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1. 发明授权

US07373060B2 Optical waveguide using polymer composed of silsesquioxane derivative 有权
标题翻译：光波导使用由倍半硅氧烷衍生物构成的聚合物
公开(公告)号：US07373060B2
公开(公告)日：2008-05-13
申请号：US11363177
申请日：2006-02-28
申请人： Hideshi Satake , Nobuyuki Ootsuka , Yasuhiro Yamamoto , Kenya Ito , Nobumasa Ootake , Kazuhiro Yoshida
发明人： Hideshi Satake , Nobuyuki Ootsuka , Yasuhiro Yamamoto , Kenya Ito , Nobumasa Ootake , Kazuhiro Yoshida
IPC分类号： G02B6/02 , C08G77/04
CPC分类号： C08G77/38 , G02B6/02033
摘要： An optical waveguide is produced by using a polymer obtained by using a silsesquioxane derivative represented by the formula (1-0). In the formula (1-0), R0 independently represents hydrogen, alkyl having 1 to 40 carbon atoms in which optional hydrogen may be replaced by fluorine and optional —CH2— may optionally be replaced by —O—, —CH═CH—, cycloalkylene, or cycloalkenylene, aryl in which optional hydrogen may optionally be replaced by halogen, or with alkyl having 1 to 20 carbon atoms whereby optional hydrogen may be replaced by fluorine and optional —CH2— may be replaced by —O—, —CH═CH—, cycloalkylene, or phenylene, or arylalkyl in which optional hydrogen in the aryl may be replaced by halogen or alkyl having 1 to 20 carbon atoms, and hydrogen in the alkylene of the arylalkyl may be replaced by fluorine, and optional —CH2— in the alkylene of the arylalkyl may be replaced by —O—, —CH═CH—, or cycloalkylene, and Y is a group represented by the formula (a) or (b):
摘要翻译：通过使用通过使用由式（1-0）表示的倍半硅氧烷衍生物获得的聚合物制备光波导。在式（1-0）中，R 0独立地表示氢，具有1至40个碳原子的烷基，其中任选的氢可以被氟取代，并且任选的-CH 2 - 可以任选地被-O-，-CH-CH-，亚环烷基或环亚烯基取代，其中任选的氢可以任选被卤素取代的芳基或具有1至20个碳原子的烷基，由此任选的氢可被氟代替和任选的-CH 2 - 可以被-O - ， - CH-，亚环烷基或亚苯基取代，或芳基烷基，其中芳基中任选的氢可被卤素或具有1 至20个碳原子，芳基烷基的亚烷基中的氢可以被氟代替，并且芳基烷基的亚烷基中任选的-CH 2 - 可以被-O - ， - CH-CH - 或亚环烷基，Y为由式（a）或（b）表示的基团：

2. 发明申请

US20060204192A1 Optical waveguide using polymer composed of silsesquioxane derivative 有权
标题翻译：光波导使用由倍半硅氧烷衍生物构成的聚合物
公开(公告)号：US20060204192A1
公开(公告)日：2006-09-14
申请号：US11363177
申请日：2006-02-28
申请人： Hideshi Satake , Nobuyuki Ootsuka , Yasuhiro Yamamoto , Kenya Ito , Nobumasa Ootake , Kazuhiro Yoshida
发明人： Hideshi Satake , Nobuyuki Ootsuka , Yasuhiro Yamamoto , Kenya Ito , Nobumasa Ootake , Kazuhiro Yoshida
IPC分类号： G02B6/02 , C08G77/04
CPC分类号： C08G77/38 , G02B6/02033
摘要： An optical waveguide is produced by using a polymer obtained by using a silsesquioxane derivative represented by the formula (1-0). In the formula (1-0), R0 independently represents hydrogen, alkyl having 1 to 40 carbon atoms in which optional hydrogen may be replaced by fluorine and optional —CH2— may be replaced by —O—, —CH═CH—, cycloalkylene, or cycloalkenylene, aryl in which optional hydrogen may be replaced by halogen, or with alkyl having 1 to 20 carbon atoms whereby optional hydrogen may be replaced by fluorine and optional —CH2— may be replaced by —O—, —CH═CH—, cycloalkylene, or phenylene, or arylalkyl in which optional hydrogen in the aryl may be replaced by halogen or alkyl having 1 to 20 carbon atoms, and optional hydrogen in the alkylene of the arylalkyl may be replaced by fluorine, and optional —CH2— in the alkylene of the arylalkyl may be replaced by —O—, —CH═CH—, or cycloalkylene, and Y is a group represented by the formula (a) or (b).
摘要翻译：通过使用通过使用由式（1-0）表示的倍半硅氧烷衍生物获得的聚合物制备光波导。在式（1-0）中，R 0独立地表示氢，具有1至40个碳原子的烷基，其中任选的氢可以被氟取代，并且任选的-CH 2 - 可以被-O - ， - CH-CH-，亚环烷基或环亚烯基取代，其中任选的氢可被卤素取代的芳基或具有1至20个碳原子的烷基，由此任选的氢可以被氟代替， -CH 2 - 可以被-O - ， - CH-，亚环烷基或亚苯基或芳基烷基取代，其中芳基中任选的氢可以被卤素或具有1至20个的烷基取代碳原子和芳基烷基的亚烷基中任选的氢可以被氟代替，芳基烷基的亚烷基中任选的-CH 2 - 可被-O - ， - CH-CH- ，或亚环烷基，Y为式（a）或（b）所示的基团。

