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1. 发明授权

US06797753B2 Plasticizers derived from vegetable oils 有权
标题翻译：来自植物油的增塑剂
公开(公告)号：US06797753B2
公开(公告)日：2004-09-28
申请号：US09849071
申请日：2001-05-04
申请人： Herman P. Benecke , Bhima R. Vijayendran , Joel D. Elhard
发明人： Herman P. Benecke , Bhima R. Vijayendran , Joel D. Elhard
IPC分类号： C08K51515
CPC分类号： C08K5/0016 , C08K5/1515 , C08L27/06
摘要： Compositions and methods for plasticizing polyvinyl chloride polymers where the plasticizers contain fatty acids derived from vegetable oils and the fatty acids are substantially fully esterified with an alcohol (monool or polyol), the fatty acids having unsaturated bonds that are substantially fully epoxidized, and wherein the fatty acids are added substantially randomly to one or more hydroxyl sites on the alcohol. The plasticizers may be added in amounts between about 10 to 230 pph of PVC resin.
摘要翻译：用于塑化聚氯乙烯聚合物的组合物和方法，其中增塑剂含有源自植物油和脂肪酸的脂肪酸基本上被醇（一元醇或多元醇）完全酯化，所述脂肪酸具有基本上完全环氧化的不饱和键，并且其中脂肪酸基本上随机地添加到醇上的一个或多个羟基位点。增塑剂可以以约10至230pph的PVC树脂的量加入。

2. 发明申请

US20100093966A1 Readily Deinkable Toners 审中-公开
标题翻译：易于脱墨的墨粉
公开(公告)号：US20100093966A1
公开(公告)日：2010-04-15
申请号：US12623577
申请日：2009-11-23
申请人： Bhima R. Vijayendran , Herman P. Benecke , Elizabeth Drotleff , Joel D. Elhard , J. David Robbins , Jeffrey Cafmeyer , Joan Muellerleile
发明人： Bhima R. Vijayendran , Herman P. Benecke , Elizabeth Drotleff , Joel D. Elhard , J. David Robbins , Jeffrey Cafmeyer , Joan Muellerleile
IPC分类号： C08G73/00
CPC分类号： G03G9/0819 , C08G69/10 , C08G69/34 , C08G69/36 , C08L77/00 , C08L89/00 , G03G9/0821 , G03G9/0823 , G03G9/08766 , G03G9/08775 , G03G9/08795 , G03G9/08797 , C08L2666/26 , C08L2666/20 , C08L2666/02
摘要： Broadly the invention provides for a deinkable toner composition, an image made with the deinkable toner, and a method for making the toner including a coloring agent; a thermoplastic polymer; and a protein. In another embodiment the toner includes a coloring agent and a thermoplastic polymer where the protein has been incorporated into the polymer itself. In typical embodiments the protein is derived from soybeans but may be from other plant or animal sources. Typically the toner has a positive triboelectric charge of between about 10 to about 40 microCoulomb/g, or a negative triboelectric charge of between about 10 to about 40 microCoulomb/g.
摘要翻译：广泛地，本发明提供了一种可脱墨调色剂组合物，用可脱墨调色剂制成的图像，以及一种用于制备包含着色剂的调色剂的方法; 热塑性聚合物; 和蛋白质。在另一个实施方案中，调色剂包括着色剂和热塑性聚合物，其中蛋白质已经被引入聚合物本身。在典型的实施方案中，蛋白质衍生自大豆，但可以来自其它植物或动物来源。通常，调色剂具有约10至约40微库仑/克的正摩擦电荷，或约10至约40微库仑/克之间的负摩擦电荷。

