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1. 发明授权

US06329478B1 Transition metal complex, process for producing the same, olefin polymerization catalyst containing the transition metal complex and process for producing olefin polymers 有权
标题翻译：过渡金属络合物，其制备方法，含有过渡金属络合物的烯烃聚合催化剂和烯烃聚合物的制备方法
公开(公告)号：US06329478B1
公开(公告)日：2001-12-11
申请号：US08983536
申请日：1999-04-30
申请人： Hiroaki Katayama , Masaaki Nabika , Akio Imai , Akira Miyashita , Tsuyoshi Watanabe , Hirofumi Johohji , Yoshiaki Oda , Hidenori Hanaoka
发明人： Hiroaki Katayama , Masaaki Nabika , Akio Imai , Akira Miyashita , Tsuyoshi Watanabe , Hirofumi Johohji , Yoshiaki Oda , Hidenori Hanaoka
IPC分类号： C08F416
CPC分类号： B01J31/143 , B01J31/146 , B01J31/2204 , B01J31/2226 , B01J31/2295 , B01J31/26 , B01J2531/40 , B01J2531/46 , C07F5/00 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F210/16 , Y10S526/943 , C08F210/14 , C08F2500/17 , C08F2500/03 , C08F2500/10
摘要： The present invention relates to a transition metal complex, a process for producing the same, a polymerization catalsyt containing the transition metal complex and a process for producing polymers which uses the catalysts.
摘要翻译：本发明涉及过渡金属络合物，其制造方法，含有过渡金属配合物的聚合催化剂和使用该催化剂的聚合物的制造方法。

2. 发明授权

US6034190A Olefin polymerization catalyst component 失效
标题翻译：烯烃聚合催化剂组分
公开(公告)号：US6034190A
公开(公告)日：2000-03-07
申请号：US122107
申请日：1998-07-24
申请人： Hiroaki Katayama , Masaaki Nabika , Akio Iami , Norio Kawamura , Hidenori Hanaoka
发明人： Hiroaki Katayama , Masaaki Nabika , Akio Iami , Norio Kawamura , Hidenori Hanaoka
IPC分类号： C07F7/00 , C08F4/642 , C08F4/643 , C08F10/00 , C08F210/16 , C08F4/44 , C08F210/00
CPC分类号： C07F7/006 , C08F10/00 , C08F210/16
摘要： An olefin polymerization catalyst component is represented by the general formula (1): ##STR1## wherein M is a transition metal of the 4.sup.th Group or the Lanthanide Series in the Periodic Table; each of A and A' is the same or different and is a hydrocarbon or halogenated hydrocarbon having 1 to 50 carbon atoms, or a hydrocarbon or halogenated hydrocarbon group having 1 to 50 carbon atoms and a substituent containing an oxygen atom; E is a residual group of an element of the 13th to 15th Groups capable of forming three bonds; each of R and R' is the same or different and is a halogen atom or a hydrocarbon group having 1 to 20 carbon atoms; R" represents a hydrocarbon or halogenated hydrocarbon group containing at least one hetero atom and having 1 to 20 carbon atoms. This component is used in a catalyst along with an aluminum or born-containing cocatalyst to produce an olefin polymer or copolymer.
摘要翻译：烯烃聚合催化剂组分由通式（1）表示：其中M是第4族的过渡金属或元素周期表中的镧系元素; A和A'各自相同或不同，为碳原子数为1〜50的烃基或卤代烃，或碳原子数为1〜50的烃基或卤代烃基及含有氧原子的取代基。 E是能够形成三键的第十三至第十五组的元素的残留组; R和R'各自相同或不同，为卤素原子或碳原子数1〜20的烃基; R“表示含有至少一个杂原子并具有1至20个碳原子的烃基或卤代烃基。该组分与铝或含天然气的助催化剂一起用于催化剂中以产生烯烃聚合物或共聚物。

