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1. 发明授权

US5728864A Liquid crystal compound having ferrielectric phase and liquid crystal composition 失效
标题翻译：具有电介质相和液晶组成的液晶化合物
公开(公告)号：US5728864A
公开(公告)日：1998-03-17
申请号：US631092
申请日：1996-04-12
申请人： Yuki Motoyama , Tomoyuki Yui , Masahiro Johno , Maki Ito , Takahiro Matsumoto , Hiroshi Mineta
发明人： Yuki Motoyama , Tomoyuki Yui , Masahiro Johno , Maki Ito , Takahiro Matsumoto , Hiroshi Mineta
IPC分类号： C07C69/94 , C09K19/02 , C09K19/20 , C07C69/76 , C09K19/12 , C09K19/22 , C09K19/30 , C09K19/34
CPC分类号： C09K19/02 , C07C69/94 , C09K19/2021
摘要： A liquid crystal compound of the formula (1) ##STR1## wherein R is a linear alkyl group having 6 to 12 carbon atoms, both X and Y are hydrogen atoms or one of X and Y is a fluorine atom and the other is a hydrogen atom, A is --CF.sub.3 or --C.sub.2 F.sub.5, m is an integer of 2 to 4, n is an integer of 2 to 4, and C* is an asymmetric carbon, having a ferrielectric phase in its phase sequence, or a ferrielectric liquid crystal composition containing the liquid crystal compound of the formula (1) having a ferrielectric phase, may be injected between substrates provided with nonlinear active elements, such as thin film transistors or diodes formed on each pixel, to form an active matrix liquid crystal display device.
摘要翻译：式（1）的液晶化合物其中R为碳原子数为6〜12的直链烷基，X和Y均为氢原子，X和Y中的一个为氟原子，另一方为是氢原子，A是-CF 3或-C 2 F 5，m是2〜4的整数，n是2〜4的整数，C *是其相序中具有电介质相的不对称碳，或包含具有电介质相的式（1）的液晶化合物的电介质液晶组合物可以注入到设置有非线性有源元件的衬底之间，诸如形成在每个像素上的薄膜晶体管或二极管，以形成有源矩阵液晶显示设备。

2. 发明授权

US06258296B1 Fluorine-substituted compounds and ferrielectric liquid-crystal composition containing the same 失效
标题翻译：氟取代的化合物和含有它们的电介质液晶组合物
公开(公告)号：US06258296B1
公开(公告)日：2001-07-10
申请号：US09462988
申请日：2000-01-19
申请人： Masahiro Johno , Yuki Motoyama , Takahiro Matsumoto , Hiroshi Mineta , Tomoyuki Yui
发明人： Masahiro Johno , Yuki Motoyama , Takahiro Matsumoto , Hiroshi Mineta , Tomoyuki Yui
IPC分类号： C09K1920
CPC分类号： C09K19/2007 , C07C69/92 , C09K19/02
摘要： A fluorine-substituted compound of the following general formula (1) or (2), and a ferrielectric liquid crystal composition comprising the above compound and a specific ferrielectric liquid crystal compound, wherein, in the formula (1), each of X1 and X2 is a hydrogen atom, or one of them is a hydrogen atom and the other is a fluorine atom, p is an integer of 0 to 3 and q is an integer of 1 to 3, and in the formula (2), each of X1 and x2 is a hydrogen atom, or one of them is a hydrogen atom and the other is a fluorine atom, p is an integer of 1 to 3 and q is an integer of 1 to 3.
摘要翻译：下述通式（1）或（2）的氟取代的化合物，以及包含上述化合物和特定的电介质液晶化合物的电介质液晶组合物，其中，在式（1）中，X 1和X 2 是氢原子，其中一个为氢原子，另一个为氟原子，p为0〜3的整数，q为1〜3的整数，式（2）中，X 1 x2为氢原子，其中一个为氢原子，另一个为氟原子，p为1〜3的整数，q为1〜3的整数。

