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    • 1. 发明授权
    • Nanoparticle composite
    • 纳米复合材料
    • US07943802B2
    • 2011-05-17
    • US11715495
    • 2007-03-08
    • Hideaki YaegashiShoko KanoMasahiko YamanakaKentarou WatanabeHiroshi YokoyamaHideo Sawada
    • Hideaki YaegashiShoko KanoMasahiko YamanakaKentarou WatanabeHiroshi YokoyamaHideo Sawada
    • C07C27/10
    • C07F7/21
    • A nanoparticle composite includes a host molecule including a chain oligomer section having a hydrophilic group and fluoroalkyl groups respectively at opposite terminals thereof and a three-dimensional silica network section, and having a structure represented by the following formula (1): where X is the hydrophilic group and is independent OH group, independent NCO group, independent NH2 group, independent NHR group (where R is alkyl group) or independent OCY group (where Y is a hydrophilic group); RF is the fluoroalkyl group having a carbon number of 2 to 10 and a molecular weight of 119 to 1000; 3D-SN is the three-dimensional silica network section; B is independent O, independent O═C—O, independent NH—C═O or independent NR—C═O (where R is alkyl group); n is 1≦n≦10; and m is 1≦m≦n; and a guest molecule included in the host molecule.
    • 纳米颗粒复合材料包括主体分子,其包括分别具有相对端的亲水基团和氟代烷基的链低聚物部分和三维二氧化硅网络部分,并具有由下式(1)表示的结构:其中X是 亲水基团,独立的OH基团,独立的NCO基团,独立的NH2基团,独立的NHR基团(其中R是烷基)或独立的OCY基团(其中Y是亲水基团); RF是碳数为2〜10,分子量为119〜1000的氟代烷基; 3D-SN是三维硅网络部分; B是独立的O,独立的O = C-O,独立的NH-C = O或独立的NR-C = O(其中R是烷基); n为1≦̸ n≦̸ 10; 并且m是1≦̸ m≦̸ n; 和宿主分子中包含的客体分子。
    • 2. 发明申请
    • Nanoparticle composite
    • 纳米复合材料
    • US20080064903A1
    • 2008-03-13
    • US11715495
    • 2007-03-08
    • Hideaki YaegashiShoko KanoMasahiko YamanakaKentarou WatanabeHiroshi YokoyamaHideo Sawada
    • Hideaki YaegashiShoko KanoMasahiko YamanakaKentarou WatanabeHiroshi YokoyamaHideo Sawada
    • C07C27/10
    • C07F7/21
    • A nanoparticle composite includes a host molecule including a chain oligomer section having a hydrophilic group and fluoroalkyl groups respectively at opposite terminals thereof and a three-dimensional silica network section, and having a structure represented by the following formula (1): where X is the hydrophilic group and is independent OH group, independent NCO group, independent NH2 group, independent NHR group (where R is alkyl group) or independent OCY group (where Y is a hydrophilic group); RF is the fluoroalkyl group having a carbon number of 2 to 10 and a molecular weight of 119 to 1000; 3D-SN is the three-dimensional silica network section; B is independent O, independent O═C—O, independent NH—C═O or independent NR—C═O (where R is alkyl group); n is 1≦n≦10; and m is 1≦m≦n; and a guest molecule included in the host molecule.
    • 纳米颗粒复合材料包括主体分子,其包括分别具有相对端的亲水基团和氟代烷基的链低聚物部分和三维二氧化硅网络部分,并具有由下式(1)表示的结构:其中X是 独立的OH基团,独立的NCO基团,独立的NH 2基团,独立的NHR基团(其中R是烷基)或独立的OCY基团(其中Y是亲水基团); R F是碳数为2〜10,分子量为119〜1000的氟代烷基; 3D-SN是三维硅网络部分; B是独立的O,独立的O-C-O,独立的NH-C-O或独立的NR-C-O(其中R是烷基); n为1 <= n <= 10; 并且m是1 <= m <= n; 和宿主分子中包含的客体分子。
    • 3. 发明授权
    • Nanoparticle and nanoparticle composite
    • 纳米颗粒和纳米颗粒复合材料
    • US08247591B2
    • 2012-08-21
    • US12910739
    • 2010-10-22
    • Hideaki YaegashiShoko KanoMasahiko YamanakaKentarou WatanabeHiroshi YokoyamaHideo Sawada
    • Hideaki YaegashiShoko KanoMasahiko YamanakaKentarou WatanabeHiroshi YokoyamaHideo Sawada
    • C07F7/21C07F7/10
    • C07F7/21
    • A nanoparticle includes a chain oligomer section having a hydrophilic group and fluoroalkyl groups respectively at its opposite terminals, a three-dimensional silica network section, and an organic chain having fluorine or silicon, and is represented by the following formula (2): where R′ is independent H or independent alkyl group; X is the hydrophilic group and is selected from the group consisting of an OH group, an NCO group, an NH2 group, an NHR group (where R is alkyl group) and a COY group (where Y is a hydrophilic group); RF is the fluoroalkyl group having a carbon number of 2 to 10 and a molecular weight of 119 to 1000; 3D-SN is the three-dimensional silica network section; B is selected from the group consisting of an O, O═C—O, NH—C═O and NR—C═O (where R is alkyl group); E is O, O═C—O, NH—C═O or NR—C═O (where R is alkyl group); L is (CH2O)l—[Si(CH3)2O]k—(CH2O)l-α, (CF2)j-α or (CF2O)h-α where α is COY group (where Y is hydrophilic group), NCO group, NH2 group, NHR group (R is alkyl group), R group (or alkyl group) or H; n is 1≦n≦10; m is 1≦m≦n; k is 1≦k≦500; l is 0≦1≦10; j is 0≦j≦20; and h is 1≦h≦20.
    • 纳米颗粒包括在其相对端具有亲水基团和氟代烷基的链寡聚体部分,三维二氧化硅网络部分和具有氟或硅的有机链,并由下式(2)表示:其中R '是独立的H或独立的烷基; X是亲水基团,选自OH基团,NCO基团,NH 2基团,NHR基团(其中R是烷基)和COY基团(其中Y是亲水基团); RF是碳数为2〜10,分子量为119〜1000的氟代烷基; 3D-SN是三维硅网络部分; B选自O,O = C-O,NH-C = O和NR-C = O(其中R是烷基); E是O,O = C-O,NH-C = O或NR-C = O(其中R是烷基); L是(CH 2 O)1- [Si(CH 3)2 O] k - (CH 2 O)1-α,(CF 2)j-α或(CF 2 O)h-α,其中α是COY基团(其中Y是亲水基团) 基团,NH 2基,NHR基(R为烷基),R基(或烷基)或H; n为1&nlE; n&nlE; 10; m为1&nlE; m&nlE; n; k是1&nlE; k&nlE; 500; l为0&nlE; 1&nlE; 10; j为0&nlE; j&nlE; 20; h为1&nlE; h&nlE; 20。