3. 发明授权

US5840646A Olefin polymerization catalyst component 失效
标题翻译：烯烃聚合催化剂组分
公开(公告)号：US5840646A
公开(公告)日：1998-11-24
申请号：US695382
申请日：1996-08-09
申请人： Hiroaki Katayama , Masaaki Nabika , Akio Iami , Norio Kawamura , Hidenori Hanaoka
发明人： Hiroaki Katayama , Masaaki Nabika , Akio Iami , Norio Kawamura , Hidenori Hanaoka
IPC分类号： C07F7/00 , C08F4/642 , C08F4/643 , C08F10/00 , C08F210/16 , B01J31/00 , C07F7/28
CPC分类号： C07F7/006 , C08F10/00 , C08F210/16
摘要： An olefin polymerization catalyst component is represented by the general formula (1); ##STR1## wherein M is titanium, zirconium or hafnium; each of A and A' is the same or different and is a hydrocarbon or halogenated hydrocarbon having 1 to 50 carbon atoms, or a hydrocarbon or halogenated hydrocarbon group having 1 to 50 carbon atoms and a substituent containing an oxygen atom; E is a residual group of an element of the 13th to 15th Groups capable of forming three bonds; each of R and R' is the same or different and is a halogen atom or a hydrocarbon group having 1 to 20 carbon atoms; R" represents a hydrocarbon or halogenated hydrocarbon group containing at least one hetero atom and having 1 to 20 carbon atoms. This component is used in a catalyst to produce an olefin polymer.
摘要翻译：烯烃聚合催化剂组分由通式（1）表示; （1）其中M为钛，锆或铪; A和A'各自相同或不同，为碳原子数为1〜50的烃基或卤代烃，或碳原子数为1〜50的烃基或卤代烃基及含有氧原子的取代基。 E是能够形成三键的第十三至第十五组的元素的残留组; R和R'各自相同或不同，为卤素原子或碳原子数1〜20的烃基; R“表示含有至少一个杂原子并具有1至20个碳原子的烃基或卤代烃基。该组分用于催化剂以制备烯烃聚合物。

4. 发明申请

US20100063228A1 TRANSITION METAL COMPLEX, PROCESS FOR PRODUCING THE SAME, AND USE 失效
标题翻译：过渡金属复合物，其生产方法和使用
公开(公告)号：US20100063228A1
公开(公告)日：2010-03-11
申请号：US12531852
申请日：2008-03-18
申请人： Hidenori Hanaoka , Masaaki Nabika
发明人： Hidenori Hanaoka , Masaaki Nabika
IPC分类号： C08F4/6592 , C07F7/28 , C08F4/44 , C08F4/52 , B01J31/12 , B01J31/14
CPC分类号： C07F17/00 , C08F10/00 , C08F210/16 , C08F2420/02 , C08F4/6592 , C08F210/14 , C08F2500/03 , C08F2500/10
摘要： A transition metal complex of the following formula (1): in which A represents an atom of Group 16 of the periodic table; B1 represents an atom of Group 14 of the periodic table; M1 represents a transition metal atom of Group 4 of the periodic table; Cp1 represents a group having a cyclopentadiene anion backbone; R1, R2, R3, R4, R5 and R6 represent independently of one another a hydrogen atom, a halogen atom, a C1-20 alkyl group optionally substituted with a halogen atom; R7, R8, R9, R10, R11 and R12 represent independently of one another a hydrogen atom, a C1-20 alkyl group optionally substituted with a halogen atom; and a 1,3-diene comprising R7, R8, R9, R10, R11, R12 and 4 carbon atoms coordinates on M1, and the 1,3-diene may be of either a cis or trans form, or a mixed form thereof, although the coordination form is not limited, and the double bonds may be delocalized. When this transition metal complex is used as a catalytic component, high molecular weight polyolefin is produced with high catalytic activity.
摘要翻译：下式（1）的过渡金属络合物：其中A表示周期表第16族的原子; B1表示周期表第14族的原子; M1表示周期表第4族的过渡金属原子; Cp1表示具有环戊二烯阴离子主链的基团; R 1，R 2，R 3，R 4，R 5和R 6彼此独立地表示氢原子，卤素原子，任选被卤素原子取代的C 1-20烷基; R 7，R 8，R 9，R 10，R 11和R 12彼此独立地表示氢原子，任选被卤素原子取代的C 1-20烷基; 和在M1上配位的包含R7，R8，R9，R10，R11，R12和4个碳原子的1,3-二烯，1,3-二烯可以是顺式或反式，或其混合形式，虽然协调形式没有限制，双重债券可能会离域。当该过渡金属络合物用作催化组分时，产生具有高催化活性的高分子量聚烯烃。

