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1. 发明授权

US4994590A Ruthenium-phoshine complex 失效
标题翻译：钌 - 磷光复合物
公开(公告)号：US4994590A
公开(公告)日：1991-02-19
申请号：US427209
申请日：1989-10-24
申请人： Hidemasa Takaya , Kazushi Mashima , Hidenori Kumobayashi , Noboru Sayo
发明人： Hidemasa Takaya , Kazushi Mashima , Hidenori Kumobayashi , Noboru Sayo
IPC分类号： B01J31/24 , C07B61/00 , C07C51/36 , C07C67/31 , C07C69/675 , C07F15/00 , C07F9/50
CPC分类号： B01J31/2452 , C07C51/36 , C07C67/31 , C07F15/0053 , B01J2231/641 , B01J2231/643 , B01J2531/0266 , B01J2531/821
摘要： A ruthenium-phosphine complex represented by formula (I)[RuX.sub.l (L).sub.m (R-BINAP)]Y.sub.n (I)wherein R-BINAP represents a tertiary phosphine represented by formula (II): ##STR1## wherein R represents a hydrogen atom or a methyl group; X represents a halogen atom; L represents substituted or unsubstituted benzene or acetonitrile; Y represents a halogen atom, CLO.sub.4, PF.sub.6, BPh.sub.4 (wherein Ph represents a phenyl group) or BF.sub.4 ; when L is substituted or unsubstituted benzene, l represents 1, m represents 1, and n represents 1; and whe L is acetonitrile, when l is 1, then m represents 2, and n represents 1, and when l is 0, the m represents 4, and n represent 2. The complex exhibits excellent catalytic activity in asymmetric reactions to provide a product of high optical purity. The complex can be produced at low cost.

2. 发明授权

US5210332A Iridium-optically active phosphine complex and process for producing optically active alcohols using the same 失效
标题翻译：铱 - 光学活性膦配合物和使用其制备光学活性醇的方法
公开(公告)号：US5210332A
公开(公告)日：1993-05-11
申请号：US856403
申请日：1992-03-20
申请人： Takanao Taketomi , Susumu Akutagawa , Hidenori Kumobayashi , Hidemasa Takaya , Kazushi Mashima
发明人： Takanao Taketomi , Susumu Akutagawa , Hidenori Kumobayashi , Hidemasa Takaya , Kazushi Mashima
IPC分类号： C07F15/00
CPC分类号： C07F15/004
摘要： An iridium-optically active phosphine complex represented by formula (I):[H.sub.2 Ir(L.sup.1)(L.sup.2)]Y (I)wherein L.sup.1 represents an optically active phosphine compound represented by formula (II): ##STR1## wherein Ar represents a phenyl group or a p- and/or m-lower alkyl-substituted phenyl group, or formula (III): ##STR2## L.sup.2 represents a tertiary phosphine compound represented by formula (IV): ##STR3## wherein Z represents a lower alkoxy group or a di-lower alkylamino group; and A represents an integer of from 1 to 3; Y represents BF.sub.4, PF.sub.6, ClO.sub.4, or BPh.sub.4, wherein Ph represents a phenyl group,and a process for producing an optically active alcohol using the above complex as an enantioselective catalyst are disclosed. The complex exhibits excellent catalytic activity to give high enantioselective yields in enantioselective synthesis, particularly enantioselective hydrogenation.
摘要翻译：由式（I）表示的铱光学活性膦配合物：[H2Ir（L1）（L2）] Y（I）其中L1表示由式（II）表示的光学活性膦化合物：其中Ar （III）表示式（IV）表示的叔膦化合物：（IV）表示的叔膦化合物：其中，）其中Z表示低级烷氧基或二低级烷基氨基; A表示1〜3的整数， Y表示BF4，PF6，ClO4或BPh4，其中Ph表示苯基，并且公开了使用上述络合物作为对映选择性催化剂制备光学活性醇的方法。复合物显示出优异的催化活性，以在对映选择性合成，特别是对映选择性氢化中提供高对映选择性的产率。

