树脂）具有粘合性和紧密接触的产品。

8. 发明授权

US5177131A Room temperature curing composition 失效
标题翻译：室温固化组合物
公开(公告)号：US5177131A
公开(公告)日：1993-01-05
申请号：US727120
申请日：1991-07-09
申请人： Toshio Takago , Hiroshi Inomata , Hirofumi Kishita , Shinichi Sato , Hitoshi Kinami , Koichi Yamaguchi , Takashi Matsuda , Hirokazu Yamada
发明人： Toshio Takago , Hiroshi Inomata , Hirofumi Kishita , Shinichi Sato , Hitoshi Kinami , Koichi Yamaguchi , Takashi Matsuda , Hirokazu Yamada
IPC分类号： C08K5/00 , C08L83/14
CPC分类号： B01D69/148 , B01D67/0048 , C08K5/0008 , C08L83/14 , B01D2323/08 , B01D2323/12 , B01D2325/30 , B01D71/027 , B01D71/70 , Y10S528/901
摘要： The present room temperature curing composition comprises an organopolysilethylenesiloxane represented by the following general formula: ##STR1## wherein R.sup.1 to R.sup.4 each represent an alkyl having up to 8 carbon atoms or a phenyl group and n is an integer of 10 or above, and an organosilane or an organosiloxane having two or more hydrolyzable groups such as alkoxy groups in the molecule. The composition can form a cured product high in rubber strength and excellent in chemical resistance.

9. 发明授权

US4623693A Room temperature-curable organopolysiloxane composition 失效
标题翻译：室温可固化的有机聚硅氧烷组合物
公开(公告)号：US4623693A
公开(公告)日：1986-11-18
申请号：US762555
申请日：1985-08-05
申请人： Yoshio Inoue , Takehide Okami , Koji Yokoo , Hitoshi Kinami
发明人： Yoshio Inoue , Takehide Okami , Koji Yokoo , Hitoshi Kinami
IPC分类号： C08L83/00 , C08K5/00 , C08K5/5419 , C08K5/5425 , C08K5/57 , C08L83/04 , C08L83/06 , C08K3/02
CPC分类号： C08L83/04 , C08G77/16 , Y10S528/901
摘要： The room temperature-curable organopolysiloxane composition of the invention is characteristic in the remarkably increased adhesive bonding strength of the rubber of the composition to the surface of a substrate of metals, plastics and others on which the composition has been cured. The composition is also advantageous in the improved thixotropy despite the admixture of an adhesion improver mentioned below. Thus, the composition comprises, in addition to conventional components in a deacidification type room temperature curable organopolysiloxane composition, a specific organic silicon compound represented by the general formula(R.sup.3 O).sub.b (MeCOO).sub.3-b Si--O--R.sup.4 --O--Si(OCOMe).sub.3-b (OR.sup.3).sub.b,in which R.sup.3 is a monovalent hydrocarbon group, R.sup.4 is a divalent hydrocarbon group or a polyoxyalkylene group of the formula --C.sub.x H.sub.2x --O).sub.n C.sub.x H.sub.2x --, x being 2 to 4 and n being a positive integer, and b is 1 or 2.
摘要翻译：本发明的室温可固化的有机基聚硅氧烷组合物的特征在于组合物的橡胶与其组合物已经固化的金属，塑料和其它基材的表面的粘合强度显着增加。尽管混合以下提及的粘合改进剂，该组合物在改善的触变性方面也是有利的。因此，除了脱酸型室温可固化的有机聚硅氧烷组合物中的常规组分外，组合物还包含由通式（R3O）b（MeCOO）3-bSi-O-R4-O-Si（MeCOO）3-bSi-O-R4-O-Si OCOMe）3-b（OR3）b，其中R3是一价烃基，R4是二价烃基或式-CxH2x-O的聚氧化烯基）nCxH2x-，x是2-4，n是正的整数和b为1或2。

10. 发明授权

US5288889A Fluorinated organic silicon compounds and method for making 失效
标题翻译：氟化有机硅化合物及其制备方法
公开(公告)号：US5288889A
公开(公告)日：1994-02-22
申请号：US60537
申请日：1993-05-13
申请人： Toshio Takago , Shinichi Sato , Hitoshi Kinami , Noriyuki Koike
发明人： Toshio Takago , Shinichi Sato , Hitoshi Kinami , Noriyuki Koike
IPC分类号： C07F7/18 , C08G65/02 , C08G65/04 , C08G65/32 , C08G65/333 , C08G65/336 , C08G65/48 , C09K3/00 , C09K3/18 , C07F7/10
CPC分类号： C08G65/33306 , C07F7/184 , C08G65/336
摘要： A fluorinated organic silicon compound of a structure having a fluorinated polyether group in its backbone and an isopropenoxysilyl group attached at either end forms a compliant coating on the surface of any substrate such as silicone rubber which is effective in imparting water and oil repellency and stain resistance to silicone rubber surface.
摘要翻译：在其主链上具有氟化聚醚基团的结构的氟化有机硅化合物和任一端连接的异丙烯氧基甲硅烷基在任何基材例如硅橡胶的表面上形成柔顺涂层，其有效地赋予拒水拒油性和抗污性到硅橡胶表面。

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