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    • 1. 发明授权
    • Chemical amplification type positive resist composition
    • 化学放大型正光刻胶组合物
    • US06548221B2
    • 2003-04-15
    • US10003441
    • 2001-12-06
    • Yasunori UetaniHiroki Inoue
    • Yasunori UetaniHiroki Inoue
    • G03F7004
    • G03F7/039G03F7/0045Y10S430/106Y10S430/115Y10S430/122
    • A positive resist composition is provided which comprises a resin having 2-alkyl-2-adamantyl (meth)acrylate polymerization unit represented by the following formula (I): wherein R1 represents hydrogen or methyl and R2 represents an alkyl, and being insoluble or barely soluble in alkali, but being converted to soluble in alkali by the action of an acid; and an acid generator represented by the following formula (V): wherein Q1, Q2 and Q3 independently represent hydrogen, a hydroxyl group, an alkyl having 1 to 6 carbon atoms or an alkoxy having 1 to 6 carbon atoms, and n is an integer of 4 to 8; and gives a good resolution upon exposure by ArF excimer laser and has little substrate dependency.
    • 提供一种正型抗蚀剂组合物,其包含具有由下式(I)表示的(甲基)丙烯酸2-烷基-2-金刚烷基酯聚合单元的树脂:其中R1表示氢或甲基,R2表示烷基,并且不溶或几乎不溶 可溶于碱,但通过酸的作用转化为可溶于碱;和由下式(V)表示的酸发生剂:其中Q1,Q2和Q3独立地表示氢,羟基,具有1〜 6个碳原子或1〜6个碳原子的烷氧基,n为4〜8的整数。 并且通过ArF准分子激光曝光时给出良好的分辨率,并且基板依赖性很小。
    • 2. 发明授权
    • Chemical amplification type positive resist composition
    • 化学放大型正光刻胶组合物
    • US06383713B1
    • 2002-05-07
    • US09482359
    • 2000-01-14
    • Yasunori UetaniHiroki Inoue
    • Yasunori UetaniHiroki Inoue
    • G03F7004
    • G03F7/039G03F7/0045Y10S430/106Y10S430/115Y10S430/122
    • A positive resist composition is provided which comprises a resin having 2-alkyl-2-adamantyl (meth)acrylate polymerization unit represented by the following formula (I): wherein R1 represents hydrogen or methyl and R2 represents an alkyl, and being insoluble or barely soluble in alkali, but being converted to soluble in alkali by the action of an acid; and an acid generator represented by the following formula (V): wherein Q1, Q2 and Q3 independently represent hydrogen, a hydroxyl group, an alkyl having 1 to 6 carbon atoms or an alkoxy having 1 to 6 carbon atoms, and n is an integer of 4 to 8. The composition exhibits good resolution upon exposure by a ArP excimer laser and has little substrate dependency.
    • 提供一种正型抗蚀剂组合物,其包含具有由下式(I)表示的(甲基)丙烯酸2-烷基-2-金刚烷基酯聚合单元的树脂:其中R1表示氢或甲基,R2表示烷基,并且不溶或几乎不溶 可溶于碱,但通过酸的作用转化为可溶于碱;和由下式(V)表示的酸发生剂:其中Q1,Q2和Q3独立地表示氢,羟基,具有1〜 6个碳原子或具有1至6个碳原子的烷氧基,n是4至8的整数。该组合物在暴露于ArP准分子激光器时表现出良好的分辨率,并且基板依赖性很小。
    • 3. 发明授权
    • Chemical amplification type positive resist
    • 化学放大型正抗蚀剂
    • US06348297B1
    • 2002-02-19
    • US09533986
    • 2000-03-24
    • Yasunori UetaniKenji OohashiHiroki Inoue
    • Yasunori UetaniKenji OohashiHiroki Inoue
    • G03F7004
    • C07C381/12G03F7/0045G03F7/039Y10S430/115Y10S430/122
    • A chemical amplification type positive resist composition which is good in resolution, provide a good pattern profile under exposure using light of wavelength of 220 nm or shorter even when applied on a basic substrate or a low reflectance substrate and which comprises an acid generator comprising an aliphatic sulfonium salt represented by the following formula (I): wherein Q1 represents an alkyl group, Q2 represents an alkyl or a residue of an alicyclic hydrocarbon and m represents an integer of 1 to 8; and onium salt selected from triphenylsulfonium salts represented by the following formula (IIa) and diphenyliodonium salts represented by the following formula (IIb): wherein Q3, Q4, Q5, Q6 and Q7each independently represent a hydrogen atom, a hydroxyl group, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, and q and p represent a integer of 4 to 8; and (2) a resin which has a polymerization unit with a group unstable to an acid, and is insoluble or barely soluble in alkali by itself but changes soluble in alkali by an action of the acid, is provided.
