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1. 发明授权

US5174867A Preparation of electrically conductive, finely divided pyrrole polymers 失效
标题翻译：电导体，精细分散聚四氟乙烯聚合物的制备
公开(公告)号：US5174867A
公开(公告)日：1992-12-29
申请号：US584315
申请日：1984-02-28
申请人： Herbert Naarmann , Walter Heckmann , Gernot Koehler , Petr Simak
发明人： Herbert Naarmann , Walter Heckmann , Gernot Koehler , Petr Simak
IPC分类号： C08F2/44 , C08F34/00 , C08G61/10 , C08G61/12 , C08L45/00 , C08L65/00 , C09D145/00 , C09D165/00 , H01B1/12 , H01M4/60
CPC分类号： H01B1/128 , C08F34/00 , C08G61/124 , H01M4/60
摘要： Electrically conductive, finely divided pyrrole polymers are prepared by a process in which a pyrrole is polymerized in the presence of a carrier and are used for the production of shaped articles and coatings.
摘要翻译：通过其中吡咯在载体存在下聚合并用于生产成形制品和涂料的方法制备导电的细碎的吡咯聚合物。

2. 发明授权

US4567250A Preparation of finely divided electrically conductive pyrrole polymers 失效
标题翻译：精细分散的导电吡咯聚合物的制备
公开(公告)号：US4567250A
公开(公告)日：1986-01-28
申请号：US631947
申请日：1984-07-18
申请人： Herbert Naarmann , Walter Heckmann , Gernot Kohler , Petr Simak
发明人： Herbert Naarmann , Walter Heckmann , Gernot Kohler , Petr Simak
IPC分类号： C08G61/00 , C08G61/10 , C08G61/12 , C08G73/06 , H01B1/12 , C08G73/20 , C07D207/30
CPC分类号： H01B1/127 , C08G61/124 , C08G73/0611
摘要： Finely divided electrically conductive pyrrole polymers are prepared by a process in which the pyrroles, in solution and in the presence of a conductive salt, are treated with an oxygen-containing oxidizing agent. The finely divided conductive pyrrole polymers can be used for the production of moldings.
摘要翻译：细分导电的吡咯聚合物通过其中在溶液中和在导电盐存在下用含氧氧化剂处理吡咯的方法制备。精细分散的导电吡咯聚合物可用于生产模制品。

3. 发明授权

US4518535A Preparation of electrically conductive systems from substituted phenalenes, and the products obtained 失效
标题翻译：由取代的非对映体制备导电体系，得到的产物
公开(公告)号：US4518535A
公开(公告)日：1985-05-21
申请号：US491717
申请日：1983-05-05
申请人： Herbert Naarmann , Volker Muench , Gernot Kohler , Petr Simak
发明人： Herbert Naarmann , Volker Muench , Gernot Kohler , Petr Simak
IPC分类号： C09K3/16 , C07F1/00 , C07F11/00 , C07F13/00 , C07F15/00 , C08G79/00 , C08K5/00 , H01B1/12 , H01L51/30 , C07F1/08 , C07F1/10 , C07F15/02
CPC分类号： H01B1/121 , C08G79/00 , C08K5/0075 , C08K5/0091 , H01L51/0051 , H01L51/0052 , H01L51/0077 , Y02E10/549
摘要： Air-stable, electrically conductive systems having conductivities greater than 1.times.10.sup.-3 .OMEGA..sup.-1 cm.sup.-1 are prepared by reacting a metal cation of an element of sub-group VII, VIII or I of the periodic table with a 1,9-substituted phenalene of the general formula (I) ##STR1## where X is O, NH, S, Se or Te and Y is OH, NH.sub.2 or SH, to give a metal chelate, and oxidizing this metal chelate by means of an organic electron acceptor. The electrically conductive systems can be used in the electrical industry for the production of solar cells and for converting and fixing radiation, for producing electric and magnetic switches and electrochemical stores, and for the antistatic treatment of plastics.
摘要翻译：通过使元素周期表第Ⅶ族，Ⅷ族或第Ⅵ族元素的金属阳离子与1,9-取代的非那苯甲醛反应，制备电导率大于1×10-3欧姆 - 1cm -1的空气稳定的导电体系的通式（I）其中X是O，NH，S，Se或Te，Y是OH，NH 2或SH，得到金属螯合物，并通过有机物氧化该金属螯合物电子受体。导电系统可用于电气工业中用于生产太阳能电池和用于转换和固定辐射，用于生产电磁开关和电化学存储器以及用于塑料的抗静电处理。