3. 发明授权

US5159093A Iridium-optically active phosphine complex and process for producing optically active alcohols using the same 失效
标题翻译：光电活性磷酸盐复合物及使用其生产光学活性醇的方法
公开(公告)号：US5159093A
公开(公告)日：1992-10-27
申请号：US769280
申请日：1991-10-01
申请人： Takanao Taketomi , Susumu Akutagawa , Hidenori Kumobayashi , Hidemasa Takaya , Kazushi Mashima
发明人： Takanao Taketomi , Susumu Akutagawa , Hidenori Kumobayashi , Hidemasa Takaya , Kazushi Mashima
IPC分类号： B01J31/24 , C07B53/00 , C07B61/00 , C07C29/145 , C07C33/03 , C07F9/50 , C07F15/00
CPC分类号： C07F15/004
摘要： An iridium-optically active phosphine complex represented by formula (I):[H.sub.2 Ir(L.sup.1)(L.sup.2)]Y (I)wherein L.sup.1 represents an optically active phosphine compound represented by formula (II): ##STR1## wherein Ar represents a phenyl group or a p- and/or m-lower alkyl-substituted phenyl group, or formula (III): ##STR2## L.sup.2 represents a tertiary phosphine compound represented by formula (IV): ##STR3## wherein Z represents a lower alkoxy group or a di-lower alkylamino group; and A represents an integer of from 1 to 3; Y represents BF.sub.4, PF.sub.6, ClO.sub.4, or BPh.sub.4, wherein Ph represents a phenyl group, and a process for producing an optically active alcohol using the above complex as an enantioselective catalyst are disclosed. The complex exhibits excellent catalytic activity to give high enantioselective yields in enantioselective synthesis, particularly enantioselective hydrogenation.

4. 发明授权

US5919962A Process for preparing ruthenium-phosphine complex 失效
标题翻译：制备钌膦配合物的方法
公开(公告)号：US5919962A
公开(公告)日：1999-07-06
申请号：US933973
申请日：1997-09-19
申请人： Noboru Sayo , Kazushi Mashima , Kyoko Tamao , Tetsuo Ota
发明人： Noboru Sayo , Kazushi Mashima , Kyoko Tamao , Tetsuo Ota
IPC分类号： B01J31/24 , C07B53/00 , C07B61/00 , C07F9/50 , C07F15/00 , C07F9/02
CPC分类号： C07F15/0053
摘要： Disclosed is a ruthenium-phosphine complex represented by formula (I):�{RuX(L)}.sub.2 (.mu.-X).sub.3 !.sup.- �R.sub.2 NH.sub.2 !.sup.+(I)wherein R is hydrogen, an alkyl group having 1 to 5 carbon atoms, a cycloalkyl group, a substituted or unsubstituted phenyl group or a substituted or unsubstituted benzyl group; X is halogen; and L is an optically active or inactive tertiary phosphine. A process for preparing the complex (I) is also disclosed, which comprises (A) reacting a ruthenium complex represented by formula: �RuX(arene)(L)!X (wherein arene is a substituted or unsubstituted phenyl group) and an ammonium salt represented by formula (III): R.sub.2 NH.HX, or (B) reacting a ruthenium complex represented by formula: �RuX.sub.2 (arene)!.sub.2, a tertiary phosphine represented by L, and an ammonium salt (III). The complex (I) useful as a catalyst for general syntheses or asymmetric syntheses can be obtained easily in good yield.
摘要翻译：公开了由式（I）表示的钌膦配合物：[{RuX（L）} 2（mu -X）3] - [R 2 NH 2] +（I）其中R是氢，具有1至5个碳原子的烷基原子，环烷基，取代或未取代的苯基或取代或未取代的苄基; X是卤素; L是光学活性或无活性的叔膦。还公开了制备络合物（I）的方法，其包括（A）使由式[RuX（芳烃）（L）] X（其中芳烃为取代或未取代的苯基）和铵由式（III）表示的盐：R2NH.HX，或（B）使由式[RuX2（芳烃）] 2表示的钌络合物，由L表示的叔膦和铵盐（III）反应。可以容易地以良好的收率获得用作一般合成或不对称合成的催化剂的络合物（I）。

