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    • 3. 发明授权
    • Apparatus for supplying ozonated ultrapure water
    • 用于提供臭氧超纯水的设备
    • US06409918B1
    • 2002-06-25
    • US09185836
    • 1998-11-04
    • Hiroshi MoritaTetsuo MizuniwaJunichi Ida
    • Hiroshi MoritaTetsuo MizuniwaJunichi Ida
    • C02F178
    • C02F1/78C02F2103/04Y10S210/90
    • An ozonated ultrapure water supply system that prevents reduction of the dissolved ozone concentration in the supply pipe system and maintains the dissolved ozone at points of use along the supply system at desired concentrations. This permits the system to supply ozonated water in long pipes. The system includes a sequential arrangement of a circulatory main pipe 3 for supplying ultrapure water, an ozonated gas supplying device 4, and at least two output branch lines 8 each having a gas/liquid separation device 9 and an ultimate point of use 7. The output branch lines are spaced downstream from the ozonated gas supplying device such that the ozone concentration in the ultrapure water has increased to a stable level and the ozonated ultrapure water at each output branch line is at this same stable ozone concentration.
    • 一种臭氧化的超纯水供应系统,其防止降低供应管系统中的溶解臭氧浓度,并在所需浓度下沿供应系统的使用点维持溶解的臭氧。 这允许系统在长管道中提供臭氧水。 该系统包括用于提供超纯水的循环主管3,臭氧化气体供应装置4和至少两个输出分支管线8的顺序排列,每个输出分支管线8具有气/液分离装置9和最终使用点7。 输出分支管线与臭氧化气体供给装置的下游隔开,使得超纯水中的臭氧浓度增加到稳定水平,并且每个输出分支管线处的臭氧化超纯水处于相同的稳定的臭氧浓度。
    • 5. 发明授权
    • Apparatus for producing water containing dissolved ozone
    • 用于生产含有溶解臭氧的水的装置
    • US06464867B1
    • 2002-10-15
    • US09958890
    • 2001-10-12
    • Hiroshi MoritaOsamu OtaTetsuo MizuniwaKazumi Tsukamoto
    • Hiroshi MoritaOsamu OtaTetsuo MizuniwaKazumi Tsukamoto
    • C02F178
    • C02F1/78B01F3/04099B01F3/04985B01F2003/04886C01B13/10C02F1/32C02F1/44C02F1/68C02F1/725C02F2103/04C02F2103/12C02F2201/782Y10S210/90
    • An apparatus for producing water containing dissolved ozone which comprises (A) a piping for supplying ultrapure water through which ultrapure water is supplied, (B) a catalytic reaction portion which is connected with the piping for supplying ultrapure water and in which the ultrapure water is brought into contact with an oxidation-reduction catalyst, (C) a filtration apparatus by which the ultrapure water treated in the catalytic reaction portion is filtered and (D) an apparatus for dissolving ozone in which ozone is dissolved into the ultrapure water discharged from the filtration apparatus; and an apparatus for producing water containing dissolved ozone which comprises an apparatus for producing ultrapure water which is equipped with an apparatus for irradiating with ultraviolet light, an apparatus for dissolving ozone in which ozone is dissolved into the ultrapure water produced in the apparatus for producing ultrapure water and a catalytic reaction portion which is packed with an oxidation-reduction catalyst and disposed between the apparatus for irradiating with ultraviolet light and the apparatus for dissolving ozone. Substances promoting decomposition of ozone which are contained in ultrapure water in very small amounts are removed and water containing dissolved ozone which shows little decrease in the concentration of ozone and has a great residual fraction of ozone dissolved in water after transportation for a long distance can be obtained.
    • 一种含有溶解臭氧的水的制造装置,其特征在于,包括:(A)供给超纯水的超纯水的配管,(B)与供给超纯水的管道连接的催化反应部,超纯水 与氧化还原催化剂接触,(C)将在催化反应部分处理的超纯水过滤的过滤装置和(D)将臭氧溶解在臭氧中的臭氧溶解装置(D) 过滤装置; 以及含有溶解臭氧的水的制造装置,其特征在于,包括:设置有紫外线照射装置的超纯水的制造装置,将臭氧溶解在超纯水装置中生成的超纯水中的臭氧溶解装置 水和催化反应部分,其被填充有氧化还原催化剂并且设置在用于照射紫外线的装置和用于溶解臭氧的装置之间。 可以除去非常少量促进超纯水中包含的臭氧分解的物质,并且在长距离运输后,溶解臭氧浓度几乎不降低,臭氧溶解在水中的溶解臭氧的含有溶解臭氧的水可以是 获得。
    • 6. 发明申请
    • WAFER WASHING WATER AND WAFER WASHING METHOD
    • WAFER洗衣水和WAFER洗衣方法
    • US20120172273A1
    • 2012-07-05
    • US13496366
    • 2010-09-28
    • Tetsuo MizuniwaShigeyuki Hoshi
    • Tetsuo MizuniwaShigeyuki Hoshi
    • C11D7/60
    • H01L21/02052
    • The invention provides a wafer washing technique which does not require complicated operations and by which a wafer is washed with ultrapure water through relatively simple operations without contaminating the wafer surface with metals even if the ultrapure water contains metal ions on the ng/L (ppt) level. Wafer washing water includes ultrapure water to which a substance having an affinity for metal ions has been added. A wafer washing method uses this wafer washing water. A substance that exhibits an affinity for metal ions is added beforehand to wafer washing ultrapure water. As a result, the substance captures metal ions present in the ultrapure water and stabilizes them in water, thereby effectively preventing the metal ions from migrating toward the wafer surface and becoming attached to the wafer surface during washing.
    • 本发明提供一种不需要复杂操作的晶片清洗技术,即使超纯水在ng / L(ppt)上含有金属离子,通过相对简单的操作也可以用超纯水洗涤晶片,而不会金属污染晶片表面, 水平。 晶片洗涤水包括已经添加了对金属离子具有亲和性的物质的超纯水。 晶圆洗涤方法使用该晶片洗涤水。 向金属离子表现出亲和性的物质预先加入到晶圆洗涤超纯水中。 结果,该物质捕获超纯水中存在的金属离子并将其稳定在水中,从而有效地防止金属离子向晶片表面迁移并在洗涤期间附着于晶片表面。