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    • 4. 发明授权
    • Apparatus for detecting chemical substances and method therefor
    • 用于检测化学物质的装置及其方法
    • US07015464B2
    • 2006-03-21
    • US10780880
    • 2004-02-19
    • Hisashi NaganoIzumi WakiYasuaki Takada
    • Hisashi NaganoIzumi WakiYasuaki Takada
    • H01J44/04G01N24/00
    • H01J49/0027H01J49/0077Y10T436/24
    • An apparatus for detecting chemical substances which is high in sensitivity and selectivity is provided. An organic acid or an organic acid salt is used to generate an organic acid gas from an organic acid gas generator to be mixed with a sample gas for introduction into an ion source for ionization, thereby obtaining a mass spectrum by a mass analysis region. A data processor determines the detection or non-detection of a specific m/z of an organic acid adduct ion obtained by adding a molecule generated from the organic acid to a molecule with specific m/z generated from a target chemical substance to be detected based on the obtained mass spectrum. When there is an ion peak with the m/z of the organic acid adduct ion, the presence of the target chemical substance to be detected is determined, and an alarm is sounded. False detection can be prevented.
    • 提供一种用于检测灵敏度和选择性高的化学物质的装置。 使用有机酸或有机酸盐从有机酸性气体发生器产生有机酸气体,并与用于引入离子源的样品气体混合,从而通过质量分析区域获得质谱。 数据处理器确定通过将由有机酸产生的分子加入到由待检测的目标化学物质产生的特定m / z的分子获得的有机酸加合物的特定m / z的检测或非检测基础上 在获得的质谱上。 当存在有机酸加合离子的m / z的离子峰时,确定要检测的目标化学物质的存在,并发出报警。 可以防止误检。
    • 6. 发明申请
    • Apparatus for detecting chemical substances and method therefor
    • 用于检测化学物质的装置及其方法
    • US20090084950A1
    • 2009-04-02
    • US12216993
    • 2008-07-14
    • Hisashi NaganoIzumi WakiYasuaki Takada
    • Hisashi NaganoIzumi WakiYasuaki Takada
    • H01J49/26
    • H01J49/0027H01J49/0077Y10T436/24
    • An apparatus for detecting chemical substances which is high in sensitivity and selectivity is provided.An organic acid or an organic acid salt is used to generate an organic acid gas from an organic acid gas generator 3 to be mixed with a sample gas for introduction into an ion source 4 for ionization, thereby obtaining a mass spectrum by a mass analysis region 5. A data processor 6 determines the detection or non-detection of a specific m/z of an organic acid adduct ion obtained by adding a molecule generated from the organic acid to a molecule with specific m/z generated from a target chemical substance to be detected based on the obtained mass spectrum. When there is an ion peak with the m/z of the organic acid adduct ion, the presence of the target chemical substance to be detected is determined, and an alarm is sounded.False detection can be prevented.
    • 提供一种用于检测灵敏度和选择性高的化学物质的装置。 使用有机酸或有机酸盐从有机酸气体发生器3产生有机酸性气体,与用于引入离子源4的样品气体混合,从而通过质量分析区域获得质谱 数据处理器6确定通过将由有机酸产生的分子加入到由目标化学物质产生的特定m / z的分子而获得的有机酸加合物的特定m / z的检测或非检测, 基于获得的质谱检测。 当存在有机酸加合离子的m / z的离子峰时,确定要检测的目标化学物质的存在,并发出报警。 可以防止误检。
    • 7. 发明授权
    • Apparatus for detecting chemical substances and method therefor
    • 用于检测化学物质的装置及其方法
    • US07820965B2
    • 2010-10-26
    • US12216993
    • 2008-07-14
    • Hisashi NaganoIzumi WakiYasuaki Takada
    • Hisashi NaganoIzumi WakiYasuaki Takada
    • H01J49/00B01D59/44
    • H01J49/0027H01J49/0077Y10T436/24
    • An apparatus for detecting chemical substances which is high in sensitivity and selectivity is provided.An organic acid or an organic acid salt is used to generate an organic acid gas from an organic acid gas generator 3 to be mixed with a sample gas for introduction into an ion source 4 for ionization, thereby obtaining a mass spectrum by a mass analysis region 5. A data processor 6 determines the detection or non-detection of a specific m/z of an organic acid adduct ion obtained by adding a molecule generated from the organic acid to a molecule with specific m/z generated from a target chemical substance to be detected based on the obtained mass spectrum. When there is an ion peak with the m/z of the organic acid adduct ion, the presence of the target chemical substance to be detected is determined, and an alarm is sounded.False detection can be prevented.