5. 发明申请

US20100249422A1 ACYLATION REACTION OF HYDROXYL GROUP 有权
标题翻译：羟基的聚合反应
公开(公告)号：US20100249422A1
公开(公告)日：2010-09-30
申请号：US12682591
申请日：2008-10-10
申请人： Kazushi Mashima , Takashi Ohshima , Takanori Iwasaki , Noboru Sayo
发明人： Kazushi Mashima , Takashi Ohshima , Takanori Iwasaki , Noboru Sayo
IPC分类号： C07D211/34 , C07D207/08 , C07C69/78
CPC分类号： C07D213/55 , C07C67/03 , C07C67/08 , C07C213/06 , C07C231/02 , C07C253/30 , C07C2601/14 , C07C2602/08 , C07C2602/10 , C07D211/34 , C07D295/195 , C07C69/618 , C07C69/24 , C07C69/612 , C07C69/76 , C07C69/78 , C07C219/14 , C07C219/18 , C07C219/22 , C07C233/69 , C07C233/73 , C07C255/57
摘要： Disclosed is a selective ester production process of an alcoholic hydroxyl group, which proceeds under chemically mild conditions, while having adequate environmental suitability, operability and economical efficiency. Specifically disclosed is a process for producing an ester compound, which is characterized in that an alcohol and a carboxylic acid ester compound are reacted in the presence of a compound containing zinc element, thereby selectively acylating a hydroxyl group of the alcohol.
摘要翻译：公开了在化学温和条件下进行的醇羟基的选择性酯生产方法，同时具有足够的环境适应性，可操作性和经济效率。具体公开了一种酯化合物的制造方法，其特征在于，在含有锌元素的化合物的存在下使醇和羧酸酯化合物反应，从而选择性地酰化醇的羟基。

6. 发明授权

US08431709B2 Acylation reaction of hydroxyl group 有权
标题翻译：羟基的酰化反应
公开(公告)号：US08431709B2
公开(公告)日：2013-04-30
申请号：US12682591
申请日：2008-10-10
申请人： Kazushi Mashima , Takashi Ohshima , Takanori Iwasaki , Noboru Sayo
发明人： Kazushi Mashima , Takashi Ohshima , Takanori Iwasaki , Noboru Sayo
IPC分类号： C07D211/34 , C07D207/08 , C07C69/78
CPC分类号： C07D213/55 , C07C67/03 , C07C67/08 , C07C213/06 , C07C231/02 , C07C253/30 , C07C2601/14 , C07C2602/08 , C07C2602/10 , C07D211/34 , C07D295/195 , C07C69/618 , C07C69/24 , C07C69/612 , C07C69/76 , C07C69/78 , C07C219/14 , C07C219/18 , C07C219/22 , C07C233/69 , C07C233/73 , C07C255/57
摘要： Disclosed is a selective ester production process of an alcoholic hydroxyl group, which proceeds under chemically mild conditions, while having adequate environmental suitability, operability and economical efficiency. Specifically disclosed is a process for producing an ester compound, which is characterized in that an alcohol and a carboxylic acid ester compound are reacted in the presence of a compound containing zinc element, thereby selectively acylating a hydroxyl group of the alcohol.
摘要翻译：公开了在化学温和条件下进行的醇羟基的选择性酯生产方法，同时具有足够的环境适应性，可操作性和经济效率。具体公开了一种酯化合物的制造方法，其特征在于，在含有锌元素的化合物的存在下使醇和羧酸酯化合物反应，从而选择性地酰化醇的羟基。

7. 发明申请

US20100155650A1 Amidine-carboxylic acid complex, briged polynuclear complex derived therefrom, production methods therefor, and use for preparing supported metal or metal oxide clusters 审中-公开
标题翻译：脒 - 羧酸络合物，由其衍生的起始多核络合物，其制备方法和用于制备负载型金属或金属氧化物簇
公开(公告)号：US20100155650A1
公开(公告)日：2010-06-24
申请号：US12308050
申请日：2007-06-07
申请人： Kazushi Mashima , Masato Ohashi , Akihiro Yagyu , Hirohito Hirata
发明人： Kazushi Mashima , Masato Ohashi , Akihiro Yagyu , Hirohito Hirata
IPC分类号： H01F1/04 , H01F1/00 , C01B13/14 , B01J23/42 , C07F15/00 , C22B5/00
CPC分类号： C07F15/0093 , B01D53/945 , B01D2251/70 , B01D2251/90 , B01J21/06 , B01J21/10 , B01J23/16 , B01J23/24 , B01J23/40 , B01J23/42 , B01J23/48 , B01J23/58 , B01J23/70 , B01J31/1616 , B01J31/1805 , B01J31/2208 , B01J35/006 , B01J37/0018 , B01J37/0203 , B01J37/086 , B01J2531/16 , B01J2531/64 , B01J2531/82 , B01J2531/822 , B01J2531/828 , B01J2531/84 , B01J2531/842 , Y02T10/22
摘要： An amidine-carboxylic acid complex in accordance with an aspect of the invention has an amidine ligand and a carboxylic acid ligand that are coordinated to one metal atom or a plurality of metal atoms of the same element. A multiple-complex-containing compound, i.e. a bridged polynuclear complex, in accordance with the aspect of the invention is formally derived from two or more such amidine-carboxylic acid complexes, linked by a polyvalent carboxylic acid ligand. The bridged polynuclear complex may be used in a production method to support metal (oxide) clusters on a porous support by impregnating these with a solution thereof, followed by drying and firing.
摘要翻译：根据本发明的一个方面的脒 - 羧酸络合物具有与一个金属原子或相同元素的多个金属原子配位的脒配体和羧酸配体。根据本发明的方面，含有多配位体的化合物，即桥连的多核络合物，正式由两个或更多个这样的脒 - 羧酸络合物衍生，通过多价羧酸配体连接。桥连多核络合物可以用于通过用溶液浸渍在多孔载体上来支持金属（氧化物）簇，随后进行干燥和烧制的方法中。