5. 发明授权

US08026324B2 Transition metal complex, process for producing the same, and use 失效
标题翻译：过渡金属络合物，生产过程和使用
公开(公告)号：US08026324B2
公开(公告)日：2011-09-27
申请号：US12531852
申请日：2008-03-18
申请人： Hidenori Hanaoka , Masaaki Nabika
发明人： Hidenori Hanaoka , Masaaki Nabika
IPC分类号： C08F4/642 , C08F4/6592 , C07F17/00 , B01J31/22
CPC分类号： C07F17/00 , C08F10/00 , C08F210/16 , C08F2420/02 , C08F4/6592 , C08F210/14 , C08F2500/03 , C08F2500/10
摘要： A transition metal complex of the following formula (1): in which A represents an atom of Group 16 of the periodic table; B1 represents an atom of Group 14 of the periodic table; M1 represents a transition metal atom of Group 4 of the periodic table; Cp1 represents a group having a cyclopentadiene anion backbone; R1, R2, R3, R4, R5 and R6 represent independently of one another a hydrogen atom, a halogen atom, a C1-20 alkyl group optionally substituted with a halogen atom; R7, R8, R9, R10, R11 and R12 represent independently of one another a hydrogen atom, a C1-20 alkyl group optionally substituted with a halogen atom; and a 1,3-diene comprising R7, R8, R9, R10, R11, R12 and 4 carbon atoms coordinates on M1, and the 1,3-diene may be of either a cis or trans form, or a mixed form thereof, although the coordination form is not limited, and the double bonds may be delocalized. When this transition metal complex is used as a catalytic component, high molecular weight polyolefin is produced with high catalytic activity.
摘要翻译：下式（1）的过渡金属络合物：其中A表示周期表第16族的原子; B1表示周期表第14族的原子; M1表示周期表第4族的过渡金属原子; Cp1表示具有环戊二烯阴离子主链的基团; R 1，R 2，R 3，R 4，R 5和R 6彼此独立地表示氢原子，卤素原子，任选被卤素原子取代的C 1-20烷基; R 7，R 8，R 9，R 10，R 11和R 12彼此独立地表示氢原子，任选被卤素原子取代的C 1-20烷基; 和在M 1上配位的包含R7，R8，R9，R10，R11，R12和4个碳原子的1,3-二烯，1,3-二烯可以是顺式或反式，或其混合形式，虽然协调形式没有限制，双重债券可能会离域。当该过渡金属络合物用作催化组分时，产生具有高催化活性的高分子量聚烯烃。

6. 发明授权

US06664208B1 Modified aluminum oxy compound, polymerization catalyst and process for producing olefin polymer and alkenyl aromatic hydrocarbon polymer 失效
标题翻译：改性铝氧化合物，聚合催化剂和烯烃聚合物和烯基芳烃聚合物的制备方法
公开(公告)号：US06664208B1
公开(公告)日：2003-12-16
申请号：US09661626
申请日：2000-09-13
申请人： Masayuki Fujita , Masaaki Nabika , Tatsuya Miyatake , Tsuyoshi Watanabe , Yoshinori Seki , Nobuo Oi
发明人： Masayuki Fujita , Masaaki Nabika , Tatsuya Miyatake , Tsuyoshi Watanabe , Yoshinori Seki , Nobuo Oi
IPC分类号： B01J3114
CPC分类号： C08F10/00 , B01J31/14 , C07F5/066 , C07F5/068 , C08F4/65908 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F110/08 , C08F210/16 , Y10S526/943 , C08F4/6428 , C08F4/64165 , C08F4/65912 , C08F2500/17 , C08F2500/03 , C08F210/14 , C08F2500/10 , C08F4/64089 , C08F4/7042 , C08F4/7006
摘要： A modified aluminum oxy compound(A) obtained by reacting an aluminum oxy compound(a), water (b) and a compound having a hydroxyl group(c); a polymerization catalyst component comprising the modified aluminum oxy compound; a polymerization catalyst obtained by contacting said modified aluminum oxy compound(A), a transition metal compound(B) and optionally an organoaluminum compound(C) and a specified boron compound; and a process for producing an olefin polymer or an alkenyl aromatic hydrocarbon polymer with the polymerization catalyst.
摘要翻译：通过使铝氧化合物（a），水（b）和具有羟基（c）的化合物反应得到的改性铝氧化合物（A）包含改性铝氧化合物的聚合催化剂组分; 通过使所述改性铝氧化合物（A），过渡金属化合物（B）和任选的有机铝化合物（C）与特定的硼化合物接触而获得的聚合催化剂; 以及使用聚合催化剂生产烯烃聚合物或烯基芳族烃聚合物的方法。