4. 发明授权

US4488986A Preparation of electrically conductive polyarylene compounds having electron-attracting side groups 失效
标题翻译：具有吸电子基团的导电聚亚芳基化合物的制备
公开(公告)号：US4488986A
公开(公告)日：1984-12-18
申请号：US519507
申请日：1983-08-02
申请人： Herbert Naarmann , Petr Simak , Gernot Kohler
发明人： Herbert Naarmann , Petr Simak , Gernot Kohler
IPC分类号： C08L65/00 , C07C57/42 , C08F8/30 , C08F8/42 , C08F38/00 , C08G16/00 , C08G61/00 , C08L101/00 , H01B1/12 , H01M4/60 , H01B1/06
CPC分类号： C07C255/00 , C07C57/42 , C08L101/00 , H01B1/128 , H01M4/60 , C08L2201/04
摘要： Electrically conductive polymeric systems having electrical conductivities greater than 10.sup.-4 S/cm are prepared by a method wherein a polyarylene compound which contains one or more chain members of the formula ##STR1## where n is greater than 1, preferably from 5 to 50, R is a nitrile, acid amide, carboxyl or ester group, R.sup.1 and R.sup.2 are each hydrogen or a nitrile, acid amide, carboxyl or ester group, with the proviso that in each case one of the radicals R.sup.1 and R.sup.2 is hydrogen and the other is a nitrile, acid amide, carboxyl or ester group, and Y is an aromatic radical, preferably phenylene, is doped, in the absence of moisture and oxygen, with from 0.03 to 0.9 mole percent of an electron-attracting or electron-donating complexing agent. The resulting electrically conductive polymeric systems are useful in the electrical industry for the production of solar cells, for converting and fixing electromagnetic radiation and for the production of electrical and magnetic switches and electrical storage devices, and can be used for the antistatic treatment of plastics.
摘要翻译：电导率大于10 -4 S / cm的导电聚合体系通过一种方法制备，其中含有一个或多个下式的链成员的聚亚芳基化合物，其中n大于1，优选为5至50， R是腈，酰胺，羧基或酯基，R 1和R 2各自为氢或腈，酰胺，羧基或酯基，条件是在每种情况下，基团R 1和R 2中的一个为氢，另一个为氢是腈，酰胺，羧基或酯基，并且Y是芳族基团，优选亚苯基，在没有水分和氧的情况下掺杂有0.03-0.9摩尔％的吸电子或给电子络合物代理商所得到的导电聚合物体系可用于电气工业中用于生产太阳能电池，用于转换和固定电磁辐射以及生产电磁开关和电存储装置，并可用于塑料的抗静电处理。