8. 发明申请

US20090198070A1 Condensation Reaction by Metal Catalyst 有权
标题翻译：金属催化剂的缩合反应
公开(公告)号：US20090198070A1
公开(公告)日：2009-08-06
申请号：US12085988
申请日：2006-12-04
申请人： Kazushi Mashima , Takashi Ohshima , Takanori Iwasaki , Hironori Maeda , Kenya Ishida
发明人： Kazushi Mashima , Takashi Ohshima , Takanori Iwasaki , Hironori Maeda , Kenya Ishida
IPC分类号： C07F15/00 , C07D263/08 , C07D263/52
CPC分类号： C07D263/12 , B01J31/2226 , B01J2531/26 , C07C53/18 , C07C231/02 , C07C253/30 , C07D263/10 , C07D263/14 , C07D263/52 , C07D413/06 , C07F3/003 , C07F7/1892 , C07F9/5022 , C07K1/088 , C07K1/10
摘要： The invention relates to a method for producing an azoline compound represented by the general formula (3): wherein R1 represents an optionally substituted hydrocarbon group, an optionally substituted alkoxy group, an optionally substituted alkoxycarbonyl group, a halogen atom, a substituted amino group, a substituted carbamoyl group or an optionally substituted heterocyclic group; R3, R4, R5 and R6 may be the same or different and each represents a hydrogen atom, an optionally substituted hydrocarbon group, an optionally substituted alkoxy group, an optionally substituted alkoxycarbonyl group, a halogen atom, a substituted amino group, a substituted carbamoyl group or an optionally substituted heterocyclic group; two arbitrary groups selected from R3, R4, R5 and R6 may bond to each other to form a ring; and Z1 represents an oxygen atom, a sulfur atom or a selenium atom; comprising reacting a carboxylic acid or a carboxylic acid derivative represented by the general formula (1): R1CO2R2 (1) wherein R1 is as defined above; R2 represents a hydrogen atom, an optionally substituted alkyl group or an optionally substituted aryl group; and R1 and R2 may bond to each other to form a ring; with an aminochalcogenide represented by the general formula (2): wherein R3, R4, R5, R6 and Z1 are as defined above; in the presence of a compound containing a group 12 metal element in the periodic table.
摘要翻译：本发明涉及一种制备由通式（3）表示的唑啉化合物的方法：其中R1表示任选取代的烃基，任选取代的烷氧基，任选取代的烷氧基羰基，卤素原子，取代的氨基，取代的氨基甲酰基或任选取代的杂环基; R3，R4，R5和R6可以相同或不同，各自表示氢原子，任选取代的烃基，任选取代的烷氧基，任选取代的烷氧基羰基，卤素原子，取代的氨基，取代的氨基甲酰基基团或任选取代的杂环基团; 选自R3，R4，R5和R6中的两个任意基团可以彼此键合形成环; Z1表示氧原子，硫原子或硒原子; 包括使由通式（1）表示的羧酸或羧酸衍生物反应：<？in-line-formula description =“In-line formula”end =“lead”？> R1CO2R2（1）<？ -formulae description =“In-line Formulas”end =“tail”？>其中R1如上定义; R2表示氢原子，任选取代的烷基或任选取代的芳基; 并且R 1和R 2可以彼此键合形成环; 与通式（2）表示的氨基硫族化物：其中R3，R4，R5，R6和Z1如上定义; 在含有元素周期表中第12族金属元素的化合物存在下进行。

