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1. 发明授权

US4080314A Polyurethane elastomers based on alcohol-modified diisocyanate 失效
标题翻译：基于醇改性二异氰酸酯的聚氨酯弹性体
公开(公告)号：US4080314A
公开(公告)日：1978-03-21
申请号：US666086
申请日：1976-03-11
申请人： Henry W. Bonk , Benjamin S. Ehrlich , Joseph Pleckaitis
发明人： Henry W. Bonk , Benjamin S. Ehrlich , Joseph Pleckaitis
IPC分类号： C08G18/00 , C08G18/80 , C08G18/81 , C08G18/76
CPC分类号： C08G18/8166 , C08G18/8064
摘要： The processing temperatures of thermoplastic polyurethane elastomers are reduced, and the extrudability and sensitivity to shear and moisture are improved, by employing as the diisocyanate, in the preparation of said elastomers, the product obtained by reacting 4,4'-methylenebis(phenyl isocyanate) with a monohydric aliphatic alcohol. Use of the latter also counteracts batch-to-batch variations in reactivity of 4,4'-methylenebis(phenyl isocyanate).
摘要翻译：热塑性聚氨酯弹性体的加工温度降低，并且通过使用二异氰酸酯作为所述弹性体，通过使4,4'-亚甲基双（苯基异氰酸酯）反应得到的产物，可以改善挤出性和对剪切和水分的敏感性，与一元脂肪醇。后者的用途也抵消了4,4'-亚甲基双（苯基异氰酸酯）反应性的批次间变化。

2. 发明授权

US4098772A Thermoplastic polyurethanes prepared with small amounts of monohydric alcohols 失效
标题翻译：用少量一元醇制备的热塑性聚氨酯
公开(公告)号：US4098772A
公开(公告)日：1978-07-04
申请号：US666088
申请日：1976-03-11
申请人： Henry W. Bonk , Benjamin S. Ehrlich , Joseph Pleckaitis
发明人： Henry W. Bonk , Benjamin S. Ehrlich , Joseph Pleckaitis
IPC分类号： C08G18/00 , C08G18/28 , C08G18/65 , C08G18/67 , C08G18/30 , C08G18/76
CPC分类号： C08G18/671 , C08G18/2815 , C08G18/283 , Y10S264/77
摘要： The processing temperatures of thermoplastic polyurethane elastomers are reduced, and the extrudability and the sensitivity to degradation by shear and by moisture are improved, by including a minute proportion (from 0.0005 to 0.05 equivalents, per equivalent of isocyanate) of a monohydric aliphatic alcohol in the reaction mixture (diisocyanate, polymeric diol and difunctional extender) employed to prepare thermoplastic polyurethane elastomers by the one-shot procedure.
摘要翻译：热塑性聚氨酯弹性体的加工温度降低，挤出性和对剪切和水分降解的敏感性得到改善，通过在其中加入微量比例（每当量异氰酸酯0.0005至0.05当量）的一元脂肪醇用于通过一次性方法制备热塑性聚氨酯弹性体的反应混合物（二异氰酸酯，聚合二醇和双官能的增量剂）。

3. 发明授权

US5089571A Regenerated, high molecular weight, thermoplastic resins and process for regenerating thermoplastic resins 失效
标题翻译：再生的高分子量热塑性树脂和再生热塑性树脂的方法
公开(公告)号：US5089571A
公开(公告)日：1992-02-18
申请号：US623487
申请日：1990-12-04
申请人： Henry W. Bonk , Augustin T. Chen , Benjamin S. Ehrlich
发明人： Henry W. Bonk , Augustin T. Chen , Benjamin S. Ehrlich
IPC分类号： B29C45/00 , B29K75/00 , B29K105/26 , C08G18/12 , C08J11/06 , C08L75/00 , C08L75/04
CPC分类号： C08J11/06 , C08G18/12 , C08L75/04 , C08J2375/04 , Y02W30/701
摘要： High molecular weight thermoplastic polyurethane resins with narrow molecular weight distribution and good physical properties are prepared by regenerating thermally degraded and/or off-grade thermoplastic polyurethane resins. The regenerated high molecular weight thermoplastic polyurethane resins do not present any processing difficulties inherent to high molecular weight resins.
摘要翻译：通过再生热降解和/或脱级热塑性聚氨酯树脂制备具有窄分子量分布和良好物理性能的高分子量热塑性聚氨酯树脂。再生的高分子量热塑性聚氨酯树脂不存在高分子量树脂固有的任何加工困难。

4. 发明授权

US4822827A Thermoplastic polyurethanes with high glass transition temperatures 失效
标题翻译：玻璃化转变温度高的热塑性聚氨酯
公开(公告)号：US4822827A
公开(公告)日：1989-04-18
申请号：US134262
申请日：1987-12-17
申请人： Henry W. Bonk , Augustin T. Chen , Benjamin S. Ehrlich
发明人： Henry W. Bonk , Augustin T. Chen , Benjamin S. Ehrlich
IPC分类号： C08G18/32 , C08G18/65 , C08G18/66 , C08L75/04 , C08G18/28
CPC分类号： C08L75/04 , C08G18/3212 , C08G18/6511 , C08G18/6674 , C08G2120/00
摘要： Disclosed are novel high flexural modulus polyurethane plastics wherein a polyisocyanate and a particular combination of extenders including cycloalkane diol are reacted optionally in the presence of a minor proportion of high molecular weight polyol.The polymers have outstanding resistance to high temperatures thereby expanding their utilities into higher temperature end-use environments than related prior art materials. Certain members of these new polymers are also possessed of outstanding optical clarity which thereby provides a combination of properties heretofore not available in a polyurethane. These polymers are easily melt-fabricated notwithstanding their inherent high temperature properties.

