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1. 发明授权

US6074981A Photocatalyst and process for the preparation thereof 失效
标题翻译：光催化剂及其制备方法
公开(公告)号：US6074981A
公开(公告)日：2000-06-13
申请号：US51223
申请日：1998-04-03
申请人： Hiroaki Tada , Koji Shimoda , Toshiya Ito , Akihiko Hattori
发明人： Hiroaki Tada , Koji Shimoda , Toshiya Ito , Akihiko Hattori
IPC分类号： B01D53/86 , B01D53/88 , B01J35/00 , C03C17/25 , C03C17/34 , B01J27/06 , B01J27/135
CPC分类号： C03C17/256 , B01D53/8687 , B01D53/885 , B01J35/002 , B01J35/004 , C03C17/3417 , B01D2255/802 , C03C2217/212 , C03C2217/241 , C03C2217/71 , C03C2218/10
摘要： Fluorine contained within a photocatalyst layer containing titanium oxide and other metallic oxide semiconductors increases the metallic oxide's photocatalytic activity. The described photocatalyst may be in the form of either film, flake, particulate, or fiber. In addition, it can be used for coating the surface of a base material of various forms, such as sheet, film, flake, particulate, bar, or fiber. When using a base material that has an alkaline-containing glass composition, establishing a fluorine-containing layer, such as a layer of fluorine-containing silicon dioxide and other metallic oxide, between the photocatalyst film and the base material can prevent the deterioration of photocatalytic activity of the photocatalyst layer. The fluorine-containing layer functions as an alkaline barrier that controls the diffusion and migration of alkali metallic ions in the glass fibers, such as Na ions, into the photocatalyst layer. Inorganic fiber- and glass sheet-based photocatalyst bearing materials have an excellent capability to decompose rarefied harmful organic gases, and are suitable for use as interior wall and air filters in super clean enclosed spaces and conveyance spaces for semiconductor production, clean rooms for various other purposes, and office and residential buildings, and for other purposes including air cleaning, antibacterial action, anti-fouling action, and defogging of clear sheets (maintaining hydrophilicity).
摘要翻译： PCT No.PCT / JP97 / 02681 Sec。 371日期：1998年4月3日 102（e）日期1998年4月3日PCT 1997年8月1日PCT PCT。公开号WO98 / 05413 日期1998年2月12日包含在含有氧化钛和其它金属氧化物半导体的光催化剂层内的氟增加了金属氧化物的光催化活性。所述的光催化剂可以是薄膜，薄片，颗粒或纤维的形式。此外，它可以用于涂覆各种形式的基材的表面，例如片，薄膜，薄片，颗粒，棒或纤维。当使用具有含碱性玻璃组合物的基材时，在光催化剂膜和基材之间建立诸如一层含氟二氧化硅和其它金属氧化物的含氟层可以防止光催化剂的劣化光催化层的活性。含氟层用作控制玻璃纤维如Na离子中的碱金属离子在光催化剂层中的扩散和迁移的碱性屏障。无机纤维和玻璃板基光催化剂轴承材料具有优异的分解稀有有害有机气体的能力，适用于超洁净封闭处所内壁和空气过滤器，半导体生产用输送空间，各种洁净室用途，办公楼和住宅建筑物，以及用于其他用途，包括空气净化，抗菌作用，防污染作用和清除片材的除雾（保持亲水性）。

