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    • 1. 发明专利
    • Organic acid decomposing catalyst and chemical decontamination method
    • 有机酸分解催化剂和化学除去方法
    • JP2003033653A
    • 2003-02-04
    • JP2001224309
    • 2001-07-25
    • Hitachi Eng Co LtdHitachi Ltd日立エンジニアリング株式会社株式会社日立製作所
    • KATAOKA ICHIROAIZAWA MOTOHIROANAZAWA KAZUMINAGASE MAKOTOISHIDA KAZUNARI
    • G21F9/06B01J23/22B01J23/42B01J23/46G21F9/28
    • PROBLEM TO BE SOLVED: To improve the performance of a catalyst to decompose a decontaminant containing an organic acid in order to reduce the load on an ion exchange resin and to decrease wastes by accompanying the chemical decontamination of radioactive deposits.
      SOLUTION: In the decomposition of the organic acid which is the decontaminant using the catalyst attached additionally with noble metals, from 10 mesh (opening of sieve mesh 1.68 mm) to 20 mesh (opening of sieve mesh 0.84 mm) are found as optimum grain sizes. The organic acid after the decontamination can be decomposed with high efficiency by applying the catalyst of such grain sizes and the shortening of the decomposition time, the downsizing of facilities and the evading of the degradation in water quality by the deterioration of the ion exchange resin are made possible. The organic acid used for the chemical decontamination can be efficiency subjected to the decomposition treatment in a short period of time by using the catalyst of the grain sizes. In addition, not only an oxalic acid but other organic acids, etc., can be efficiently decomposed.
      COPYRIGHT: (C)2003,JPO
    • 要解决的问题:提高催化剂的性能,以分解含有机酸的去污剂,以减少离子交换树脂的负荷,并通过伴随放射性沉积物的化学去污来减少废物。 解决方案:在使用附加贵金属的催化剂除去污染物的有机酸的分解中,从10目(筛网1.68mm)至20目(筛孔0.84mm的开孔)被发现为最佳粒度 。 去污后的有机酸可以通过应用这种晶粒尺寸的催化剂和缩短分解时间,设备的小型化以及通过离子交换树脂的劣化避免水质退化来高效分解。 成为可能 用于化学去污的有机酸可以通过使用粒度的催化剂在短时间内进行有效的分解处理。 此外,不仅可以有效地分解草酸,而且其它有机酸等。
    • 3. 发明专利
    • Decontamination method and decontamination agent
    • 去除方法和去污剂
    • JP2003057393A
    • 2003-02-26
    • JP2001246908
    • 2001-08-16
    • Hitachi Eng Co LtdHitachi LtdKurita Engineering Co Ltd日立エンジニアリング株式会社栗田エンジニアリング株式会社株式会社日立製作所
    • KAZAMA MASAHIKOYOSHIKAWA HIROOAIZAWA MOTOHIRONAGASE MAKOTO
    • G21F9/28B01J47/02B01J47/04G21F9/06G21F9/12
    • PROBLEM TO BE SOLVED: To provide a decontamination method and a decontamination agent suitable for chemical decontamination of structural parts including a copper oxide in a nuclear power plant. SOLUTION: Malonic acid 5 is injected as the decontamination agent in circulating lines 15, 16, and circulated through lines 15, 16 to dissolve copper oxide from a radioactive insoluble substance stuck to a decontamination object 1 (a copper removal process). Dissolved copper ions are removed by making decontamination agent liquid flow to a cation exchange resin column 3 (a metal ion removal process). After the completion of the copper removal process, ascorbic acid 5 is injected in the circulating lines 15, 16 to dissolve iron oxide remaining in the copper removal process, from the decontamination object 1 (an iron removal process). Dissolved iron ions are removed in the cation exchange resin column 3. Hydrogen peroxide 9 is injected in the decontamination agent liquid from which iron ions are removed and the decontamination agent liquid is circulated through a catalyst column 8 to decompose the decontamination agent into carbon dioxide and water, and further passed through a mixed bed resin column 4 for final purification.
