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1. 发明授权

US4576628A Oxime ethers, compositions containing them and the use thereof 失效
标题翻译：肟醚，含有它们的组合物及其用途
公开(公告)号：US4576628A
公开(公告)日：1986-03-18
申请号：US733352
申请日：1985-05-13
申请人： Henry Martin , Urs Fricker
发明人： Henry Martin , Urs Fricker
IPC分类号： A01N25/32 , A01N33/24 , A01N35/10 , A01N43/20 , A01N43/32 , A01P13/00 , C07C67/00 , C07C239/00 , C07C251/50 , C07C251/54 , C07C313/00 , C07C315/04 , C07C317/32 , C07C319/20 , C07C323/47 , C07D307/12 , C07D309/06 , C07D309/12 , C07D317/18 , C07D317/22 , C07D319/06 , C07D321/02 , C07D321/06 , C07D339/06 , C07D339/08 , C07C131/00 , A01N33/06 , A01N37/00 , A01N37/10 , A01N37/18 , A01N37/34 , A01N37/36 , A01N43/08 , A01N43/28 , A01N43/40 , A01N43/64 , A01N43/82
CPC分类号： C07D319/06 , A01N25/32 , C07D307/12 , C07D309/06 , C07D317/22 , C07D321/06 , C07D339/06 , C07D339/08
摘要： The oxime ethers of the formula I below are able to act as antidotes or safeners to protect cultivated plants from the phytotoxic effects of herbicides. Such cultivated plants are preferably sorghum, cereals, maize and rice, and herbicides are principally chloroacetanilides and thiocarbamates. The oxime ethers have the formula I ##STR1## wherein n is 1 or 2, each of R.sub.1 and R.sub.2 is hydrogen or C.sub.1 -C.sub.4 alkyl each of R.sub.3 and R.sub.4 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkylthio, C.sub.1 -C.sub.4 alkylsulfinyl, C.sub.1 -C.sub.4 alkylsulfonyl, C.sub.1 -C.sub.4 haloalkylsulfinyl, C.sub.1 -C.sub.4 haloalkylsulfonyl or nitro; each of R.sub.5 and R.sub.6 independently of the other is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.2 -C.sub.8 alkoxyalkyl, C.sub.3 -C.sub.4 alkenyl, C.sub.3 -C.sub.4 alkynyl, or together form a 2- to 6-membered alkylene or alkenylene bridge which may be substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.4 alkenyloxy, C.sub.2 -C.sub.8 alkoxyalkyl or C.sub.3 -C.sub.8 alkenyloxyalkyl groups; each of A and B independently of the other is oxygen or sulfur, or one of A and b is the methine group, X is a fluorinated C.sub.1 -C.sub.3 alkyl radical which may also additionally contain chlorine, and Y is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy or phenyl.
摘要翻译：以下式I的肟醚能够用作解毒剂或安全剂，以保护栽培植物免受除草剂的植物毒性作用。这样的栽培植物优选是高粱，谷物，玉米和水稻，除草剂主要是氯乙酰苯胺和硫代氨基甲酸盐。肟醚具有式I（I）其中n为1或2，R 1和R 2各自为氢或R 3和R 4各自为C 1 -C 4烷基，卤素，C 1 -C 4烷基，C 1 -C 4 卤代烷基，C1-C4烷氧基，C1-C4卤代烷氧基，C1-C4烷硫基，C1-C4卤代烷硫基，C1-C4烷基亚磺酰基，C1-C4烷基磺酰基，C1-C4卤代烷基亚磺酰基，C1-C4卤代烷基磺酰基或硝基; R 5和R 6各自独立地是C 1 -C 4烷基，C 1 -C 4卤代烷基，C 2 -C 8烷氧基烷基，C 3 -C 4烯基，C 3 -C 4炔基，或一起形成2-至6-元亚烷基或亚烯基桥，其中可以被1至4个C 1 -C 4烷基，C 1 -C 4卤代烷基，C 1 -C 4烷氧基，C 2 -C 4烯氧基，C 2 -C 8烷氧基烷基或C 3 -C 8链烷氧基烷基取代; A和B各自独立地是氧或硫，或者A和b中的一个是次甲基，X是还可以另外含有氯的氟化的C 1 -C 3烷基，Y是氢，C 1 -C 4烷基，C 1 -C 4卤代烷基，C 1 -C 4烷氧基，C 1 -C 4卤代烷氧基或苯基。