3. 发明申请

US20060204680A1 Varnish for forming liquid crystal alignment layer and liquid crystal display element using the same 有权
标题翻译：用于形成液晶取向层的清漆和使用其的液晶显示元件
公开(公告)号：US20060204680A1
公开(公告)日：2006-09-14
申请号：US11363175
申请日：2006-02-28
申请人： Takayuki Hattori , Keizo Iwatani , Nobuyuki Ootsuka , Takashi Katoh , Kenya Ito , Nobumasa Ootake , Kazuhiro Yoshida
发明人： Takayuki Hattori , Keizo Iwatani , Nobuyuki Ootsuka , Takashi Katoh , Kenya Ito , Nobumasa Ootake , Kazuhiro Yoshida
IPC分类号： C09K19/00
CPC分类号： G02F1/133719 , C09K19/56 , Y10T428/1014 , Y10T428/1045 , Y10T428/1068
摘要： A varnish for forming a liquid crystal alignment layer is prepared by formulating a polymer obtained by using a silsesquioxane derivative represented by the formula (1), and a solvent. In the formula (1), R independently represents an unsubstituted phenyl, cyclopentyl, cyclohexyl, or t-butyl group, and Y1 independently represents a group selected from the following formulae (a-1) to (a-6).
摘要翻译：通过配制通过使用由式（1）表示的倍半硅氧烷衍生物获得的聚合物和溶剂来制备用于形成液晶取向层的清漆。在式（1）中，R独立地表示未取代的苯基，环戊基，环己基或叔丁基，Y 1独立地表示选自下式（a-1）至（ a-6）。

4. 发明授权

US07507450B2 Varnish for forming liquid crystal alignment layer and liquid crystal display element using the same 有权
标题翻译：用于形成液晶取向层的清漆和使用其的液晶显示元件
公开(公告)号：US07507450B2
公开(公告)日：2009-03-24
申请号：US11363175
申请日：2006-02-28
申请人： Takayuki Hattori , Keizo Iwatani , Nobuyuki Ootsuka , Takashi Katoh , Kenya Ito , Nobumasa Ootake , Kazuhiro Yoshida
发明人： Takayuki Hattori , Keizo Iwatani , Nobuyuki Ootsuka , Takashi Katoh , Kenya Ito , Nobumasa Ootake , Kazuhiro Yoshida
IPC分类号： C08L83/00
CPC分类号： G02F1/133719 , C09K19/56 , Y10T428/1014 , Y10T428/1045 , Y10T428/1068
摘要： A varnish for forming a liquid crystal alignment layer is prepared by formulating a polymer obtained by using a silsesquioxane derivative represented by the formula (1), and a solvent. In the formula (1), R independently represents an unsubstituted phenyl, cyclopentyl, cyclohexyl, or t-butyl group, and Y1 independently represents a group selected from the following formulae (a-1) to (a-6).
摘要翻译：通过配制通过使用由式（1）表示的倍半硅氧烷衍生物获得的聚合物和溶剂来制备用于形成液晶取向层的清漆。在式（1）中，R独立地表示未取代的苯基，环戊基，环己基或叔丁基，Y1独立地表示选自下式（a-1）至（a-6）的基团。

