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1. 发明授权

US4717769A Production of epsilon-caprolactam 失效
标题翻译：生产ε-己内酰胺
公开(公告)号：US4717769A
公开(公告)日：1988-01-05
申请号：US019851
申请日：1987-02-27
申请人： Hiroshi Sato , Kenichi Hirose , Masaru Kitamura , Youichi Umada , Norio Ishii , Hideto Tojima
发明人： Hiroshi Sato , Kenichi Hirose , Masaru Kitamura , Youichi Umada , Norio Ishii , Hideto Tojima
IPC分类号： B01J27/00 , B01J29/04 , B01J29/86 , B01J29/87 , B01J29/88 , B01J29/89 , C07B61/00 , C07D201/04
CPC分类号： C07D201/04 , B01J29/04 , Y02P20/52
摘要： .epsilon.-caprolactam is produced by gas phase catalytic synthesis with high selectivity of lactam wherein cyclohexanone oxime is brought into contact with a crystalline metallo-silicate catalyst having Si/metal atomic ratio is more than 500. The metal moiety in the catalyst is Ga, Fe, B, Zr, Bi, Nb, Zn, Be, Cr, La, Ti, Hf, V and/or Cu.
摘要翻译： ε-己内酰胺通过气相催化合成以内酰胺的高选择性制备，其中环己酮肟与具有Si /金属原子比的结晶金属硅酸盐催化剂接触超过500.催化剂中的金属部分是Ga，Fe ，B，Zr，Bi，Nb，Zn，Be，Cr，La，Ti，Hf，V和/或Cu。

2. 发明授权

US4717770A Process for producing epsilon-caprolactam 失效
标题翻译：生产ε-己内酰胺的方法
公开(公告)号：US4717770A
公开(公告)日：1988-01-05
申请号：US19921
申请日：1987-02-27
申请人： Hiroshi Sato , Kenichi Hirose , Masaru Kitamura , Hideto Tojima , Norio Ishii
发明人： Hiroshi Sato , Kenichi Hirose , Masaru Kitamura , Hideto Tojima , Norio Ishii
IPC分类号： C07B61/00 , B01J25/00 , B01J29/06 , B01J31/00 , B01J31/12 , C07D201/04
CPC分类号： C07D201/04 , Y02P20/52
摘要： .epsilon.-caprolactam is prepared by gas phase catalytic synthesis where cyclohexanone oxime is brought into contact with a crystalline zeolite, for example, aluminosilicate zeolite or metallosilicate zeolite having a constraint index of 1-12 which has been surface treated with an organometallic compound represented by the general formula: R.sub.4-n MX.sub.n wherein R which may be identical or different represent an alkyl group of 1-6 carbon atoms or phenyl group, M represnets Si or Ge, X represents Cl or an alkoxy group of 1-6 carbon atoms and n represents 1 or 2.
摘要翻译： ε-己内酰胺通过气相催化合成法制备，其中环己酮肟与结晶沸石接触，例如具有1-12的约束指数的铝硅酸盐沸石或金属硅酸盐沸石，其已经用由下式表示的有机金属化合物通式R4-nMXn其中R可相同或不同，表示1-6个碳原子的烷基或苯基，M表示Si或Ge，X表示C1或1-6个碳原子的烷氧基，n表示 1或2。

3. 发明授权

US4709024A Production of epsilon-caprolactam 失效
标题翻译：生产ε-己内酰胺
公开(公告)号：US4709024A
公开(公告)日：1987-11-24
申请号：US896008
申请日：1986-08-13
申请人： Hiroshi Sato , Kenichi Hirose , Norio Ishii , Youichi Umada
发明人： Hiroshi Sato , Kenichi Hirose , Norio Ishii , Youichi Umada
IPC分类号： B01J25/00 , B01J29/035 , B01J29/40 , B01J29/70 , C07B61/00 , C07D201/04
CPC分类号： C07D201/04 , Y02P20/52
摘要： .epsilon.-caprolactam is prepared by gas phase catalytic synthesis in which cyclohexanone oxime is brought into contact with crystalline alluminosilicate, for example, ZSM-5 H.sup.+ form) having 1-12 of constraint index, 500 or more, preferably 1000 or more, of Si/Al atomic ratio and 5.mu. equivalent/g or less, preferably 2.mu. equivalent/g, of external acid amount.
摘要翻译： ε-己内酰胺通过气相催化合成法制备，其中环己酮肟与具有1-12约束指数的结晶二硅铝酸盐例如ZSM-5 H +形式接触，其中500重量％以上，优选1000个以上的Si /原子比，5当量/ g以下，优选为2当量/ g的外部酸量。