    • 要解决的问题:提供一种适用于核电厂中包括氧化铜在内的结构部件的化学去污的去污方法和去污剂。 解决方案:丙二酸5作为净化剂在循环管线15,16中注入,并通过管线15,16循环,以从粘附到去污物体1上的放射性不溶物质(铜除去过程)中溶解氧化铜。 通过使去污剂液体流到阳离子交换树脂柱3(金属离子去除法)除去溶解的铜离子。 在完成铜去除工艺之后,将抗坏血酸5注入循环管线15,16中以从去污物1(铁除去过程)中除去残留在除铜过程中的氧化铁。 在阳离子交换树脂柱3中除去溶解的铁离子3.将过氧化氢9注入除去铁离子的去污剂液体中,并且去污剂液体通过催化剂塔8循环,以将去污剂分解成二氧化碳, 水,并进一步通过混合床树脂柱4进行最终纯化。
    • 4. 发明专利
    • Gap water quality measuring method and gap water quality measuring instrument
    • GAP水质测量方法和GAP水质测量仪器
    • JP2008008744A
    • 2008-01-17
    • JP2006179304
    • 2006-06-29
    • Hitachi Ltd株式会社日立製作所
    • WADA YOICHIISHIDA KAZUNARITACHIBANA MASAHIKOAIZAWA MOTOHIROUSUI NAOSHI
    • G01N27/28G01N17/00G01N27/07G01N27/26G01N27/30G01N27/416G21C17/003G21C17/02
    • PROBLEM TO BE SOLVED: To provide a gap water quality measuring method for precisely measuring the quantity of state related to the quality of the water in a crack and more precisely estimating a crack developing speed, and a gap water quality measuring instrument. SOLUTION: The gap water quality sensor 36 of the gap water quality measuring instrument 18 has a gap forming member 31 containing gap forming parts 32a and 32b which form a gap 1 and electrodes 2a and 2b are attached to the gap forming part 32b in an electrically insulated state. The electrode 2a is arranged to the opening part 33 of the gap 1 and the electrode 2b is arranged to the leading end part 34 of the gap 1. The measuring instrument 37 of the gap water quality measuring instrument 18 has an ammeter 5 and an electric cable 4 containing wirings 4a and 4b. The wiring 4a is connected to the electrode 2a and the wiring 4b is connected to the electrode 2b. The ammeter 5 measures the current flowing across the electrodes 2a and 2b. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供一种用于精确测量与裂纹中水的质量有关的状态量并更准确地估计裂纹展开速度的间隙水质量测量方法,以及间隙水质量测量仪。 间隙水质测量仪18的间隙水质传感器36具有间隙形成部件31,间隙形成部件31包含形成间隙1的间隙形成部32a,32b,电极2a,2b与间隙形成部32b 处于电绝缘状态。 电极2a设置在间隙1的开口部33上,电极2b配置在间隙1的前端部34.间隙水质测定器18的测定器37具有电流表5和电 电缆4包含布线4a和4b。 配线4a与电极2a连接,配线4b与电极2b连接。 电流表5测量流过电极2a和2b的电流。 版权所有(C)2008,JPO&INPIT
    • 5. 发明专利
    • Method for zinc supply to reactor
    • 锌供应给反应器的方法
    • JP2007033352A
    • 2007-02-08
    • JP2005219994
    • 2005-07-29
    • Hitachi Ltd株式会社日立製作所
    • AIZAWA MOTOHIROHOSOKAWA HIDEYUKIISHIDA KAZUNARI
    • G21D3/08G21C19/307G21D1/00G21D1/02
    • Y02E30/40
    • PROBLEM TO BE SOLVED: To provide a method for zinc supply to a reactor capable of drastically reducing additional placing cost of zinc supply facility for suppressing adhesion of radioactive materials on inner surface of piping and component containing radioactive materials, operation and maintenance cost and management cost.
      SOLUTION: This method for zinc supply is for a boiling water reactor power plant having a boiling water reactor 1, steam turbines 3 and 4 for driving a generator with the steam, a condenser 5 for cooling the steam having driven the steam turbine 4 returning to water, a condensate filter 7 for purifying the condensate water, a condensate demineralizer 8 and supply water heaters 10 and 12 for heating purified water and returning to the reactor. The zinc concentration in the condensate filter 7 outlet water is raised by precoating particles containing zinc in the filtering surface of processed water inlet side of the condensate filter 7. Part of condensate water flow passing the condensate filter 7 is bypassed with a condensate filter bypass valve and a bypass pipe 25, iron concentration in condensate filter 7 outlet water is increased and zinc is supplied to the reactor 1.
      COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供一种能够大大降低锌供应设备的附加放置成本的锌供应方法,用于抑制放射性物质在管道内部表面和含有放射性物质的成分的附着,操作和维护成本 和管理成本。 解决方案:这种锌供应方法是用于具有沸水反应器1,用于驱动具有蒸汽的发电机的蒸汽轮机3和4的沸水反应堆发电厂,用于冷却已经驱动汽轮机的蒸汽的冷凝器5 4返回水中,用于净化冷凝水的冷凝水过滤器7,冷凝水脱盐机8和用于加热净化水并返回到反应器的供水热水器10和12。 冷凝水过滤器7出水中的锌浓度通过在冷凝水过滤器7的处理水入口侧的过滤表面中预涂涂覆锌的颗粒来提高。通过冷凝物过滤器7的冷凝水流的一部分用冷凝器过滤器旁通阀旁路 和旁通管25,冷凝过滤器7出口水中的铁浓度增加,并且向反应器1供应锌。版权所有(C)2007,JPO&INPIT
    • 7. 发明专利
    • Stress corrosion cracking suppression method
    • 应力腐蚀开裂抑制方法
    • JP2005283530A
    • 2005-10-13
    • JP2004101804