5. 发明授权

US07399819B2 Silicon compound 有权
标题翻译：硅化合物
公开(公告)号：US07399819B2
公开(公告)日：2008-07-15
申请号：US10528001
申请日：2003-09-17
申请人： Mikio Yamahiro , Hisao Oikawa , Kazuhiro Yoshida , Kenya Ito , Yasuhiro Yamamoto , Masami Tanaka , Nobumasa Ootake , Kenichi Watanabe , Kohji Ohno , Yoshinobu Tsujii , Takeshi Fukuda
发明人： Mikio Yamahiro , Hisao Oikawa , Kazuhiro Yoshida , Kenya Ito , Yasuhiro Yamamoto , Masami Tanaka , Nobumasa Ootake , Kenichi Watanabe , Kohji Ohno , Yoshinobu Tsujii , Takeshi Fukuda
IPC分类号： C08G77/24
CPC分类号： C08G77/442 , C07F7/21 , C08G77/045 , C08G77/38
摘要： A large part of conventional organic-inorganic composite materials is obtained by mechanical blending silsesquioxanes with organic polymers, and therefore it has been very difficult to control the structure thereof as the molecular aggregate of the composite materials. An object of the present invention is to provide a novel silicon compound having a living radical polymerization-initiating ability for an addition-polymerizable monomer and a polymer obtained using the same to thereby solve the problem described above regarding the conventional organic-inorganic composite materials. The present inventors have found that a novel silsesquioxane derivative to which a group having an ability to initiate polymerization of a monomer is useful as means for solving the problem described above. That is, the silsesquioxane derivative of the present invention is represented by Formula (1): wherein R1 is hydrogen, alkyl, aryl or arylalkyl; R2 and R3 are alkyl, phenyl or cyclohexyl; and A is a group having an ability to initiate polymerization of a monomer.
摘要翻译：通过将倍半硅氧烷与有机聚合物机械共混获得大部分常规有机 - 无机复合材料，因此非常难以控制其作为复合材料的分子骨料的结构。本发明的目的是提供一种具有可加聚单体的活性自由基聚合引发能力的新型硅化合物和使用该硅化合物获得的聚合物，从而解决了有关常规有机 - 无机复合材料的上述问题。本发明人已经发现，具有引发单体聚合能力的基团的新型倍半硅氧烷衍生物可用作解决上述问题的手段。也就是说，本发明的倍半硅氧烷衍生物由式（1）表示：其中R 1是氢，烷基，芳基或芳基烷基; R 2和R 3是烷基，苯基或环己基; 而A是具有引发单体聚合能力的基团。

6. 发明授权

US07964692B2 Polymer obtained by addition-polymerization initiated by a silicon compound 有权
标题翻译：通过硅化合物引发的加成聚合得到的聚合物
公开(公告)号：US07964692B2
公开(公告)日：2011-06-21
申请号：US12318733
申请日：2009-01-07
申请人： Mikio Yamahiro , Hisao Oikawa , Kenya Ito , Yasuhiro Yamamoto , Masami Tanaka , Nobumasa Ootake , Kenichi Watanabe , Kohji Ohno , Yoshinobu Tsujii , Takeshi Fukuda
发明人： Mikio Yamahiro , Hisao Oikawa , Kenya Ito , Yasuhiro Yamamoto , Masami Tanaka , Nobumasa Ootake , Kenichi Watanabe , Kohji Ohno , Yoshinobu Tsujii , Takeshi Fukuda
IPC分类号： C08G77/04
CPC分类号： C08G77/04 , C07F7/21 , C08F10/00 , C08F30/08 , C08F2500/03
摘要： A polymer represented by Formula (7): wherein all variables are defined in the specification, including P1 which is a polymer chain obtained by polymerizing an addition-polymerizable monomer, which makes it possible to control the structure of the polymer as a molecular aggregate.
摘要翻译：由式（7）表示的聚合物：其中所有变量在本说明书中定义，包括P1是通过聚合可加聚单体获得的聚合物链，其可以将聚合物的结构控制为分子聚集体。