3. 发明授权

US5951914A Racemic compound and anti-ferroelectric liquid crystal composition 失效
标题翻译：外消旋化合物和反铁电液晶组合物
公开(公告)号：US5951914A
公开(公告)日：1999-09-14
申请号：US923287
申请日：1997-09-04
申请人： Takahiro Matsumoto , Hiroshi Mineta , Tomoyuki Yui , Masahiro Johno
发明人： Takahiro Matsumoto , Hiroshi Mineta , Tomoyuki Yui , Masahiro Johno
IPC分类号： C07C69/90 , C09K19/20 , C09K19/12
CPC分类号： C07C69/90 , C09K19/2007 , C09K19/2021
摘要： A racemic compound of the formula (1) ##STR1## and an anti-ferroelectric liquid crystal composition consisting essentially of said racemic compound and one anti-ferroelectric liquid crystal compound of the formula (2) or a mixture of two or more compounds selected from anti-ferroelectric liquid crystal compounds of the formula (2), ##STR2## said composition having excellent steepness of threshold, having an anti-ferroelectric phase in a broad temperature range and having the performance of a high response speed and a high contrast.
摘要翻译：式（1）的外消旋化合物和基本上由所述外消旋化合物和式（2）的一种反铁电液晶化合物或两种或更多种选自抗铁电体的化合物的混合物组成的反铁电液晶组合物式（2）的液晶化合物，所述组合物具有优异的阈值陡度，在宽温度范围内具有抗铁电相，具有高响应速度和高对比度的性能。

4. 发明授权

US5976409A Swallow-tail-shaped liquid crystal compound 失效
标题翻译：燕尾形液晶复合物
公开(公告)号：US5976409A
公开(公告)日：1999-11-02
申请号：US99772
申请日：1998-06-19
申请人： Hiroshi Mineta , Masahiro Johno , Tomoyuki Yui , Takahiro Matsumoto
发明人： Hiroshi Mineta , Masahiro Johno , Tomoyuki Yui , Takahiro Matsumoto
IPC分类号： C07C69/94 , C09K19/02 , C09K19/20 , C09K19/12 , C07C69/76
CPC分类号： C09K19/0266 , C07C69/94 , C09K19/2007
摘要： A swallow-tail-shaped liquid crystal compound of the following general formula (1), ##STR1## wherein A is --O--, --COO-- or a single bond (--), m is an integer of 4 to 12, and n is an integer of 2 to 4.The above swallow-tail-shaped liquid crystal compound of the present invention is a novel achiral anti-ferroelectric liquid crystal and can be converted to an optically active anti-ferroelectric liquid crystal by mixing it with an optically active compound as a chiral dopant.
摘要翻译：下述通式（1）的燕尾型液晶化合物，其中A为-O-，-COO-或单键（ - ），m为4〜12的整数，n为整数本发明的燕尾型液晶化合物是新型的非手性反铁电液晶，可以通过将光学活性化合物与光学活性化合物混合而转化为光学活性的反铁电液晶手性掺杂剂。

