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1. 发明授权

US4620038A Process for producing methyl ethyl ketone 失效
标题翻译：甲基乙基酮的制备方法
公开(公告)号：US4620038A
公开(公告)日：1986-10-28
申请号：US706263
申请日：1985-02-27
申请人： Hirotoshi Tanimoto , Mutsuo Yamada , Yoshijiro Arikawa , Taiji Kamiguchi , Yasuyuki Nishimura , Hiroyuki Kaku
发明人： Hirotoshi Tanimoto , Mutsuo Yamada , Yoshijiro Arikawa , Taiji Kamiguchi , Yasuyuki Nishimura , Hiroyuki Kaku
IPC分类号： B01J31/00 , B01J31/16 , B01J31/18 , B01J31/24 , C07B61/00 , C07C45/00 , C07C45/28 , C07C45/30 , C07C45/34 , C07C49/10 , C07C67/00 , C07F15/00
CPC分类号： C07F15/0093 , B01J31/1845 , B01J31/188 , B01J31/24 , C07C45/28 , C07C45/30 , C07C45/34 , C07F15/0066 , B01J2531/16 , B01J2531/46 , B01J2531/56 , B01J2531/824
摘要： A process for producing methyl ethyl ketone selectively and with a high yield by oxygen-oxidizing 1-butene under mild conditions is provided, which process is characterized by using a composite catalyst containing a complex (MmXn.Ll) capable of forming an oxygen complex by coordination of the complex with oxygen and a complex catalyst (M'm'Xn'.L'l') capable of forming a 1-butene complex by coordination of the complex with 1-butene, wherein M represents a specified transition metal such as Cu; X, an anion; L, an organic phosphorus compound as ligand; M', a specified transition metal such as palladium; L', a nitrile, organic fluorine or phosphorus compound as ligand; m, m', n and n', each a number determined by the valences of the transition metals and the anion; l and l', each the number of ligands.
摘要翻译：提供了在温和条件下通过氧化1-丁烯氧选择性且高收率生产甲基乙基酮的方法，该方法的特征在于使用含有能够形成氧络合物的络合物（MmXn.L1）的复合催化剂，配合物与氧的配位以及能够通过配合物与1-丁烯配位而形成1-丁烯络合物的复合催化剂（M'''n''L'1'），其中M表示特定的过渡金属，例如铜 X，阴离子; L，有机磷化合物作为配体; M'，特定的过渡金属如钯; L'，腈，有机氟或磷化合物作为配体; m，m'，n和n'，每个数字由过渡金属和阴离子的化合价决定; l和l'，每个配体数目。

2. 发明授权

US4605776A Process for producing acetone 失效
标题翻译：丙酮生产工艺
公开(公告)号：US4605776A
公开(公告)日：1986-08-12
申请号：US694099
申请日：1985-01-23
申请人： Taiji Kamiguchi , Mutsuo Yamada , Yoshijiro Arikawa , Takanori Kuwahara , Hirotoshi Tanimoto , Yasuyuki Nishimura , Hiroyuki Kaku
发明人： Taiji Kamiguchi , Mutsuo Yamada , Yoshijiro Arikawa , Takanori Kuwahara , Hirotoshi Tanimoto , Yasuyuki Nishimura , Hiroyuki Kaku
IPC分类号： C07C49/00 , C07C45/27 , C07C45/28 , C07C45/30 , C07C45/32 , C07C45/35 , C07F15/00
CPC分类号： C07F15/0066 , C07C45/27 , C07C45/28 , C07C45/30 , C07C45/35
摘要： A process for producing acetone selectively and with a high yield by oxidizing propylene by means of the combined oxygen in an oxygen complex under milder conditions and at a single stage is provided wherein a composite catalyst comprising as catalyst components, a transition metal complex with the metal ion of which oxygen molecule can coordinate to form an oxygen complex, and another kind transition metal complex with the metal ion of which propylene can coordinate to form a propylene complex is employed, and propylene activated by the complex formation is oxidized by the combined oxygen activated by the complex formation to thereby obtain acetone.
摘要翻译：提供了一种通过在较温和的条件和单一阶段通过在氧络合物中的组合氧氧化丙烯而选择性且高产率的方法，其中复合催化剂包含作为催化剂组分的过渡金属络合物与金属氧分子可以配位以形成氧络合物的离子，以及与丙烯可以配位以形成丙烯络合物的金属离子的另一种过渡金属络合物，并且通过复合氧化活化的丙烯被氧化通过络合物形成从而获得丙酮。