4. 发明授权

US4654457A Method for selective dealkylation of 1,4-dialkylbenzene 失效
标题翻译： 1,4-二烷基苯的选择性脱烷基化方法
公开(公告)号：US4654457A
公开(公告)日：1987-03-31
申请号：US788290
申请日：1985-10-17
申请人： Hiroshi Sato , Norio Ishii , Kenichi Hirose
发明人： Hiroshi Sato , Norio Ishii , Kenichi Hirose
IPC分类号： C07C4/18 , B01J29/00 , B01J29/40 , B01J29/65 , B01J29/70 , C07B61/00 , C07C1/00 , C07C7/148 , C07C11/02 , C07C15/02 , C07C67/00 , C07C4/12
CPC分类号： B01J29/40 , C07C4/18 , B01J29/65 , B01J29/70 , C07C2529/40 , C07C2529/65 , C07C2529/70 , Y02P20/584
摘要： A method for selectively dealkylating a 1,4-dialkylbenzene in a dialkylbenzene mixture is disclosed, comprising contacting the mixture with a zeolite catalyst which is prepared by the steps of: (1) hydrothermally synthesizing a zeolite from a system in which an alkali metal cation and an organic cation or its precursor coexist and then calcining the zeolite; and (2) modifying the zeolite with a metal or metalloid oxide. This method permits selective dealkylation of a 1,4-dialkylbenzene while maintaining the yield and purity of olefins formed during the dealkylation at high levels.
摘要翻译：公开了一种选择性地使二烷基苯混合物中的1,4-二烷基苯脱烷基的方法，包括使该混合物与沸石催化剂接触，所述沸石催化剂通过以下步骤制备：（1）从其中碱金属阳离子有机阳离子或其前体共存，然后煅烧沸石; 和（2）用金属或准金属氧化物改性沸石。该方法允许1,4-二烷基苯的选择性脱烷基化，同时保持在脱烷基化期间形成的烯烃在高水平下的产率和纯度。

5. 发明授权

US4642409A Method for selective dealkylation of a dialkylbenzene at the paraposition thereof 失效
标题翻译：二苯基苯选择性脱烷基化的方法
公开(公告)号：US4642409A
公开(公告)日：1987-02-10
申请号：US827698
申请日：1986-02-10
申请人： Hiroshi Sato , Norio Ishii , Kenichi Hirose
发明人： Hiroshi Sato , Norio Ishii , Kenichi Hirose
IPC分类号： B01J29/40 , B01J29/65 , B01J29/70 , C07C4/18 , C07C4/12
CPC分类号： B01J29/40 , C07C4/18 , B01J29/65 , B01J29/70 , C07C2529/40 , C07C2529/65 , C07C2529/70
摘要： An industrially excellent method for selectively dealkylating a 1,4-dialkylbenzene in a dialkylbenzene mixture by the use of a specified zeolite catalyst is disclosed, which catalyst is a crystalline zeolite ion-exchanged with sodium ion, potassium ion, potassium ion, rubidium ion, or cesium ion. The specific zeolite catalyst is easy to prepare and allows selective dealkylation of the 1,4-dialkylbenzene and recovery of the formed olefins in a high yield and a high purity.
摘要翻译：公开了通过使用特定的沸石催化剂选择性地使二烷基苯混合物中的1,4-二烷基苯脱烷基化的工业上优异的方法，该催化剂是与钠离子，钾离子，钾离子，铷离子离子交换的结晶沸石，或铯离子。特定的沸石催化剂易于制备，并允许1,4-二烷基苯的选择性脱烷基化和以高产率和高纯度回收形成的烯烃。

6. 发明授权

US5004846A Process for producing nitrobenzenes 失效
公开(公告)号：US5004846A
公开(公告)日：1991-04-02
申请号：US352022
申请日：1989-05-15
申请人： Hiroshi Sato , Kenichi Hirose , Koichi Nagai , Hiroshi Yoshioka , Yoshihiko Nagaoka
发明人： Hiroshi Sato , Kenichi Hirose , Koichi Nagai , Hiroshi Yoshioka , Yoshihiko Nagaoka
IPC分类号： B01J21/16 , B01J23/06 , B01J23/24 , C07B61/00 , C07C67/00 , C07C201/00 , C07C201/08 , C07C205/06 , C07C205/11 , C07C205/12
CPC分类号： C07C201/08
摘要： Nitrobenzenes are prepared by nitrating benzenes in a vapor phase with dilute or concentrated nitric acid wherein the following (A) or (B) is used as a catalyst:(A) acidic sheet clay minerals ion-exchanged with polyvalent metals, or(B) acidic composite oxides comprising oxides of metals belonging to Group IVA of the Mendeleefs' periodic table and tungsten oxide, molybdenum oxide, niobium oxide or zinc oxide.These catalysts have high catalyst activity and selectivity for vapor phase nitration reaction of benzenes with nitric acid and besides the activity is retained for a long time.

