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    • 2. 发明申请
    • Glass Article and Method of Producing the Same
    • 玻璃制品及其制造方法
    • US20090181843A1
    • 2009-07-16
    • US12084072
    • 2006-10-31
    • Hiromitsu SetoAkihiro KoyamaYukihito Nagashima
    • Hiromitsu SetoAkihiro KoyamaYukihito Nagashima
    • C03C3/095
    • C03C3/087C03C4/02Y10T428/315
    • The present invention provides a glass article using a glass composition including a base glass composition and colorants. The base glass composition includes, expressed in mass %: 65 to 80% of SiO2; 0 to 5% of Al2O3; 0 to 10% of MgO; 0 to 15% of CaO; 5 to 15% of MgO+CaO; 10 to 18% of Na2O; 0 to 5% of K2O; 10 to 20% of Na2O+K2O; and 0 to 5% of B2O3, and the colorants consist essentially of, expressed in mass %: 0.6% to 1.0% of T-Fe2O3; 0.026 to 0.8% of TiO2; 0 to 2.0% of CeO2; 0.01 to 0.03% of CoO; 0 to 0.0008% of Se; and 0.06 to 0.20% of NiO. The glass article has a grayish color tone, and has a visible light transmittance in a range of 15% to 40%, which is measured with the illuminant A at a thickness of 3.1 mm.
    • 本发明提供一种使用玻璃组合物的玻璃制品,所述玻璃组合物包括基础玻璃组合物和着色剂。 基础玻璃组成包括以质量%表示:65〜80%的SiO 2; 0〜5%的Al2O3; 0〜10%的MgO; 0〜15%的CaO; 5〜15%的MgO + CaO; 10〜18%的Na2O; 0〜5%K2O; 10-20%Na2O + K2O; 和0〜5%的B2O3,着色剂基本上由质量%表示:0.6%〜1.0%的T-Fe2O3; 0.026〜0.8%的TiO2; 0〜2.0%的CeO2; 0.01〜0.03%的CoO; 0〜0.0008%的Se; 和0.06〜0.20%的NiO。 玻璃制品具有灰色色调,并且具有15%至40%范围内的可见光透射率,其以3.1mm的厚度用光源A测量。
    • 3. 发明授权
    • Glass article and method of producing the same
    • 玻璃制品及其制造方法
    • US08017537B2
    • 2011-09-13
    • US12084072
    • 2006-10-31
    • Hiromitsu SetoAkihiro KoyamaYukihito Nagashima
    • Hiromitsu SetoAkihiro KoyamaYukihito Nagashima
    • C03C3/087B32B17/00C03B32/00C03B27/044
    • C03C3/087C03C4/02Y10T428/315
    • The present invention provides a glass article using a glass composition including a base glass composition and colorants. The base glass composition includes, expressed in mass %: 65 to 80% of SiO2; 0 to 5% of Al2O3; 0 to 10% of MgO; 0 to 15% of CaO; 5 to 15% of MgO+CaO; 10 to 18% of Na2O; 0 to 5% of K2O; 10 to 20% of Na2O+K2O; and 0 to 5% of B2O3, and the colorants consist essentially of, expressed in mass %: 0.6% to 1.0% of T-Fe2O3; 0.026 to 0.8% of TiO2; 0 to 2.0% of CeO2; 0.01 to 0.03% of CoO; 0 to 0.0008% of Se; and 0.06 to 0.20% of NiO. The glass article has a grayish color tone, and has a visible light transmittance in a range of 15% to 40%, which is measured with the illuminant A at a thickness of 3.1 mm.