9. 发明申请

US20090036696A1 IRIDIUM COMPLEXES 有权
标题翻译： IRIDIUM复合物
公开(公告)号：US20090036696A1
公开(公告)日：2009-02-05
申请号：US11660935
申请日：2004-08-27
申请人： Kazushi Mashima , Tsuneaki Yamagata
发明人： Kazushi Mashima , Tsuneaki Yamagata
IPC分类号： C07F15/00
CPC分类号： C07B53/00 , B01J31/2265 , B01J31/24 , B01J31/2452 , B01J2231/643 , B01J2531/827 , C07D211/04 , C07F15/004
摘要： The present invention has as its object to provide an iridium complex represented by the general formula: [(l r H L1 L2)2(μ-X1)(μ-X2)(μ-X3)]X4 (1) (wherein L1 and L2 may be the same or different and each represent a monodendate neutral ligand, or each cooperate with the other to form a bidendate neutral ligand; X1, X2 and X3 may be the same or different, and each represent a halogen atom; and X4 is a counter-anion). Also, the present invention provides a novel catalyst which can achieve excellent performance as a catalyst for asymmetric synthesis, especially asymmetric hydrogenation, in terms of chemical selectivity, enantioselectivity and catalytic activity, and the like.
摘要翻译：本发明的目的是提供由以下通式表示的铱络合物：<？in-line-formula description =“In-line formula”end =“lead”？> [（lr H L1 L2）2（mu -X1）（mu-X2）（mu-X3）] X4（1）<？in-line-formula description =“In-line Formulas”end =“tail”？>（其中L1和L2可以相同或各自代表一个单体中性配体，或者每个与另一个配位，以形成一种双羟纶中性配体; X 1，X 2和X 3可以相同或不同，各自表示卤素原子; X 4是抗衡阴离子）。此外，本发明提供了一种新颖的催化剂，其在化学选择性，对映选择性和催化活性等方面可以获得作为不对称合成，特别是不对称氢化的催化剂的优异性能。

10. 发明授权

US07977271B2 Multiple-metal complex-containing compound and metal complex, and manufacture methods therefor, and exhaust gas purification catalyst manufacture method using the same 失效
标题翻译：含金属络合物的复合物和金属络合物及其制造方法以及使用其的废气净化催化剂制造方法
公开(公告)号：US07977271B2
公开(公告)日：2011-07-12
申请号：US12281186
申请日：2007-02-28
申请人： Kazushi Mashima , Masato Ohashi , Akihiro Yagyu , Hirohito Hirata
发明人： Kazushi Mashima , Masato Ohashi , Akihiro Yagyu , Hirohito Hirata
IPC分类号： B01J31/12 , B01J31/20 , B01J37/08 , B01J37/02 , C07F15/00
CPC分类号： C07F15/0093 , B01D53/945 , B01D53/9454 , B01J21/06 , B01J21/10 , B01J23/16 , B01J23/28 , B01J23/40 , B01J23/42 , B01J23/48 , B01J23/58 , B01J23/70 , B01J31/16 , B01J31/1625 , B01J31/1805 , B01J31/1865 , B01J31/1875 , B01J31/2208 , B01J31/226 , B01J31/24 , B01J35/0013 , B01J35/006 , B01J35/008 , B01J37/0018 , B01J37/0203 , B01J37/086 , B01J2531/16 , B01J2531/64 , B01J2531/822 , B01J2531/824 , B01J2531/828 , B01J2531/842 , B01J2531/847 , Y02T10/22
摘要： A multiple-metal complex-containing compound in accordance with an embodiment has a plurality of metal complexes in each of which a ligand is coordinated to one metal atom or a plurality of metal atoms of the same kind. The plurality of metal complexes are bound to each other via a polydentate ligand that substitutes partially the ligands of the two or more metal complexes, and have 2 to 1000 metal atoms.
摘要翻译：根据实施方案的含多金属络合物的化合物具有多个金属配合物，其中每个金属配合物配位于一个金属原子或多个相同类型的金属原子。多个金属络合物通过多部分配位体彼此结合，该多齿配体部分代替两个或更多个金属络合物的配体，并且具有2至1000个金属原子。

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