2. 发明授权

US4707182A Phenoxine-ketal ethers, compositions containing them and the use thereof 失效
标题翻译：苯氧基 - 缩酮醚，含有它们的组合物及其用途
公开(公告)号：US4707182A
公开(公告)日：1987-11-17
申请号：US733353
申请日：1985-05-13
申请人： Henry Martin , Urs Fricker
发明人： Henry Martin , Urs Fricker
IPC分类号： A01N25/32 , A01N33/24 , A01N35/10 , A01N43/20 , A01N43/32 , A01P13/00 , C07C67/00 , C07C239/00 , C07C251/50 , C07C251/54 , C07C313/00 , C07C315/04 , C07C317/32 , C07C319/20 , C07C323/47 , C07D307/12 , C07D309/06 , C07D309/12 , C07D317/18 , C07D317/22 , C07D319/06 , C07D321/02 , C07D321/06 , C07D339/06 , C07D339/08 , A01N43/40 , A01N43/08 , C07D317/16
CPC分类号： C07D319/06 , A01N25/32 , C07D307/12 , C07D309/06 , C07D317/22 , C07D321/06 , C07D339/06 , C07D339/08
摘要： The oxime ethers of the formula I below are able to act as antidotes or safeners to protect cultivated plants from the phytotoxic effects of herbicides. Such cultivated plants are preferably sorghum, cereals, maize and rice, and herbicides are principally chloroacetanilides and thiocarbamates. The oxime ethers have the formula I ##STR1## wherein n is 1 or 2, each of R.sub.1 and R.sub.2 is hydrogen or C.sub.1 -C.sub.4 alkyl each of R.sub.3 and R.sub.4 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkylthio, C.sub.1 -C.sub.4 alkylsulfinyl, C.sub.1 -C.sub.4 alkylsulfonyl, C.sub.1 -C.sub.4 haloalkylsulfinyl, C.sub.1 -C.sub.4 haloalkylsulfonyl or nitro; each of R.sub.5 and R.sub.6 independently of the other is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.2 -C.sub.8 alkoxyalkyl, C.sub.3 -C.sub.4 alkenyl, C.sub.3 -C.sub.4 alkynyl, or together form a 2- to 6-membered alkylene or alkenylene bridge which may be substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.4 alkenyloxy, C.sub.2 -C.sub.8 alkoxyalkyl or C.sub.3 -C.sub.8 alkenyloxyalkyl groups; each of A and B independently of the other is oxygen or sulfur, or one of A and B is the methine group, X is a fluorinated C.sub.1 -C.sub.3 alkyl radical which may also additionally contain chlorine, and Y is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy or phenyl.
摘要翻译：以下式I的肟醚能够用作解毒剂或安全剂，以保护栽培植物免受除草剂的植物毒性作用。这样的栽培植物优选是高粱，谷物，玉米和水稻，除草剂主要是氯乙酰苯胺和硫代氨基甲酸盐。肟醚具有式I（I）其中n为1或2，R 1和R 2各自为氢或R 3和R 4各自为C 1 -C 4烷基，卤素，C 1 -C 4烷基，C 1 -C 4 卤代烷基，C1-C4烷氧基，C1-C4卤代烷氧基，C1-C4烷硫基，C1-C4卤代烷硫基，C1-C4烷基亚磺酰基，C1-C4烷基磺酰基，C1-C4卤代烷基亚磺酰基，C1-C4卤代烷基磺酰基或硝基; R 5和R 6各自独立地是C 1 -C 4烷基，C 1 -C 4卤代烷基，C 2 -C 8烷氧基烷基，C 3 -C 4烯基，C 3 -C 4炔基，或一起形成2-至6-元亚烷基或亚烯基桥，其中可以被1至4个C 1 -C 4烷基，C 1 -C 4卤代烷基，C 1 -C 4烷氧基，C 2 -C 4烯氧基，C 2 -C 8烷氧基烷基或C 3 -C 8链烷氧基烷基取代; A和B各自独立地是氧或硫，或者A和B中的一个是次甲基，X是还可以另外含有氯的氟化的C 1 -C 3烷基，Y是氢，C 1 -C 4烷基，C 1 -C 4卤代烷基，C 1 -C 4烷氧基，C 1 -C 4卤代烷氧基或苯基。

