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    • 4. 发明申请
    • Organic Silane Compound, Method of Producing the Same, and Organic Thin Film Using the Same
    • 有机硅烷化合物,其制造方法和使用其的有机薄膜
    • US20080312463A1
    • 2008-12-18
    • US11658502
    • 2005-08-17
    • Hiroshi ImadaHiroyuki HanatoToshihiro Tamura
    • Hiroshi ImadaHiroyuki HanatoToshihiro Tamura
    • C07F7/02
    • H01L51/0056C07F7/12C07F7/1804H01B1/12H01L51/0012H01L51/0094
    • The present invention provides a highly ordered, crystallized organic thin film superior in electroconductive properties that is resistant to exfoliation, a compound for preparation of the thin film, and a method of producing the same.An organic silane compound, characterized in that a molecule represented by General Formula (I) is substituted with a silyl group.A method of producing the organic silane compound, comprising halogenating a molecule (I) and allowing it to react with a silane derivative.An organic thin film, wherein the organic silane compound molecule is oriented with its silyl group located in the substrate side and the molecule (I) region in the film surface side. (wherein, x1 and x2 are integers satisfying 1≦x1, 1≦x2, and 2≦x1+x2≦8; each of y1 and z1 is independently an integer of 2 to 8; each of y2 and z2 is independently an integer of 0 to 8; and the skeleton may be substituted with a hydrophobic group).
    • 本发明提供了耐剥离性优异的导电性优异的结晶有机薄膜,用于制备薄膜的化合物及其制造方法。 一种有机硅烷化合物,其特征在于由通式(I)表示的分子被甲硅烷基取代。 一种制备有机硅烷化合物的方法,包括使分子(I)卤化并使其与硅烷衍生物反应。 有机薄膜,其中有机硅烷化合物分子以其甲硅烷基位于基片侧和薄膜表面侧的分子(I)区域取向。 (其中,x1和x2是满足1 <= x1,1 <= x2,2 <= x1 + x2 <= 8的整数,y1和z1各自独立地为2〜8的整数,y2和z2分别为 独立地为0〜8的整数,骨架可以被疏水性基团取代)。
    • 5. 发明申请
    • Electron-Conjugated Organic Silane Compound, Functional Organic Thin Film And Production Method Thereof
    • 电子共轭有机硅烷化合物,功能性有机薄膜及其制备方法
    • US20080075950A1
    • 2008-03-27
    • US11632217
    • 2005-07-28
    • Hiroshi ImadaHiroyuki HanatoToshihiro Tamura
    • Hiroshi ImadaHiroyuki HanatoToshihiro Tamura
    • B32B5/00C07F7/08C07F7/18
    • H01B1/127B82Y10/00C07F7/1804H01B1/128H01L51/0068H01L51/0094H01L51/0595Y10T428/261
    • The present invention provides a highly orientated (crystallized) and highly-densely packed functional organic thin film that can be formed in a simple production method by solution method and adsorb tightly to a surface of a substrate, an organic silane compound for preparation of the thin film, and methods of preparing the same. An organic silane compound represented by General Formula; A-B—C—SiX1X2X3 (wherein, A represents a monovalent aliphatic hydrocarbon group having 1 to 30 carbon atoms; B represents an oxygen or sulfur atom; C represents a π-electron-conjugated bivalent organic group; and each of X1 to X3 represents a group giving a hydroxyl group by hydrolysis). A functional organic thin film obtained by using the organic silane compound. A method of producing the organic silane compound, comprising introducing an aliphatic hydrocarbon group A onto a compound represented by General Formula; H—C—H (wherein, C is the same as above) via an ether or thioether bond in Williamson reaction, and additionally introducing a silyl group in reaction thereof with a compound represented by General Formula; X4—SiX1X2X3 (wherein, X1 to X3 are the same as above). A method of producing the functional organic thin film, comprising forming a unimolecular film directly adsorbed on a substrate by hydrolyzing the silyl group in the organic silane compound and allowing the hydrolysate to react with the substrate surface, and washing and removing the unreacted organic silane compound on the unimolecular film with a nonaqueous organic solvent.
    • 本发明提供了一种高取向(结晶)和高密度堆积的功能性有机薄膜,其可以通过溶液法以简单的制备方法形成并且紧密地吸附到基材的表面上,制备薄的有机硅烷化合物 电影及其制作方法。 由通式表示的有机硅烷化合物; (其中,A表示碳原子数1〜30的一价脂肪族烃基,B表示氧原子) 或硫原子; C表示π-电子共轭二价有机基团; X 1〜X 3各自表示通过水解得到羟基的基团)。 通过使用有机硅烷化合物获得的功能性有机薄膜。 一种制备有机硅烷化合物的方法,包括将脂族烃基A引入到由通式表示的化合物上; 在Williamson反应中,通过醚或硫醚键进行H-C-H(其中C与上述相同),另外引入甲硅烷基与通式表示的化合物反应; X 4 -SiX 1 X 2 X 3(其中,X 1〜X 3) X 3与上述相同)。 一种生产该功能性有机薄膜的方法,包括通过水解有机硅烷化合物中的甲硅烷基并使该水解产物与基材表面反应形成直接吸附在基材上的单分子膜,以及洗涤和除去未反应的有机硅烷化合物 在非分子膜上用非水有机溶剂。
    • 7. 发明授权
    • Discharge lamp driving circuit provided with discharge detecting pattern
    • 具有放电检测图案的放电灯驱动电路
    • US07098609B2
    • 2006-08-29
    • US11007712
    • 2004-12-07
    • Shinichi SuzukiHiroshi Imada
    • Shinichi SuzukiHiroshi Imada
    • G05F1/00
    • H05B41/2856
    • In a discharge lamp driving circuit comprising: a transformer having one end of a discharge lamp connected to one end of the secondary side thereof; a current-voltage converting circuit provided at the other end of the discharge lamp and functioning to convert a lamp current to a voltage; and a lamp current controlling pattern provided at the other end of the discharge lamp, there is provided a discharge detecting pattern at a grounding end of the secondary side of the transformer so as to be located close to and in parallel with the lamp current controlling pattern, whereby a voltage induced in the discharge detecting pattern is detected, and the supply of electric power to the secondary side of the transformer is stopped. Thus, the discharge lamp driving circuit is deactivated when a discharge occurs at the wiring at the secondary side of the high-voltage transformer.