5. 发明授权

US4412942A Preparation of electrically conductive polymers 失效
标题翻译：导电聚合物的制备
公开(公告)号：US4412942A
公开(公告)日：1983-11-01
申请号：US373158
申请日：1982-04-29
申请人： Herbert Naarmann , Klaus Penzien , Johannes Schlag , Petr Simak
发明人： Herbert Naarmann , Klaus Penzien , Johannes Schlag , Petr Simak
IPC分类号： C08F8/00 , C08F8/30 , C08F8/42 , H01B1/12 , H01L51/30 , H01L51/42 , H01B1/06
CPC分类号： H01B1/125 , C08F8/42 , H01L51/0041 , H01L51/42 , Y02E10/549
摘要： A process for the preparation of stable electrically conductive polymers, having conductivities greater than 10.sup.-2 S/cm, wherein a polyacetylene is reacted with from 1 to 100, preferably from 10 to 33, % by weight of tosylmethyl isocyanide and from 0.1 to 70, preferably from 5 to 35, % by weight of an alkali metal or its amide, or of a Lewis acid. The polymers obtained can be used in electrical engineering for the production of solar cells, for the conversion and fixing of radiation and for the production of electrical and magnetic switches and electrical storage devices, and can also be used for the antistatic treatment of plastics.
摘要翻译：用于制备电导率大于10-2S / cm的稳定导电聚合物的方法，其中聚乙炔与1至100重量比，优选10至33重量％的甲苯磺酰甲基异氰化物和0.1至70重量％，优选5至35重量％的碱金属或其酰胺或路易斯酸。获得的聚合物可用于生产太阳能电池的电气工程，用于辐射的转换和固定以及用于生产电磁开关和电存储装置，并且也可用于塑料的抗静电处理。

6. 发明授权

US4411826A Preparation of stable electrically conductive polymers 失效
标题翻译：稳定导电聚合物的制备
公开(公告)号：US4411826A
公开(公告)日：1983-10-25
申请号：US344013
申请日：1982-01-29
申请人： Herbert Naarmann , Klaus Penzien , Johannes Schlag , Petr Simak
发明人： Herbert Naarmann , Klaus Penzien , Johannes Schlag , Petr Simak
IPC分类号： C08L49/00 , C08F8/42 , C08F8/50 , H01B1/12 , H01L51/00 , H01L51/30 , H01B1/06
CPC分类号： H01L51/00 , C08F8/42 , C08F8/50 , H01B1/125 , H01L51/0041 , Y02E10/549
摘要： Stable electrically conductive polymers having conductivities greater than 10.sup.-2 S/cm are prepared by heating p-doped polyacetylenes, in the absence of oxygen and moisture, for from 0.1 to 3 hours, preferably from 0.5 to 1.0 hour, at from 500.degree. to 1,100.degree. C., preferably from 550.degree. to 850.degree. C. The electrically conductive polymers obtained can be used in the electrical industry for the production of solar cells, for the utilization and fixing of radiation, for the production of electrical and magnetic switches and stores, and for the antistatic treatment of plastics.
摘要翻译：电导率大于10 -2 S / cm的稳定的导电聚合物是通过在不存在氧和水分的情况下将p掺杂的聚乙炔加热0.1至3小时，优选0.5至1.0小时，在500至所得的导电聚合物可用于电气工业中用于生产太阳能电池，用于辐射的利用和固定，用于生产电气和磁性开关和商店，以及塑料的抗静电处理。

7. 发明授权

US4568483A Electrically conductive pyrrole copolymers and their preparation 失效
标题翻译：导电吡咯共聚物及其制备方法
公开(公告)号：US4568483A
公开(公告)日：1986-02-04
申请号：US504724
申请日：1983-06-16
申请人： Herbert Naarmann , Petr Simak , Gernot Kohler
发明人： Herbert Naarmann , Petr Simak , Gernot Kohler
IPC分类号： H01M4/62 , C08G61/00 , C08G61/10 , C08G61/12 , C08G73/06 , C08J7/04 , C08L65/00 , C25B3/10 , H01B1/12 , H01L21/331 , H01L29/73 , H01L51/05 , H01L51/30 , C08F26/06
CPC分类号： C08G61/124 , C08G73/0611 , H01B1/127
摘要： Highly electrically conductive copolymers of pyrroles and other heterocyclic compounds having a conjugated .pi.-electron system, which possess good mechanical properties coupled with a well-balanced spectrum of properties, are prepared by anodic polymerization of the pyrroles and other heterocyclic compounds and/or their dimers or oligomers in a polar solvent in the presence of a suitable conductive salt.
摘要翻译：通过吡咯和其它杂环化合物和/或其二聚体的阳极聚合制备具有共轭π电子系统的具有良好机械性能与良好平衡的性质光谱的吡咯和其它杂环化合物的高导电性共聚物或低聚物在极性溶剂中，在合适的导电盐存在下。