3. 发明授权

US4530716A Oxime ethers, compositions containing them and the use thereof 失效
标题翻译：肟醚，含有它们的组合物及其用途
公开(公告)号：US4530716A
公开(公告)日：1985-07-23
申请号：US473905
申请日：1983-03-10
申请人： Henry Martin , Urs Fricker
发明人： Henry Martin , Urs Fricker
IPC分类号： A01N25/32 , A01N33/24 , A01N35/10 , A01N43/20 , A01N43/32 , A01P13/00 , C07C67/00 , C07C239/00 , C07C251/50 , C07C251/54 , C07C313/00 , C07C315/04 , C07C317/32 , C07C319/20 , C07C323/47 , C07D307/12 , C07D309/06 , C07D309/12 , C07D317/18 , C07D317/22 , C07D319/06 , C07D321/02 , C07D321/06 , C07D339/06 , C07D339/08 , A01N43/00 , C07D317/00
CPC分类号： C07D319/06 , A01N25/32 , C07D307/12 , C07D309/06 , C07D317/22 , C07D321/06 , C07D339/06 , C07D339/08
摘要： The oxime ethers of the formula I below are able to act as antidotes or safeners to protect cultivated plants from the phytotoxic effects of herbicides. Such cultivated plants are preferably sorghum, cereals, maize and rice, and herbicides are principally chloroacetanilides and thiocarbamates. The oxime ethers have the formula I ##STR1## wherein n is 1 or 2, each of R.sub.1 and R.sub.2 is hydrogen or C.sub.1 -C.sub.4 alkyl each of R.sub.3 and R.sub.4 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkylthio, C.sub.1 -C.sub.4 alkylsulfinyl, C.sub.1 -C.sub.4 alkylsulfonyl, C.sub.1 -C.sub.4 haloalkylsulfinyl, C.sub.1 -C.sub.4 haloalkylsulfonyl or nitro; each of R.sub.5 and R.sub.6 independently of the other is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.2 -C.sub.8 alkoxyalkyl, C.sub.3 -C.sub.4 alkenyl, C.sub.3 -C.sub.4 alkynyl, or together form a 2- to 6-membered alkylene or alkenylene bridge which may be substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.4 alkenyloxy, C.sub.2 -C.sub.8 alkoxyalkyl or C.sub.3 -C.sub.8 alkenyloxyalkyl groups; each of A and B independently of the other is oxygen or sulfur, or one of A and B is the methine group, X is a fluorinated C.sub.1 -C.sub.3 alkyl radical which may also additionally contain chlorine, and Y is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy or phenyl.
摘要翻译：以下式I的肟醚能够用作解毒剂或安全剂，以保护栽培植物免受除草剂的植物毒性作用。这样的栽培植物优选是高粱，谷物，玉米和水稻，除草剂主要是氯乙酰苯胺和硫代氨基甲酸盐。肟醚具有式I（I）其中n为1或2，R 1和R 2各自为氢或R 3和R 4各自为C 1 -C 4烷基，卤素，C 1 -C 4烷基，C 1 -C 4 卤代烷基，C1-C4烷氧基，C1-C4卤代烷氧基，C1-C4烷硫基，C1-C4卤代烷硫基，C1-C4烷基亚磺酰基，C1-C4烷基磺酰基，C1-C4卤代烷基亚磺酰基，C1-C4卤代烷基磺酰基或硝基; R 5和R 6各自独立地是C 1 -C 4烷基，C 1 -C 4卤代烷基，C 2 -C 8烷氧基烷基，C 3 -C 4烯基，C 3 -C 4炔基，或一起形成2-至6-元亚烷基或亚烯基桥，其中可以被1至4个C 1 -C 4烷基，C 1 -C 4卤代烷基，C 1 -C 4烷氧基，C 2 -C 4烯氧基，C 2 -C 8烷氧基烷基或C 3 -C 8链烷氧基烷基取代; A和B各自独立地是氧或硫，或者A和B中的一个是次甲基，X是还可以另外含有氯的氟化的C 1 -C 3烷基，Y是氢，C 1 -C 4烷基，C 1 -C 4卤代烷基，C 1 -C 4烷氧基，C 1 -C 4卤代烷氧基或苯基。