2. 发明授权

US06194346B1 Photocatalyst and method of making 失效
标题翻译：光催化剂及其制备方法
公开(公告)号：US06194346B1
公开(公告)日：2001-02-27
申请号：US09472832
申请日：1999-12-28
申请人： Hiroaki Tada , Koji Shimoda , Toshiya Ito , Akihiko Hattori
发明人： Hiroaki Tada , Koji Shimoda , Toshiya Ito , Akihiko Hattori
IPC分类号： B01J2706
CPC分类号： C03C17/256 , B01D53/8687 , B01D53/885 , B01D2255/802 , B01J35/002 , B01J35/004 , C03C17/3417 , C03C2217/212 , C03C2217/241 , C03C2217/71 , C03C2218/10
摘要： Fluorine contained within a photocatalyst layer containing titanium oxide and other metallic oxide semiconductors increases the metallic oxide's photocatalytic activity. The described photocatalyst may be in the form of either film, flake, particulate, or fiber. In addition, it can be used for coating the surface of a base material of various forms, such as sheet, film, flake, particulate, bar, or fiber. When using a base material that has an alkaline-containing glass composition, establishing a fluorine-containing layer, such as a layer of fluorine-containing silicon dioxide and other metallic oxide, between the photocatalyst film and the base material can prevent the deterioration of photocatalytic activity of the photocatalyst layer. The fluorine-containing layer functions as an alkaline barrier that controls the diffusion and migration of alkali metallic ions in the glass fibers, such as Na ions, into the photocatalyst layer. Inorganic fiber- and glass sheet-based photocatalyst bearing materials have an excellent capability to decompose rarefied harmful organic gases, and are suitable for use as interior wall and air filters in super clean enclosed spaces and conveyance spaces for semiconductor production, clean rooms for various other purposes, and office and residential buildings, and for other purposes including air cleaning, antibacterial action, anti-fouling action, and defogging of clear sheets (maintaining hydrophilicity).
摘要翻译：含有氧化钛和其它金属氧化物半导体的光催化剂层内的氟增加了金属氧化物的光催化活性。所述的光催化剂可以是薄膜，薄片，颗粒或纤维的形式。此外，它可以用于涂覆各种形式的基材的表面，例如片，薄膜，薄片，颗粒，棒或纤维。当使用具有含碱性玻璃组合物的基材时，在光催化剂膜和基材之间建立诸如一层含氟二氧化硅和其它金属氧化物的含氟层可以防止光催化剂的劣化光催化层的活性。含氟层用作控制玻璃纤维（例如Na离子）中的碱金属离子在光催化剂层中的扩散和迁移的碱性屏障。无机纤维和玻璃板基光催化剂轴承材料具有优异的分解稀有有害有机气体的能力，适用于超洁净封闭处所内壁和空气过滤器，半导体生产用输送空间，各种洁净室用途，办公楼和住宅建筑物，以及用于其他用途，包括空气净化，抗菌作用，防污染作用和清除片材的除雾（保持亲水性）。

3. 发明授权

US06379776B1 Nonfogging and stainproof glass articles 失效
标题翻译：防雾防污玻璃制品
公开(公告)号：US06379776B1
公开(公告)日：2002-04-30
申请号：US09125406
申请日：1999-07-16
申请人： Hiroaki Tada , Koji Shimoda , Akihiko Hattori , Kazuhiro Doushita , Takashi Sunada
发明人： Hiroaki Tada , Koji Shimoda , Akihiko Hattori , Kazuhiro Doushita , Takashi Sunada
IPC分类号： D06N704
CPC分类号： C03C17/3417 , C03C17/42 , C03C2217/71 , C03C2217/77 , Y10T428/24421 , Y10T428/252 , Y10T428/31612 , Y10T428/31663
摘要： The present invention relates to An anti-fogging and stain-prevented glass article having an alkali shut-off film and a photocatalytic film in the order laminated on the surface of glass substrate, in which dents and projections having an arithmetical mean roughness (Ra) from 1.5 to 80 nm and mean interval (Sm) of dents and projections from 4 to 300 nm are formed thereon, and to An anti-fogging and stain-prevented glass article having an alkali shut-off film, a photocatalytic film, and a silicon oxide monocomponent equivalent layer or a layer of organosilane including at least one kind of functional group selected from polyalkyleneoxide group, alkyl group, alkenyl group and aryl group in its molecules or its hydrolyzed substance, laminated in the order on the surface of a glass article. The abovementioned anti-fogging and stain-prevented glass article can be used for window glasses of automobiles and buildings, and glasses, etc.
摘要翻译：本发明涉及一种防雾防污玻璃制品，其具有层压在玻璃基板表面上的顺序具有碱切断膜和光催化膜，其中具有算术平均粗糙度（Ra）的凹陷和突起，在其上形成1.5至80nm的平均间隔（Sm）和4至300nm的突起的平均间隔（Sm），以及具有碱切断膜，光催化膜和氧化硅单组分当量层或包含选自分子中的聚环氧烷基，烷基，烯基和芳基中的至少一种官能团的有机硅烷或其水解物，按照玻璃制品的表面顺序层叠。上述防雾防污玻璃制品可用于汽车和建筑物以及眼镜等的窗玻璃。

