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    • 4. 发明申请
    • Method for producing low thermal expansion Ni-base superalloy
    • 生产低热膨胀Ni基超级合金的方法
    • US20050236079A1
    • 2005-10-27
    • US11115159
    • 2005-04-27
    • Shigeki UetaToshiharu NodaRyuichi YamamotoYoshikuni KadoyaRyotaro MagoshiShin Nishimoto
    • Shigeki UetaToshiharu NodaRyuichi YamamotoYoshikuni KadoyaRyotaro MagoshiShin Nishimoto
    • C22C19/03C22C19/05C22F1/00C22F1/10
    • C22C19/056C22C19/03C22C19/057C22C19/058C22F1/10
    • The present invention provides a method for producing a low thermal expansion Ni-base superalloy, which includes: preparing an alloy including, by weight %, C: 0.15% or less, Si: 1% or less, Mn: 1% or less, Cr: 5 to 20%, at least one of Mo, W and Re, which satisfy the relationship Mo+½(W+Re): 17 to 27%, Al: 0.1 to 2%, Ti: 0.1 to 2%, Nb and Ta, which satisfy the relationship Nb+Ta/2: 1.5% or less, Fe: 10% or less, Co: 5% or less, B: 0.001 to 0.02%, Zr: 0.001 to 0.2%, a reminder of Ni and inevitable components; subjecting the alloy to a solution heat treatment under the condition of at a temperature of 1000 to 1200° C.; subjecting the alloy to either a carbide stabilizing treatment for making aggregated carbides on grain boundaries and stabilizing the carbides under the conditions of at a temperature of not less than 850° C. and less than 1000° C. and for 1 to 50 hours, or a carbide stabilizing treatment for making aggregated carbides on grain boundaries and stabilizing the carbides by cooling from the temperature in the solution heat treatment to 850° C. at a cooling rate of 100° C. or less per hour; subjecting the alloy to a first aging treatment for precipitating γ′ phase under the conditions of at a temperature of 720 to 900° C. and for 1 to 50 hours; and subjecting the alloy to a second aging treatment for precipitating A2B phase under the conditions of at a temperature of 550 to 700° C. and for 5 to 100 hours.
    • 本发明提供一种低热膨胀型Ni基超合金的制造方法,其特征在于,包括:以重量%计含有C:0.15%以下,Si:1%以下,Mn:1%以下的合金, Cr:5〜20%,满足Mo +½(W + Re):17〜27%,Al:0.1〜2%,Ti:0.1〜2%的Mo,W和Re中的至少一种,Nb 和Ta,其满足Nb + Ta / 2:1.5%以下的关系,Fe:10%以下,Co:5%以下,B:0.001〜0.02%,Zr:0.001〜0.2%,提示Ni 和不可避免的组成部分; 在1000〜1200℃的温度下对合金进行固溶热处理; 使合金进行碳化物稳定化处理,在晶界上形成凝集碳化物,并在不低于850℃且小于1000℃的温度和1至50小时的条件下稳定碳化物,或 碳化物稳定化处理,用于通过从固溶热处理中的温度冷却至850℃,以每小时100℃或更低的冷却速度使晶界上的聚集碳化物稳定化; 在720〜900℃的温度和1〜50小时的条件下对合金进行第一时效处理以使γ相析出; 并在550-700℃的温度和5〜100小时的条件下对该合金进行第二时效处理以沉淀A 2 B相。
    • 5. 发明授权
    • Thermal fatigue resistant cast steel
    • 耐热疲劳铸钢
    • US07326307B2
    • 2008-02-05
    • US10395236
    • 2003-03-25
    • Shigeki UetaShuji HamanoToshiharu Noda
    • Shigeki UetaShuji HamanoToshiharu Noda
    • C22C38/48
    • C22C38/60C21D1/34C22C38/02C22C38/04C22C38/44C22C38/48C22C38/50
    • Disclosed is a heat resistant cast steel having not only good heat resistance but also good thermal fatigue resistance, which is suitable as the material for engine parts, particularly, such as exhaust gas manifold and turbo-housing, which are repeatedly exposed to such a high temperature as 900° C. or higher. The heat resistant cast steel comprises, by weight percent, C: 0.2-1.0%, Ni: 8.0-45.0%, Cr: 15.0-30.0%, W: up to 10% and Nb: 0.5-3.0%, provided that [%C]-0.13[%Nb]: 0.05-0.95%, the balance being Fe and inevitable impurities, and the cast structure contains dispersed therein, by atomic percent, MC-type carbides: 0.5-3.0% and M23C6-type carbides: 0.5-10.0%. The matrix of the steel is an austenitic phase mainly composed of Fe—Ni—Cr and the steel has the mean coefficient of thermal expansion in the range from room temperature to 1050° C. up to 20.0×10−4 and a tensile strength in the temperature range up to 1050° C. 50 MPa or higher.
