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    • 1. 发明授权
    • Electrophotographic photoreceptor and electrophotographic printing plate
precursor comprising phthalocyanine pigment and thiobarbituric acid
derivative
    • 电子显微照相机和电泳印刷机前体包含羟基苯甲酸颜料和硫代酸衍生物
    • US5102760A
    • 1992-04-07
    • US584027
    • 1990-09-18
    • Hiroaki YokoyaHiromichi TachikawaSyu WataraiSyunichi KondoSeiji Horie
    • Hiroaki YokoyaHiromichi TachikawaSyu WataraiSyunichi KondoSeiji Horie
    • C07D239/60C07D405/06C07D409/06G03G5/06
    • C07D405/06C07D239/60C07D409/06G03G5/0638G03G5/0661G03G5/0696
    • A novel electrophotographic photoreceptor for copiers or photoprinters is provided comprising a photoconducting layer provided on an electrically conductive support, wherein said photoconducting layer comprises a phthalocyanine pigment and at least one compound represented by the general formula (I) or (II): ##STR1## wherein Z represents a sulfur atom or oxygen atom; R.sup.1 and R.sup.2 may be the same or different and each represents a hydrogen atom, alkyl group, aryl group or aralkyl group; A represents an alkyl group, aryl group, aralkyl group or monovalent heterocyclic group; and B represents an alkylene group, arylene group, polymethylene group or aralkylene group.A novel electrophotographic printing plate precursor is also provided which comprises a photoconducting layer containing at least a photoconducting pigment and a binder resin on an electrically conductive support and is adapted to form a printing plate in an electrophotographic process comprising forming a toner image, and then removing said photoconducting layer from the non-image portions except said toner image portions, characterized in that said photoconducting pigment is a phthalocyanine pigment and said photoconducting layer further comprises a compound represented by the general formula [I] or [II]: ##STR2## wherein Z represents a sulfur atom or oxygen atom; R.sup.1 and R.sup.2 may be the same or different and each represents a hydrogen atom, alkyl group, aryl group or aralkyl group; A represents an alkyl group, aryl group, aralkyl group or monovalent heterocyclic group; and B represents an alkylene group, arylene group, polymethylene group or aralkylene group.
    • 提供了一种用于复印机或照相印刷机的新型电子照相感光体,其包括设置在导电载体上的光导层,其中所述光导层包含酞菁颜料和至少一种由通式(I)或(II)表示的化合物: (I)其中Z表示硫原子或氧原子; R1和R2可以相同或不同,各自表示氢原子,烷基,芳基或芳烷基; A表示烷基,芳基,芳烷基或1价杂环基; B表示亚烷基,亚芳基,多亚甲基或亚芳烷基。 还提供了一种新颖的电子照相印版前体,其包括在导电载体上至少含有光导颜料和粘合剂树脂的光导层,并且适于在电子照相方法中形成印版,包括形成调色剂图像,然后除去 所述光导体层除了所述调色剂图像部分之外的非图像部分,其特征在于所述光导颜料是酞菁颜料,并且所述光导层还包含由通式[I]或[II]表示的化合物:( I)其中Z表示硫原子或氧原子;(II)其中Z表示硫原子或氧原子; R1和R2可以相同或不同,各自表示氢原子,烷基,芳基或芳烷基; A表示烷基,芳基,芳烷基或1价杂环基; B表示亚烷基,亚芳基,多亚甲基或亚芳烷基。
    • 2. 发明授权
    • Electrophotographic photoreceptor containing phthalocyanine
    • US5035969A
    • 1991-07-30
    • US476909
    • 1990-02-08
    • Syunichi KondoHiroaki YokoyaSeiji Horie
    • Syunichi KondoHiroaki YokoyaSeiji Horie
    • G03G5/06
    • G03G5/0629G03G5/0618G03G5/062G03G5/0631G03G5/0637G03G5/0638G03G5/0661
    • A novel electrophotographic photoreceptor for copying machine or photoprinter is provided comprising on an electrically conductive support a photoconductive layer, characterized in that said photoconductive layer contains a phthalocyanine pigment and a compound represented by the general formula (I), (II), (III), (IV) or (VI): ##STR1## wherein Z represents a sulfur or oxygen atom; Ar represents a monovalent aromatic hydrocarbon group or monovalent heterocyclic group; R.sub.3 represents a hydrogen atom, alkyl group, aryl group or aralkyl group; Ar and R.sub.3 may together form a ring; and R.sub.1 and R.sub.2 may be the same or different and each represents an alkyl group, aryl group or aralkyl group, ##STR2## wherein Z represents a sulfur or oxygen atom; R.sub.4 represents an alkyl group, alkoxy group, monovalent or bicyclic condensed aryl group, monocyclic or bicyclic condensed aryloxy group or monovalent group derived from heterocyclic group; the two R.sub.4 's in the general formula (IV) being the same or different; R.sup.5 and R.sup.6 may be the same or different and each represents a hydrogen atom, alkyl group, monocyclic or bicyclic condensed aryl group or monovalent group derived from heterocyclic group; R.sup.7 represents a methylene group, polymethylene group, branched alkanediyl group or arylene group; and R.sup.4 and R.sup.5 or R.sup.5 and R.sup.6 may be connected to each other, ##STR3## wherein Z represents a sulfur or oxygen atom; R.sup.8, R.sup.9, R.sup.10, R.sup.11, R.sup.12 and R.sup.13 may be the same or different and each represents a hydrogen atom, an alkyl group, aryl group or monovalent group derived from heterocyclic group, R.sup.8 and R.sup.9 or R.sup.10 and R.sup.11 being optionally connected to each other; R.sup.8, R.sup.9, R.sup.10 and R.sup.11 in the general formula (V) being optionally connected to each other to form a crosslinked ring; and R.sup.14 represents a divalent arylene group, aralkylene group, polymethylene group or alkylene group.