4. 发明授权

US06941041B2 Gradient index rod lens unit and microchemical system having the same 失效
标题翻译：渐变折射杆镜片单元和微化学系统具有相同的特性
公开(公告)号：US06941041B2
公开(公告)日：2005-09-06
申请号：US10754761
申请日：2004-01-09
申请人： Jun Yamaguchi , Akihiko Hattori , Takehiko Kitamori
发明人： Jun Yamaguchi , Akihiko Hattori , Takehiko Kitamori
IPC分类号： G01N25/16 , G01N21/41 , G01N27/447 , G01N37/00 , G02B3/00 , G02B6/028 , G02B6/32 , G02B6/00
CPC分类号： G02B3/0087
摘要： There is provided a gradient index rod lens unit having a desired chromatic aberration. The gradient index rod lens unit is comprised of two gradient index rod lenses 11 and 12 with different chromatic aberrations and the entire lengths thereof adjusted, which are disposed in series with the optical axes thereof in alignment. The chromatic aberration of the gradient index rod lens unit can be set to a value falling within chromatic aberration ranges inherently possessed by the respective gradient index rod lenses 11 and 12.
摘要翻译：提供了具有期望的色差的梯度折射率棒状透镜单元。梯度分度杆透镜单元由具有不同色差的两个梯度折射率棒透镜11和12组成，并且其整个长度被调整，其与其光轴对准地排列成一列。梯度折射率棒状透镜单元的色差可以被设定为落在各个梯度折射率棒状透镜11和12固有地具有的色像差范围内的值。

5. 发明申请

US20050140971A1 Microchemical system chip and microchemical system 审中-公开
标题翻译：微化学系统芯片和微化学系统
公开(公告)号：US20050140971A1
公开(公告)日：2005-06-30
申请号：US10944653
申请日：2004-09-17
申请人： Jun Yamaguchi , Akihiko Hattori , Takehiko Kitamori , Manabu Tokeshi
发明人： Jun Yamaguchi , Akihiko Hattori , Takehiko Kitamori , Manabu Tokeshi
IPC分类号： B01L3/00 , G01N21/03 , G01N21/05 , G01N21/25 , G01N21/64
CPC分类号： G01N21/05 , B01L3/502715 , B01L2300/0654 , B01L2300/0816 , G01N2021/0346
摘要： A microchemical system chip and a microchemical system that can be reduced in size while improving measurement sensitivity. The microchemical system chip 1 is comprised of a plate-shaped glass substrate 10, and the glass substrate 10 has a U-shaped channel 11 therein. The U-shaped channel 11 is comprised of a longitudinal channel 11a, and a pair of transverse channels 11b and 11c that are connected to the two ends of the longitudinal channel 11a. The glass substrate 10 has therein two voids provided coaxially with the longitudinal channel 11a near the two ends of the longitudinal channel 11a, and gradient index rod lenses 14 and 15 are housed respectively in the two voids. An optical fiber 16 that propagates detecting light emitted from a light source is connected to the gradient index rod lens 14, and an optical fiber 17 that leads detecting light received by the gradient index rod lens 15 to a detector is connected to the gradient index rod lens 15.
摘要翻译：微化学系统芯片和微化学系统，可以减小尺寸，同时提高测量灵敏度。微化学系统芯片1由板状的玻璃基板10构成，玻璃基板10具有U形的通道11。 U形通道11包括纵向通道11a和连接到纵向通道11a的两端的一对横向通道11b和11c。玻璃基板10具有在纵向通道11a的两端附近与纵向通道11a同轴设置的两个空隙，梯度分度杆透镜14和15分别容纳在两个空隙中。将从光源发出的检测光传播的光纤16连接到梯度折射率棒状透镜14，将由梯度折射率棒状透镜15接收的检测光引导到检测器的光纤17连接到梯度折射率棒镜头15。

6. 发明授权

US4678652A Process for producing silica in fine powder form 失效
标题翻译：用于生产细粉末形式的二氧化硅的方法
公开(公告)号：US4678652A
公开(公告)日：1987-07-07
申请号：US785806
申请日：1985-10-09
申请人： Hiroyuki Tamenori , Akihiko Hattori , Mitsugi Yoshiyagawa
发明人： Hiroyuki Tamenori , Akihiko Hattori , Mitsugi Yoshiyagawa
IPC分类号： C01B33/152 , C01B33/154 , C01B33/155 , C01B33/187 , C01B33/12
CPC分类号： C01B33/187 , C01P2006/80
摘要： A process for producing silica in fine powder form, which comprises(a) adding at least one water-miscible alcohol selected from water-miscible monohydric and dihydric alcohols to an aqueous solution of an alkali metal silicate having an SiO.sub.2 concentration of 9 to 20% by weight until a solid precipitate forms and the solution begins, or is about, to become turbid,(b) adding a mineral acid to the resulting mixture in an amount 35 to 80% of the stoichiometrical amount required to neutralize the alkali metal silicate to precipitate silica as a fine powder, and(c) thereafter bringing the resulting slurry into contact with a mineral acid under an acidity of at least 1N.
摘要翻译：一种制备细粉末形式的二氧化硅的方法，其包括（a）将至少一种选自水混溶性一元醇和二元醇的水混溶性醇添加到SiO 2浓度为9〜20％的碱金属硅酸盐水溶液中，重量直到形成固体沉淀物并且溶液开始或大约变得混浊，（b）向所得混合物中加入无机酸，其量为中和碱金属硅酸盐所需的化学计量量的35-80％将二氧化硅作为细粉末析出，（c）此后，使得到的浆料与酸性至少为1N的无机酸接触。