3. 发明授权

US07645549B2 Readily deinkable toners 失效
标题翻译：容易脱墨的调色剂
公开(公告)号：US07645549B2
公开(公告)日：2010-01-12
申请号：US10546744
申请日：2004-02-27
申请人： Bhima R. Vijayendran , Herman P. Benecke , Elizabeth Drotleff , Joel D. Elhard , J. David Robbins , Jeffrey Cafmeyer , Joan Muellerleile
发明人： Bhima R. Vijayendran , Herman P. Benecke , Elizabeth Drotleff , Joel D. Elhard , J. David Robbins , Jeffrey Cafmeyer , Joan Muellerleile
IPC分类号： G03G9/087
CPC分类号： G03G9/0819 , C08G69/10 , C08G69/34 , C08G69/36 , C08L77/00 , C08L89/00 , G03G9/0821 , G03G9/0823 , G03G9/08766 , G03G9/08775 , G03G9/08795 , G03G9/08797 , C08L2666/26 , C08L2666/20 , C08L2666/02
摘要： Broadly the invention provides for a deinkable toner composition, an image made with the deinkable toner, and a method for making the toner including a coloring agent; a thermoplastic polymer; and a protein. In another embodiment the toner includes a coloring agent and a thermoplastic polymer where the protein has been incorporated into the polymer itself. In typical embodiments the protein is derived from soybeans but may be from other plant or animal sources. Typically the toner has a positive triboelectric charge of between about 10 to about 40 microCoulomb/g, or a negative triboelectric charge of between about 10 to about 40 microCoulomb/g.
摘要翻译：广泛地，本发明提供了一种可脱墨调色剂组合物，用可脱墨调色剂制成的图像，以及一种用于制备包含着色剂的调色剂的方法; 热塑性聚合物; 和蛋白质。在另一个实施方案中，调色剂包括着色剂和热塑性聚合物，其中蛋白质已经被引入聚合物本身。在典型的实施方案中，蛋白质衍生自大豆，但可以来自其它植物或动物来源。通常，调色剂具有约10至约40微库仑/克的正摩擦电荷，或约10至约40微库仑/克之间的负摩擦电荷。

4. 发明授权

US08148501B2 Absorbent protein meal base hydrogels 有权
标题翻译：吸收蛋白粉基础水凝胶
公开(公告)号：US08148501B2
公开(公告)日：2012-04-03
申请号：US12918929
申请日：2009-02-23
申请人： Herman P. Benecke , Bhima R. Vijayendran , Kevin B. Spahr
发明人： Herman P. Benecke , Bhima R. Vijayendran , Kevin B. Spahr
IPC分类号： C08H1/00
CPC分类号： A61L15/60 , A61L15/32 , C08F220/06 , C08F220/56 , C08F222/1006
摘要： Absorbent hydrogels are formed by reacting a protein meal base, a radical initiator and a polymerizable monomer. Optionally, a cross-linking agent and/or a radical accelerant, such as tetramethylethylenediamine (TMEDA) or sodium bisulfite (NaHSO3), is also added to the mixture. Preferably, the radical initiator is ammonium persulfate (APS) or potassium persulfate (KPS), and the cross-linking agent is preferably trifunctional trimethylolpropane trimethacrylate (TMPTMA) or methylene bis acrylamide (MBA). The polymerizable monomer is preferably acrylic acid, or a combination of acrylic acid and acrylamide. The as-formed hydrogel is washed in order to extract non-reactant components from the gel and then dried. The resultant absorbent and superabsorbent hydrogels have high water uptake ratios, and can be utilized for a variety of applications.
摘要翻译：吸收性水凝胶是通过使蛋白质膳食碱，自由基引发剂和可聚合单体反应形成的。任选地，还向混合物中加入交联剂和/或自由基促进剂，例如四甲基乙二胺（TMEDA）或亚硫酸氢钠（NaHSO 3）。优选自由基引发剂为过硫酸铵（APS）或过硫酸钾（KPS），交联剂优选为三官能三羟甲基丙烷三甲基丙烯酸酯（TMPTMA）或亚甲基双丙烯酰胺（MBA）。可聚合单体优选为丙烯酸，或丙烯酸和丙烯酰胺的组合。洗涤形成的水凝胶以从凝胶中提取非反应性组分，然后干燥。所得的吸收性和超吸收性水凝胶具有高吸水率，并可用于各种应用。