5. 发明授权

US5491194A Thermally processable blends of high modulus polyurethanes and mass polymerized ABS resins 失效
标题翻译：高模量聚氨酯和大量聚合ABS树脂的热可加工共混物
公开(公告)号：US5491194A
公开(公告)日：1996-02-13
申请号：US484367
申请日：1995-06-07
申请人： David E. Henton , Augustin Chen , Paul J. Moses , Benjamin S. Ehrlich , Douglas E. Beyer
发明人： David E. Henton , Augustin Chen , Paul J. Moses , Benjamin S. Ehrlich , Douglas E. Beyer
IPC分类号： C08G18/32 , C08L51/04 , C08L55/02 , C08L75/00 , C08L75/04
CPC分类号： C08L55/02 , C08G18/3212 , C08L75/04
摘要： The toughness of a thermoplastic, rigid polyurethane is markedly improved by incorporating a mass ABS resin such as styrene/butadiene rubber grafted with a copolymer of styrene and acrylonitrile. This toughened polyurethane is particularly useful in making structural automotive body parts and housings for electrical appliances.
摘要翻译：热塑性硬质聚氨酯的韧性通过掺入接枝有苯乙烯和丙烯腈共聚物的ABS / ABS树脂等ABS树脂显着提高。这种增韧的聚氨酯在制造用于电器的结构汽车车身部件和外壳中特别有用。

6. 发明授权

US4169196A Process for improving thermoplastic polyurethanes 失效
标题翻译：改进热塑性聚氨酯的方法
公开(公告)号：US4169196A
公开(公告)日：1979-09-25
申请号：US842063
申请日：1977-10-14
申请人： Benjamin S. Ehrlich , Curtis P. Smith
发明人： Benjamin S. Ehrlich , Curtis P. Smith
IPC分类号： C08G18/16 , C08G18/24 , C08G18/28 , C08G18/66 , C08K5/51 , C07C41/12 , C08K5/52
CPC分类号： C08G18/6607 , C08G18/161 , C08G18/24 , C08G18/28 , C08K5/49 , C08K5/51
摘要： An improved process for the preparation of thermoplastic polyurethane elastomers by a one-shot reaction of an organic diisocyanate, a polymeric diol, and a diol extender is disclosed wherein the diol components, either singly or together, are treated with a trivalent phosphorus compound prior to their reaction with the diisocyanate in the presence of a stannous tin urethane catalyst. The process when carried out with pure urethane grade diol components results in very efficient catalysis which in turn requires lower levels of stannous tin catalyst than would otherwise be employed. Moreover, the process can be carried out with diol components that are not urethane grade materials but which are contaminated by high levels of peroxidic impurities and which materials would otherwise be useless for the preparation of high grade elastomer products.
摘要翻译：公开了通过有机二异氰酸酯，聚合二醇和二醇增量剂的单次反应制备热塑性聚氨酯弹性体的改进方法，其中单独或一起的二醇组分在三价磷化合物之前用它们与二异氰酸酯在亚锡锡聚氨酯催化剂存在下的反应。用纯氨基甲酸乙酯级二醇组分进行的方法导致非常有效的催化，其反过来需要比其它方法更低水平的锡锡催化剂。此外，该方法可以用不是聚氨酯级材料但被高水平过氧化物杂质污染的二醇组分进行，否则这些材料对于制备高级弹性体产品将是无用的。

7. 发明授权

US5648412A Blow-moldable rigid thermoplastic polyurethane resins 失效
标题翻译：可塑成型的刚性热塑性聚氨酯树脂
公开(公告)号：US5648412A
公开(公告)日：1997-07-15
申请号：US380767
申请日：1995-01-30
申请人： Gary S. Mistry , Kuan J. Wang , Benjamin S. Ehrlich
发明人： Gary S. Mistry , Kuan J. Wang , Benjamin S. Ehrlich
IPC分类号： B29C49/00 , B29K75/00 , C08G18/00 , C08G18/08 , C08G18/22 , C08K5/13 , C08G18/24 , C08L75/04
CPC分类号： C08G18/089
摘要： A rigid thermoplastic polyurethane with improved melt strength can be prepared by deactivating the catalyst for the polymer subsequent to the onset of urethane bond formation. Catalyst deactivation is accomplished either with a latent deactivator for the catalyst, or an active deactivator. The further addition of a crosslinker to the reaction mixture can provide an even greater improvement of melt strength.
摘要翻译：具有改善的熔体强度的刚性热塑性聚氨酯可以通过在氨基甲酸酯键形成开始之后使聚合物催化剂失活来制备。催化剂失活通过催化剂的潜在钝化剂或活性钝化剂来完成。将交联剂进一步添加到反应混合物中可以提供更大的熔体强度的改进。