7. 发明申请

US20080124247A1 Chip element for micro chemical system and micro chemical system using the chip element 审中-公开
标题翻译：用于微化学系统的芯片元件和使用芯片元件的微量化学系统
公开(公告)号：US20080124247A1
公开(公告)日：2008-05-29
申请号：US11983917
申请日：2007-11-13
申请人： Yoshinori Matsuoka , Jun Yamaguchi , Takashi Fukuzawa , Akihiko Hattori , Takehiko Kitamori
发明人： Yoshinori Matsuoka , Jun Yamaguchi , Takashi Fukuzawa , Akihiko Hattori , Takehiko Kitamori
IPC分类号： G01N21/64 , G01N21/00
CPC分类号： G01N21/0303 , B01L3/5027 , G01N21/171 , G01N21/645
摘要： There are provided a chip for micro chemical systems which can obviate the need of alignment at every measurement and can improve the measurement sensitivity and reduce the variation of measurement, and a micro chemical system using the chip. A thermal lens spectrometry system 10 comprises: a micro chemical chip 2 having a groove 1 into which a sample solution is injected; a rod lens 3 disposed on the micro chemical chip 2 at a predetermined spacing above the groove 1; a lens holder 9 disposed above the micro chemical chip 2; a securing section 4; an optical fiber 5; a ferrule 6 secured by the securing section 4 above the rod lens 3; a light source unit 7 connected to the optical fiber 5, and a detection device 8 disposed below the micro chemical chip 2. The securing section 4 comprises a seating 32 laid on the micro chemical chip 2, and a metal split sleeve 33 for fitting the ferrule 6 and the lens holder 9 at the outside thereof.
摘要翻译：提供了一种用于微量化学系统的芯片，可以消除每次测量时对准的需要，并且可以提高测量灵敏度并减少测量的变化，以及使用该芯片的微型化学系统。热透镜分光系统10包括：微化学芯片2，其具有注入样品溶液的槽1; 棒状透镜3，以规定的间隔配置在微细化学品片2上，设置在微化学芯片2上方的透镜架9; 固定部分4; 光纤5; 由杆状透镜3上方的固定部4固定的套圈6; 连接到光纤5的光源单元7和设置在微化学芯片2下方的检测装置8。固定部分4包括放置在微化学芯片2上的座32和用于将套圈6和透镜保持器9装配在其外侧的金属分开套筒33。

8. 发明授权

US07304734B2 Fluorescence analysis optical multiplexer/demultiplexer, fluorescence analysis optical module, fluorescence analyzer, fluorescence/photothermal conversion spectroscopic analyzer, and fluorescence analysis chip 有权
公开(公告)号：US07304734B2
公开(公告)日：2007-12-04
申请号：US11329456
申请日：2006-01-09
申请人： Takashi Fukuzawa , Jun Yamaguchi , Akihiko Hattori , Takao Miwa
发明人： Takashi Fukuzawa , Jun Yamaguchi , Akihiko Hattori , Takao Miwa
IPC分类号： G01J3/30
CPC分类号： G01N21/645 , G01N2021/6482 , G01N2021/6484
摘要： A fluorescence analysis optical multiplexer/demultiplexer, a fluorescence analysis optical module, a fluorescence analyzer, a fluorescence/photothermal conversion spectroscopic analyzer, and a fluorescence analysis chip, according to which LIF analysis can be carried out easily and with high sensitivity, and moreover photothermal conversion spectroscopic analysis can be carried out easily and simultaneously with the LIF analysis. A microchemical system 100 as the fluorescence analyzer is comprised of a fluorescence analysis optical module 100a, a probe 50 that condenses exciting light onto a sample solution in a channel 204 inside a fluorescence analysis chip 20, and a sample stage 21 on which the fluorescence analysis chip 20 is mounted. The fluorescence analysis optical module 100a is comprised of an exciting light source 53 that outputs exciting light of dominant wavelength λ1, a fluorescence analysis optical multiplexer/demultiplexer 56 for use in the fluorescence analyzer which analyzes fluorescence of dominant wavelength λ2 (λ2>λ1) emitted from the sample upon the sample being irradiated with the exciting light via the probe 50, a detector 54 that receives the fluorescence, an optical fiber 106 that connects the fluorescence analysis optical multiplexer/demultiplexer 56 to the exciting light source 53, an optical fiber 107 that connects the fluorescence analysis optical multiplexer/demultiplexer 56 to the probe 50, and an optical fiber 108 that connects the fluorescence analysis optical multiplexer/demultiplexer 56 to the detector 54. The channel 204 through which the sample solution is passed is coated with a reflective metal film 205.