    • 本发明提供一种使用玻璃组合物的玻璃制品,所述玻璃组合物包括基础玻璃组合物和着色剂。 基础玻璃组成包括以质量%表示:65〜80%的SiO 2; 0〜5%的Al2O3; 0〜10%的MgO; 0〜15%的CaO; 5〜15%的MgO + CaO; 10〜18%的Na2O; 0〜5%K2O; 10-20%Na2O + K2O; 和0〜5%的B2O3,着色剂基本上由质量%表示:0.6%〜1.0%的T-Fe2O3; 0.026〜0.8%的TiO2; 0〜2.0%的CeO2; 0.01〜0.03%的CoO; 0〜0.0008%的Se; 和0.06〜0.20%的NiO。 玻璃制品具有灰色色调,并且具有15%至40%范围内的可见光透射率,其以3.1mm的厚度用光源A测量。
    • 4. 发明授权
    • Ultraviolet-infrared absorbent low transmittance glass
    • 紫外线 - 红外吸收剂低透光率玻璃
    • US06524713B2
    • 2003-02-25
    • US09884924
    • 2001-06-21
    • Hiromitsu SetoYukihito NagashimaShigekazu Yoshii
    • Hiromitsu SetoYukihito NagashimaShigekazu Yoshii
    • B32B1700
    • C03C3/087C03C4/02C03C4/082C03C4/085Y10S501/904Y10S501/905
    • The ultraviolet/infrared absorbent low transmittance glass has an almost neutral color such as greenish gray, low visible light transmittance, low total solar energy transmittance, and low ultraviolet transmittance, and is suitable for a rear window of a vehicle and capable of protecting privacy. The glass consists of base glass including: 65 to 80 wt. % SiO2; 0 to 5 wt. % Al2O3; 0 to 10 wt. % MgO; 5 to 15 wt. % CaO wherein a total amount of MgO and CaO is between 5 and 15 wt. %; 10 to 18 wt. % Na2O; 0 to 5 wt. % K2O wherein a total amount of Na2O and K2O is between 10 and 20 wt. %; and 0 to 5 wt. % B2O3, and colorants including: 1.25 to 1.5 wt. % total iron oxide (T—Fe2O3) expressed as Fe2O3; 0.01 to 0.019 wt. % CoO; more than 0.0008 wt. % and equal to or less than 0.003 wt. % Se; and 0.055 to 0.1 wt. % NiO. The glass with a thickness between 2 and 5 mm has a visible light transmittance (YA) in a range from 10% to 25% using illuminant “A”, a solar energy transmittance in a range from 5% to 20% and an ultraviolet transmittance (Tuv) of not more than 15%.
    • 紫外线/红外吸收剂低透光率玻璃具有几乎中性的绿色灰色,低可见光透射率,低太阳能透光率和低紫外线透射率,适用于车辆的后窗并且能够保护隐私。 该玻璃由基础玻璃组成,包括:65至80wt。 %SiO2; 0至5wt。 %Al2O3; 0〜10重量% %MgO; 5至15wt。 %CaO,其中MgO和CaO的总量为5至15wt。 %; 10至18wt。 %Na2O; 0至5wt。 %K 2 O,其中Na 2 O和K 2 O的总量为10至20重量%。 %; 和0-5重量% %B 2 O 3,着色剂包括:1.25〜1.5重量% 以Fe2O3表示的总氧化铁(T-Fe2O3)%; 0.01〜0.019重量% %CoO; 大于0.0008重量 %且等于或小于0.003wt。 %Se; 和0.055〜0.1重量% %NiO。 厚度在2和5mm之间的玻璃具有使用光源“A”的10%至25%的范围内的可见光透射率(YA),5%至20%的太阳能透射率和紫外线透射率 (Tuv)不超过15%。
    • 6. 发明授权
    • Ultraviolet/infrared absorbent low transmittance glass
    • 紫外线/红外吸收剂低透光率玻璃
    • US5952255A
    • 1999-09-14
    • US941366
    • 1997-09-30
    • Hiromitsu SetoYukihito NagashimaShigekazu Yoshii
    • Hiromitsu SetoYukihito NagashimaShigekazu Yoshii
    • C03C3/078C03C3/087C03C3/095C03C4/02C03C4/08
    • C03C3/095C03C3/087C03C4/02C03C4/082C03C4/085Y10S501/904Y10S501/905
    • The ultraviolet/infrared absorbent low transmittance glass has an almost neutral greenish color, middle visible light transmittance, low total solar energy transmittance, and low ultraviolet transmittance, and is suitable for a window of a vehicle or a building and capable of preventing degradation and discoloration of interior materials and protecting privacy. The glass consists of base glass including: 65 to 80 wt. % SiO.sub.2 ; 0 to 5 wt. % Al.sub.2 O.sub.3 ; 0 to 10 wt. % MgO; 5 to 15 wt. % CaO wherein a total amount of MgO and CaO is between sand 15 wt. %; 10 to 20 wt. % Na.sub.2 O; 0 to 5 wt. % K.sub.2 O wherein a total amount of Na.sub.2 O and K.sub.2 O is between 10 to 20 wt. %; and 0 to 5 wt. % B.sub.2 O.sub.3, and colorants including: 0.7 to 0.95 wt. % total iron oxide (T-Fe.sub.2 O.sub.3) expressed as Fe.sub.2 O.sub.3 ; 1.1 to 2.3% TiO.sub.2, 0 to 2.0% CeO.sub.2, 0.013 to 0.025 wt. % CoO; 0 to 0.0008% Se; and 0.01 to 0.07% NiO. A visible light transmittance (YA) in a range from 25% to 45% and a total solar energy transmittance is in a range from 10% to 40% at a thickness between 3.1 and 5 mm.