4. 发明授权

US5041663A Novel oxime ethers, the preparation thereof, compositions containing them and the use thereof 失效
标题翻译：新型肟醚，其制备方法，含有它们的组合物及其用途
公开(公告)号：US5041663A
公开(公告)日：1991-08-20
申请号：US626080
申请日：1990-12-11
申请人： Henry Martin , Urs Fricker
发明人： Henry Martin , Urs Fricker
IPC分类号： A01N47/24 , A01N25/32 , A01N33/24 , A01N35/10 , A01N37/00 , A01N37/10 , A01N37/18 , A01N37/22 , A01N37/34 , A01N37/48 , A01N41/00 , A01N41/10 , A01N43/00 , A01N43/20 , A01N43/36 , A01N43/40 , A01N43/828 , A01N43/84 , A01N47/02 , A01N47/06 , A01N47/08 , A01N47/12 , A01N51/00 , C07C67/00 , C07C239/00 , C07C251/32 , C07C251/48 , C07C251/50 , C07C251/52 , C07C251/54 , C07C251/58 , C07C251/60 , C07C251/66 , C07C251/68 , C07C255/62 , C07C271/60 , C07C307/02 , C07C309/65 , C07C309/66 , C07C309/73 , C07C313/00 , C07C315/04 , C07C317/32 , C07C319/20 , C07C323/47 , C07C323/52 , C07C323/62 , C07C325/00 , C07C327/22 , C07C327/28 , C07C327/40 , C07C327/42 , C07C333/00 , C07C333/08 , C07D207/40 , C07D207/404 , C07D207/44 , C07D207/448 , C07D207/452 , C07D209/48 , C07D213/63 , C07D213/79 , C07D213/89 , C07D239/30 , C07D261/18 , C07D277/56 , C07D285/06 , C07D295/08 , C07D295/088 , C07D295/22 , C07D303/12 , C07D303/22 , C07D307/12 , C07D307/68 , C07D309/28 , C07D327/06 , C07D333/38
CPC分类号： C07D207/404 , A01N25/32 , C07D207/452 , C07D209/48 , C07D213/63 , C07D213/79 , C07D239/30 , C07D261/18 , C07D277/56 , C07D285/06 , C07D295/088 , C07D303/12 , C07D307/68 , C07D309/28 , C07D327/06 , C07D333/38
摘要： The invention relates to novel oxime ethers of the formula I ##STR1## wherein R.sub.1 is hydrogen, halogen, lower alkyl, lower haloalkyl, lower alkoxy, lower haloalkoxy, lower alkylthio, lower haloalkylthio, lower alkylsulfinyl, lower alkylsulfonyl, lower haloalkylsulfinyl, lower haloalkylsulfonyl or nitro, each of R.sub.2 and R.sub.3 is hydrogen, halogen, lower alkyl, lower alkoxy or lower haloalkoxy, and Q is an unsubstituted or substituted lower alkyl, lower alkenyl, lower alkynyl or cycloalkyl group, a lower alkanoyl radical, an aliphatic, cycloaliphatic, aromatic or heterocyclic acyl radical which may be substituted or unsubstituted, a carbonyl or thiocarbonyl radical, an aryl or aralkyl radical, an acylimidomethyl radical, a phthalimidomethyl radical or a heterocyclic radical.These compounds are able to act as antidotes or safeners for protecting cultivated plants from the phytotoxic action of aggressive herbicides. Preferred crops are sorghum, cereals, maize and rice, and herbicides are chiefly chloroacetanilides and thiocarbamates.