    • 本发明公开了一种不仅具有良好的耐热性,而且具有良好的耐热疲劳性的耐热铸钢,其适合作为反复暴露于这样高的发动机部件,特别是排气歧管和涡轮壳体的材料 温度为900℃以上。 耐热铸钢以C:0.2-1.0%,Ni:8.0-45.0%,Cr:15.0-30.0%,W:至多10%和Nb:0.5-3.0%的重量百分比包含,条件是[% C] -0.13 [%Nb]:0.05-0.95%,余量为Fe和不可避免的杂质,并且铸态结构含有分散在其中的原子百分比为MC-型碳化物:0.5-3.0%和M 23 / 6类型碳化物:0.5-10.0%。 钢的基质是主要由Fe-Ni-Cr组成的奥氏体相,并且钢的平均热膨胀系数在室温至1050℃至20.0×10 -4的范围内 >和在1050℃以上的温度范围内的拉伸强度为50MPa以上。
    • 6. 发明授权
    • Free-cutting Ni-base heat-resistant alloy
    • 易切削Ni基耐热合金
    • US06752883B2
    • 2004-06-22
    • US10158167
    • 2002-05-31
    • Kiyohito IshidaKatsunari OikawaShigeki UetaToshiharu NodaTakashi Ebata
    • Kiyohito IshidaKatsunari OikawaShigeki UetaToshiharu NodaTakashi Ebata
    • C22C1905
    • C22C19/056C22C19/053C22C19/055C22C19/058
    • A free-cutting Ni-base heat-resistant alloy excellent in the high-temperature strength and corrosion resistance was proposed. The alloy contains Ni as a major component, 0.01 to 0.3 wt % of C and 14 to 35 wt % of Cr, and further contains at least one element selected from Ti, Zr and Hf in a total amount of 0.1 to 6 wt %, and S in an amount of 0.015 to 0.5 wt %. The alloy has dispersed in the matrix thereof a machinability improving compound phase, where such phase contains any one of Ti, Zr and Hf as a major constituent of the metal elements, essentially contains C and either S or Se as a binding component for such metal elements. The alloy also satisfies the relations of WTi+0.53WZr+0.27WHf>2WC+0.75WS and WC>0.37WS, where WTi represents Ti content (wt %), WZr represents Zr content (wt %), WHf represents Hf content (wt %), WC represents C content (wt %) and WS represents S content (wt %). This successfully suppresses the amount of free S residing in the alloy, which results in an improved machinability while preventing the hot workability from being degraded.