5. 发明授权

US06217954B1 Phenyl triester compound and anti-ferroelectric liquid crystal composition containing the same 失效
标题翻译：苯基三酯化合物和含有它的反铁电液晶组合物
公开(公告)号：US06217954B1
公开(公告)日：2001-04-17
申请号：US09413482
申请日：1999-10-06
申请人： Yuki Motoyama , Takahiro Matsumoto , Masahiro Johno , Tomoyuki Yui
发明人： Yuki Motoyama , Takahiro Matsumoto , Masahiro Johno , Tomoyuki Yui
IPC分类号： C09K1912
CPC分类号： C09K19/0266 , C07C69/90 , C09K19/2021 , Y10T428/10
摘要： An anti-ferroelectric liquid crystal composition containing a phenyl triester compound of the formula (1), wherein R1 is a linear alkyl group having 6 to 12 carbon atoms, m is an integer of 0 to 3, n is an integer of 1 to 3, and X1 is a hydrogen atom or a fluorine atom, and an anti-ferroelectric liquid crystal compound of the formula (2), wherein R2 is a linear alkyl group having 6 to 12 carbon atoms, X2 is a hydrogen atom or a fluorine atom, A is —CH3 or —CF3, r is 0 or 1 and C* is an asymmetric carbon, provided that when A is —CH3, r is 0 and p is an integer of 4 to 10, that when A is —CF3 and when r is 0, p is an integer of 6 to 8, and further than when A is —CF3 and when r is 1, q is an integer of 5 to 8 and p is 2 or 4. The phenyl triester compound and anti-ferroelectric liquid crystal compound composition is not only improved in response speed but also shows remarkably controlled layer rotation, and it can achieve a simple matrix liquid crystal display device which is free of a change in contrast and is highly reliable in use for a long period of time.
摘要翻译：一种含有式（1）的苯基三酯化合物的反铁电液晶组合物，其中，R 1为碳原子数6〜12的直链烷基，m为0〜3的整数，n为1〜3的整数。，X 1为氢原子或氟原子，式（2）的反铁电液晶化合物，其中，R2为碳原子数6〜12的直链烷基，X2为氢原子或氟原子 A为-CH 3或-CF 3，r为0或1，C *为不对称碳，条件是当A为-CH 3时，r为0，p为4至10的整数，当A为-CF 3和当r为0时，p为6至8的整数，并且当A为-CF 3时，当r为1时，q为5至8的整数，p为2或4.苯基三酯化合物和抗 - 铁电液晶化合物组合物不仅提高了响应速度，而且显示出显着控制的层旋转，并且可以实现简单的矩阵液晶显示装置，其不含ch 相比之下，在长时间使用中是高度可靠的。

6. 发明授权

US5716544A Phenyl ester compound and liquid crystal composition containing the same 失效
标题翻译：苯酯化合物和含有它们的液晶组合物
公开(公告)号：US5716544A
公开(公告)日：1998-02-10
申请号：US635320
申请日：1996-04-19
申请人： Yuki Motoyama , Tomoyuki Yui , Masahiro Johno , Takahiro Matsumoto , Teruyo Tomiyama
发明人： Yuki Motoyama , Tomoyuki Yui , Masahiro Johno , Takahiro Matsumoto , Teruyo Tomiyama
IPC分类号： C07C69/90 , C09K19/02 , C09K19/46 , C09K19/12 , C09K19/20
CPC分类号： C09K19/0266 , C07C69/90 , C09K19/46
摘要： A phenyl ester compound of the following general formula (1), ##STR1## wherein m is an integer of 3 to 8, n is an integer of 3 to 11, both of X.sup.1 and X.sup.2 are hydrogen atoms, or one of X.sup.1 and X.sup.2 is a fluorine atom and the other is a hydrogen atom, and A is a hydrogen atom or --CH.sub.3 ; and an anti-ferroelectric liquid crystal composition containing the above phenyl ester compound and a specific anti-ferroelectric liquid crystal compound or a specific liquid crystal compound having ferrielectric-phase.
摘要翻译：下述通式（1）的苯基酯化合物，其中m为3〜8的整数，n为3〜11的整数，X1和X2均为氢原子，或者为 X1和X2是氟原子，另一个是氢原子，A是氢原子或-CH 3; 以及含有上述苯基酯化合物和特定的抗铁电液晶化合物的反铁电液晶组合物或具有铁电相的特定液晶化合物。