7. 发明授权

US07863396B2 Silicon compounds 有权
标题翻译：硅化合物
公开(公告)号：US07863396B2
公开(公告)日：2011-01-04
申请号：US10548365
申请日：2004-03-05
申请人： Mikio Yamahiro , Hisao Oikawa , Kenya Ito , Yasuhiro Yamamoto , Masami Tanaka , Nobumasa Ootake , Kenichi Watanabe , Kohji Ohno , Yoshinobu Tsujii , Takeshi Fukuda
发明人： Mikio Yamahiro , Hisao Oikawa , Kenya Ito , Yasuhiro Yamamoto , Masami Tanaka , Nobumasa Ootake , Kenichi Watanabe , Kohji Ohno , Yoshinobu Tsujii , Takeshi Fukuda
IPC分类号： C08F130/08
CPC分类号： C08G77/04 , C07F7/21 , C08F10/00 , C08F30/08 , C08F2500/03
摘要： The present invention provides a silicon compound represented by Formula (1) and a polymer obtained by using the same, and this makes it possible not only to obtain an organic-inorganic composite material having a distinct structure but also to control the structure of the above polymer as a molecular aggregate. wherein R1 is a group independently selected from hydrogen, alkyl having a carbon atom number of 1 to 40, substituted or non-substituted aryl and substituted or non-substituted arylalkyl; in this alkyl having a carbon atom number of 1 to 40, optional hydrogens may be substituted with fluorine, and optional —CH2— may be substituted with —O—, —CH═CH—, cycloalkylene or cycloalkenylene; in alkylene in this arylalkyl, optional hydrogens may be substituted with fluorine, and optional —CH2— may be substituted with —O— or —CH═CH—; and A1 is a group having an α-haloester group.
摘要翻译：本发明提供由式（1）表示的硅化合物和使用它的聚合物，不仅可以获得具有不同结构的有机 - 无机复合材料，而且可以控制上述结构聚合物作为分子聚集体。其中R1是独立地选自氢，碳原子数为1至40的烷基，取代或未取代的芳基和取代或未取代的芳基烷基的基团; 在该碳原子数为1至40的烷基中，任选的氢可以被氟取代，并且任选的-CH 2 - 可以被-O - ， - CH = CH-，亚环烷基或环亚烯基取代; 在该芳烷基中的亚烷基中，任选的氢可以被氟取代，并且任选的-CH 2 - 可以被-O-或-CH = CH-取代; A1为具有α-卤代基团的基团。

8. 发明授权

US07662985B2 Production process for a silicon compound 有权
标题翻译：硅化合物的生产工艺
公开(公告)号：US07662985B2
公开(公告)日：2010-02-16
申请号：US12318736
申请日：2009-01-07
申请人： Mikio Yamahiro , Hisao Oikawa , Kenya Ito , Yasuhiro Yamamoto , Masami Tanaka , Nobumasa Ootake , Kenichi Watanabe , Kohji Ohno , Yoshinobu Tsujii , Takeshi Fukuda
发明人： Mikio Yamahiro , Hisao Oikawa , Kenya Ito , Yasuhiro Yamamoto , Masami Tanaka , Nobumasa Ootake , Kenichi Watanabe , Kohji Ohno , Yoshinobu Tsujii , Takeshi Fukuda
IPC分类号： C07F7/04
CPC分类号： C08G77/04 , C07F7/21 , C08F10/00 , C08F30/08 , C08F2500/03
摘要： A production process for a silicon compound represented by Formula (6), characterized by reacting a compound represented by Formula (4) with a compound represented by Formula (5): wherein all of the variables are defined in the specification.
摘要翻译：一种由式（6）表示的硅化合物的制备方法，其特征在于使由式（4）表示的化合物与式（5）表示的化合物反应：其中所有变量在说明书中定义。