5. 发明授权

US5032169A Novel oxime ethers, the preparation thereof, compositions containing them and the use thereof 失效
公开(公告)号：US5032169A
公开(公告)日：1991-07-16
申请号：US199225
申请日：1988-05-26
申请人： Henry Martin , Urs Fricker
发明人： Henry Martin , Urs Fricker
IPC分类号： A01N47/24 , A01N25/32 , A01N33/24 , A01N35/10 , A01N37/00 , A01N37/10 , A01N37/18 , A01N37/22 , A01N37/34 , A01N37/48 , A01N41/00 , A01N41/10 , A01N43/00 , A01N43/20 , A01N43/36 , A01N43/40 , A01N43/828 , A01N43/84 , A01N47/02 , A01N47/06 , A01N47/08 , A01N47/12 , A01N51/00 , C07C67/00 , C07C239/00 , C07C251/32 , C07C251/48 , C07C251/50 , C07C251/52 , C07C251/54 , C07C251/58 , C07C251/60 , C07C251/66 , C07C251/68 , C07C255/62 , C07C271/60 , C07C307/02 , C07C309/65 , C07C309/66 , C07C309/73 , C07C313/00 , C07C315/04 , C07C317/32 , C07C319/20 , C07C323/47 , C07C323/52 , C07C323/62 , C07C325/00 , C07C327/22 , C07C327/28 , C07C327/40 , C07C327/42 , C07C333/00 , C07C333/08 , C07D207/40 , C07D207/404 , C07D207/44 , C07D207/448 , C07D207/452 , C07D209/48 , C07D213/63 , C07D213/79 , C07D213/89 , C07D239/30 , C07D261/18 , C07D277/56 , C07D285/06 , C07D295/08 , C07D295/088 , C07D295/22 , C07D303/12 , C07D303/22 , C07D307/12 , C07D307/68 , C07D309/28 , C07D327/06 , C07D333/38
CPC分类号： C07D207/404 , A01N25/32 , C07D207/452 , C07D209/48 , C07D213/63 , C07D213/79 , C07D239/30 , C07D261/18 , C07D277/56 , C07D285/06 , C07D295/088 , C07D303/12 , C07D307/68 , C07D309/28 , C07D327/06 , C07D333/38
摘要： The invention relates to novel oxime ethers of the formula I ##STR1## wherein R.sub.1 is hydrogen, halogen, lower alkyl, lower haloalkyl, lower alkoxy, lower haloalkoxy, lower alkylthio, lower haloalkylthio, lower alkylsulfinyl, lower alkylsulfonyl, lower haloalkylsulfinyl, lower haloalkylsulfonyl or nitro, each of R.sub.2 and R.sub.3 is hydrogen, halogen, lower alkyl, lower alkoxy or lower haloalkoxy, and Q is an unsubstituted or substituted lower alkyl, lower alkenyl, lower alkynyl or cycloalkyl group, a lower alkanoyl radical, an aliphatic, cycloaliphatic, aromatic or heterocyclic acyl radical which may be substituted or unsubstituted, a carbonyl or thiocarbonyl radical, an aryl or aralkyl radical, an acylimidomethyl radical, a phthalimidomethyl radical or a heterocyclic radical.These compounds are able to act as antidotes or safeners for protecting cultivated plants from the phytotoxic action of aggressive herbicides. Preferred crops are sorghum, cereals, maize and rice, and herbicides are chiefly chloroacetanilides and thiocarbamates.