7. 发明授权

US5980780A Racemic compound and anti-ferroelectric liquid crystal composition containing the compound 失效
标题翻译：含有该化合物的外消旋化合物和反铁电液晶组合物
公开(公告)号：US5980780A
公开(公告)日：1999-11-09
申请号：US55211
申请日：1998-04-06
申请人： Yuki Motoyama , Takahiro Matsumoto , Tomoyuki Yui , Masahiro Johno
发明人： Yuki Motoyama , Takahiro Matsumoto , Tomoyuki Yui , Masahiro Johno
IPC分类号： G02F1/13 , C07C69/92 , C09K19/02 , C09K19/20 , C09K19/46 , C09K19/21
CPC分类号： C09K19/0266 , C07C69/92 , C09K19/2021
摘要： A racemic compound of the formula (1) ##STR1## and an anti-ferroelectric liquid crystal composition consisting essentially of said racemic compound and one anti-ferroelectric liquid crystal compound of the formula (2) or a mixture of two or more compounds selected from anti-ferroelectric liquid crystal compounds of the formula (2), ##STR2## said composition of the present invention, exhibiting a small spontaneous polarization and a fast response so that a display device having a high display quality can be achieved.
摘要翻译：式（1）的外消旋化合物和基本上由所述外消旋化合物和式（2）的一种反铁电液晶化合物或两种或更多种选自抗铁电体的化合物的混合物组成的反铁电液晶组合物式（2）的液晶化合物，本发明的所述组合物，具有小的自发极化和快速响应，从而可以实现具有高显示质量的显示装置。

8. 发明授权

US06372308B1 Liquid crystal composition 失效
标题翻译：液晶组成
公开(公告)号：US06372308B1
公开(公告)日：2002-04-16
申请号：US09521956
申请日：2000-03-09
申请人： Yasue Yoshioka , Masahiro Johno , Tomoyuki Yui , Takahiro Matsumoto
发明人： Yasue Yoshioka , Masahiro Johno , Tomoyuki Yui , Takahiro Matsumoto
IPC分类号： C09K1912
CPC分类号： C09K19/0266 , C09K19/2021 , Y10T428/10
摘要： A liquid crystal composition includes (1) an anti-ferroelectric liquid crystal compound of formula (1) and (2) a ferrielectric liquid crystal compound or racemic compound thereof. The composition ratio of (1) to (2) is in the range extending from a value which extends from within 5 mol % of the boundary compositional ratio on the anti-ferroelectric phase side and to within 25 mol % of the boundary compositional ratio on the ferrielectric phase side. The boundary compositional ratio is obtained on the basis of a liquid crystal phase diagram prepared on the basis of conoscopic image observations obtained by changing the mixing ratio of (1) and (2). The liquid crystal composition has the following properties: (b) an optical response in a positive voltage region and a negative voltage region and free or substantially free of hysteresis; and (c) excellent alignment stability. The liquid crystal composition is substantially free from sticking, is excellent in alignment and alignment stability and exhibits a V-letter-shaped optical response so that it can be used in a highly reliable active matrix liquid crystal display device.
摘要翻译：液晶组合物包括（1）式（1）的反铁电液晶化合物和（2）电介质液晶化合物或其外消旋化合物。（1）〜（2）的组成比在从反铁电相侧的边界成分比例的5摩尔％以内的值延伸到边界成分比的25摩尔％以下的范围内电介质相侧。基于通过改变（1）和（2）的混合比获得的虹膜图像观察准备的液晶相图获得边界组成比。液晶组合物具有以下性质：（b）在正电压区域和负电压区域中的光学响应，并且具有自由或基本上没有迟滞; 和（c）极好的取向稳定性。液晶组合物基本上没有粘附，对准和取向稳定性优异，呈V字形的光学响应，因此可用于高可靠性的有源矩阵液晶显示装置。