    • 提供一种用于检测灵敏度和选择性高的化学物质的装置。 使用有机酸或有机酸盐从有机酸气体发生器3产生有机酸性气体,与用于引入离子源4的样品气体混合,从而通过质量分析区域获得质谱 数据处理器6确定通过将由有机酸产生的分子加入到由目标化学物质产生的特定m / z的分子而获得的有机酸加合物的特定m / z的检测或非检测, 基于获得的质谱检测。 当存在有机酸加合离子的m / z的离子峰时,确定要检测的目标化学物质的存在,并发出报警。 可以防止误检。
    • 8. 发明授权
    • Apparatus for detecting chemical substances and method therefor
    • 用于检测化学物质的装置及其方法
    • US07408153B2
    • 2008-08-05
    • US11324231
    • 2006-01-04
    • Hisashi NaganoIzumi WakiYasuaki Takada
    • Hisashi NaganoIzumi WakiYasuaki Takada
    • H01J44/04G01N24/00
    • H01J49/0027H01J49/0077Y10T436/24
    • An apparatus for detecting chemical substances which is high in sensitivity and selectivity is provided.An organic acid or an organic acid salt is used to generate an organic acid gas from an organic acid gas generator 3 to be mixed with a sample gas for introduction into an ion source 4 for ionization, thereby obtaining a mass spectrum by a mass analysis region 5. A data processor 6 determines the detection or non-detection of a specific m/z of an organic acid adduct ion obtained by adding a molecule generated from the organic acid to a molecule with specific m/z generated from a target chemical substance to be detected based on the obtained mass spectrum. When there is an ion peak with the m/z of the organic acid adduct ion, the presence of the target chemical substance to be detected is determined, and an alarm is sounded.False detection can be prevented.
    • 提供一种用于检测灵敏度和选择性高的化学物质的装置。 使用有机酸或有机酸盐从有机酸气体发生器3产生有机酸性气体,与用于引入离子源4的样品气体混合,从而通过质量分析区域获得质谱 5。 数据处理器6确定通过将由有机酸产生的分子加入到由待检测的目标化学物质产生的具有特定m / z的分子而获得的有机酸加合物的特定m / z的检测或非检测 基于获得的质谱。 当存在有机酸加合离子的m / z的离子峰时,确定要检测的目标化学物质的存在,并发出报警。 可以防止误检。
    • 9. 发明申请
    • Mass spectrometric apparatus and ion source
    • 质谱仪和离子源
    • US20050199799A1
    • 2005-09-15
    • US11009485
    • 2004-12-13
    • Yasuaki TakadaHisashi NaganoMasao SugaHideo KashimaIzumi Waki
    • Yasuaki TakadaHisashi NaganoMasao SugaHideo KashimaIzumi Waki
    • G01N27/62H01J27/08H01J49/10H01J49/12H01J49/26
    • H01J49/0095H01J49/0422H01J49/168
    • A mass spectrometric apparatus capable of generating and detecting positive and negative ions stably at the same time. The apparatus preferably comprises: an opening through which a sample gas is introduced; an ion source to generate ions of the sample gas; and a mass spectrometer to analyze the mass of the generated ions. The ion source utilized with the mass spectrometric device comprises: a first needle electrode on which a voltage is applied in order to generate positive ions of the sample gas introduced through the opening; a first counter electrode having a first opening through which the sample gas and the positive ions pass; a second counter electrode disposed opposite the first counter electrode having a second opening through which the sample gas and the positive ions pass; a second needle electrode on which voltage is applied in order to generate negative ions of the sample gas; and a vent through which the sample gas is ejected. Generated ions are then introduced into a vacuum region via an aperture and subjected to mass analysis.
    • 能够同时稳定地产生和检测正离子和负离子的质谱仪。 该装置优选地包括:开口,样品气体通过该开口被引入; 用于产生样品气体的离子的离子源; 和用于分析所产生的离子质量的质谱仪。 与质谱仪一起使用的离子源包括:第一针电极,其上施加电压以产生通过开口引入的样品气体的正离子; 第一对电极,其具有第一开口,样品气体和正离子通过该第一开口; 与第一对置电极相对配置的第二对置电极,具有第二开口,样品气体和正离子通过该第二开口; 施加电压以产生样品气体的负离子的第二针状电极; 以及排出样品气体的排气口。 然后将产生的离子经由孔引入真空区域并进行质量分析。