    • 4. 发明授权
    • Liquid developer for electrostatic photography
    • 静电摄影用液体显影剂
    • US5344694A
    • 1994-09-06
    • US885353
    • 1992-05-19
    • Seiji HorieKenji SanoNobuo SuzukiSyu Watarai
    • Seiji HorieKenji SanoNobuo SuzukiSyu Watarai
    • G03G5/05G03G9/13B32B9/00
    • G03G5/0521G03G9/131G03G9/133Y10T428/24802
    • A liquid developer for electrostatic photography, said liquid developer comprising resin particles dispersed in a non-aqueous solvent having a volume resistivity of at least 10.sup.9 .OMEGA.cm, said dispersed resin particles being obtained by polymerizing(a) at least one member of methyl methacrylate and ethyl methacrylate soluble in said non-aqueous solvent and(b) at least one member selected from the group consisting of acrylic esters and methacrylic esters having an alkyl group having not more than 4 carbon atoms, said esters being soluble in said non-aqueous solvent, but being made insoluble by polymerization,said components (a) and (b) being polymerized in the presence of a dispersion stabilizing resin which is soluble in said non-aqueous solvent, and said dispersion stabilizing resin comprising a graft copolymer formed by polymerizing(i) at least one member of macromonomers (M) having a weight-average molecular weight of 1.times.10.sup.3 to 4.times.10.sup.4, said macromonomers (M) having a polymerizable double bond containing group represented by the formula (I) defined in the specification bonded to one terminal of the main polymer chain, said macromonomers (M) containing at least one member of polymer components represented by formula (II) defined in the specification in the main chain thereof, and(ii) at least one member of monomers represented by formula (III) as defined in the specification,said monomers (a) and (b) being made insoluble by polymerization.
    • 一种用于静电摄影的液体显影剂,所述液体显影剂包括分散在体积电阻率为至少10 9欧米亚厘米的非水溶剂中的树脂颗粒,所述分散的树脂颗粒通过聚合(a)至少一种甲基丙烯酸甲酯和 可溶于所述非水溶剂的甲基丙烯酸乙酯和(b)选自具有不超过4个碳原子的烷基的丙烯酸酯和甲基丙烯酸酯的至少一种,所述酯可溶于所述非水溶剂 但是通过聚合使其不溶,所述组分(a)和(b)在可溶于所述非水溶剂的分散体稳定树脂的存在下聚合,所述分散体稳定树脂包含通过聚合形成的接枝共聚物 i)至少一种重均分子量为1×10 3至4×10 4的大分子单体(M)的成员,所述大分子单体(M)具有可聚合的 所述大分子单体(M)含有在本说明书中定义的至少一种由式(II)表示的聚合物组分的组分中的至少一种聚合物组分, 其主链,和(ii)说明书中定义的至少一种由式(III)表示的单体,所述单体(a)和(b)通过聚合而不溶解。
    • 6. 发明授权
    • Lithographic printing plate
    • 平版印刷版
    • US5637428A
    • 1997-06-10
    • US526980
    • 1995-09-12
    • Seiji HorieSyunichi Kondo
    • Seiji HorieSyunichi Kondo
    • G03F7/004G03F7/027G03G5/05G03G9/135G03G13/28G03G13/26
    • G03G9/135G03F7/0045G03F7/027G03G13/28G03G5/0514G03G5/0517G03G5/0521G03G5/0542G03G5/0546
    • A lithographic printing plate formed by charging a printing original plate which comprises an electroconductive support and provided thereon at least one photosensitive layer containing a photoconductive compound and a positive working photosensitive composition, imagewise exposing the printing original plate to form a latent image, forming a toner image with a liquid developer, exposing the whole surface of the positive working photosensitive composition with an active light, and removing the photosensitive layer in a non-image area other than the toner image area with an eluting solution comprising an alkaline solvent is disclosed. The positive working photosensitive composition contains (a) a compound having at least two enol ether groups represented by formula (I):(R.sup.2)(R.sup.1)C.dbd.C(R.sup.3)--O-- (I)wherein R.sup.1, R.sup.2 and R.sup.3 are defined in the disclosure, (b) a linear polymer having an acid group and/or hydroxy group, and (c) a compound which generates an acid by decomposition upon irradiation with the active light, and wherein the component (a) and the component (b) are thermally crosslinked during or after formation of the photosensitive layer. The lithographic printing plate precursor according to the present invention has a high sensitivity to a semiconductor laser light source, a shortened time for the whole surface exposure and an enlarged elusion latitude, and provides a lithographic printing plate having good printing image reproducibility and printing durability.
    • 一种平版印刷版,其通过对包含导电性支持体的印刷原版进行充电而形成,所述印刷原版在其上设置有至少一层含有光导性化合物和正性感光性组合物的感光层,成像曝光印刷原版以形成潜像,形成调色剂 用液体显影剂形成图像,用活性光曝光正性光敏组合物的整个表面,并用含有碱性溶剂的洗脱溶液除去调色剂图像区域之外的非图像区域中的感光层。 正性工作感光性组合物含有(a)具有式(I)表示的至少两个烯醇醚基的化合物:(R2)(R1)C = C(R3)-O-(Ⅰ)其中R1,R2和R3为 在本发明中限定,(b)具有酸基和/或羟基的线性聚合物,和(c)在用活性光照射时通过分解产生酸的化合物,其中组分(a)和组分 (b)在形成感光层期间或之后被热交联。 根据本发明的平版印刷版原版具有对半导体激光光源的高灵敏度,整个表面曝光的缩短时间和缩小的纬度,并提供具有良好的印刷图像再现性和印刷耐久性的平版印刷版。