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    • 1. 发明授权
    • Martensitic stainless steel having excellent hot workability and sulfide
stress cracking resistance
    • 具有优异的热加工性和耐硫化物应力开裂性的马氏体不锈钢
    • US5820699A
    • 1998-10-13
    • US776125
    • 1997-04-17
    • Hitoshi AsahiTakuya HaraAkira Kawakami
    • Hitoshi AsahiTakuya HaraAkira Kawakami
    • C21D9/08C21D6/00C22C38/00C22C38/42C22C38/44C22C38/50
    • C21D6/004C22C38/42C22C38/44C21D2211/008
    • A martensitic stainless steel capable of developing a tempered martensitic structure, comprising by weight C: 0.005 to 0.05%, Si.ltoreq.0.50%, Mn: 0.1 to 1.0%, P.ltoreq.0.03%, S.ltoreq.0.005%, Mo: 1.0 to 3.0%, Cu: 1.0 to 4.0%, Ni: 5 to 8%, Al.ltoreq.0.06%, Cr and Mo satisfying a requirement represented by the formula Cr+1.6Mo.gtoreq.13; and C, N, Ni, Cu, Cr, and Mo satisfying a requirement represented by the formula Ni(eq): 40C+34N+Ni+0.3Cu-1.1Cr-1.8Mo.gtoreq.-10.5, and optionally at least one member selected from the group consisting of Ti, Zr, Ca, and REM, with the balance consisting essentially of Fe. The present invention provides a martensitic stainless steel having excellent resistance to corrosion by CO.sub.2 and sulfide stress cracking and good hot workability.
    • PCT No.PCT / JP95 / 01453 Sec。 371日期1997年04月17日 102(e)日期1997年4月17日PCT提交1995年7月21日PCT公布。 出版物WO96 / 03532 日期:1996年2月8日具有显影回火马氏体组织的马氏体系不锈钢,其含量为C:0.005〜0.05%,Si≤0.50%,Mn:0.1〜1.0%,P≤0.03% /=0.005%,Mo:1.0〜3.0%,Cu:1.0〜4.0%,Ni:5〜8%,Al:0.06%,Cr和Mo满足式Cr + 1.6Mo> 13; 和C,N,Ni,Cu,Cr和Mo满足由式Ni(eq)表示的要求:40℃+ 34N + Ni + 0.3Cu-1.1Cr-1.8Mo> = 10.5,以及任选的至少一种 选自Ti,Zr,Ca和REM组成的组分,余量基本上由Fe组成。 本发明提供一种马氏体不锈钢,具有优异的耐CO 2腐蚀性和耐硫化应力开裂性以及良好的热加工性。
    • 5. 发明授权
    • High-strength steel pipe excellent in low temperature toughness and toughness at weld heat-affected zone
    • 焊接热影响区的低温韧性和韧性优良的高强度钢管
    • US07601231B2
    • 2009-10-13
    • US10444743
    • 2003-05-23
    • Takuya HaraHitoshi Asahi
    • Takuya HaraHitoshi Asahi
    • C22C38/04C22C38/14C22C38/12
    • C22C38/02C21D8/0226C21D8/10C21D8/1261C21D2211/002C21D2211/008C22C38/42C22C38/44C22C38/46C22C38/58Y10S148/909
    • A high-strength steel pipe excellent in weldability on site and a method for producing the steel pipe by improving the reliability of the low temperature toughness of a steel are provided. For example, the steel pipe includes elements to enhance hardenability for furthering high-strengthening and also improving toughness at a weld heat affected zone subjected to double or more layer welding. In the method, the steel is made to consist of a structure composed of bainite and/or martensite by containing prescribed amounts of C, Si, Mn, P, S, Ni, Mo, Nb, Ti, Al and N, and, as occasion demands, one or more of B, V, Cu, Cr, Ca, REM, and Mg, and regulating C, Si, Mn, Cr, Ni, Cu, V and Mo. Such elements enhancing hardenability, by a specific relational expression. The diameter of prior austenite grains may be regulated in a prescribed range. The method may include heating a casting to a temperature not lower than the Ac3 point, hot rolling such casting, and thereafter cooling the resulting hot-rolled steel plate at a prescribed cooling rate.