5. 发明申请

US20090215619A1 Absorbent Soy Protein Isolate Base Hydrogels 审中-公开
标题翻译：吸收大豆蛋白分离基础水凝胶
公开(公告)号：US20090215619A1
公开(公告)日：2009-08-27
申请号：US12390923
申请日：2009-02-23
申请人： Herman P. Benecke , Bhima R. Vijayendran , Kevin B. Spahr
发明人： Herman P. Benecke , Bhima R. Vijayendran , Kevin B. Spahr
IPC分类号： B01J20/22 , B01J13/00
CPC分类号： A61L15/60 , A61L15/32 , C08F220/06 , C08F220/56 , C08F222/1006
摘要： Absorbent hydrogels are formed from soy protein isolate. More specifically, an absorbent hydrogel is formed by contacting soy protein isolate with urea to produce solubilized soy protein isolate which is combined with 2-mercaptoethanol to form a first mixture. The first mixture is heated and combined with a polymerizable monomer and ammonium persulfate to form a second mixture. The second mixture is then heated, followed by removal of the hydrogel from the second mixture. Optionally, the as-formed hydrogel may be subjected to a washing process to extract non-reactant components from the gel and then dried.
摘要翻译：吸收性水凝胶由大豆蛋白分离物形成。更具体地，通过使大豆蛋白分离物与尿素接触以产生溶解的大豆蛋白分离物形成吸收性水凝胶，其与2-巯基乙醇组合以形成第一混合物。将第一混合物加热并与可聚合单体和过硫酸铵组合以形成第二混合物。然后将第二混合物加热，然后从第二混合物中除去水凝胶。任选地，所形成的水凝胶可以进行洗涤过程以从凝胶中提取非反应性组分，然后干燥。

6. 发明授权

US08378056B2 Formaldehyde free binders 失效
公开(公告)号：US08378056B2
公开(公告)日：2013-02-19
申请号：US13592481
申请日：2012-08-23
申请人： Herman P. Benecke , Daniel B. Garbark , Alex W. Kawczak , Michael C. Clingerman
发明人： Herman P. Benecke , Daniel B. Garbark , Alex W. Kawczak , Michael C. Clingerman
IPC分类号： C08G69/44
CPC分类号： C07D307/34 , C08G63/6854
摘要： New polyols; oligomers, and polymers made from the polyols; and binders made from the new polyols, oligomers, or polymers that can be used in binders, where the binders typically include one or more polyols, and a polyfunctional acid or a polyfunctional nitrile.

7. 发明申请

US20120316307A1 FORMALDEHYDE FREE BINDERS 失效
标题翻译：甲醛免费粘合剂
公开(公告)号：US20120316307A1
公开(公告)日：2012-12-13
申请号：US13592481
申请日：2012-08-23
申请人： Herman P. Benecke , Daniel B. Garbark , Alex W. Kawczak , Michael C. Clingerman
发明人： Herman P. Benecke , Daniel B. Garbark , Alex W. Kawczak , Michael C. Clingerman
IPC分类号： C07D307/68 , C08G63/16 , C08G69/00
CPC分类号： C07D307/34 , C08G63/6854
摘要： New polyols; oligomers, and polymers made from the polyols; and binders made from the new polyols, oligomers, or polymers that can be used in binders, where the binders typically include one or more polyols, and a polyfunctional acid or a polyfunctional nitrile.
摘要翻译：新型多元醇低聚物和由多元醇制成的聚合物; 和由可用于粘合剂的新的多元醇，低聚物或聚合物制成的粘合剂，其中粘合剂通常包括一种或多种多元醇，以及多官能酸或多官能腈。

