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1. 发明授权

US06896571B2 Methods of manufacturing electron-emitting device, electron source, and image display apparatus 失效
标题翻译：制造电子发射器件，电子源和图像显示装置的方法
公开(公告)号：US06896571B2
公开(公告)日：2005-05-24
申请号：US10372853
申请日：2003-02-26
申请人： Hironobu Mizuno , Takashi Iwaki , Toshihiko Takeda , Noritake Suzuki , Kazuya Miyazaki , Koki Nukanobu
发明人： Hironobu Mizuno , Takashi Iwaki , Toshihiko Takeda , Noritake Suzuki , Kazuya Miyazaki , Koki Nukanobu
IPC分类号： H01J9/02 , H01J1/316 , H01J9/00 , H01J9/04 , H01J9/24 , H01J31/12
CPC分类号： H01J9/027 , H01J31/127
摘要： In a process of reducing a resistivity of a polymer film for carbonization in a surface conduction electron-emitting device, by irradiating an energy beam onto the polymer film, when an energy intensity of the beam given in a unit area in a unit time is assumed to be W W/m2, W satisfies a formula W≧2×T×(ρsub·Csub·λsub/τ)1/2, where T is defined as a temperature ° C. at which the polymer film is heated for one hour in a vacuum degree of 1×10−4 Pa to reduce a resistivity of the polymer film to 0.1 Ω·cm, Csub is a specific heat J/kg·K of the substrate, ρsub is a specific gravity kg/m3 of the substrate, λsub is a heat conductivity W/m·K of the substrate, and τ is an irradiation time in the range of 10−9 sec to 10 sec.
摘要翻译：在降低表面传导电子发射器件中用于碳化的聚合物膜的电阻率的过程中，通过将能量束照射到聚合物膜上，当在单位时间内以单位面积给出的光束的能量强度为假定时 W满足公式W> = 2xTx（rho>>> ambda / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / 其中T定义为聚合物膜在1×10 -4真空度下加热1小时的温度℃ > Pa以将聚合物膜的电阻率降低至0.1Ω·cm，C _{SUB是基质的比热J / kg.K，特别是碱衬底的重力kg / m 3，λ是衬底的热传导率W / mK，τ是在10°范围内的照射时间， -9秒至10秒。}

2. 发明申请

US20050164591A1 Methods of manufacturing electron-emitting device, electron source, and image display apparatus 失效
标题翻译：制造电子发射器件，电子源和图像显示装置的方法
公开(公告)号：US20050164591A1
公开(公告)日：2005-07-28
申请号：US11082785
申请日：2005-03-18
申请人： Hironobu Mizuno , Takashi Iwaki , Toshihiko Takeda , Kazuya Miyazaki , Koki Nukanobu
发明人： Hironobu Mizuno , Takashi Iwaki , Toshihiko Takeda , Kazuya Miyazaki , Koki Nukanobu
IPC分类号： H01J9/02 , H01J1/316 , H01J9/00 , H01J9/04 , H01J9/24 , H01J31/12
CPC分类号： H01J9/027 , H01J31/127
摘要： In a process of reducing a resistivity of a polymer film for carbonization in a surface conduction electron-emitting device, by irradiating an energy beam onto the polymer film, when an energy intensity of the beam given in a unit area in a unit time is assumed to be W W/m2, W satisfies a formula W≧2×T×(ρsub·Csub·λsub/τ)1/2, where T is defined as a temperature ° C. at which the polymer film is heated for one hour in a vacuum degree of 1×10−4 Pa to reduce a resistivity of the polymer film to 0.1 Ω·cm, Csub is a specific heat J/kg·K of the substrate, ρsub is a specific gravity kg/m3 of the substrate, λsub is a heat conductivity W/m·K of the substrate, and τ is an irradiation time in the range of 10−9 sec to 10 sec.
摘要翻译：在降低表面传导电子发射器件中用于碳化的聚合物膜的电阻率的过程中，通过将能量束照射到聚合物膜上，当在单位时间内以单位面积给出的光束的能量强度为假定时 W满足公式W> = 2 xTx（rho＆lt; sub＆gt;。＆lt; sub＆lt; sub＆lt; sub＆lt; 其中T定义为在1×10 -4真空度下将聚合物膜加热1小时的温度℃， SUP> Pa以将聚合物膜的电阻率降低至0.1Ω·cm，C _{SUB是基材的比热J / kg.K，衬底的比重为kg / m 3，λ为衬底的热导率W / mK，τ为10 -9 秒至10秒。}

