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    • 1. 发明申请
    • Glass material for use in press-molding and method of manufacturing optical glass elements
    • 用于压制成型的玻璃材料和制造光学玻璃元件的方法
    • US20050183454A1
    • 2005-08-25
    • US10741003
    • 2003-12-22
    • Hideki MutouTakeshi TakahashiShigeaki Ohmi
    • Hideki MutouTakeshi TakahashiShigeaki Ohmi
    • C03B11/08C03B40/02C03C17/22C03C17/28
    • C03C17/22C03B40/02C03C2217/282C03C2218/152
    • A method of manufacturing glass materials for press molding comprising a film-forming step in which hydrocarbon is fed into a reaction chamber containing a glass material and the fed hydrocarbon is thermally decomposed to form a carbon-based film on the surface of the glass material. In the film-forming step, a cycle comprising a sub-step of feeding and thermally decomposing hydrocarbon and a sub-step of subsequently evacuating the reaction chamber is conducted two or more times. A method of manufacturing optical glass elements comprising heat softening and press molding a glass material having on the surface thereof a carbon-based film obtained by the above manufacturing method. Provided is a glass material for press molding permitting the prevention of flaws and cracks during the molding of an optical glass element and permitting the prevention of fogging of the optical glass element following molding. Further provided is an optical glass element without flaws, cracking, or fogging obtained from such a glass material for press molding.
    • 一种制造压制成形用玻璃材料的方法,其特征在于,在成膜工序中,将碳氢化合物进料到含有玻璃材料的反应室中,并将进料的碳氢化合物热分解,在玻璃材料的表面形成碳基膜。 在成膜步骤中,进行包括进料和热分解碳氢化合物的子步骤和随后抽空反应室的子步骤的循环两次或更多次。 一种制造光学玻璃元件的方法,其包括在其表面上具有通过上述制造方法获得的碳基膜的热软化和压制成型玻璃材料。 提供一种用于压制成型的玻璃材料,其允许在模制光学玻璃元件期间防止瑕疵和裂纹,并且可以防止模制后的光学玻璃元件起雾。 还提供了一种光学玻璃元件,其不会由这种用于压制成型的玻璃材料获得的缺陷,开裂或起雾。
    • 2. 发明授权
    • Process for producing optical glass
    • 光学玻璃生产工艺
    • US4851024A
    • 1989-07-25
    • US148570
    • 1988-01-26
    • Hiroyuki SakaiShigeaki OhmiYoshitaka YonedaYoshiyuki Asahara
    • Hiroyuki SakaiShigeaki OhmiYoshitaka YonedaYoshiyuki Asahara
    • G02B3/00C03B8/00C03B32/00C03C21/00
    • C03C21/001
    • A uniform refractive index-type glass is prepared by ion exchange in which a glass containing ions of a first type is immersed in a molten salt containing ions of a second type, the ions in the molten salt having a higher refractive index than the ions in the glass. The glass is removed from the molten salt at a predetermined point and before the saturation point or equilibrium and the ion distribution becomes uniform throughout the glass. The concentration of first and second ions is not uniform from the center of the glass to its outer surface. The glass is next heated to make the concentrations of the first and second ions substantially uniform throughout the glass from the center to the outer surface. Optionally, this glass is then immersed in a molten salt containing a third type of ion having a lower refractive index than the second ion for exchange with part of the ions in the second type. A gradient refractive index-type glass in which the concentration of the second type of ions decreases parabolically from the center of the glass to the outer surface while the concentration of the third type of ions increases parabolically from the center of the glass to the outer surface.
    • 通过离子交换制备均匀的折射率型玻璃,其中将含有第一类型的离子的玻璃浸入含有第二类离子的熔盐中,熔融盐中的离子的折射率高于 玻璃。 在预定点和饱和点或平衡之前从熔融盐中除去玻璃,并且整个玻璃中的离子分布变得均匀。 第一和第二离子的浓度从玻璃的中心到其外表面是不均匀的。 接着加热玻璃使得第一和第二离子的浓度在整个玻璃中从中心到外表面基本上均匀。 任选地,将该玻璃浸入含有比第二离子低的折射率的第三类离子的熔盐中,以与第二类型的部分离子交换。 梯度折射率型玻璃,其中第二类离子的浓度从玻璃的中心向抛物线减少到外表面,同时第三类离子的浓度从玻璃的中心向抛物面增加到外表面 。
    • 3. 发明授权
    • Methods for producing oxides or composites thereof
    • 生产氧化物或其复合材料的方法
    • US06589906B2
    • 2003-07-08
    • US10042217
    • 2002-01-11
    • Koji SatoShigeaki Ohmi
    • Koji SatoShigeaki Ohmi
    • B01J2300
    • C03C17/25B01J35/002B01J35/004C01B13/363C01G23/047C01P2002/84C01P2006/60C03C17/007C03C17/256C03C2217/212C03C2217/23C03C2217/24C03C2217/45C03C2217/477C03C2217/479C03C2217/71
    • Disclosed are methods for producing films of a composite comprising a metal oxide in combination with one or more other oxides or metals as a third component, or a composite comprising a metal oxide doped with metal ions as a third component, methods for producing titanium oxide coating layers having transparency, low peeling property and weather resistance, which are comparable to or even more excellent than those of conventional ones, as well as surface hardness comparable to that of coating films produced by using sintering, on plastic substrates, and methods for producing titanium oxide which exhibits photocatalytic activity even with light of visible light range. These methods do not require a treatment at a high temperature. Also disclosed are anti-fogging materials excellent in anti-fogging property, which have transparency, peeling property and weather resistance, which are comparable to or even more excellent than those of conventional ones, as well as surface hardness comparable to that of coating films produced by using sintering, and have excellent photocatalytic function of titanium oxide and a reflectance lower than titanium oxide.
    • 公开了一种制备复合材料的方法,该复合材料包括与一种或多种其它氧化物或金属组合的金属氧化物作为第三组分,或包含掺杂金属离子作为第三组分的金属氧化物的复合材料,用于生产氧化钛涂层的方法 具有与常规相比甚至更优异的透明度,低剥离性和耐候性的层,以及与通过使用烧结制造的涂膜在塑料基板上的表面硬度相当的表面硬度,以及用于生产钛的方法 氧化物即使在可见光范围的光下也表现出光催化活性。 这些方法不需要在高温下进行处理。 还公开了具有与现有技术相当甚至更优异的具有透明性,剥离性和耐候性的防雾性优异的防雾材料,以及与制造的涂膜相当的表面硬度 通过烧结,具有优异的氧化钛光催化功能,反射率低于氧化钛。