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1. 发明授权

US08466227B2 Crosslinked fluorine-containing elastomer fine particles, preparation process of same, and composition 有权
标题翻译：交联的含氟弹性体微粒，其制备方法和组成
公开(公告)号：US08466227B2
公开(公告)日：2013-06-18
申请号：US13289948
申请日：2011-11-04
申请人： Hideto Nakagawa , Haruhiko Mohri , Hirokazu Aoyama , Junpei Terada , Rumi Takeuchi
发明人： Hideto Nakagawa , Haruhiko Mohri , Hirokazu Aoyama , Junpei Terada , Rumi Takeuchi
IPC分类号： B32B5/16 , C08L27/10 , C08L27/12
CPC分类号： C08J3/12 , C08J3/24 , C08J2327/12 , C08L2205/02 , C08L2205/22 , Y10T428/2982 , C08L27/18 , C08L27/16
摘要： There are provided novel crosslinked fluorine-containing elastomer fine particles, a process for preparing crosslinked fluorine-containing elastomer fine particles and a resin composition comprising the same. The crosslinked fluorine-containing elastomer fine particles are crosslinked fluorine-containing elastomer fine particles having a gel fraction of not less than 85% by mass or crosslinked fluorine-containing elastomer fine particles obtained by crosslinking fluorine-containing elastomer particles having at least three iodine atoms per one polymer molecule at an end thereof. The composition is one comprising those fine particles and a synthetic resin. The preparation process is a process for preparing crosslinked fluorine-containing elastomer fine particles, characterized by subjecting peroxide-crosslinkable fluorine-containing elastomer particles to peroxide-crosslinking by heating an aqueous dispersion comprising the fluorine-containing elastomer particles, a peroxide and a polyfunctional unsaturated compound.
摘要翻译：提供了新型交联的含氟弹性体微粒，制备交联的含氟弹性体微粒的方法和包含其的树脂组合物。交联的含氟弹性体微粒是具有不小于85质量％的凝胶分数的交联的含氟弹性体微粒或通过交联含有至少三个碘原子的含氟弹性体颗粒获得的交联的含氟弹性体微粒每一个聚合物分子在其末端。该组合物是包含这些细颗粒和合成树脂的组合物。制备方法是制备交联的含氟弹性体微粒的方法，其特征在于通过加热含氟弹性体颗粒，过氧化物和多官能不饱和的含水弹性体颗粒，使过氧化物交联的含氟弹性体颗粒进行过氧化物交联复合。

2. 发明申请

US20100160503A1 SURFACE-MODIFIED NANOFILLER AND POLYMER COMPOSITE MATERIAL 有权
标题翻译：表面改性纳米复合材料和聚合物复合材料
公开(公告)号：US20100160503A1
公开(公告)日：2010-06-24
申请号：US11993446
申请日：2006-06-22
申请人： Hideto Nakagawa , Haruhiko Mohri , Hirokazu Aoyama
发明人： Hideto Nakagawa , Haruhiko Mohri , Hirokazu Aoyama
IPC分类号： C08K5/3445 , C08K5/02 , C08K5/56 , C08K5/053 , C08K5/50 , C07F5/06 , C07F9/02 , C07D233/64
CPC分类号： C08J5/005 , B82Y30/00 , C08K9/04
摘要： A polymer composite material provides superior heat resistance, mechanical physical properties, substance permeation barrier properties, flame retardant properties, electrical conductivity and the like. Moreover, a novel surface-modified nanofiller utilizes this type of polymer composite material. The polymer composite material contains nanofillers, fluorocompounds and polymers. Fluoruocompounds bond to the surface of the nanofillers. The nanofillers to which fluorocompounds are surface-bonded are mixed with or dispersed in polymers.
摘要翻译：聚合物复合材料提供优异的耐热性，机械物理性能，物质渗透阻挡性能，阻燃性能，导电性等。此外，新型表面改性纳米填料利用这种类型的聚合物复合材料。聚合物复合材料包含纳米填料，氟化合物和聚合物。氟化合物键合到纳米填料的表面。氟化合物表面结合的纳米填料与聚合物混合或分散在聚合物中。