3. 发明授权

US07077716B2 Methods of manufacturing electron-emitting device, electron source, and image display apparatus 失效
标题翻译：制造电子发射器件，电子源和图像显示装置的方法
公开(公告)号：US07077716B2
公开(公告)日：2006-07-18
申请号：US11082785
申请日：2005-03-18
申请人： Hironobu Mizuno , Takashi Iwaki , Toshihiko Takeda , Kazuya Miyazaki , Koki Nukanobu
发明人： Hironobu Mizuno , Takashi Iwaki , Toshihiko Takeda , Kazuya Miyazaki , Koki Nukanobu
IPC分类号： H01J9/00
CPC分类号： H01J9/027 , H01J31/127
摘要： In a process of reducing a resistivity of a polymer film for carbonization in a surface conduction electron-emitting device, by irradiating an energy beam onto the polymer film, when an energy intensity of the beam given in a unit area in a unit time is assumed to be W W/m2, W satisfies a formula W≧2×T×(ρsub·Csub·λsub/τ)1/2, where T is defined as a temperature ° C. at which the polymer film is heated for one hour in a vacuum degree of 1×10−4 Pa to reduce a resistivity of the polymer film to 0.1 Ω·cm, Csub is a specific heat J/kg·K of the substrate, ρsub is a specific gravity kg/m3 of the substrate, λsub is a heat conductivity W/m·K of the substrate, and τ is an irradiation time in the range of 10−9 sec to 10 sec.
摘要翻译：在降低表面传导电子发射器件中用于碳化的聚合物膜的电阻率的过程中，通过将能量束照射到聚合物膜上，当在单位时间内以单位面积给出的光束的能量强度为假定时 W满足公式W> = 2xTx（rho＆lt; sub＆gt;。＆lt; sub＆lt; sub＆gt;＆lt; 其中T定义为聚合物膜在1×10 -4真空度下加热1小时的温度℃ > Pa以将聚合物膜的电阻率降低至0.1Ω·cm，C _{SUB是基质的比热J / kg.K，特别是碱衬底的重力kg / m 3，λ是衬底的热传导率W / mK，τ是在10°范围内的照射时间， -9秒至10秒。}

4. 发明授权

US06781667B2 Method of manufacturing image-forming apparatus 失效
标题翻译：图像形成装置的制造方法
公开(公告)号：US06781667B2
公开(公告)日：2004-08-24
申请号：US10078456
申请日：2002-02-21
申请人： Takahiro Horiguchi , Hironobu Mizuno , Takashi Iwaki , Masaaki Shibata , Kazuya Miyazaki
发明人： Takahiro Horiguchi , Hironobu Mizuno , Takashi Iwaki , Masaaki Shibata , Kazuya Miyazaki
IPC分类号： G02F113
CPC分类号： H01J9/027 , H01J9/241 , H01J31/127
摘要： This invention provides an image-forming apparatus manufacturing method capable of simplifying the electron-emitting device forming process and manufacturing a low-cost image-forming apparatus exhibiting high display quality for a long term. A plurality of electrode pairs each formed from electrodes are formed on a first substrate. Polymer films for connecting the electrodes are arranged. Then, the polymer films are irradiated with a laser beam or particle beam to reduce the resistances at least partially and change the polymer films into conductive films containing carbon as a main component. A current is flowed between the electrodes to form gaps in parts of the conductive films. The first substrate, and the second substrate on which an image-forming member is arranged are joined via bonding in a reduced-pressure atmosphere, constituting an image-forming apparatus.
摘要翻译：本发明提供了能够简化电子发射器件形成工艺并制造长期显示出高显示质量的低成本成像设备的图像形成装置制造方法。在第一基板上形成由电极形成的多个电极对。布置用于连接电极的聚合物膜。然后，用激光束或粒子束照射聚合物膜，以至少部分地降低电阻，并将聚合物膜改变为含有碳作为主要成分的导电膜。电流在电极之间流动，以在导电膜的一部分中形成间隙。第一基板和其上配置有图像形成部件的第二基板通过在构成图像形成装置的减压气氛中的接合而接合。

5. 发明授权

US07335081B2 Method for manufacturing image-forming apparatus involving changing a polymer film into an electroconductive film 失效
标题翻译：涉及使聚合物膜变为导电膜的图像形成装置的制造方法
公开(公告)号：US07335081B2
公开(公告)日：2008-02-26
申请号：US09941782
申请日：2001-08-30
申请人： Takashi Iwaki , Hironobu Mizuno , Masaaki Shibata , Kazuya Miyazaki
发明人： Takashi Iwaki , Hironobu Mizuno , Masaaki Shibata , Kazuya Miyazaki
IPC分类号： H01J9/00 , H01J9/44 , H01J9/24 , H01J9/04 , H01J9/12
CPC分类号： H01J9/027
摘要： The present invention provides a method for manufacturing an electron-emitting device, comprising a step for forming a polymer film between a pair of electrodes formed on a substrate, a step for giving conductivity to the polymer film by heating, and a step for providing potential difference between the pair of electrodes.
摘要翻译：本发明提供了一种制造电子发射器件的方法，包括在形成在衬底上的一对电极之间形成聚合物膜的步骤，通过加热使聚合物膜导电的步骤和提供电位的步骤一对电极之间的差异。