    • 提出了具有优异耐高温和耐腐蚀性的易切削Ni基耐热合金。 该合金含有Ni作为主要成分,0.01〜0.3重量%的C和14〜35重量%的Cr,还含有选自Ti,Zr和Hf中的至少一种元素,总量为0.1〜6重量% 和S为0.015〜0.5重量%。 该合金在其基体中分散有可机械加工的化合物相,其中这种相含有Ti,Zr和Hf中的任何一种作为金属元素的主要成分,基本上含有C和S或Se作为这种金属的结合成分 元素。 该合金还满足WTi + 0.53WZr + 0.27WHf> 2WC + 0.75WS和WC> 0.37WS的关系,其中WTi表示Ti含量(wt%),WZr表示Zr含量(wt%),WHf表示Hf含量(wt %),WC表示C含量(wt%),WS表示S含量(wt%)。 这成功地抑制了存在于合金中的游离S的量,这导致改善的机械加工性,同时防止热加工性降低。
    • 7. 发明授权
    • Method for producing low thermal expansion Ni-base superalloy
    • 生产低热膨胀Ni基超级合金的方法
    • US08083874B2
    • 2011-12-27
    • US11115159
    • 2005-04-27
    • Shigeki UetaToshiharu NodaRyuichi YamamotoYoshikuni KadoyaRyotaro MagoshiShin Nishimoto
    • Shigeki UetaToshiharu NodaRyuichi YamamotoYoshikuni KadoyaRyotaro MagoshiShin Nishimoto
    • C22F1/10C22C19/05
    • C22C19/056C22C19/03C22C19/057C22C19/058C22F1/10
    • A method for producing a low thermal expansion Ni-base superalloy including the steps of subjecting the alloy to a solution heat treatment under the condition of at a temperature of 1000 to 1200° C. and subjecting the alloy to either a carbide stabilizing treatment for making aggregated carbides on grain boundaries and stabilizing the carbides under the conditions of at a temperature of not less than 850° C. and less than 1000° C. and for 1 to 50 hours, or a carbide stabilizing treatment for making aggregated carbides on grain boundaries and stabilizing the carbides by cooling from the temperature in the solution heat treatment to 850° C. at a cooling rate of 100° C. or less per hour. The method also including the steps of subjecting the alloy to a first aging treatment for precipitating y′ phase under the conditions of at a temperature of 720 to 900° C. and for 1 to 50 hours, and subjecting the alloy to a second aging treatment for precipitating A2B phase under the conditions of at a temperature of 550 to 700° C. and for 5 to 100 hours.
    • 一种生产低热膨胀Ni基超合金的方法,包括以下步骤:在1000-1200℃的温度下对合金进行固溶热处理,并对合金进行碳化物稳定化处理 在不低于850℃,小于1000℃的温度和1〜50小时的条件下,在晶界上凝集的碳化物并使碳化物稳定,或者在晶界上形成碳化碳的碳化物稳定化处理 并且通过从固溶热处理中的温度冷却至850℃,以每小时100℃或更低的冷却速度来稳定碳化物。 该方法还包括以下步骤:在720至900℃的温度和1至50小时的条件下对合金进行第一时效处理以沉淀y相,并对合金进行第二时效处理 用于在550-700℃的温度和5-100小时的条件下沉淀A2B相。
    • 8. 发明授权
    • Ni-base alloy, heat-resistant spring made of the alloy, and process for producing the spring
    • 镍基合金,由合金制成的耐热弹簧,以及弹簧的制造方法
    • US06918972B2
    • 2005-07-19
    • US10371363
    • 2003-02-20
    • Shigeki UetaToshiharu Noda
    • Shigeki UetaToshiharu Noda
    • F16F1/02C22C19/05C22F1/00C22F1/10
    • C22C19/055C22C19/056C22F1/10
    • A Ni-base alloy which has excellent resistance to permanent set at high temperature and which can be produced at low cost, a heat-resistant spring made of the Ni-base alloy, and a process for producing the spring. The Ni-base alloy of the present invention consists of 0.01 to 0.15 mass % of C, 2.0 mass % or less of Si, 2.5 mass % or less of Mn, 12 to 25 mass % of Cr, 5.0 mass % or less of Mo and/or 5.0 mass % or less of W on condition that Mo+W/2 does not exceed 5.0 mass % or less, 1.5 to 3.5 mass % of Ti, 0.7 to 2.5 mass % of Al, 20 mass % or less of Fe, and the balance of Ni and unavoidable impurities. The ratio of Ti/Al in terms of atomic percentage ranges from 0.6 to 1.5 and the total content of Ti and Al ranges from 4.0 to 8.5 atomic %.
    • 具有优异的耐高温永久变形并且可以低成本制造的Ni基合金,由Ni基合金制成的耐热弹簧和制造弹簧的方法。 本发明的Ni基合金由C:0.01〜0.15质量%,Si:2.0质量%以下,Mn:2.5质量%以下,Cr:12〜25质量%,Mo:5.0质量%以下 和/或5.0质量%以下的W,条件是Mo + W / 2不超过5.0质量%以下,Ti为1.5〜3.5质量%,Al为0.7〜2.5质量%,Fe为20质量%以下 ,余量为Ni和不可避免的杂质。 Ti / Al的原子百分比为0.6〜1.5,Ti和Al的总量为4.0〜8.5原子%。