    • 提供了一种现场焊接性优异的高强度钢管和通过提高钢的低温韧性的可靠性来制造钢管的方法。 例如,钢管包括提高淬火性的元素,以进一步提高强化强度,并提高经受双层或多层焊接的焊接热影响区的韧性。 在该方法中,通过含有规定量的C,Si,Mn,P,S,Ni,Mo,Nb,Ti,Al和N,由贝氏体和/或马氏体构成的结构,由钢构成,作为 需要B,V,Cu,Cr,Ca,REM和Mg中的一种或多种,​​调节C,Si,Mn,Cr,Ni,Cu,V和Mo。这些元素通过具体的关系式提高淬透性 。 原奥氏体晶粒的直径可以在规定的范围内调节。 该方法可以包括将铸件加热到不低于Ac3点的温度,热轧这种铸造,然后以规定的冷却速度冷却所得到的热轧钢板。
    • 6. 发明授权
    • High-strength steel sheet and high-strength steel pipe excellent in deformability and method for producing the same
    • 可变形性优异的高强度钢板和高强度钢管及其制造方法
    • US08070887B2
    • 2011-12-06
    • US10410014
    • 2003-04-09
    • Hitoshi AsahiYasuhiro ShinoharaTakuya Hara
    • Hitoshi AsahiYasuhiro ShinoharaTakuya Hara
    • C21D9/08C22C38/00C22C38/18
    • C22C38/04C21D8/0226C21D8/0263C21D2211/002C21D2211/005C22C38/001C22C38/02C22C38/12C22C38/14
    • The present invention provides a line pipe of, e.g., the API standard X60 to X100 class. The line pipe has an excellent deformability, as well as excellent low temperature toughness and high productivity, a steel plate used as the material of the steel pipe. Methods for producing the steel pipe and the steel plate are also provided. In particular, a high-strength steel plate excellent in the deformability has a ferrite phase is dispersed finely, and accounts for 5% to 40% in area percentage in a low temperature transformation structure mainly composed of a bainite phase. For example, most grain sizes of the ferrite phase are smaller than the average grain size of the bainite phase. A high-strength steel pipe excellent in deformability is also provided, in which a large diameter steel pipe is produced through forming the steel plate into a pipe shape. The steel pipe has the above-referenced structure, and satisfies the conditions that YS/TS is 0.95 or less and YS×uEL is 5,000 or more. Methods for producing such steel plate and steel pipe are also provided.
    • 本发明提供了例如API标准X60至X100类的管线管。 线管具有优异的变形性,以及优异的低温韧性和高生产率,用作钢管材料的钢板。 还提供了生产钢管和钢板的方法。 特别是,在主要由贝氏体相组成的低温转变结构中,变形性优异的高强度钢板的铁素体相分散细小,占面积率的5〜40%。 例如,铁素体相的大部分晶粒尺寸小于贝氏体相的平均晶粒尺寸。 还提供了一种变形能力优异的高强度钢管,其中通过将钢板形成管状而制造大直径钢管。 钢管具有上述结构,满足YS / TS为0.95以下,YS×uEL为5000以上的条件。 还提供了生产这种钢板和钢管的方法。
    • 7. 发明授权
    • Ultrahigh strength welded joint and ultrahigh strength welded steel pipe excellent in cold cracking resistance of weld metal, and methods for producing the same
    • 焊接金属的耐寒裂纹性优异的超高强度焊接接头和超高强度焊接钢管及其制造方法
    • US08049131B2
    • 2011-11-01
    • US10898307
    • 2004-07-23
    • Takuya HaraHitoshi Asahi
    • Takuya HaraHitoshi Asahi
    • B23K9/18B23K25/00
    • B23K35/0261B23K9/0253B23K9/186B23K9/23B23K35/3066B23K2101/06B23K2103/04Y10T428/12972
    • The present invention, in a welded joint of steel sheets and a steel pipe body having a tensile strength of 800 MPa or more (over X100 in API Standards), provides: the welded joint of the steel sheets and the steel pipe produced by forming a steel sheet into a cylindrical shape and welding both the ends thereof, both excellent in cold cracking resistance; and methods for producing them. The present invention includes an ultrahigh strength welded joint and an ultrahigh strength welded steel pipe excellent in the cold cracking resistance of a weld metal, characterized in that the amount of non-diffusible hydrogen in the inner side weld metal is 0.01 ppm or more. It is preferable that the ratio of the non-diffusible hydrogen amount to the total hydrogen amount in said inner side weld metal is 0.5% or more. Further, it is preferable that Mo carbide is contained by not less than 1 piece/μm2 in said inner side weld metal. The present invention also includes a method for producing said welded joint and welded steel pipe, characterized by welding the butted portion from the inner side and thereafter welding it from the outer side so that the reheating temperature of the inner side weld metal may reach within the range from 500° C. to 700° C.
    • 本发明在钢板焊接接头和抗拉强度为800MPa以上(在API标准中为X100以上)的钢管体中,提供:钢板的焊接接头和通过形成 钢板成为圆筒状并焊接其两端,耐寒性均优异; 及其生产方法。 本发明包括焊接金属的耐寒裂性优异的超高强度焊接接头和超高强度焊接钢管,其特征在于,内侧焊接金属中的非扩散性氢的量为0.01ppm以上。 优选所述内侧焊接金属中的所述非扩散性氢量与所述总氢量的比率为0.5%以上。 此外,优选在所述内侧焊接金属中含有不小于1个/μm2的Mo碳化物。 本发明还包括一种用于制造所述焊接接头和焊接钢管的方法,其特征在于,从内侧焊接对接部分,然后从外侧焊接,使得内侧焊接金属的再加热温度可达到 范围从500°C到700°C