6. 发明授权

US07104859B2 Methods for manufacturing carbon fibers, electron-emitting device, electron source, image display apparatus, light bulb, and secondary battery using a thermal CVD method 有权
标题翻译：使用热CVD法制造碳纤维，电子发射器件，电子源，图像显示装置，灯泡和二次电池的方法
公开(公告)号：US07104859B2
公开(公告)日：2006-09-12
申请号：US10802854
申请日：2004-03-18
申请人： Takeo Tsukamoto , Shinichi Kawate , Kazunari Oyama , Takahiro Sato , Shin Kitamura , Kazuya Miyazaki , Takashi Iwaki , Akira Shimazu
发明人： Takeo Tsukamoto , Shinichi Kawate , Kazunari Oyama , Takahiro Sato , Shin Kitamura , Kazuya Miyazaki , Takashi Iwaki , Akira Shimazu
IPC分类号： H01J9/00
CPC分类号： B82Y30/00 , B82Y10/00 , B82Y40/00 , C01B32/162 , C23C16/0281 , C23C16/26 , D01F9/1275 , H01J2201/30469 , H01J2209/0223 , Y10T428/2913
摘要： In a method for manufacturing carbon fibers by means of a thermal CVD method through catalysts, the method capable of obtaining a uniform film thickness regardless of a growth position and a growth area on a substrate is provided. The substrate on which a catalyst layer is formed is disposed in a reaction container. An atmosphere in the reaction container is set to be a reduced pressure atmosphere including a carbon containing gas having a partial pressure of 10 Pa or less, and the substrate is heated in the atmosphere to grow carbon fibers on the catalyst layer.
摘要翻译：在通过热CVD法通过催化剂制造碳纤维的方法中，提供了能够获得与基板上的生长位置和生长面积无关的均匀膜厚度的方法。其上形成有催化剂层的基板设置在反应容器中。将反应容器的气氛设定为包含分压为10Pa以下的含碳气体的减压气氛，在大气中加热基板，在催化剂层上生长碳纤维。

7. 发明授权

US08080931B2 Conductive film, electron emitting device and image display apparatus 失效
标题翻译：导电膜，电子发射器件和图像显示装置
公开(公告)号：US08080931B2
公开(公告)日：2011-12-20
申请号：US12183614
申请日：2008-07-31
申请人： Masahiro Terada , Makoto Kojima , Takashi Iwaki , Takeru Mizue , Tsuyoshi Ibe
发明人： Masahiro Terada , Makoto Kojima , Takashi Iwaki , Takeru Mizue , Tsuyoshi Ibe
IPC分类号： H01J1/00
CPC分类号： H01J1/316 , B82Y30/00 , C01G23/047 , C01G51/04 , C01G53/04 , C01P2004/64 , C01P2006/40 , C23C18/1216 , C23C18/1225 , C23C18/127 , C23C18/1295 , C23C30/00 , H01J31/127 , H01J2201/3165 , H01J2329/0489 , Y10T428/26
摘要： A conductive film of thickness of from 3 nm to 50 nm made from a metal or ally formed on a substrate, wherein the ratio of density thereof to bulk density of the metal or alloy is from 0.2 to 0.5, and the ratio of resistivity thereof to bulk resistivity of the metal or alloy is from 100 to 100000.
摘要翻译：由在基板上形成的金属或铝合金制成的厚度为3nm〜50nm的导电膜，其中，所述金属或合金的密度与体积密度之比为0.2〜0.5，电阻率与金属或合金的体电阻率为100〜100000。