8. 发明授权

US4640749A Electrically conductive pyrrole copolymers and their preparation 失效
标题翻译：导电吡咯共聚物及其制备方法
公开(公告)号：US4640749A
公开(公告)日：1987-02-03
申请号：US731458
申请日：1985-05-07
申请人： Herbert Naarmann , Gernot Koehler , Johannes Schlag
发明人： Herbert Naarmann , Gernot Koehler , Johannes Schlag
IPC分类号： H01M4/60 , C08F38/00 , C08G61/00 , C08G61/10 , C08G61/12 , C08J7/02 , C08L65/00 , H01B1/12 , H01L21/331 , H01L29/73 , H01L51/05 , H01L51/30 , H01L51/40 , C25C1/00
CPC分类号： H01B1/127 , C08G61/124 , Y10T428/31855 , Y10T428/8305
摘要： Highly electrically conductive copolymers of pyrroles and alkynes and/or aromatics, which possess good mechanical properties coupled with a well-balanced spectrum of properties, are prepared by anodic polymerization of the pyrroles and alkynes and/or aromatics in a polar solvent in the presence of a suitable conductive salt.
摘要翻译：通过吡咯和炔和/或芳族化合物在极性溶剂中的存在下阳极聚合，制备具有良好机械性能与良好平衡的性质光谱的吡咯和炔和/或芳族化合物的高度导电的共聚物合适的导电盐。

9. 发明授权

US4532188A Electrically conductive pyrrole copolymer article 失效
标题翻译：导电吡咯共聚物制品
公开(公告)号：US4532188A
公开(公告)日：1985-07-30
申请号：US504723
申请日：1983-06-16
申请人： Herbert Naarmann , Gernot Koehler , Johannes Schlag
发明人： Herbert Naarmann , Gernot Koehler , Johannes Schlag
IPC分类号： H01M4/60 , C08F38/00 , C08G61/00 , C08G61/10 , C08G61/12 , C08J7/02 , C08L65/00 , H01B1/12 , H01L21/331 , H01L29/73 , H01L51/05 , H01L51/30 , H01L51/40 , B32B27/00 , C25B11/00
CPC分类号： H01B1/127 , C08G61/124 , Y10T428/31855 , Y10T428/8305
摘要： Highly electrically conductive copolymers of pyrroles and alkynes and/or aromatics, which possess good mechanical properties coupled with a well-balanced spectrum of properties, are prepared by anodic polymerization of the pyrroles and alkynes and/or aromatics in a polar solvent in the presence of a suitable conductive salt.
摘要翻译：通过吡咯和炔和/或芳族化合物在极性溶剂中的存在下阳极聚合，制备具有良好机械性能与良好平衡的性质光谱的吡咯和炔和/或芳族化合物的高度导电的共聚物合适的导电盐。

10. 发明授权

US4925897A Modified polyacetylene 失效
标题翻译：改性聚乙炔
公开(公告)号：US4925897A
公开(公告)日：1990-05-15
申请号：US295395
申请日：1989-01-10
申请人： Herbert Naarmann , Gernot Koehler
发明人： Herbert Naarmann , Gernot Koehler
IPC分类号： C08F38/00 , C08F8/00
CPC分类号： C08F8/46
摘要： Polyacetylene which is modified by reaction with a dienophilic compound, preparation of the said polyacetylene and its use for the production of moldings by processing by a thermoplastic method.
摘要翻译：通过与双亲性化合物反应而改性的聚乙炔，所述聚乙炔的制备及其用于通过热塑性方法加工生产模制品的用途。

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