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    • 3. 发明授权
    • Electroless palladium plating bath and electroless palladium plating method
    • 无电镀钯浴和无电镀钯法
    • US07678183B2
    • 2010-03-16
    • US12067662
    • 2006-09-22
    • Akihiko MurasumiSeigo KurosakaHiromu InagawaYukinori Oda
    • Akihiko MurasumiSeigo KurosakaHiromu InagawaYukinori Oda
    • C23C18/44
    • C23C18/44C23C18/1651C23C18/54H01L24/43H01L24/745H01L2224/45664
    • Disclosed is an electroless palladium plating bath containing a palladium compound, at least one complexing agent selected from ammonia and amine compounds, at least one reducing agent selected from phosphinic acid and phosphinates, and at least one unsaturated carboxylic acid compound selected from unsaturated carboxylic acids, unsaturated carboxylic acid anhydrides, unsaturated carboxylates and unsaturated carboxylic acid derivatives. Such an electroless palladium plating bath has high bath stability, and decomposition of the bath hardly occurs. Consequently, the electroless palladium plating bath of the present invention has a longer bath life than conventional electroless palladium plating baths. In addition, this electroless palladium plating bath enables to obtain excellent solder bonding characteristics and wire bonding characteristics since it does not affect plating film characteristics even when it is used for a long time.
    • 公开了含有钯化合物,至少一种选自氨和胺化合物的络合剂,至少一种选自次膦酸和次膦酸盐的还原剂和至少一种选自不饱和羧酸的不饱和羧酸化合物的化学镀钯浴, 不饱和羧酸酐,不饱和羧酸酯和不饱和羧酸衍生物。 这种无电镀钯浴具有高的浴稳定性,并且几乎不发生浴的分解。 因此,本发明的无电镀钯浴比常规化学镀钯浴具有更长的浴寿命。 此外,该无电镀钯浴能够获得优异的焊接特性和引线接合特性,因为即使长时间使用也不影响电镀膜特性。