3. 发明授权

US4806692A Process for producing an oxygen-containing organic compound from olefins 失效
标题翻译：从烯烃生产含氧有机化合物的方法
公开(公告)号：US4806692A
公开(公告)日：1989-02-21
申请号：US820004
申请日：1986-01-21
申请人： Mutsuo Yamada , Taiji Kamiguchi , Hirotoshi Tanimoto , Yoshijiro Arikawa , Hiroyuki Kaku , Shigehito Takamoto
发明人： Mutsuo Yamada , Taiji Kamiguchi , Hirotoshi Tanimoto , Yoshijiro Arikawa , Hiroyuki Kaku , Shigehito Takamoto
IPC分类号： C07C47/06 , C07C45/27 , C07C45/28 , C07C45/30 , C07C45/34 , C07F15/00 , C07C45/33
CPC分类号： C07F15/00 , C07C45/27 , C07C45/28 , C07C45/30 , C07C45/34
摘要： A process for producing an oxygen-containing organic compound by oxidizing olefins under milder conditions is provided, which process comprises oxidizing an olefin activated by its complex formation, in the presence of a platinum group metal complex capable of forming an olefin complex through coordination of the platinum group metal with said olefin, and also in the presence of water, and further oxidizing and regenerating the resulting reduced platinum group metal complex with oxygen coordinated with a transition metal and activated thereby.
摘要翻译：提供了一种通过在较温和的条件下氧化烯烃来生产含氧有机化合物的方法，该方法包括在能够形成烯烃络合物的铂族金属配合物的存在下氧化由其络合物形成活化的烯烃，铂族金属与所述烯烃反应，并且还在水的存在下进一步氧化和再生所得到的还原的铂族金属络合物与过渡金属配位的氧并被活化。

4. 发明授权

US4691053A Process for producing organic compounds by utilizing oxygenic complexes 失效
标题翻译：利用氧配合物生产有机化合物的方法
公开(公告)号：US4691053A
公开(公告)日：1987-09-01
申请号：US617187
申请日：1984-06-04
申请人： Mutsuo Yamada , Yasuyuki Nishimura , Yoshijiro Arikawa , Takanori Kuwahara , Taiji Kamiguchi , Hirotoshi Tanimoto
发明人： Mutsuo Yamada , Yasuyuki Nishimura , Yoshijiro Arikawa , Takanori Kuwahara , Taiji Kamiguchi , Hirotoshi Tanimoto
IPC分类号： B01J31/18 , C07C45/38 , C07C45/34 , C07C45/39 , C07C51/235 , C07C51/255 , C07D307/34 , C07D307/89
CPC分类号： B01J31/1845 , B01J2231/70 , B01J2531/16 , B01J2531/17 , B01J2531/46 , B01J2531/48 , B01J2531/56 , B01J2531/57 , B01J2531/842 , B01J2531/845 , B01J2531/847
摘要： A novel process for producing oxygen-containing organic compounds with high selectivity and good yield by oxidizing organic compounds under mild conditions is provided, which process comprises using as a catalyst for the oxidation, a complex (M.sub.m X.sub.n.L.sub.l) consisting of a transition metal compound (M.sub.m X.sub.n) and an organic phosphorous compound (L) as a ligand, wherein M represents a transition metal belonging to group I, group IV.about.VII or iron group in group VIII of the periodic table; X represents an anion such as a halogen; ligand L represents an organic phosphorous compound; and m and n mean a number of the atomic valence of said transition metal (ion) M and said anion X, respectively, and l means a number of said ligand.
摘要翻译：提供了一种通过在温和条件下氧化有机化合物来生产具有高选择性和良好产率的含氧有机化合物的新方法，该方法包括使用由过渡金属化合物组成的络合物（MmXn.Ll）（MmXn）和作为配体的有机磷化合物（L），其中M表示属于元素周期表第I族，第IV族Ⅶ族或第Ⅷ族铁族的过渡金属; X表示阴离子，例如卤素; 配体L表示有机磷化合物; m和n分别表示所述过渡金属（离子）M和所述阴离子X的原子价数，l表示所述配体的数目。