3. 发明申请

US20100247913A1 CROSSLINKED FLUORINE-CONTAINING ELASTOMER FINE PARTICLES, PREPARATION PROCESS OF SAME, AND COMPOSITION 审中-公开
标题翻译：含交联氟化物的弹性体微粒，其制备方法和组合物
公开(公告)号：US20100247913A1
公开(公告)日：2010-09-30
申请号：US12599912
申请日：2008-05-02
申请人： Hideto Nakagawa , Haruhiko Mohri , Hirokazu Aoyama , Junpei Terada , Rumi Takeuchi
发明人： Hideto Nakagawa , Haruhiko Mohri , Hirokazu Aoyama , Junpei Terada , Rumi Takeuchi
IPC分类号： C08F259/08 , C08L27/12 , B32B15/02
CPC分类号： C08J3/12 , C08J3/24 , C08J2327/12 , C08L2205/02 , C08L2205/22 , Y10T428/2982 , C08L27/18 , C08L27/16
摘要： There are provided novel crosslinked fluorine-containing elastomer fine particles, a process for preparing crosslinked fluorine-containing elastomer fine particles and a resin composition comprising the same. The crosslinked fluorine-containing elastomer fine particles are crosslinked fluorine-containing elastomer fine particles having a gel fraction of not less than 85% by mass or crosslinked fluorine-containing elastomer fine particles obtained by crosslinking fluorine-containing elastomer particles having at least three iodine atoms per one polymer molecule at an end thereof. The composition is one comprising those fine particles and a synthetic resin. The preparation process is a process for preparing crosslinked fluorine-containing elastomer fine particles, characterized by subjecting peroxide-crosslinkable fluorine-containing elastomer particles to peroxide-crosslinking by heating an aqueous dispersion comprising the fluorine-containing elastomer particles, a peroxide and a polyfunctional unsaturated compound.
摘要翻译：提供了新型交联的含氟弹性体微粒，制备交联的含氟弹性体微粒的方法和包含其的树脂组合物。交联的含氟弹性体微粒是具有不小于85质量％的凝胶分数的交联的含氟弹性体微粒或通过交联含有至少三个碘原子的含氟弹性体颗粒获得的交联的含氟弹性体微粒每一个聚合物分子在其末端。该组合物是包含这些细颗粒和合成树脂的组合物。制备方法是制备交联的含氟弹性体微粒的方法，其特征在于通过加热含氟弹性体颗粒，过氧化物和多官能不饱和的含水弹性体颗粒，使过氧化物交联的含氟弹性体颗粒进行过氧化物交联复合。

4. 发明授权

US07989535B2 Surface-modified nanofiller and polymer composite material 有权
标题翻译：表面改性纳米填料和聚合物复合材料
公开(公告)号：US07989535B2
公开(公告)日：2011-08-02
申请号：US11993446
申请日：2006-06-22
申请人： Hideto Nakagawa , Haruhiko Mohri , Hirokazu Aoyama
发明人： Hideto Nakagawa , Haruhiko Mohri , Hirokazu Aoyama
IPC分类号： C08K3/34 , C08K5/02
CPC分类号： C08J5/005 , B82Y30/00 , C08K9/04
摘要： A polymer composite material provides superior heat resistance, mechanical physical properties, substance permeation barrier properties, flame retardant properties, electrical conductivity and the like. Moreover, a novel surface-modified nanofiller utilizes this type of polymer composite material. The polymer composite material contains nanofillers, fluorocompounds and polymers. Fluoruocompounds bond to the surface of the nanofillers. The nanofillers to which fluorocompounds are surface-bonded are mixed with or dispersed in polymers.
摘要翻译：聚合物复合材料提供优异的耐热性，机械物理性能，物质渗透阻挡性能，阻燃性能，导电性等。此外，新型表面改性纳米填料利用这种类型的聚合物复合材料。聚合物复合材料包含纳米填料，氟化合物和聚合物。氟化合物键合到纳米填料的表面。氟化合物表面结合的纳米填料与聚合物混合或分散在聚合物中。