    • 一种放电灯驱动电路,包括:变压器,其一端与二次侧的一端连接; 电流 - 电压转换电路,设置在放电灯的另一端并用于将灯电流转换成电压; 以及设置在放电灯的另一端的灯电流控制图案,在变压器的次级侧的接地端设置有放电检测图案,以使其与灯电流控制图案接近并且平行 从而检测出放电检测图案中感应的电压,并且停止向变压器的次级侧供电。 因此,当在高压变压器的次级侧的布线处发生放电时,放电灯驱动电路被去激活。
    • 8. 发明申请
    • Organic compound having functional groups different in elimination reactivity at both terminals, organic thin film, organic device and method of producing the same
    • 在两端具有不同消除反应性的官能团的有机化合物,有机薄膜,有机装置及其制造方法
    • US20070195576A1
    • 2007-08-23
    • US11596980
    • 2005-05-27
    • Hiroshi ImadaHiroyuki HanatoToshihiro Tamura
    • Hiroshi ImadaHiroyuki HanatoToshihiro Tamura
    • G11C17/00B05D7/00B05D1/36B32B13/04C07F7/04
    • H01L51/0512H01L51/0012H01L51/005H01L51/0052H01L51/0056H01L51/0068H01L51/0075H01L51/0094H01L51/0545H01L51/424H01L51/5012H01L2251/308
    • Provided are a single monomolecular film uniform in film thickness and highly ordered in molecule alignment and its multilayer film, an organic compound allowing production of such films at high reproducibility, an organic device superior in electroconductive properties and a method of producing the same. An organic compound represented by Formula: Si(A1)(A2)(A3)-B—Si(A4)(A5)(A6) (A1 to A6 each represent a hydrogen atom, a halogen atom, an alkoxy group or an alkyl group and satisfy the relationship in elimination reactivity of: A1 to A3>A4 to A6; and B represents a bivalent organic group), an organic thin film using the compound, and an organic device having the thin film; A method of producing an organic thin film and organic device, comprising a step of forming a single monomolecular film by allowing the silyl group having A1 to A3 in the organic compound to react with the substrate surface; a step of removing unreacted organic compounds by using a non-aqueous solvent; and a step of forming an additional monomolecular film of the organic compound by using the unreacted silyl groups present on the film surface side of the monomolecular film obtained as the sites for adsorption reaction.
    • 本发明提供一种薄膜均匀且分子排列高度有序的单分子膜及其多层膜,能够以高再现性制造这种膜的有机化合物,导电性优异的有机器件及其制造方法。 由式表示的有机化合物:<?in-line-formula description =“In-line formula”end =“lead”?> Si(A <1> SUP) (A 3+)(A 3+)(A 3+)(A 3 S 5) <?in-line-formula description =“在线公式”end =“tail”?>(A 1 至A 6 各自表示氢原子,卤素 原子,烷氧基或烷基,并且满足下列关系:A 1与A 3 A 4 SUP> 6; B表示二价有机基团),使用该化合物的有机薄膜和具有该薄膜的有机器件; 一种制备有机薄膜和有机装置的方法,包括通过使有机化合物中具有A 1〜3的甲硅烷基形成单一单分子膜的步骤 与基板表面反应; 通过使用非水溶剂除去未反应的有机化合物的步骤; 以及通过使用作为吸附反应位点获得的单分子膜的膜表面侧上存在的未反应的甲硅烷基形成有机化合物的附加单分子膜的工序。
    • 9. 发明申请
    • Discharge lamp driving circuit provided with discharge detecting pattern
    • 具有放电检测图案的放电灯驱动电路
    • US20050134199A1
    • 2005-06-23
    • US11007712
    • 2004-12-07
    • Shinichi SuzukiHiroshi Imada
    • Shinichi SuzukiHiroshi Imada
    • G02F1/133H05B41/24H05B41/285H05B39/04
    • H05B41/2856
    • In a discharge lamp driving circuit comprising: a transformer having one end of a discharge lamp connected to one end of the secondary side thereof; a current-voltage converting circuit provided at the other end of the discharge lamp and functioning to convert a lamp current to a voltage; and a lamp current controlling pattern provided at the other end of the discharge lamp, there is provided a discharge detecting pattern at a grounding end of the secondary side of the transformer so as to be located close to and in parallel with the lamp current controlling pattern, whereby a voltage induced in the discharge detecting pattern is detected, and the supply of electric power to the secondary side of the transformer is stopped. Thus, the discharge lamp driving circuit is deactivated when a discharge occurs at the wiring at the secondary side of the high-voltage transformer.
    • 一种放电灯驱动电路,包括:变压器,其一端与二次侧的一端连接; 电流 - 电压转换电路,设置在放电灯的另一端并用于将灯电流转换成电压; 以及设置在放电灯的另一端的灯电流控制图案,在变压器的次级侧的接地端设置有放电检测图案,以使其与灯电流控制图案接近并且平行 从而检测出放电检测图案中感应的电压,并且停止向变压器的次级侧供电。 因此,当在高压变压器的次级侧的布线处发生放电时,放电灯驱动电路被去激活。