6. 发明授权

US4759789A Oxime ethers as herbicidal safeners 失效
标题翻译：肟醚作为除草安全剂
公开(公告)号：US4759789A
公开(公告)日：1988-07-26
申请号：US730512
申请日：1985-05-06
申请人： Henry Martin , Urs Fricker
发明人： Henry Martin , Urs Fricker
IPC分类号： A01N47/24 , A01N25/32 , A01N33/24 , A01N35/10 , A01N37/00 , A01N37/10 , A01N37/18 , A01N37/22 , A01N37/34 , A01N37/48 , A01N41/00 , A01N41/10 , A01N43/00 , A01N43/20 , A01N43/36 , A01N43/40 , A01N43/828 , A01N43/84 , A01N47/02 , A01N47/06 , A01N47/08 , A01N47/12 , A01N51/00 , C07C67/00 , C07C239/00 , C07C251/32 , C07C251/48 , C07C251/50 , C07C251/52 , C07C251/54 , C07C251/58 , C07C251/60 , C07C251/66 , C07C251/68 , C07C255/62 , C07C271/60 , C07C307/02 , C07C309/65 , C07C309/66 , C07C309/73 , C07C313/00 , C07C315/04 , C07C317/32 , C07C319/20 , C07C323/47 , C07C323/52 , C07C323/62 , C07C325/00 , C07C327/22 , C07C327/28 , C07C327/40 , C07C327/42 , C07C333/00 , C07C333/08 , C07D207/40 , C07D207/404 , C07D207/44 , C07D207/448 , C07D207/452 , C07D209/48 , C07D213/63 , C07D213/79 , C07D213/89 , C07D239/30 , C07D261/18 , C07D277/56 , C07D285/06 , C07D295/08 , C07D295/088 , C07D295/22 , C07D303/12 , C07D303/22 , C07D307/12 , C07D307/68 , C07D309/28 , C07D327/06 , C07D333/38 , C07C101/00 , A01N43/02
CPC分类号： C07D207/404 , A01N25/32 , C07D207/452 , C07D209/48 , C07D213/63 , C07D213/79 , C07D239/30 , C07D261/18 , C07D277/56 , C07D285/06 , C07D295/088 , C07D303/12 , C07D307/68 , C07D309/28 , C07D327/06 , C07D333/38
摘要： The invention relates to novel oxime ethers of the formula I ##STR1## wherein R.sub.1 is hydrogen, halogen, lower alkyl, lower haloalkyl, lower alkoxy, lower haloalkoxy, lower alkylthio, lower haloalkylthio, lower alkylsulfinyl, lower alkylsulfonyl, lower haloalkylsulfinyl, lower haloalkylsulfonyl or nitro, each of R.sub.2 and R.sub.3 is hydrogen, halogen, lower alkyl, lower alkoxy or lower haloalkoxy, and Q is an unsubstituted or substituted lower alkyl, lower alkenyl, lower alkynyl or cycloalkyl group, a lower alkanoyl radical, an aliphatic, cycloaliphatic, aromatic or heterocyclic acyl radical which may be substituted or unsubstituted, a carbonyl or thiocarbonyl radical, an aryl or aralkyl radical, an acylimidomethyl radical, a phthalimidomethyl radical or a heterocyclic radical.These compounds are able to act as antidotes or safeners for protecting cultivated plants from the phytotoxic action of aggressive herbicides. Preferred crops are sorghum, cereals, maize and rice, and herbicides are chiefly chloroacetanilides and thiocarbamates.
摘要翻译：本发明涉及式Ⅰ的肟醚（Ⅰ）其中R1是氢，卤素，低级烷基，低级卤代烷基，低级烷氧基，低级卤代烷氧基，低级烷硫基，低级卤代烷硫基，低级烷基亚磺酰基，低级烷基磺酰基，低级卤代烷基亚硫酰基，低级卤代烷基磺酰基或硝基，R2和R3各自为氢，卤素，低级烷基，低级烷氧基或低级卤代烷氧基，Q为未取代或取代的低级烷基，低级烯基，低级炔基或环烷基，低级烷酰基，可以被取代或未取代的脂族，脂环族，芳族或杂环酰基，羰基或硫代羰基，芳基或芳烷基，酰亚胺基甲基，苯二甲酰亚氨基甲基或杂环基。这些化合物能够用作解毒剂或安全剂，以保护栽培植物免受侵蚀性除草剂的植物毒性作用。优选的作物是高粱，谷物，玉米和大米，除草剂主要是氯乙酰苯胺和硫代氨基甲酸盐。

