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    • 3. 发明授权
    • Recording materials containing chromenoindoles
    • 含有色烯吲哚的记录材料
    • US4220356A
    • 1980-09-02
    • US16465
    • 1979-03-01
    • Hideo UsuiSadao IshigeKeiso Saeki
    • Hideo UsuiSadao IshigeKeiso Saeki
    • G03C1/72B41M5/136B41M5/323C07D491/04C07D491/052C09B11/26C09B57/00C09D11/00C09D11/16C09D11/18C09D11/52C09D13/00G03C1/675B41M5/16B41M5/22
    • B41M5/323B41M5/136C07D491/04Y10S428/914
    • A chromenoindole derivative of the following general formula (I): ##STR1## wherein R.sub.1 and R.sub.2, which may be the same or different, each represents an alkyl group, an alkyl group substituted with one or more of a cyano group, a halogen atom or an alkoxy group, an aralkyl group, a phenyl group or a phenyl group substituted with one or more of an alkyl group or a halogen atom; X represents a hydrogen atom, an alkoxy group, a dialkylamino group, an alkylarylamino group, an alkylaralkylamino group, a diaralkylamino group, an acylamino group, a halogen atom or an alkyl group; Y represents a hydrogen atom, an alkyl group, a halogen atom, an alkoxy group of a nitro group; Z represents an acyl group, or a sulfonyl group; Q.sub.1 and Q.sub.2, which may be the same or different, each represents a hydrogen atom, a lower alkyl group or a halogen atom; and A.sub.1, A.sub.2, A.sub.3 and A.sub.4, which may be the same or different, each represents a halogen atom, an alkyl group or an alkoxy group; which upon contact with an electron acceptor material forms a color with superior light fastness and which is useful as a color former in various recording materials such as pressure-sensitive recording sheets, thermosensitive recording sheets, electrothermosensitive recording sheets, and photosensitive recording sheets.
    • 下列通式(I)的色烯衍生物:其中R 1和R 2可以相同或不同,各自表示烷基,被一个或多个氰基取代的烷基, 卤素原子或烷氧基,芳烷基,苯基或被一个或多个烷基或卤素原子取代的苯基; X表示氢原子,烷氧基,二烷基氨基,烷基芳基氨基,烷基芳基烷基氨基,二芳基烷基氨基,酰基氨基,卤素原子或烷基。 Y表示氢原子,烷基,卤素原子,硝基的烷氧基; Z表示酰基或磺酰基; Q1和Q2可以相同或不同,分别表示氢原子,低级烷基或卤素原子; 和可以相同或不同的A1,A2,A3和A4各自表示卤素原子,烷基或烷氧基; 其与电子受体材料接触形成具有优异耐光性的颜色,并且其可用作各种记录材料如压敏记录片材,热敏记录片材,电热敏记录片材和感光记录片材中的成色剂。
    • 4. 发明授权
    • Thiazine production
    • 噻嗪生产
    • US4119777A
    • 1978-10-10
    • US751874
    • 1976-12-17
    • Hideo UsuiSadao IshigeKeiso Saeki
    • Hideo UsuiSadao IshigeKeiso Saeki
    • C09B21/00B41M5/136C07D279/08C07D513/04C07D513/10C07D513/20C07D279/14C07D279/16
    • C07D513/04B41M5/136C07D279/08C07D513/10
    • A thiazine derivative, which forms a color on contact with an electron accepting material, represented by the formula (II): ##STR1## wherein A.sub.1 and A.sub.2, which may be the same or different, each represents an aryl group or a heterocyclic group and A.sub.1 and A.sub.2 may combine together to form a heterocyclic ring or a fluorene ring, the ring B represents an aromatic hydrocarbon ring or a heterocyclic ring, and Y represents a hydrogen atom, an aliphatic group, an aryl group, a heterocyclic group, an amino group, an amido group, an oxy group or a thio group, but at least one of A.sub.1 and A.sub.2 or the ring formed by the combination of A.sub.1 and A.sub.2 represents an electron donating aryl group or an electron donating heterocyclic group, and a process for preparing the thiazine derivatives represented by the formula (II) by oxidizing a thioamide derivative represented by the formula (I): ##STR2## wherein A.sub.1, A.sub.2, B and Y are as above described.
    • 由式(II)表示的形成与电子接受材料接触的颜色的噻嗪衍生物:其中A1和A2可以相同或不同,各自表示芳基或 杂环基和A1和A2可以结合在一起形成杂环或芴环,环B表示芳香族烃环或杂环,Y表示氢原子,脂肪族基团,芳基,杂环基 氨基,酰胺基,氧基或硫基,但A1和A2中的至少一个或通过A1和A2的组合形成的环表示给电子芳基或给电子杂环基,并且 通过氧化由式(I)表示的硫代酰胺衍生物制备式(II)表示的噻嗪衍生物的方法:其中A1,A2,B和Y如上所述。
    • 5. 发明授权
    • Recording material
    • 录音材料
    • US4132436A
    • 1979-01-02
    • US764618
    • 1977-02-01
    • Sadao IshigeHideo UsuiKeiso Saeki
    • Sadao IshigeHideo UsuiKeiso Saeki
    • C07D279/08B41M5/136B41M5/20B41M5/323C09B11/00C09B11/26C09B11/28C09B21/00G03C1/73B41M5/22B41M5/18
    • B41M5/20B41M5/136B41M5/323Y10S428/913Y10S428/914
    • A recording material comprising (1) at least one thiazine compound capable of forming a color when contacted with an electron accepting material and represented by the following general formula (I): ##STR1## wherein A.sub.1 and A.sub.2, which may be the same or different, each represents an aryl group or a hetero ring residue or, when taken together, A.sub.1 and A.sub.2 represent a hetero ring or a fluorene ring; ring B represents an aromatic hydrocarbon ring or a hetero ring; and Y represents a hydrogen atom, an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a hetero ring residue, an amino group, an amido group, a hydroxy group or a thio group; provided that at least one of A.sub.1 and A.sub.2 or, when A.sub.1 and A.sub.2 are taken together, the ring formed by A.sub.1 and A.sub.2, is an electron donating aryl group, an electron donating hetero ring residue or an electron donating fluorene ring residue; and (2) an electron accepting material.