9. 发明授权

US06930778B2 Microchemical system 失效
标题翻译：微化学系统
公开(公告)号：US06930778B2
公开(公告)日：2005-08-16
申请号：US10733491
申请日：2003-12-10
申请人： Jun Yamaguchi , Akihiko Hattori , Takehiko Kitamori , Manabu Tokeshi
发明人： Jun Yamaguchi , Akihiko Hattori , Takehiko Kitamori , Manabu Tokeshi
IPC分类号： G01N25/16 , G01N21/17 , G02B6/42 , G01N21/00
CPC分类号： G01N21/171
摘要： A microchemical system is provided, which can improve the working efficiency of the user and can be designed compact in size. The microchemical system is provided with an optical fiber 10 with a gradient index rod lens 102 mounted on an end thereof. The lens-possessing optical fiber 10 is comprised of an optical fiber 101 that transmits exciting light and detecting light in the single mode, and a ferrule 103 for expanding the outer diameter of the optical fiber 101 to the same value as that of the gradient index rod lens 102. The gradient index rod lens 102 and the optical fiber 101 are rigidly joined together by means of a sleeve 104.
摘要翻译：提供了一种微化学系统，可以提高用户的工作效率，设计尺寸紧凑。微化学系统设置有光纤10，其具有安装在其一端的梯度折射率棒透镜102。具有透镜的光纤10包括以单模发射激发光并检测光的光纤101，以及用于将光纤101的外径扩大到与梯度指数相同的值的套圈103 棒状透镜102。梯度分度杆透镜102和光纤101通过套筒104刚性地接合在一起。

10. 发明授权

US06498380B1 Substrate for photoelectric conversion device, and photoelectric conversion device using the same 有权
标题翻译：光电转换装置用基板及使用其的光电转换装置
公开(公告)号：US06498380B1
公开(公告)日：2002-12-24
申请号：US09594264
申请日：2000-06-15
申请人： Tsuyoshi Otani , Yukio Sueyoshi , Akira Fujisawa , Masahiro Hirata , Akihiko Hattori
发明人： Tsuyoshi Otani , Yukio Sueyoshi , Akira Fujisawa , Masahiro Hirata , Akihiko Hattori
IPC分类号： H01L310232
CPC分类号： C03C17/3417 , C03C17/36 , C03C17/3678 , C03C2217/77 , H01L31/022466 , H01L31/022475 , H01L31/0236 , H01L31/03921 , H01L31/1884 , Y02E10/50
摘要： On a glass sheet, undercoating layers and a transparent conductive film containing tin oxide as the main component are formed in this order. The surface of the transparent conductive film is provided with roughness including convex portions and concave portions. The convex portions have a mean diameter in a range between 0.05 &mgr;m and 0.3 &mgr;m and include five convex portions or less with diameters of at least 0.5 &mgr;m per 100 &mgr;m2 of the surface. On the transparent conductive film, a photovoltaic unit and a back electrode are formed, thus obtaining a photoelectric conversion device.
摘要翻译：在玻璃板上，依次形成底涂层和含有氧化锡作为主要成分的透明导电膜。透明导电膜的表面设置有包括凸部和凹部的粗糙度。凸部的平均直径在0.05μm〜0.3μm之间的范围内，并且包括表面的直径为至少0.5μm/ m 2的五个凸部或更小的直径。在透明导电膜上形成光电单元和背面电极，从而获得光电转换装置。

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