9. 发明授权

US5938973A Swallow-tailed compound and ferrielectric liquid crystal composition containing the same 失效
标题翻译：燕尾化合物和含有它的电致液晶组合物
公开(公告)号：US5938973A
公开(公告)日：1999-08-17
申请号：US927795
申请日：1997-09-11
申请人： Yuki Motoyama , Tomoyuki Yui , Masahiro Johno , Takahiro Matsumoto
发明人： Yuki Motoyama , Tomoyuki Yui , Masahiro Johno , Takahiro Matsumoto
IPC分类号： G02F1/13 , C07C69/86 , C07C69/90 , C09K19/02 , C09K19/06 , C09K19/20 , C09K19/46 , C09K19/12 , C07C69/76
CPC分类号： C09K19/2021 , C07C69/90 , C09K19/02 , C09K19/06
摘要： A swallow-tailed compound of the following general formula (1), ##STR1## wherein m is an integer of 4 to 10, n is an integer of 2 to 6, p is 0 or 1 and each of X and Y is independently a hydrogen or fluorine atom; and a ferrielectric liquid crystal composition consisting essentially of the swallow-tailed compound of the general formula (1) and a ferrielectric liquid crystal compound of the following general formula (2), ##STR2## wherein R is a linear alkyl group having 6 to 12 carbon atoms, Z is a hydrogen or fluorine atom, r is an integer of 2 to 4 and s is an integer of 2 to 4. The ferrielectric liquid crystal composition has a ferrielectric phase in a broad temperature range and attains a fast response and a large tilt angle in a broad temperature range so that a ferrielectric liquid crystal display device having high display qualities can be provided.
摘要翻译：下述通式（1）的燕尾化合物，其中m为4〜10的整数，n为2〜6的整数，p为0或1，X和Y各自独立地为氢或氟原子; 和基本上由通式（1）的燕尾化合物和以下通式（2）的电介质液晶化合物组成的电介质液晶组合物，其中R是具有6至12个碳原子的直链烷基， Z为氢或氟原子，r为2〜4的整数，s为2〜4的整数。电介质液晶组合物具有宽温度范围内的电介质相，具有快速响应和大倾角在宽的温度范围内，可以提供具有高显示质量的电介质液晶显示装置。

10. 发明授权

US6151095A Anti-ferroelectric liquid crystal cell 失效
标题翻译：反铁电液晶电池
公开(公告)号：US6151095A
公开(公告)日：2000-11-21
申请号：US194203
申请日：1998-11-20
申请人： Yasushi Suzuki , Akira Suguro , Tomoyuki Yui , Masahiro Johno , Takahiro Matsumoto
发明人： Yasushi Suzuki , Akira Suguro , Tomoyuki Yui , Masahiro Johno , Takahiro Matsumoto
IPC分类号： C09K19/02 , C09K19/20 , G02F1/133 , G02F1/141 , C09K19/12
CPC分类号： C09K19/0266 , C09K19/2021 , G02F1/141 , G02F1/13306 , G02F2001/1412
摘要： An antiferroelectric liquid crystal cell having a high-speed response and wide viewing angle characteristic free of an image sticking phenomenon is provided. This antiferroelectric liquid crystal cell is composed of an antiferroelectric liquid crystal material held between a pair of parallel substrates. The antiferroelectric liquid crystal material filled between the parallel substrates has such a characteristic that when a sinusoidal voltage value with a changing reference frequency is applied to the antiferroelectric liquid crystal cell, the imaginary part of the complex dielectric constant obtained by Fourier transform of the output voltage value output from the antiferroelectric liquid crystal cell has no local maximum value within the reference frequency range of 100 Hz to 5 kHz. In other words, this characteristic is similar to a characteristic such that when the real part and the imaginary part of the complex dielectric constant are plotted by using a Cole--Cole plot for each frequency, a characteristic curve having no local maximum value within the reference frequency range of 100 Hz to 5 kHz is obtained.
摘要翻译： PCT No.PCT / JP98 / 01195 Sec。 371日期：1998年11月20日 102（e）1998年11月20日日期PCT 1998年3月19日PCT PCT。 WO98 / 42801 PCT出版物日期1998年10月1日提供了具有无图像残留现象的高速响应和宽视角特征的反铁电液晶单元。该反铁电液晶单元由保持在一对平行基板之间的反铁电液晶材料构成。填充在平行基板之间的反铁电液晶材料具有以下特征：当将具有变化的基准频率的正弦电压值施加到反铁电液晶单元时，通过傅里叶变换输出电压获得的复介电常数的虚部来自反铁电液晶单元的输出值在100Hz至5kHz的参考频率范围内没有局部最大值。换句话说，该特性类似于这样的特性，即当通过使用每个频率的Cole-Cole绘图绘制复介电常数的实部和虚部时，在参考中没有局部最大值的特性曲线获得100Hz至5kHz的频率范围。

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