5. 发明授权

US4521631A Process for producing acetaldehyde 失效
标题翻译：乙醛生产方法
公开(公告)号：US4521631A
公开(公告)日：1985-06-04
申请号：US620336
申请日：1984-06-13
申请人： Yasuyuki Nishimura , Mutsuo Yamada , Yoshijiro Arikawa , Taiji Kamiguchi , Takanori Kuwahara , Hirotoshi Tanimoto
发明人： Yasuyuki Nishimura , Mutsuo Yamada , Yoshijiro Arikawa , Taiji Kamiguchi , Takanori Kuwahara , Hirotoshi Tanimoto
IPC分类号： C07C47/06 , C07C45/34 , C07C47/07 , C07C45/28 , C07C45/33
CPC分类号： C07C45/34
摘要： A process for producing acetaldehyde from ethylene under mild reaction conditions, selectively and with high yield is provided, which process comprises preparing a composite catalyst comprising a complex of a transition metal capable of forming an oxygen complex by coordination of oxygen molecule with the metal ion of the transition metal, and a complex of a transition metal capable of forming an ethylene complex by coordination of ethylene with the metal ion of the transition metal, and oxidizing ethylene activated by forming the ethylene complex with the combined oxygen in the oxygen complex, activated by forming the oxygen complex.
摘要翻译：提供了一种在温和的反应条件下，从温和的反应条件下，以高产率从乙烯中生产乙醛的方法，该方法包括制备复合催化剂，该复合催化剂包括能够通过氧分子与氧分子配位的过渡金属配合物与过渡金属和能够通过乙烯与过渡金属的金属离子配位形成乙烯络合物的过渡金属的络合物，以及通过与氧络合物中的组合氧形成乙烯络合物来活化乙烯，由形成氧络合物。

6. 发明授权

US4935549A Process for producing acetic acid 失效
标题翻译：生产乙酸的方法
公开(公告)号：US4935549A
公开(公告)日：1990-06-19
申请号：US35209
申请日：1987-04-06
申请人： Taiji Kamiguchi , Mutsuo Yamada , Yoshijiro Arikawa , Hirotoshi Tanimoto , Yasuyuki Nishimura
发明人： Taiji Kamiguchi , Mutsuo Yamada , Yoshijiro Arikawa , Hirotoshi Tanimoto , Yasuyuki Nishimura
IPC分类号： C07C51/21 , B01J31/00 , C07B61/00 , C07C51/00 , C07C51/25 , C07C53/08 , C07C67/00
CPC分类号： C07C51/25
摘要： A process for producing acetic acid directly from ethylene under mild conditions is provided, wherein ethylene and oxygen are respectively coordinated with the respective transition metals contained in a specified composite catalyst system, and ethylene activated thereby is successively oxidized by two kinds of oxygen complexes contained in the system and having their electric charge states adjusted, the composite catalyst system comprising a complex represented by a formula (MmXn.Ll) and a complex represented by a formula (M'm'Xn'.L'l') wherein is a transition metal of the groups I, IV.about.VII and iron group; X, an anion; L, an organic phosphorus compound as a ligand; M', a transition metal of Pt group; L', a nitrile, organic fluorine compound or organic phosphorus compound as a ligand; m, m', n and n', each a number determined by the valences of the transition metals and anion; and l and l' each the number of ligands.
摘要翻译：提供了一种在温和条件下直接从乙烯生产乙酸的方法，其中乙烯和氧分别与指定的复合催化剂体系中所含的各种过渡金属配位，由此活化的乙烯依次被两种含有该系统并且调整其电荷状态，复合催化剂体系包含由式（MmXn.L1）表示的络合物和由式（M'm'Xn'L'1'）表示的络合物，其中， I，IV差异VII和铁组的金属; X，阴离子; L，有机磷化合物作为配体; M'，Pt族的过渡金属; L'，腈，有机氟化合物或有机磷化合物作为配体; m，m'，n和n'，每个数字由过渡金属和阴离子的化合价决定; 和l和l'各自配体的数目。

7. 发明授权

US08502440B2 Organic electroluminescent light source 有权
标题翻译：有机电致发光光源
公开(公告)号：US08502440B2
公开(公告)日：2013-08-06
申请号：US12989196
申请日：2009-04-10
申请人： Hiroyasu Inoue , Hirotoshi Tanimoto
发明人： Hiroyasu Inoue , Hirotoshi Tanimoto
IPC分类号： H01L51/50
CPC分类号： H01L51/5268 , H01L51/524 , H01L51/5271
摘要： An organic electroluminescent light source device includes, in the following order from a light-emitting surface side, a first transparent electrode layer, a luminescent layer, a second transparent electrode layer, and a reflecting layer, wherein the reflecting layer includes a concavo-convex structure with an average inclination angle of 12 to 45°. An organic electroluminescent light source device includes, in the following order, a first transparent electrode layer, a luminescent layer, a second transparent electrode layer, a diffusing layer, and a reflecting-scattering layer, wherein the diffusing layer has a concavo-convex surface including a concavo-convex structure with an average inclination angle of 17 to 45°.
摘要翻译：一种有机电致发光光源装置，从发光面侧依次包括第一透明电极层，发光层，第二透明电极层和反射层，其中反射层包括凹凸平均倾角为12〜45°的结构。有机电致发光光源装置按照以下顺序包括第一透明电极层，发光层，第二透明电极层，漫射层和反射散射层，其中漫射层具有凹凸表面包括平均倾斜角为17°〜45°的凹凸结构。