5. 发明授权

US08236887B2 Fluorine-containing polymer having heteroaromatic ring 有权
标题翻译：具有杂芳环的含氟聚合物
公开(公告)号：US08236887B2
公开(公告)日：2012-08-07
申请号：US12278613
申请日：2007-02-05
申请人： Yuzo Komatsu , Haruhiko Mohri , Hirokazu Aoyama
发明人： Yuzo Komatsu , Haruhiko Mohri , Hirokazu Aoyama
IPC分类号： C08K3/04
CPC分类号： H01G9/038 , C08F8/44 , C08F14/18 , C08F214/26 , C08F214/28 , C08F216/1408 , C08F2800/10 , C08F2810/40 , C08K3/04 , C08L27/12 , C08L2205/02 , H01G11/56 , H01M2/16 , H01M8/1023 , H01M8/1039 , H01M10/0565 , H01M10/0567 , H01M10/0568 , H01M2300/0045 , H01M2300/0082 , H01M2300/0085 , Y02E60/13 , C08L2666/04 , C08F120/06 , C08F112/14 , C08F8/30 , C08F14/22 , C08F114/185
摘要： There is provided a fluorine-containing polymer having an ionic group which has a heteroaromatic ring and is useful as a material comprising various heteroaromatic ring compounds having a stable fluorine-containing heteroaromatic ring, and further a fluorine-containing polymer having a heteroaromatic ring which is useful as a starting material of the above-mentioned polymer or a curing agent. Also, there is provided a fluorine-containing polymer having a heteroaromatic ring such as imidazole in its side chain, a polymer salt thereof, and a polymer composition comprising such a polymer and a polymer salt and a nano filler.
摘要翻译：提供具有离子性基团的含氟聚合物，其具有杂芳环，并且可用作包含具有稳定的含氟杂芳环的各种杂芳环化合物的材料，并且还含有具有杂芳环的含氟聚合物，可用作上述聚合物或固化剂的原料。另外，提供了在其侧链中具有杂芳环如咪唑的含氟聚合物，其聚合物盐和包含这种聚合物和聚合物盐和纳米填料的聚合物组合物。

6. 发明授权

US08212053B2 Process for preparing heteroaromatic ring compound having N-Rf group 有权
公开(公告)号：US08212053B2
公开(公告)日：2012-07-03
申请号：US12159439
申请日：2006-12-11
申请人： Yuzo Komatsu , Haruhiko Mohri , Hirokazu Aoyama
发明人： Yuzo Komatsu , Haruhiko Mohri , Hirokazu Aoyama
IPC分类号： C07D233/54 , C07D233/60
CPC分类号： C07D207/325 , C07D209/08 , C07D209/20 , C07D231/12 , C07D233/56 , C07D233/60 , C07D233/64 , C07D249/08 , C07D473/00 , C07D473/08
摘要： There is provided a preparation process in which a N—H group of a heteroaromatic ring compound having a N—H group in its ring is converted directly to a N—Rf group at a high reaction efficiency without using a catalyst. The preparation process is a process for preparing a compound comprising a heteroaromatic ring structure having a N—Rf group (—Rf is a fluorine-containing organic group) in its ring and is characterized in that the heteroaromatic ring compound having a N—H group in its ring is allowed to react with fluoroalkene in the absence of an alkali metal.