7. 发明授权

US4648895A Oxime ethers, the preparation thereof, compositions containing them and use thereof 失效
标题翻译：肟醚，其制备方法，含有它们的组合物及其用途
公开(公告)号：US4648895A
公开(公告)日：1987-03-10
申请号：US699488
申请日：1985-02-08
申请人： Henry Martin , Urs Fricker
发明人： Henry Martin , Urs Fricker
IPC分类号： C07D317/18 , A01N25/32 , A01N43/28 , C07D317/22 , C07D317/72 , A01N43/00 , C07D317/00
CPC分类号： C07D317/72 , A01N25/32 , A01N43/28 , C07D317/22
摘要： The invention relates to oxime ethers of the formula I ##STR1## wherein n is 1 or 2, each of R.sub.1 and R.sub.2 is hydrogen or C.sub.1 -C.sub.4 alkyl each of R.sub.3 and R.sub.4 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkylthio, C.sub.1 -C.sub.4 alkylsulfinyl, C.sub.1 -C.sub.4 alkylsulfonyl, C.sub.1 -C.sub.4 haloalkylsulfinyl, C.sub.1 -C.sub.4 haloalkylsulfonyl or nitro; each of R.sub.5 and R.sub.6 independently of the other is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, phenyl or phenyl which is substituted by halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 alkylsulfinyl, C.sub.1 -C.sub.4 alkylsulfonyl, carboxyl, carbamoyl, C.sub. 1 -C.sub.4 alkylcarbamoyl, nitro or cyano, or R.sub.5 and R.sub.6 together are also a 2- to 6-membered alkylene or alkenylene chain which may be substituted by C.sub.1 -C.sub.4 alkyl radicals; X is hydrogen, cyano, nitro, chlorine, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.3 -C.sub.6 cycloalkyl, carboxyl, carbamoyl, C.sub.1 -C.sub.4 alkylcarbonyl, C.sub.1 -C.sub.4 alkoxycarbonyl or C.sub.1 -C.sub.4 alkylcarbamoyl.The oxime ethers of the formula I are able to act as antidotes or safeners to protect cultivated plants from the phytotoxic effects of herbicides. Such cultivated plants are preferably sorghum, cereals, maize and rice.
摘要翻译：本发明涉及式I的肟醚，其中n为1或2，R 1和R 2各自为氢或R 3和R 4各自为C 1 -C 4烷基，卤素，C 1 -C 4烷基， C1-C4卤代烷基，C1-C4烷氧基，C1-C4卤代烷氧基，C1-C4烷硫基，C1-C4卤代烷硫基，C1-C4烷基亚磺酰基，C1-C4烷基磺酰基，C1-C4卤代烷基亚磺酰基，C1-C4卤代烷基磺酰基或硝基; C 1 -C 4烷氧基，C 1 -C 4卤代烷氧基，C 1 -C 4卤代烷基，C 1 -C 4卤代烷基，C 1 -C 4卤代烷基，，C 1 -C 4烷硫基，C 1 -C 4烷基亚磺酰基，C 1 -C 4烷基磺酰基，羧基，氨基甲酰基，C 1 -C 4烷基氨基甲酰基，硝基或氰基，或R 5和R 6一起也是2-至6-元亚烷基或亚烯基链，被C1-C4烷基取代; X是氢，氰基，硝基，氯，C 1 -C 4烷基，C 1 -C 4卤代烷基，C 3 -C 6环烷基，羧基，氨基甲酰基，C 1 -C 4烷基羰基，C 1 -C 4烷氧基羰基或C 1 -C 4烷基氨基甲酰基。式I的肟醚能够用作解毒剂或安全剂，以保护栽培植物免受除草剂的植物毒性作用。这些栽培植物优选为高粱，谷物，玉米和大米。