9. 发明申请

US20060287454A1 Silicon compounds 有权
标题翻译：硅化合物
公开(公告)号：US20060287454A1
公开(公告)日：2006-12-21
申请号：US10548365
申请日：2004-03-05
申请人： Mikio Yamahiro , Hisao Oikawa , Kenya Ito , Yasuhiro Yamamoto , Masami Tanaka , Nobumasa Ootake , Kenichi Watanabe , Kohji Ohno , Yoshinobu Tsujii , Takeshi Fukuda
发明人： Mikio Yamahiro , Hisao Oikawa , Kenya Ito , Yasuhiro Yamamoto , Masami Tanaka , Nobumasa Ootake , Kenichi Watanabe , Kohji Ohno , Yoshinobu Tsujii , Takeshi Fukuda
IPC分类号： C08F230/08 , C07F7/04
CPC分类号： C08G77/04 , C07F7/21 , C08F10/00 , C08F30/08 , C08F2500/03
摘要： The present invention provides a silicon compound represented by Formula (1) and a polymer obtained by using the same, and this makes it possible not only to obtain an organic-inorganic composite material having a distinct structure but also to control the structure of the above polymer as a molecular aggregate. wherein R1 is a group independently selected from hydrogen, alkyl having a carbon atom number of 1 to 40, substituted or non-substituted aryl and substituted or non-substituted arylalkyl; in this alkyl having a carbon atom number of 1 to 40, optional hydrogens may be substituted with fluorine, and optional —CH2— may be substituted with —O—, —CH═CH—, cycloalkylene or cycloalkenylene; in alkylene in this arylalkyl, optional hydrogens may be substituted with fluorine, and optional —CH2— may be substituted with —O— or —CH═CH—; and A1 is a group having an α-haloester bond.
摘要翻译：本发明提供由式（1）表示的硅化合物和使用它的聚合物，不仅可以获得具有不同结构的有机 - 无机复合材料，而且可以控制上述结构聚合物作为分子聚集体。其中R 1是独立地选自氢，碳原子数为1至40的烷基，取代或未取代的芳基和取代或未取代的芳基烷基的基团; 在该碳原子数为1至40的烷基中，任选的氢可被氟取代，并且任选的-CH 2 - 可以被-O-，-CH-CH-，亚环烷基或环亚烯基在该芳烷基中的亚烷基中，任选的氢可以被氟取代，任选的-CH 2 - 可以被-O-或-CH-CH-取代; 且A 1是具有α-卤代酯键的基团。

10. 发明申请

US20090143606A1 Production process for a silicon compound 有权
标题翻译：硅化合物的生产工艺
公开(公告)号：US20090143606A1
公开(公告)日：2009-06-04
申请号：US12318736
申请日：2009-01-07
申请人： Mikio Yamahiro , Hisao Oikawa , Kenya Ito , Yasuhiro Yamamoto , Masami Tanaka , Nobumasa Ootake , Kenichi Watanabe , Kohji Ohno , Yoshinobu Tsujii , Takeshi Fukuda
发明人： Mikio Yamahiro , Hisao Oikawa , Kenya Ito , Yasuhiro Yamamoto , Masami Tanaka , Nobumasa Ootake , Kenichi Watanabe , Kohji Ohno , Yoshinobu Tsujii , Takeshi Fukuda
IPC分类号： C07F7/07
CPC分类号： C08G77/04 , C07F7/21 , C08F10/00 , C08F30/08 , C08F2500/03
摘要： The present invention provides a silicon compound represented by Formula (1) and a polymer obtained by using the same, and this makes it possible not only to obtain an organic-inorganic composite material having a distinct structure but also to control the structure of the above polymer as a molecular aggregate. wherein R1 is a group independently selected from hydrogen, alkyl having a carbon atom number of 1 to 40, substituted or non-substituted aryl and substituted or non-substituted arylalkyl; in this alkyl having a carbon atom number of 1 to 40, optional hydrogens may be substituted with fluorine, and optional —CH2— may be substituted with —O—, —CH═CH—, cycloalkylene or cycloalkenylene; in alkylene in this arylalkyl, optional hydrogens may be substituted with fluorine, and optional —CH2— may be substituted with —O— or —CH═CH—; and A1 is a group having an α-haloester bond.
摘要翻译：本发明提供由式（1）表示的硅化合物和使用它的聚合物，不仅可以获得具有不同结构的有机 - 无机复合材料，而且可以控制上述结构聚合物作为分子聚集体。其中R1是独立地选自氢，碳原子数为1至40的烷基，取代或未取代的芳基和取代或未取代的芳基烷基的基团; 在该碳原子数为1至40的烷基中，任选的氢可以被氟取代，任选的-CH 2 - 可以被-O - ， - CH-CH-，亚环烷基或环亚烯基取代; 在该芳基烷基中的亚烷基中，任选的氢可以被氟取代，并且任选的-CH 2 - 可以被-O-或-CH-CH-取代; 并且A1是具有α-卤代酯键的基团。

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