7. 发明申请

US20100222598A1 PROCESS FOR PREPARING HETEROAROMATIC RING COMPOUND HAVING N-Rf GROUP 有权
标题翻译：制备具有N-Rf基团的异构环化合物的方法
公开(公告)号：US20100222598A1
公开(公告)日：2010-09-02
申请号：US12159439
申请日：2006-12-11
申请人： Yuzo Komatsu , Haruhiko Mohri , Hirokazu Aoyama
发明人： Yuzo Komatsu , Haruhiko Mohri , Hirokazu Aoyama
IPC分类号： C07D233/68
CPC分类号： C07D207/325 , C07D209/08 , C07D209/20 , C07D231/12 , C07D233/56 , C07D233/60 , C07D233/64 , C07D249/08 , C07D473/00 , C07D473/08
摘要： There is provided a preparation process in which a N—H group of a heteroaromatic ring compound having a N—H group in its ring is converted directly to a N—Rf group at a high reaction efficiency without using a catalyst. The preparation process is a process for preparing a compound comprising a heteroaromatic ring structure having a N—Rf group (—Rf is a fluorine-containing organic group) in its ring and is characterized in that the heteroaromatic ring compound having a N—H group in its ring is allowed to react with fluoroalkene in the absence of an alkali metal.
摘要翻译：提供了一种制备方法，其中在其环中具有N-H基团的杂芳环化合物的N-H基团在不使用催化剂的情况下以高反应效率直接转化为N-Rf基团。制备方法是在环中制备包含具有N-Rf基（-Rf为含氟有机基团）的杂芳环结构的化合物的方法，其特征在于具有N-H基的杂芳环化合物在不存在碱金属的情况下使其与氟代烯烃反应。

8. 发明申请

US20100164330A1 ACTUATOR ELEMENT 有权
标题翻译：执行元件
公开(公告)号：US20100164330A1
公开(公告)日：2010-07-01
申请号：US12161275
申请日：2007-01-22
申请人： Yuzo Komatsu , Keiko Hirata , Haruhiko Mohri , Hirokazu Aoyama
发明人： Yuzo Komatsu , Keiko Hirata , Haruhiko Mohri , Hirokazu Aoyama
IPC分类号： H01L41/193 , H01L41/18
CPC分类号： H01B1/122 , C08K5/0008 , C08K5/3445 , C08K7/24 , C09D127/12 , H02N11/006 , Y10S310/80
摘要： There is provided an actuator element which can be driven at low voltages, is operated stably in air and in vacuo with a quick response, exhibits a large degree of displacement and a large displacement force, has high mechanical strength including flexibility, thus giving long-term durability for repeated use, can be produced by a very simple method, can be formed into a small size because of a simple structure, and can be put into practical use in wide applications. The actuator element is comprised of an ion-conducting layer for an actuator element comprising (I) a fluorine-containing polymer having functional group and (II) an ionic liquid, in which the fluorine-containing polymer having functional group is a polymer having functional group selected from the group consisting of —OH, —COOH, —COOR, —CN, iodine atom, epoxy group and (meth)acryloyl group in a polymer side chain and/or at an end of a polymer trunk chain, and an electrode layer comprising (I) the fluorine-containing polymer having functional group, (II) an ionic liquid and (III) an electroconductive nano-filler.
摘要翻译：提供了可以在低电压下驱动的致动器元件，在空气中和在真空中以快速响应稳定地操作，表现出大的位移和大的位移力，具有高的机械强度，包括柔性，反复使用的长期耐用性可以通过非常简单的方法制造，由于结构简单而可以形成小尺寸，并且可以广泛应用于实际应用中。致动器元件包括用于致动器元件的离子传导层，其包括（I）具有官能团的含氟聚合物和（II）离子液体，其中具有官能团的含氟聚合物是具有官能团的聚合物在聚合物侧链和/或聚合物主链的末端选自-OH，-COOH，-COOR，-CN，碘原子，环氧基和（甲基）丙烯酰基的基团，和电极层（I）具有官能团的含氟聚合物，（II）离子液体和（III）导电纳米填料。