    • 使用分辨率好的化学放大型正光刻胶组合物即使施加在基底或低反射率基底上也能使波长为220nm以下的光即使在曝光下也能提供良好的图案形状,并且包括含有脂肪族 由下式(I)表示的锍盐:其中Q1表示烷基,Q2表示脂肪族烃的烷基或残基,m表示1〜8的整数, 和选自由下式(IIa)表示的三苯基锍盐和下式(IIb)表示的二苯基碘鎓盐的鎓盐:其中Q3,Q4,Q5,Q6和Q7各自独立地表示氢原子,羟基,烷基 具有1至6个碳原子,具有1至6个碳原子的烷氧基,q和p表示4至8的整数; 和(2)具有聚合单元的树脂,其具有对酸不稳定的基团,并且其本身不溶或几乎不溶于碱,但是通过酸的作用变化溶于碱。
    • 5. 发明授权
    • Chemical amplification type positive resist compositions and sulfonium salts
    • 化学扩增型正性抗蚀剂组合物和锍盐
    • US06406830B2
    • 2002-06-18
    • US09849523
    • 2001-05-07
    • Hiroki InoueYasunori Uetani
    • Hiroki InoueYasunori Uetani
    • G03F7004
    • G03F7/0045C07C381/12G03F7/039Y10S430/122Y10S430/123
    • A chemical amplifying type positive resist composition having high transmittance, superior in sensitivity and resolution in a lithography utilizing a light having a wavelength of 220 nm or lower and confering a good profile is provided, Which comprises an aliphatic sulfonium salt represented by the following formula (I): wherein either Q1, Q2, Q3 and Q4 represent an alkyl group or a cycloalkyl group, or Q1 and Q2 and/or Q3 and Q4 form, together with the adjacent sulfur atom, a heterocyclic group, and m represents an integer of 1 to 8; at least one onium salt selected from the group consisting of a triphenylsulfonium salt and a diphenyliodonium salt; and a resin which contains a polymerization unit having a group unstable to an acid, and which is insoluble in alkali by itself but becomes soluble in alkali by the action of an acid.
    • 提供了一种具有高透射率,灵敏度和分辨率优异的化学放大型正光刻胶组合物,其利用波长为220nm或更低的光并具有良好外形的光刻技术,其包括由下式(I)表示的脂族锍盐 ):其中Q1,Q2,Q3和Q4表示烷基或环烷基,或Q1和Q2和/或Q3和Q4与相邻的硫原子一起形成杂环基,m表示1的整数 至8;至少一种选自三苯基锍盐和二苯基碘鎓盐的鎓盐; 和含有具有对酸不稳定的基团的聚合单元的树脂,其本身不溶于碱,但通过酸的作用变得易溶于碱。
    • 7. 发明授权
    • Organic photoelectric converter
    • 有机光电转换器
    • US08723163B2
    • 2014-05-13
    • US12922107
    • 2009-03-05
    • Yasunori Uetani
    • Yasunori Uetani
    • H01L51/54C07D333/02
    • H01L51/0068H01L51/0036H01L51/0039H01L51/0043H01L51/0067H01L51/0072H01L51/0074H01L51/4253Y02E10/549
    • Disclosed is an organic photoelectric conversion device including a pair of electrodes, at least one of which is transparent or semi-transparent, and an organic layer arranged between the electrodes and containing a conjugated polymer compound and a sulfur-containing heterocyclic compound, wherein the sulfur-containing heterocyclic compound has a condensed polycyclic structure or a bithiophene structure. Examples of the sulfur-containing heterocyclic compound include a compound represented by formula (1): (wherein, a plurality of R1's may be the same or different and each represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an alkylthio group, an aryl group, an aryloxy group, an arylthio group, an arylalkyl group, an arylalkoxy group or an arylalkylthio group, and a hydrogen atom or atoms contained in these groups may be substituted by a fluorine atom or atoms; and m represents an integer of 0 to 10) or the like.
    • 公开了一种有机光电转换装置,其包括一对电极,其至少一个是透明或半透明的,并且有机层布置在电极之间并含有共轭高分子化合物和含硫杂环化合物,其中硫 的杂环化合物具有缩合多环结构或双噻吩结构。 含硫杂环化合物的实例包括由式(1)表示的化合物:(其中,多个R 1可以相同或不同,各自表示氢原子,卤素原子,烷基,烷氧基, 烷硫基,芳基,芳氧基,芳硫基,芳烷基,芳烷氧基或芳烷硫基,这些基中所含的氢原子或原子可以被氟原子或原子取代; m 表示0〜10的整数)等。