    • 一种记录材料,其包含(1)当与电子接受材料接触并且由以下通式(I)表示时能够形成颜色的至少一种噻嗪化合物:其中A1和A2可以是 相同或不同,各自表示芳基或杂环残基,或者当一起为A1和A2表示杂环或芴环时; 环B表示芳族烃环或杂环; Y表示氢原子,烷基,芳烷基,烯基,炔基,芳基,杂环残基,氨基,酰胺基,羟基或硫基; 条件是A1和A2中的至少一个,或者当A1和A2合在一起时,由A1和A2形成的环是供电子基团,给电子杂环残基或给电子芴环残基; 和(2)电子接受材料。
    • 7. 发明授权
    • Optical image-recording material
    • 光学图像记录材料
    • US5051333A
    • 1991-09-24
    • US541865
    • 1990-06-21
    • Naoto YanagiharaKen IwakuraTosiaki EndoKeiso Saeki
    • Naoto YanagiharaKen IwakuraTosiaki EndoKeiso Saeki
    • G03C1/00G03F7/004
    • G03C1/002G03F7/002
    • An optical image-recording material comprising:(a) microcapsules, in which at least one leuco dye capable of forming a color by oxidation and at least one photo-oxidizing agent are enclosed together, and (b) at least one reducing agent not enclosed in the microcapsules, or(c) microcapsules, in which at least one reducing agent is enclosed, and (d) both at least one leuco dye capable of forming a color by oxidation and at least one photo-oxidizing agent not enclosed in the microcapsules,wherein the microcapsules have capsule walls made from a material which lowers its permeability barrier to at least one component selected from the photo-oxidizing agent and the reducing agent when the capsule wall material is heated above its glass transition temperature, and the leuco dye is a xanthene compound having an N-substituted anilino group substituted by an electron attracting group.
    • 一种光学图像记录材料,包括:(a)微胶囊,其中至少一种能够通过氧化形成颜色的无色染料和至少一种光氧化剂被包封在一起,和(b)至少一种不包含的还原剂 在微胶囊中,或(c)其中封闭有至少一种还原剂的微胶囊,和(d)能够通过氧化形成颜色的至少一种无色染料和不包封在微胶囊中的至少一种光氧化剂 其中,所述微胶囊具有由将所述胶囊壁材料加热到高于其玻璃化转变温度时将其对所述光氧化剂和还原剂中的至少一种成分的透过性阻挡性降低的材料制成的胶囊壁,所述无色染料为 具有被吸电子基团取代的N-取代苯胺基的呫吨化合物。
    • 8. 发明授权
    • Color developer sheet
    • 彩色显影片
    • US4870048A
    • 1989-09-26
    • US179356
    • 1988-04-08
    • Katsumi MatsuokaShojiro SanoKeiso SaekiMasanobu TakashimaKen Iwakura
    • Katsumi MatsuokaShojiro SanoKeiso SaekiMasanobu TakashimaKen Iwakura
    • B41M5/333B41M5/155C07F15/04C07F15/06
    • B41M5/155Y10S428/914Y10T428/277
    • A color developer sheet which brings about color development by contact with a substantially colorless electron-donating color former, where said sheet contains an organometallic compound represented by the following general formula (I), (II) or (III) to enhance light resistance and stability of the color product obtained by the color development: ##STR1## wherein M represents a nickel atom, a copper atom, a cobalt atom, or a zinc atom; X.sub.1 and X.sub.2 each represents an oxygen atom, a sulfur atom, or --NR.sub.5 --, in which R.sub.5 represents a hydrogen atom, an alkyl group, an aryl group, or a hydroxyl group; X.sub.3 represents a hydroxyl group, or a mercapto group; Y represents an oxygen atom, a sulfur atom, or --CHR.sub.6, in which R.sub.6 represents a hydrogen atom, an alkyl group, or an aryl group; R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents a hydrogen atom, a halogen atom, a cyano group, or an alkyl, aryl, cycloalkyl or heterocyclyl group attached to the carbon atom directly or via a divalent linkage group, or at least either combination of R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4 may be connected to each other to form a 5- or 6-membered ring together with the carbon atoms; and Z represents an organic ligand which forms a complex by binding to M via its hetero atom.
    • 一种通过与基本上无色的给电子成色剂接触而引起显色的彩色显影片,其中所述片含有由以下通式(I),(II)或(III)表示的有机金属化合物,以提高耐光性, (II)其中M表示镍原子,铜原子,钴原子或锌原子;(III)其中M表示镍原子, X 1和X 2各自表示氧原子,硫原子或-NR 5 - ,其中R 5表示氢原子,烷基,芳基或羟基; X3表示羟基或巯基; Y表示氧原子,硫原子或-CHR6,其中R6表示氢原子,烷基或芳基; R 1,R 2,R 3和R 4各自表示直接或经由二价连接基团连接到碳原子上的氢原子,卤原子,氰基或烷基,芳基,环烷基或杂环基,或至少 R 1和R 2和/或R 3和R 4可以彼此连接以与碳原子一起形成5-或6-元环; Z表示通过其杂原子与M结合形成络合物的有机配体。