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    • 2. 发明授权
    • Method for producing a skin-formed polyurethane foam molded product
    • 用于生产表皮形成的聚氨酯泡沫模制产品的方法
    • US5437822A
    • 1995-08-01
    • US9096
    • 1993-01-26
    • Hiroshi WadaHisakazu HaradaShoji Hayashida
    • Hiroshi WadaHisakazu HaradaShoji Hayashida
    • C08G18/40C08G18/48C08G18/63C08G18/66B29C44/06
    • C08G18/4804C08G18/409C08G18/4841C08G18/4866C08G18/632C08G18/667C08G2101/0033
    • A method for producing a skin-formed polyurethane foam molded product, which comprises reacting a high molecular weight active hydrogen compound containing at least 80% by weight of a polyoxyalkylene polyol having from 2 to 8 hydroxyl groups and a hydroxyl value of from 3 to 60 (mgKOH/g) and consisting essentially of from 20 to 100% by weight of the following component (a) and from 0 to 80% by weight of the following component (b), a chain extender and a polyisocyanate compound in a closed molding tool in the presence of a catalyst and a blowing agent comprising as the main component, at least one member selected from the group consisting of water, a heat decomposable blowing agent capable of generating a gas upon heat decomposition and an inert gas:(a) a polyoxyalkytene polyol having from 2 to 8 hydroxyl groups and a hydroxyl value X (mgKOH/g) of 3.ltoreq.X.ltoreq.60, provided that when 3.ltoreq.X.ltoreq.32.5, the total unsaturated degree Y(meq/g) is Y.ltoreq.0.04, and when 32.5.ltoreq.X.ltoreq.60, X and Y satisfy the relation of the following formula (I):Y.ltoreq.0.9/(X-10) (1)or a polymer-dispersed polyol having such a polyoxyalkylene polyol as matrix,(b) a polyoxyalkylene polyol other than the above component (a), or a polymer-dispersed polyol having such polyoxyalkylene polyol as matrix.
    • 一种皮肤形成的聚氨酯发泡成型体的制造方法,其特征在于,使含有至少80重量%的含有2〜8个羟基的聚氧化烯多羟基和羟基值为3〜60的高分子量活性氢化合物 (mgKOH / g),并且基本上由以下组分(a)的20至100重量%和以下组分(b)的0至80重量%,闭合模塑中的扩链剂和多异氰酸酯化合物 在催化剂和发泡剂存在下的工具,其包含作为主要成分的至少一种选自水,能够在热分解时产生气体的热分解发泡剂和惰性气体中的至少一种:(a) 具有2至8个羟基并且羟值X(mgKOH / g)为3≤X≤60的聚氧化亚烷基多元醇,条件是当3≤X≤32.5时,总不饱和度Y( meq / g)为Y <= 0.04,当32.5