    • 2004-03-31
    • Hitachi Ltd株式会社日立製作所
    • WADA YOICHIISHIDA KAZUNARITACHIBANA MASAHIKOAIZAWA MOTOHIROUSUI NAOSHINAKAMURA MASAHITO
    • G21C19/307G21D1/00G21D3/08
    • Y02E30/40
    • PROBLEM TO BE SOLVED: To suppress stress corrosion cracking by lowering corrosion potential of reactor structure material. SOLUTION: Oxide existing on the surface of structure and piping of a BWR contacting reactor water is removed. Then, hydrazine is added to reactor water together with hydrogen in an operation cycle of a boiling water reactor. As hydrazine is added to the reactor water in addition to hydrogen, oxygen and hydrogen peroxide generated in the reactor are made to react with hydrazine to be water and nitrogen so that the concentration of oxygen and hydrogen peroxide in reactor water is efficiently reduced. Since oxide is removed, the effect of hydrazine to directly lower the corrosion potential of materials can be duplicated. As the results, the corrosion potential of the reactor structure materials sufficiently lowers and stress corrosion cracking can be suppressed. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:通过降低反应堆结构材料的腐蚀电位来抑制应力腐蚀开裂。

      解决方案:除去存在于BWR接触反应器水的结构和管道表面上的氧化物。 然后,在沸水反应器的操作循环中,将肼与氢气一起加入到反应器水中。 当将肼加入反应器中除了氢气之外,使在反应器中产生的氧气和过氧化氢与肼反应成水和氮,从而有效降低反应器水中氧气和过氧化氢的浓度。 由于除去氧化物,可以重复肼直接降低材料的腐蚀电位的影响。 结果,可以抑制反应堆结构材料的腐蚀电位充分降低,并且可以抑制应力腐蚀开裂。 版权所有(C)2006,JPO&NCIPI

    • 8. 发明专利
    • Reductive nitrogen compound injecting operation method for atomic power plant
    • 减少氮化合物注入原子能发电厂的操作方法
    • JP2005283528A
    • 2005-10-13
    • JP2004101797
    • 2004-03-31
    • Hitachi Ltd株式会社日立製作所
    • AIZAWA MOTOHIROWADA YOICHIISHIDA KAZUNARI
    • G21C19/307G21D1/00G21D3/08
    • Y02E30/40
    • PROBLEM TO BE SOLVED: To suppress stress corrosion cracking (SCC) of materials constituting a reactor core internal structure and a pressure boundary in a boiling water atomic power plant.
      SOLUTION: Hydrogen and a reductive nitrogen compound are injected to reactor cooling water. The injection quantity of the reductive nitrogen compound is controlled by using oxygen concentration and ammonia concentration contained in cooling water at the reactor bottom as an indicator. The injection quantity of the hydrogen is controlled by using the dose rate of a main steam pipe or the hydrogen concentration contained in the cooling water at the reactor bottom as an indicator. Further, hydrazine carbonate, carbon dioxide or carbonate is injected to obtain a tolerance of reactor water quality management and to reduce the plant dose rate.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:抑制沸水原子发电厂中构成反应堆芯内部结构的材料和压力边界的应力腐蚀开裂(SCC)。 解决方案:将氢和还原性氮化合物注入反应器冷却水中。 通过使用反应器底部的冷却水中所含的氧浓度和氨浓度作为指标来控制还原氮化合物的注入量。 通过使用主蒸汽管的剂量率或反应器底部的冷却水中所含的氢浓度作为指标来控制氢的喷射量。 此外,注入碳酸肼,二氧化碳或碳酸盐以获得反应堆水质管理的耐受性并降低植物剂量率。 版权所有(C)2006,JPO&NCIPI
    • 9. 发明专利
    • Corrosion potential sensor
    • 腐蚀潜在传感器
    • JP2005140608A
    • 2005-06-02
    • JP2003376507
    • 2003-11-06
    • Hitachi Ltd株式会社日立製作所
    • WADA YOICHIISHIDA KAZUNARITACHIBANA MASAHIKOAIZAWA MOTOHIRO
    • G01N27/26G01N27/416G21C17/02G21D1/00
    • Y02E30/40
    • PROBLEM TO BE SOLVED: To facilitate the use of a simple structure for a long time, over wide water-quality conditions. SOLUTION: A zirconium electrode 1 is used for an electrode for generating a reference potential and held by a zirconia insulator 2. An end of the zirconium electrode 1 and a core wire 6b of a mineral insulated cable 6 are connected by spot welding. Thermal spraying of zirconia is implemented on a partial surface of the zirconium electrode 1 and the zirconia insulator 2 so as to reduce oxygen diffusion, and a coating film 4 is formed. The reference potential is generated, in a part of the zirconium electrode 1 coated with the coating film 4 and is outputted to an external measuring system via the core wire 6b. COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:为了方便长时间使用简单的结构,在广泛的水质条件下。 解决方案:锆电极1用于产生参考电位并由氧化锆绝缘体2保持的电极。锆电极1的端部和矿物绝缘电缆6的芯线6b通过点焊连接 。 在锆电极1和氧化锆绝缘体2的部分表面上进行氧化锆的热喷涂,以减少氧扩散,形成涂膜4。 在涂覆有涂膜4的锆电极1的一部分中产生参考电位,并通过芯线6b输出到外部测量系统。 版权所有(C)2005,JPO&NCIPI