7. 发明授权

US06356033B1 Light source using dielectric barrier discharge lamp, and power supply 有权
标题翻译：光源采用介质阻挡放电灯和电源
公开(公告)号：US06356033B1
公开(公告)日：2002-03-12
申请号：US09423312
申请日：2000-02-14
申请人： Masashi Okamoto , Takashi Asahina , Masaki Yoshioka , Takafumi Mizojiri , Kenichi Hirose
发明人： Masashi Okamoto , Takashi Asahina , Masaki Yoshioka , Takafumi Mizojiri , Kenichi Hirose
IPC分类号： H05B3702
CPC分类号： H05B41/24 , H05B41/2806 , Y02B20/22
摘要： A dielectric-barrier discharge lamp light source with a dielectric-barrier discharge lamp, the light source including a discharge plasma space filled with a discharge gas in which excimer molecules are formed by dielectric-barrier discharge, two electrodes adapted to induce a discharge phenomenon in the discharge gas, at least one of the two electrodes being separated from the discharge gas by a dielectric, and a power supply for impressing a substantially cyclical, high-voltage alternating current on the two electrodes of the dielectric-barrier discharge lamp in a manner that when the power supply completes a discharge in the dielectric-barrier discharge lamp and the voltage impressed on the dielectric-barrier discharge lamp changes for a subsequent discharge, there is a period of gradual change in a lamp voltage waveform (Vs(t)) before reaching a voltage required for beginning of the subsequent discharge, wherein subsequent to the period of gradual change, the voltage impressed on the dielectric-barrier discharge lamp by the power supply changes sharply.
摘要翻译：一种具有介质阻挡放电灯的介质阻挡放电灯光源，该光源包括一个填充有放电气体的放电等离子体空间，其中通过电介质阻挡放电形成准分子分子，两个电极适于引起放电现象放电气体，两个电极中的至少一个通过电介质与放电气体分离;以及电源，用于以介电阻挡放电灯的两个电极施加基本上周期性的高压交流电当电源完成介电阻挡放电灯中的放电并且施加在电介质阻挡放电灯上的电压随后的放电而改变时，灯电压波形（Vs（t））的逐渐变化的周期在达到开始后续放电所需的电压之前，其中在逐渐变化的周期之后，施加在电压上的电压电介质阻挡放电灯由电源急剧变化。

8. 外观设计

USD421856S Disc case 失效
公开(公告)号：USD421856S
公开(公告)日：2000-03-28
申请号：US76118
申请日：1997-09-04
申请人： Kazushi Kirihara , Kenichi Hirose
设计人： Kazushi Kirihara , Kenichi Hirose

9. 发明授权

US07390590B2 Battery storage case 失效
标题翻译：电池储存盒
公开(公告)号：US07390590B2
公开(公告)日：2008-06-24
申请号：US10075183
申请日：2002-02-14
申请人： Yoshiaki Wani , Kenichi Hirose
发明人： Yoshiaki Wani , Kenichi Hirose
IPC分类号： H01M2/10
CPC分类号： H01M2/105 , H01M2/1005
摘要： A battery storage case including a main body and a lid portion. In one embodiment, the case includes first and second projection trains formed on the main body and a third projection train formed on the lid portion, wherein the third projection train is adapted to engage one of the first projection train and the second projection train. In one embodiment, a through-hole is formed through a head portion of the lid portion.
摘要翻译：一种电池储存盒，包括主体和盖部。在一个实施例中，壳体包括形成在主体上的第一和第二突出列，以及形成在盖部上的第三突出列，其中第三突出列适于接合第一突出列和第二突出列之一。在一个实施例中，穿过盖部分的头部形成通孔。

10. 发明授权

US6147836A Tape cassette having visible display of remaining tape 失效
标题翻译：磁带盒可以显示剩余磁带
公开(公告)号：US6147836A
公开(公告)日：2000-11-14
申请号：US154769
申请日：1998-09-17
申请人： Hirokazu Odagiri , Kenichi Hirose
发明人： Hirokazu Odagiri , Kenichi Hirose
IPC分类号： G11B23/087 , G11B23/38 , G11B23/02
CPC分类号： G11B23/0875
摘要： A tape cassette having such a structure that a pattern is printed on a surface of a transparent or semi-transparent cassette housing, a scale display portion which becomes a yardstick for a remaining volume for a tape is formed on the lowest layer of this pattern printing portion and this scale display portion can penetratingly be seen from a surface of an opposite side of the cassette housing.
摘要翻译：具有图案印刷在透明或半透明盒壳体的表面上的结构的带盒，在该图案印刷的最低层上形成作为纸带剩余容积的标尺的标尺显示部分部分，并且可以从盒壳体的相对侧的表面上看到该刻度显示部分。

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