8. 发明申请

US20090274618A1 TADG-15: an extracellular serine protease overexpressed in carcinomas 有权
标题翻译： TADG-15：细胞外丝氨酸蛋白酶在癌中过表达
公开(公告)号：US20090274618A1
公开(公告)日：2009-11-05
申请号：US11978259
申请日：2007-10-29
申请人： Timothy J. O'Brien , Hirotoshi Tanimoto
发明人： Timothy J. O'Brien , Hirotoshi Tanimoto
IPC分类号： A61K51/00 , C12N15/00 , C12N1/21 , C12N5/06 , C12N5/04 , C12N15/87 , C12N15/82 , C12N15/11 , A61K31/7088 , A61K39/395 , A61K39/00 , C12Q1/37
CPC分类号： C12N9/6424 , A61K39/00 , C12Q1/6851 , C12Q1/6886 , C12Q2600/136 , Y10T436/25
摘要： The present invention provides DNA encoding a TADG-15 protein as well as a TADG-15 protein. Also provided is a vector capable of expressing the DNA of the present invention adapted for expression in a recombinant cell and regulatory elements necessary for expression of the DNA in the cell. The present invention further provides for methods of inhibiting TADG-15 expression and/or protease activity, methods of detecting TADG-15 mRNA and/or protein and methods of screening for TADG-15 inhibitors. Additionally, the present invention provides for cell-specific targeting via TADG-15 and methods of vaccinating an individual against TADG-15. The methods described are useful in the diagnosis, treatment and prevention of cancer, particularly breast and ovarian cancer.
摘要翻译：本发明提供编码TADG-15蛋白质和TADG-15蛋白质的DNA。还提供了能够表达适于在重组细胞中表达的本发明的DNA的载体和在细胞中表达DNA所需的调节元件。本发明还提供了抑制TADG-15表达和/或蛋白酶活性的方法，检测TADG-15mRNA和/或蛋白质的方法以及筛选TADG-15抑制剂的方法。另外，本发明提供了通过TADG-15进行的细胞特异性靶向和针对TADG-15接种个体的方法。所描述的方法可用于诊断，治疗和预防癌症，特别是乳腺癌和卵巢癌。

9. 发明申请

US20090142328A1 Uses of antileukoprotease in carcinoma 审中-公开
标题翻译：癌细胞中抗白蛋白酶的使用
公开(公告)号：US20090142328A1
公开(公告)日：2009-06-04
申请号：US11906596
申请日：2007-10-03
申请人： Timothy J. O'Brien , Lowell J. Underwood , Hirotoshi Tanimoto , Kazushi Shigemasa
发明人： Timothy J. O'Brien , Lowell J. Underwood , Hirotoshi Tanimoto , Kazushi Shigemasa
IPC分类号： A61K38/48
CPC分类号： A61K38/57 , C12Q1/37 , G01N33/57449
摘要： The present invention provides a method of detecting/monitoring tumor growth and progression in a tissue by measuring the level of antileukoprotease. Also provided is a method of treating an individual having a tumor by administering antileukoprotease to inhibit the activity of stratum corneum chymotryptic enzyme. Specifically, the tumor is an ovarian carcinoma.
摘要翻译：本发明提供了通过测定抗白蛋白酶水平来检测/监测组织中肿瘤生长和进展的方法。还提供了通过施用抗白蛋白酶来抑制角质层糜蛋白酶的活性来治疗患有肿瘤的个体的方法。具体来说，肿瘤是卵巢癌。

10. 发明授权

US5138003A Ring opening method and reaction solution 失效
标题翻译：开环法和反应液
公开(公告)号：US5138003A
公开(公告)日：1992-08-11
申请号：US764992
申请日：1991-09-23
申请人： Kin-ichi Okumura , Munetoshi Nakano , Hirotoshi Tanimoto , Motoyuki Yamato
发明人： Kin-ichi Okumura , Munetoshi Nakano , Hirotoshi Tanimoto , Motoyuki Yamato
IPC分类号： B29C39/00 , B29C45/00 , C08G61/02 , C08G61/06 , C08G61/08
CPC分类号： C08G61/02 , B29K2023/00 , B29K2023/083 , Y02P70/26
摘要： Described herein is an oily, transparent reaction product which is prepared by heat treating at 110.degree.-220.degree. C. a dicyclopentadiene and a vinyl aromatic compound. This reaction product can be polymerized by ring-opening in presence or absence of a norbornene monomer to produce a thermoset polymer. Freezing point of the reaction product is below 10.degree. C.
摘要翻译：本文描述了一种油状透明的反应产物，其通过在110℃-220℃下热处理制备二环戊二烯和乙烯基芳族化合物。该反应产物可以在存在或不存在降冰片烯单体的情况下通过开环聚合以产生热固性聚合物。反应产物的凝固点低于10℃

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