    • 紫外线/红外吸收剂低透光率玻璃具有几乎中性的绿色,中等的可见光透射率,低的太阳能透光率,低的紫外线透射率,并且适用于车辆或建筑物的窗户并且能够防止降解和变色 的室内材料和保护隐私。 该玻璃由基础玻璃组成,包括:65至80wt。 %SiO2; 0至5wt。 %Al2O3; 0〜10重量% %MgO; 5至15wt。 %CaO,其中MgO和CaO的总量在砂15重量%之间。 %; 10〜20重量% %Na2O; 0至5wt。 %K 2 O,其中Na 2 O和K 2 O的总量为10至20wt。 %; 和0-5重量% %B 2 O 3,着色剂包括:0.7〜0.95重量% 以Fe2O3表示的总氧化铁(T-Fe2O3)%; 1.1〜2.3%TiO 2,0〜2.0%CeO 2,0.013〜0.025重量% %CoO; 0〜0.0008%Se; 和0.01〜0.07%的NiO。 25%〜45%范围内的可见光透射率(YA)和总太阳能透射率在3.1〜5mm之间的厚度范围为10%〜40%。
    • 8. 发明授权
    • Ultraviolet and infrared radiation absorbing and low transmitting glass
    • 紫外线和红外辐射吸收和低透光玻璃
    • US5998316A
    • 1999-12-07
    • US979858
    • 1997-11-26
    • Hiromitsu SetoYukihito NagashimaShigekazu Yoshii
    • Hiromitsu SetoYukihito NagashimaShigekazu Yoshii
    • C03C3/078C03C3/087C03C3/091C03C3/095C03C4/02C03C4/08
    • C03C4/082C03C3/087C03C4/02C03C4/085Y10S501/904
    • An ultraviolet and infrared radiation absorbing and low transmitting glass having neutral gray to neutral grayish green tint and also having low visible light and solar energy transmission and a low ultraviolet light transmission, further showing an excellent protection of interior trim of automobiles against deterioration and fading, and also showing privacy protection effect when applied especially to window glass of automobiles and to window glass of buildings. The ultraviolet and infrared radiation absorbing and low transmitting glass comprising in % by weight: basic glass components comprising 65 to 80% SiO.sub.2, 0 to 5% Al.sub.2 O.sub.3, 0 to 10% MgO, 5 to 15% CaO, 5 to 15% MgO+CaO, 10 to 20% Na.sub.2 O, 0 to 5% K.sub.2 O, 10 to 20% Na.sub.2 O+K.sub.2 O, and 0 to 5% B.sub.2 O.sub.3, and coloring components comprising 0.65 to 0.95% total iron oxide (T-Fe.sub.2 O.sub.3) in terms of Fe.sub.2 O.sub.3, 0.9 to 2.3% TiO.sub.2, 0 to 2.0% CeO.sub.2, 0.019 to 0.04% CoO, 0 to 0.002% Se, and 0.01 to 0.2% NiO, wherein the glass has a visible light transmission (YA) and a solar energy transmission (TG) of 30% or less and 10 to 35%, respectively, when the glass has a thickness of 3.1 to 5 mm.
    • 具有中性灰色至中性灰绿色色调的紫外和红外辐射吸收和低透射玻璃,并且还具有低可见光和太阳能透射率以及低紫外光透射率,进一步显示出汽车内部装饰对抗劣化和褪色的极好保护, 并且还特别适用于汽车窗玻璃和建筑物的窗玻璃时的隐私保护效果。 包含重量%的紫外线和红外辐射吸收和低透射玻璃:包含65至80%SiO 2,0至5%Al 2 O 3,0至10%MgO,5至15%CaO,5至15%MgO + CaO,10〜20%Na 2 O,0〜5%K 2 O,10〜20%Na 2 O + K 2 O和0〜5%B 2 O 3,着色成分以Fe 2 O 3换算为0.65〜0.95%的总氧化铁(T-Fe 2 O 3) 0.9〜2.3%的TiO 2,0〜2.0%的CeO 2,0.019〜0.04%的CoO,0〜0.002%的Se和0.01〜0.2%的NiO,其中玻璃具有可见光透过率(YA)和太阳能透射率(TG) 当玻璃的厚度为3.1〜5mm时,分别为30%以下,10〜35%。
    • 9. 发明授权
    • Near infrared absorbent green glass composition, and laminated glass using the same
    • 近红外吸收剂绿色玻璃组合物和使用其的夹层玻璃
    • US07820575B2
    • 2010-10-26
    • US10581980
    • 2004-12-24
    • Yukihito NagashimaHiromitsu SetoHarunori MurakamiHiroyuki Tanaka
    • Yukihito NagashimaHiromitsu SetoHarunori MurakamiHiroyuki Tanaka
    • C03C3/095C03C3/087B32B17/10
    • C03C3/095C03C3/091C03C4/02C03C4/082Y10T428/269Y10T428/31616Y10T428/31627
    • The present invention provides a near-infrared absorbent green glass composition which contains basic glass components and 0.6 to 1.3% total iron oxide amount in terms of Fe2O3 (T-Fe2O3), 0 to 2.0% CeO2 and, 300 ppm or less MnO expressed in units of mass and wherein a mass ratio (FeO ratio) of FeO converted into Fe2O3 relative to the T-Fe2O3 is from 0.21 to 0.35. Further the glass composition satisfies at least one of the following a) and b):a) when the glass composition is formed to have a thickness in the range of 1.3 to 2.4 mm, a visible light transmittance is at least 80%, a total solar energy transmittance is 62% or less, a dominant wavelength is from 500 to 540 nm, and an integrated value obtained by integrating transmittance of every 1 nm in the wavelength from 1100 to 2200 nm is 62000 or less; b) when the glass composition is formed to have a thickness in the range of 3 to 5 mm, a visible light transmittance is at least 70%, a total solar energy transmittance is 45% or less, a dominant wavelength is from 495 to 540 nm, and an integrated value obtained as above is 62000 or less.