8. 发明申请

US20090033223A1 CONDUCTIVE FILM, ELECTRON EMITTING DEVICE AND IMAGE DISPLAY APPARATUS 失效
标题翻译：导电膜，电子发射装置和图像显示装置
公开(公告)号：US20090033223A1
公开(公告)日：2009-02-05
申请号：US12183614
申请日：2008-07-31
申请人： Masahiro Terada , Makoto Kojima , Takashi Iwaki , Takeru Mizue , Tsuyoshi Ibe
发明人： Masahiro Terada , Makoto Kojima , Takashi Iwaki , Takeru Mizue , Tsuyoshi Ibe
IPC分类号： H01J17/49 , B32B5/00
CPC分类号： H01J1/316 , B82Y30/00 , C01G23/047 , C01G51/04 , C01G53/04 , C01P2004/64 , C01P2006/40 , C23C18/1216 , C23C18/1225 , C23C18/127 , C23C18/1295 , C23C30/00 , H01J31/127 , H01J2201/3165 , H01J2329/0489 , Y10T428/26
摘要： A conductive film of thickness of from 3 nm to 50 nm made from a metal or ally formed on a substrate, wherein the ratio of density thereof to bulk density of the metal or alloy is from 0.2 to 0.5, and the ratio of resistivity thereof to bulk resistivity of the metal or alloy is from 100 to 100000.
摘要翻译：由在基板上形成的金属或铝合金制成的厚度为3nm〜50nm的导电膜，其中，所述金属或合金的密度与体积密度之比为0.2〜0.5，电阻率与金属或合金的体电阻率为100〜100000。

9. 发明授权

US06783414B2 Method for manufacturing cathode, electron source, and image forming apparatus 失效
标题翻译：阴极，电子源和图像形成装置的制造方法
公开(公告)号：US06783414B2
公开(公告)日：2004-08-31
申请号：US10054884
申请日：2002-01-25
申请人： Masato Minami , Takashi Iwaki
发明人： Masato Minami , Takashi Iwaki
IPC分类号： H01J944
CPC分类号： H01J9/027 , H01J2201/3165
摘要： A method for manufacturing a cathode comprises the steps of: a process for applying onto a substrate a fluid mixture comprising polymers or precursors to the polymers, fine particles of electroconductive material or organic metal compound, and solvent; a process for removing the solvent by heating the fluid mixture applied on the substrate, thereby obtaining an electroconductive organic film comprising the polymers and the electroconductive material; and a process for forming a gap at a portion of the electroconductive organic film by applying an electrical current thereto. Accordingly, a simple method for manufacturing cathodes, electron sources, and image forming apparatuses with excellent electron emitting properties can be realized.
摘要翻译：一种用于制造阴极的方法包括以下步骤：将在聚合物上包含聚合物或前体的流体混合物，导电材料或有机金属化合物的细颗粒和溶剂施加到基底上的方法; 通过加热施加在基板上的流体混合物来除去溶剂的方法，从而获得包含聚合物和导电材料的导电有机膜; 以及通过向其施加电流在导电有机膜的一部分处形成间隙的工艺。因此，可以实现用于制造具有优异的电子发射特性的阴极，电子源和图像形成装置的简单方法。

10. 发明授权

US6123876A Metal-containing composition for forming electron-emitting device 失效
标题翻译：用于形成电子发射器件的含金属组合物
公开(公告)号：US6123876A
公开(公告)日：2000-09-26
申请号：US627566
申请日：1996-04-04
申请人： Shin Kobayashi , Tsuyoshi Furuse , Satoshi Yuasa , Naoko Miura , Takashi Iwaki , Yasuko Tomida
发明人： Shin Kobayashi , Tsuyoshi Furuse , Satoshi Yuasa , Naoko Miura , Takashi Iwaki , Yasuko Tomida
IPC分类号： H01J1/316 , H01B1/06 , H01B1/14 , H01B1/22
CPC分类号： H01J1/316 , H01J2329/00
摘要： A metal-containing composition contains an organic acid group, a transition metal, an alcohol amine, and water. The alcohol amine is preferably expressed by chemical formula (1):NH.sub.m R1.sub.n (R2OH).sub.3-m-n (1)where R1 is an alkyl group having 1 to 4 carbon atoms, R2 is an alkyl carbon chain having 1 to 4 carbon atoms and m and n are integers of 0 to 2 that satisfy the relationship of (m+n)
摘要翻译：含金属的组合物含有有机酸基，过渡金属，醇胺和水。醇胺优选由化学式（1）表示：NHmR1n（R2OH）3-mn（1）其中R1是具有1至4个碳原子的烷基，R2是具有1至4个碳原子的烷基碳链，m 和n为0〜2的整数，满足关系式（m + n）<3或化学式（2）：NH2CR3R4CHR5（CH2）kOH（2）其中R3为选自H，CH3，CH2OH的取代基， CH 2 CH 3，R 4为H或CH 2 OH，R 5为H或CH 3，k为0〜2的整数。该组合物还可含有水溶性聚合物和/或水溶性多元醇或一元醇。该组合物用于形成电子发射器件。

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