9. 发明申请

US20100292408A1 PROCESS FOR PREPARING END-MODIFIED VINYLIDENE FLUORIDE ELASTOMER 有权
标题翻译：制备末端改性的乙烯基氟化物弹性体的方法
公开(公告)号：US20100292408A1
公开(公告)日：2010-11-18
申请号：US12863549
申请日：2009-01-20
申请人： Yuzo Komatsu , Haruhiko Mohri , Hirokazu Aoyama , Takanori Fukushima , Takuzo Aida
发明人： Yuzo Komatsu , Haruhiko Mohri , Hirokazu Aoyama , Takanori Fukushima , Takuzo Aida
IPC分类号： C08F114/22
CPC分类号： C08C19/20 , C08F2/38 , C08F8/20 , C08F8/26 , C08F8/34 , C08F8/36 , C08F8/38 , C08F14/22 , C08F114/22 , C08F214/18 , C08F214/22 , C08F2810/40 , C08F214/28 , C08F8/12
摘要： The present invention provides a preparation process for converting to a vinylidene fluoride elastomer having a group having sulfinic acid, sulfinic acid derivative, sulfonic acid or sulfonic acid derivative at one end or both ends of its trunk chain, and the preparation process provides a vinylidene fluoride elastomer having, at one end or both ends of its trunk chain, end groups represented by the formula: —CR1R2—CR3R4—SO2H, wherein R1 to R4 may be the same or different and each is hydrogen atom or fluorine atom, by allowing a vinylidene fluoride elastomer having, at one end or both ends of its trunk chain, end groups represented by the formula: —CR1R2—CR3R4—X1, wherein R1 to R4 are as defined above, X1 is bromine atom or iodine atom, to react with a sulfur compound represented by the formula: (M1)nH2−nS2O4, wherein M1 is a monovalent or divalent metal ion or ammonium ion, n is an integer of 0 to 2.
摘要翻译：本发明提供一种在其主链的一端或两端转化为具有亚磺酸，亚磺酸衍生物，磺酸或磺酸衍生物的基团的偏二氟乙烯弹性体的制备方法，其制备方法提供偏二氟乙烯在其主链的一端或两端具有由下式表示的端基的弹性体：-CR1R2-CR3R4-SO2H，其中R1至R4可以相同或不同，各自为氢原子或氟原子，通过使偏二氟乙烯弹性体在其主链的一端或两端具有由下式表示的端基：-CR1R2-CR3R4-X1，其中R1至R4如上定义，X1为溴原子或碘原子，与由式（M1）nH2-nS2O4表示的硫化合物，其中M1是一价或二价金属离子或铵离子，n是0-2的整数。

10. 发明申请

US20090105400A1 FLUORINE-CONTAINING POLYMER HAVING HETEROAROMATIC RING 有权
标题翻译：含氟聚合物具有异构环
公开(公告)号：US20090105400A1
公开(公告)日：2009-04-23
申请号：US12278613
申请日：2007-02-05
申请人： Yuzo Komatsu , Haruhiko Mohri , Hirokazu Aoyama
发明人： Yuzo Komatsu , Haruhiko Mohri , Hirokazu Aoyama
IPC分类号： C08K3/04 , C08F18/20
CPC分类号： H01G9/038 , C08F8/44 , C08F14/18 , C08F214/26 , C08F214/28 , C08F216/1408 , C08F2800/10 , C08F2810/40 , C08K3/04 , C08L27/12 , C08L2205/02 , H01G11/56 , H01M2/16 , H01M8/1023 , H01M8/1039 , H01M10/0565 , H01M10/0567 , H01M10/0568 , H01M2300/0045 , H01M2300/0082 , H01M2300/0085 , Y02E60/13 , C08L2666/04 , C08F120/06 , C08F112/14 , C08F8/30 , C08F14/22 , C08F114/185
摘要： There is provided a fluorine-containing polymer having an ionic group which has a heteroaromatic ring and is useful as a material comprising various heteroaromatic ring compounds having a stable fluorine-containing heteroaromatic ring, and further a fluorine-containing polymer having a heteroaromatic ring which is useful as a starting material of the above-mentioned polymer or a curing agent. Also, there is provided a fluorine-containing polymer having a heteroaromatic ring such as imidazole in its side chain, a polymer salt thereof, and a polymer composition comprising such a polymer and a polymer salt and a nano filler.
摘要翻译：提供具有离子性基团的含氟聚合物，其具有杂芳环，并且可用作包含具有稳定的含氟杂芳环的各种杂芳环化合物的材料，并且还含有具有杂芳环的含氟聚合物，可用作上述聚合物或固化剂的原料。另外，提供了在其侧链中具有杂芳环如咪唑的含氟聚合物，其聚合物盐和包含这种聚合物和聚合物盐和纳米填料的聚合物组合物。

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