8. 发明授权

US4707525A Oxymethylene polymer molding compositions having enhanced impact resistance and article molded therefrom 失效
标题翻译：氧化亚甲基聚合物模塑组合物具有增强的耐冲击性和由其模制的制品
公开(公告)号：US4707525A
公开(公告)日：1987-11-17
申请号：US930989
申请日：1986-11-14
申请人： H. Leslie LaNieve, III , Robert S. Drzal , Benjamin S. Ehrlich
发明人： H. Leslie LaNieve, III , Robert S. Drzal , Benjamin S. Ehrlich
IPC分类号： C08G2/18 , C08L59/02 , C08L75/08 , C08G63/76
CPC分类号： C08L59/02 , C08G2/18 , C08L75/08
摘要： Articles molded from oxymethylene polymer molding compositions of the present invention exhibit enhanced impact strength properties, especially at low temperatures such as -20.degree. F. It has now been found that the impact strength of articles molded from oxymethylene polymer molding compositions may be improved when the compositions include an elastomeric polyurethane, which is the reaction product of:(i) 4,4'-methylenebis(phenyl isocyanate),(ii) polyoxytetramethylene glycol having a molecular weight within the range of about 1500 to about 3000, and(iii) at least one diol extender selected from the group consisting of aliphatic straight chain diols having from 2 to about 6 carbon atoms, bis(2-hydroxy-ethyl) ether of hydroquinone, and bis(2-hydroxy-ethyl) ether of resorcinol.
摘要翻译：由本发明的甲醛聚合物模塑组合物成型的制品表现出增强的冲击强度性能，特别是在-20°F的低温下。现在已经发现，当甲醛聚合物模塑组合物模制的制品的冲击强度可以改善组合物包括弹性体聚氨酯，其是以下物质的反应产物：（i）4,4'-亚甲基双（异氰酸苯酯），（ii）分子量在约1500至约3000范围内的聚氧四亚甲基二醇，和（iii）至少一种选自具有2至约6个碳原子的脂族直链二醇，氢醌的双（2-羟基 - 乙基）醚和间苯二酚的双（2-羟基 - 乙基）醚的二醇增量剂。

9. 发明授权

US4379904A Novel polyurethane product 失效
标题翻译：新型聚氨酯产品
公开(公告)号：US4379904A
公开(公告)日：1983-04-12
申请号：US371534
申请日：1982-04-26
申请人： Benjamin S. Ehrlich , Richard W. Oertel, III
发明人： Benjamin S. Ehrlich , Richard W. Oertel, III
IPC分类号： C08G18/40 , C08G18/48 , C08G18/66
CPC分类号： C08G18/4018 , C08G18/4804 , C08G18/66
摘要： Improved thermoplastic polyurethane elastomers are disclosed which are the reaction product of 4,4'-methylene-bis(phenyl isocyanate); a polymeric diol; and an extender wherein the equivalent proportions of said diol to said extender fall within the range of about 1:2 to about 1:20 and the isocyanate to total hydroxyl equivalents are within the range of about 0.99:1 to 1.06:1, the improvement which comprises replacing at least about 15 percent by weight of said polymeric diol by a polyol selected from the class consisting of: (i) polyoxypropylene-polyoxyethylene glycols having a molecular weight of about 3500 to about 4500 and an ethylene oxide content of about 10 to about 60 percent by weight; (ii) polyoxypropylene-polyoxyethylene triols having a molecular weight from about 5000 to about 7000 and an ethylene oxide content of about 10 to about 40 percent by weight; and (iii) mixtures of (i) and (ii).The elastomers find particular utility in the manufacture of ski boots, hockey boots and automotive exterior panels, bumpers, fascia, and the like.
摘要翻译：公开了改进的热塑性聚氨酯弹性体，其是4,4'-亚甲基 - 双（苯基异氰酸酯）的反应产物; 聚合二醇; 和增量剂，其中所述二醇与所述增量剂的当量比例在约1:2至约1:20的范围内，异氰酸酯与总羟基当量的比例在约0.99:1至1.06:1的范围内，改进其包括用选自以下的多元醇代替至少约15重量％的所述聚合二醇：（i）分子量为约3500至约4500的聚氧丙烯 - 聚氧乙烯二醇和约10至约10的环氧乙烷含量，约60重量％（ii）分子量为约5000至约7000并且环氧乙烷含量为约10至约40重量％的聚氧丙烯 - 聚氧乙烯三醇; 和（iii）（i）和（ii）的混合物。弹性体在制造滑雪靴，曲棍球靴和汽车外部面板，保险杠，面板等方面具有特别的用途。

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