7. 发明授权

US06921800B2 Modified aluminum oxy compound, polymerization catalyst and process for producing olefin polymer and alkenyl 失效
标题翻译：改性铝氧化合物，聚合催化剂和烯烃聚合物和链烯基的制备方法
公开(公告)号：US06921800B2
公开(公告)日：2005-07-26
申请号：US10734218
申请日：2003-12-15
申请人： Masayuki Fujita , Masaaki Nabika , Tatsuya Miyatake , Tsuyoshi Watanabe , Yoshinori Seki , Nobuo Oi
发明人： Masayuki Fujita , Masaaki Nabika , Tatsuya Miyatake , Tsuyoshi Watanabe , Yoshinori Seki , Nobuo Oi
IPC分类号： B01J31/00 , B01J31/14 , C07F5/06 , C08F4/02 , C08F4/42 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/08 , C08F210/16
CPC分类号： C08F10/00 , B01J31/14 , C07F5/066 , C07F5/068 , C08F4/65908 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F110/08 , C08F210/16 , Y10S526/943 , C08F4/6428 , C08F4/64165 , C08F4/65912 , C08F2500/17 , C08F2500/03 , C08F210/14 , C08F2500/10 , C08F4/64089 , C08F4/7042 , C08F4/7006
摘要： A modified aluminum oxy compound (A) obtained by reacting an aluminum oxy compound (a), water (b) and a compound having a hydroxyl group (c); a polymerization catalyst component comprising the modified aluminum oxy compound; a polymerization catalyst obtained by contacting said modified aluminum oxy compound (A), a transition metal compound (B) and optionally an organoaluminum compound (C) and a specified boron compound; and a process for producing an olefin polymer or an alkenyl aromatic hydrocarbon polymer with the polymerization catalyst.
摘要翻译：通过使铝氧化合物（a），水（b）和具有羟基（c）的化合物反应获得的改性铝氧基化合物（A）包含改性铝氧化合物的聚合催化剂组分; 通过使所述改性铝氧化合物（A），过渡金属化合物（B）和任选的有机铝化合物（C）与特定的硼化合物接触而获得的聚合催化剂; 以及使用聚合催化剂生产烯烃聚合物或烯基芳族烃聚合物的方法。

8. 发明授权

US06881802B2 Catalyst for addition polymerization and process for producing an addition polymer 失效
标题翻译：用于加成聚合的催化剂和用于制备加成聚合物的方法
公开(公告)号：US06881802B2
公开(公告)日：2005-04-19
申请号：US10166379
申请日：2002-06-11
申请人： Kiyoshi Fujisawa , Masaaki Nabika
发明人： Kiyoshi Fujisawa , Masaaki Nabika
IPC分类号： C08F4/695 , C08F4/60 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/42
CPC分类号： C08F10/00 , C08F110/02 , C08F210/16 , C08F4/695 , C08F210/14 , C08F2500/12 , C08F2500/10 , C08F2500/03
摘要： A catalyst obtained by contacting a specific transition metal compound (A) of Group 7 of the Periodic Table of the Elements, having a pyrazolyl group with an aluminum compound selected from organoaluminums and aluminoxanes and/or a specific boron compound, and a process for producing an addition polymer which comprises polymerizing an addition polymerizable monomer with the catalyst.
摘要翻译：通过使具有吡唑基的元素周期表第7族的特定过渡金属化合物（A）与选自有机铝和铝氧烷的铝化合物和/或特定的硼化合物接触而获得的催化剂及其制备方法加成聚合物，其包括使可加聚单体与催化剂聚合。