    • 本发明提供一种近红外吸收性绿色玻璃组合物,其包含碱性玻璃成分,以Fe2O3(T-Fe2O3)换算为0.6〜1.3%的总铁氧化物量,CeO 2为0〜2.0%,MnO为300ppm以下, 其中相对于T-Fe 2 O 3转化为Fe 2 O 3的FeO的质量比(FeO比)为0.21〜0.35。 此外,玻璃组合物满足以下a)和b)中的至少一个:a)当玻璃组合物形成为具有1.3至2.4mm范围内的厚度时,可见光透射率为至少80%,总共 太阳能透射率为62%以下,主波长为500〜540nm,通过将波长为1100〜2200nm的每1nm的透射率积分而得到的积分值为62000以下。 b)当玻璃组合物形成为厚度在3至5mm的范围内时,可见光透射率为至少70%,总太阳能透射率为45%以下,主波长为495〜540 nm,并且如上获得的积分值为62000以下。
    • 10. 发明申请
    • Near Infrared Absorbent Green Glass Composition, And Laminated Glass Using The Same
    • 近红外吸收剂绿色玻璃组合物和使用其的层压玻璃
    • US20080026211A1
    • 2008-01-31
    • US10581980
    • 2004-12-24
    • Yukihito NagashimaHiromitsu SetoHarunori MurakamiHiroyuki Tanaka
    • Yukihito NagashimaHiromitsu SetoHarunori MurakamiHiroyuki Tanaka
    • C03C4/08C03C27/12C03C3/087C03C3/089C03C3/091C03C3/095
    • C03C3/095C03C3/091C03C4/02C03C4/082Y10T428/269Y10T428/31616Y10T428/31627
    • The present invention provides a near-infrared absorbent green glass composition which contains basic glass components and 0.6 to 1.3% total iron oxide amount in terms of Fe2O3 (T-Fe2O3), 0 to 2.0% CeO2 and, 300 ppm or less MnO expressed in units of mass and wherein a mass ratio (FeO ratio) of FeO converted into Fe2O3 relative to the T-Fe2O3 is from 0.21 to 0.35. Further the glass composition satisfies at least one of the following a) and b): a) when the glass composition is formed to have a thickness in the range of 1.3 to 2.4 mm, a visible light transmittance is at least 80%, a total solar energy transmittance is 62% or less, a dominant wavelength is from 500 to 540 nm, and an integrated value obtained by integrating transmittance of every 1 nm in the wavelength from 1100 to 2200 nm is 62000 or less; b) when the glass composition is formed to have a thickness in the range of 3 to 5 mm, a visible light transmittance is at least 70%, a total solar energy transmittance is 45% or less, a dominant wavelength is from 495 to 540 nm, and an integrated value obtained as above is 62000 or less.
    • 本发明提供一种近红外吸收性绿色玻璃组合物,其含有碱性玻璃成分,以Fe 2 O 3(T-3)计为0.6〜1.3%的总氧化铁量, Fe 2 O 3 3),0〜2.0%CeO 2 2,300ppm以下MnO,以质量单位表示,其中质量比 相对于T-Fe 2 O 3 3转化成Fe 2 O 3 O 3的FeO(FeO比)为 从0.21到0.35。 此外,玻璃组合物满足以下a)和b)中的至少一个:a)当玻璃组合物形成为具有1.3至2.4mm范围内的厚度时,可见光透射率为至少80%,总共 太阳能透射率为62%以下,主波长为500〜540nm,通过将波长为1100〜2200nm的每1nm的透射率积分而得到的积分值为62000以下。 b)当玻璃组合物形成为厚度在3至5mm的范围内时,可见光透射率为至少70%,总太阳能透射率为45%以下,主波长为495〜540 nm,并且如上获得的积分值为62000以下。