8. 发明申请

US20100280186A1 FURANIC-MODIFIED AMINE-BASED CURATIVES 审中-公开
标题翻译：基于改性的基于胺的曲线
公开(公告)号：US20100280186A1
公开(公告)日：2010-11-04
申请号：US12550349
申请日：2009-08-28
申请人： Herman P. Benecke , Alex W. Kawczak , Daniel B. Garbark
发明人： Herman P. Benecke , Alex W. Kawczak , Daniel B. Garbark
IPC分类号： C08G71/02 , C07D407/12 , C07C233/53
CPC分类号： C07D307/68 , C08G18/3246 , C08G18/3825 , C08G2120/00
摘要： Aromatic polyamines are derivatized with polycarboxylic acids or their derivatives to form polyamine amides) containing pendant amine groups; the derivatives have enhanced curative properties when used as curatives for polyureas, hybrid epoxy-urethanes, hybrid urea-urethanes, chain extenders for polyurethane and polyurea elastomers, and also for reaction injection molding (RIM) products.
摘要翻译：芳族多胺用多元羧酸或其衍生物衍生形成多胺酰胺），其含有侧基胺基; 当用作聚脲，混合环氧 - 氨基甲酸酯，混合尿素 - 氨基甲酸酯，聚氨酯和聚脲弹性体的增链剂以及反应注射成型（RIM）产品时，衍生物具有增强的固化性能。

9. 发明授权

US5675021A Method to produce and purify cyclic esters 失效
标题翻译：生产和纯化环酯的方法
公开(公告)号：US5675021A
公开(公告)日：1997-10-07
申请号：US417597
申请日：1995-04-05
申请人： Timothy J. Eggeman , Herman P. Benecke
发明人： Timothy J. Eggeman , Herman P. Benecke
IPC分类号： C07C51/48 , C07D319/12 , C08G63/06 , C08J5/18 , C08L67/04 , C09D167/04 , C07D321/00 , C07D321/10
CPC分类号： C07C51/48 , C07D319/12 , C08J5/18 , C08L67/04 , C09D167/04 , B01J2219/1942 , C08J2367/04
摘要： Methods are provided for the production, recovery and purification of cyclic esters. Such methods include producing a cyclic ester composition containing at least one impurity, contacting the cyclic ester composition with at least one adsorbent to remove the impurity and recovering the purified cyclic esters. Also included are methods of cyclic ester purification involving multiple adsorption operations. The methods of the present invention can produce highly purified cyclic esters. Such compositions are suitable for use in the manufacture of polymers having an average degree of polymerization in excess of about 1700.
摘要翻译：提供了环酯的生产，回收和纯化的方法。这样的方法包括制备含有至少一种杂质的环酯组合物，使环酯组合物与至少一种吸附剂接触以除去杂质并回收纯化的环酯。还包括涉及多次吸附操作的环酯纯化方法。本发明的方法可以生产高纯度的环酯。这种组合物适用于制造平均聚合度超过约1700的聚合物。

10. 发明授权

US08940914B2 Esters of 5-hydroxymethylfurfural and methods for their preparation 有权
标题翻译： 5-羟甲基糠醛的酯及其制备方法
公开(公告)号：US08940914B2
公开(公告)日：2015-01-27
申请号：US13554525
申请日：2012-07-20
申请人： Herman P. Benecke , Jerry L. King, II , Alex Walter Kawczak , Donald W. Zehnder, II , Erica E. Hirschl
发明人： Herman P. Benecke , Jerry L. King, II , Alex Walter Kawczak , Donald W. Zehnder, II , Erica E. Hirschl
IPC分类号： C07D307/54 , C07D307/46
CPC分类号： C07D307/54 , C07D307/46
摘要： Disclosed are compositions and methods for the production of mono-esters and di-esters from the reaction of HMF and a reactant selected from a diacid or a diacid derivative; typical reactants are PAN, phthaloyl dichloride, dimethyl phthalate, maleic acid, and maleic anhydride or mono-esters that can be prepared from HMF and MAN.
摘要翻译：公开了从HMF和选自二酸或二酸衍生物的反应物的反应制备单酯和二酯的组合物和方法; 典型的反应物是可以由HMF和MAN制备的PAN，邻苯二甲酰二氯，邻苯二甲酸二甲酯，马来酸和马来酸酐或单酯。

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