9. 发明授权

US07323611B2 Process for producing olefin oligomer 失效
标题翻译：烯烃低聚物的制备方法
公开(公告)号：US07323611B2
公开(公告)日：2008-01-29
申请号：US11423009
申请日：2006-06-08
申请人： Masaaki Nabika
发明人： Masaaki Nabika
IPC分类号： C07C2/24
CPC分类号： C07C2/36 , C07C2531/14 , C07C2531/24 , C07C11/02
摘要： A process for producing an olefin oligomer, which comprises the steps of (1) contacting an olefin with an organoaluminum compound to produce a contact product (i), (2) contacting a transition metal compound with a compound represented by the formula, R1R2A-G-AR3R4, to produce a contact product (ii), and (3) contacting the contact product (i), the contact product (ii), an alumoxane compound, and optionally an olefin with one another, wherein A is a nitrogen atom, a phosphorus atom, an arsenic atom or an antimony atom, and As are the same as or different from each other; G is a divalent group; and R1, R2, R3 and R4 are independently of one another a hydrocarbyl group, a halogenated hydrocarbyl group, an oxygen-containing hydrocarbyl group, a sulfur-containing hydrocarbyl group, a selenium-containing hydrocarbyl group, or a tellurium-containing hydrocarbyl group.
摘要翻译：一种制备烯烃低聚物的方法，其包括以下步骤：（1）使烯烃与有机铝化合物接触以产生接触产物（i），（2）使过渡金属化合物与式以产生接触产物（ⅱ），和（3）接触产物（ⅱ），（ⅲ）使接触产物（i），接触产物（ii），铝氧烷化合物和任选的烯烃彼此接触，其中A为氮原子，磷原子，砷原子或锑原子，As为相同或不同; G是二价基团; 且R 1，R 2，R 3和R 4彼此独立地为烃基，卤代烃基，含氧烃基，含硫烃基，含硒烃基或含碲烃基。

10. 发明授权

US5965758A Method for producing bridged type transition metal complex 失效
标题翻译：制备桥连型过渡金属络合物的方法
公开(公告)号：US5965758A
公开(公告)日：1999-10-12
申请号：US99306
申请日：1998-06-18
申请人： Masaaki Nabika , Kotohiro Nomura
发明人： Masaaki Nabika , Kotohiro Nomura
IPC分类号： C07F7/28 , C07F17/00 , C07F7/00
CPC分类号： C07F17/00 , Y10S526/943
摘要： A method for producing a bridged type transition metal complex represented by the following formula (1), comprising the following steps (i) and (ii):step (i); a step for reacting a specific cyclopentadiene compound with an organic alkaline metal compound or an organomagnesium compound to produce an alkaline metal salt compound or a magnesium salt compound of the cyclopentadiene compound; andstep (ii); a step for reacting the alkaline metal salt compound or magnesium salt compound of the cyclopentadiene compound with a specific transition metal compound, wherein at least the step (ii) is performed in the presence of an amine compound.According to the present invention, there can be provided a method for producing a bridged type transition metal complex having one cyclopentadiene type anion skeleton on an industrial scale in high yield without requiring an industrially disadvantageous low temperature and replacement of the solvent, which is capable of reducing the number of the steps.
摘要翻译：一种制备由下式（1）表示的桥连型过渡金属配合物的方法，包括以下步骤（i）和（ii）：步骤（i）; 使特定的环戊二烯化合物与有机碱金属化合物或有机镁化合物反应以制备环戊二烯化合物的碱金属盐化合物或镁盐化合物的步骤; 和步骤（ii）; 使环戊二烯化合物的碱金属盐化合物或镁盐化合物与特定的过渡金属化合物反应的步骤，其中至少步骤（ii）在胺化合物的存在下进行。根据本发明，可以提供以工业规模高产率制备具有一个环戊二烯型阴离子骨架的桥连型过渡金属络合物的方法，而不需要工业上不利的低温和更换溶剂，其能够减少步数。

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