8. 发明授权

US4566901A Novel oxime ethers, the preparation thereof, compositions containing them and the use thereof 失效
标题翻译：新型肟醚，其制备方法，含有它们的组合物及其用途
公开(公告)号：US4566901A
公开(公告)日：1986-01-28
申请号：US490055
申请日：1983-04-29
申请人： Henry Martin , Urs Fricker
发明人： Henry Martin , Urs Fricker
IPC分类号： A01N47/24 , A01N25/32 , A01N33/24 , A01N35/10 , A01N37/00 , A01N37/10 , A01N37/18 , A01N37/22 , A01N37/34 , A01N37/48 , A01N41/00 , A01N41/10 , A01N43/00 , A01N43/20 , A01N43/36 , A01N43/40 , A01N43/828 , A01N43/84 , A01N47/02 , A01N47/06 , A01N47/08 , A01N47/12 , A01N51/00 , C07C67/00 , C07C239/00 , C07C251/32 , C07C251/48 , C07C251/50 , C07C251/52 , C07C251/54 , C07C251/58 , C07C251/60 , C07C251/66 , C07C251/68 , C07C255/62 , C07C271/60 , C07C307/02 , C07C309/65 , C07C309/66 , C07C309/73 , C07C313/00 , C07C315/04 , C07C317/32 , C07C319/20 , C07C323/47 , C07C323/52 , C07C323/62 , C07C325/00 , C07C327/22 , C07C327/28 , C07C327/40 , C07C327/42 , C07C333/00 , C07C333/08 , C07D207/40 , C07D207/404 , C07D207/44 , C07D207/448 , C07D207/452 , C07D209/48 , C07D213/63 , C07D213/79 , C07D213/89 , C07D239/30 , C07D261/18 , C07D277/56 , C07D285/06 , C07D295/08 , C07D295/088 , C07D295/22 , C07D303/12 , C07D303/22 , C07D307/12 , C07D307/68 , C07D309/28 , C07D327/06 , C07D333/38 , C07C121/66
CPC分类号： C07D207/404 , A01N25/32 , C07D207/452 , C07D209/48 , C07D213/63 , C07D213/79 , C07D239/30 , C07D261/18 , C07D277/56 , C07D285/06 , C07D295/088 , C07D303/12 , C07D307/68 , C07D309/28 , C07D327/06 , C07D333/38
摘要： The invention relates to novel oxime ethers of the formula I ##STR1## wherein R.sub.1 is hydrogen, halogen, lower alkyl, lower haloalkyl, lower alkoxy, lower haloalkoxy, lower alkylthio, lower haloalkylthio, lower alkylsulfinyl, lower alkylsulfonyl, lower haloalkylsulfinyl, lower haloalkylsulfonyl or nitro, each of R.sub.2 and R.sub.3 is hydrogen, halogen, lower alkyl, lower alkoxy or lower haloalkoxy, and Q is an unsubstituted or substituted lower alkyl, lower alkenyl, lower alkynyl or cycloalkyl group, a lower alkanoyl radical, an aliphatic, cycloaliphatic, aromatic or heterocyclic acyl radical which may be substituted or unsubstituted, a carbonyl or thiocarbonyl radical, an aryl or aralkyl radical, an acylimidomethyl radical, a phthalimidomethyl radical or a heterocyclic radical.These compounds are able to act as antidotes or safeners for protecting cultivated plants from the phytotoxic action of aggressive herbicides. Preferred crops are sorghum, cereals, maize and rice, and herbicides are chiefly chloroacetanilides and thiocarbamates.
摘要翻译：本发明涉及式Ⅰ的肟醚（Ⅰ），其中R1是氢，卤素，低级烷基，低级卤代烷基，低级烷氧基，低级卤代烷氧基，低级烷硫基，低级卤代烷硫基，低级烷基亚磺酰基，低级烷基磺酰基，低级卤代烷基亚硫酰基，低级卤代烷基磺酰基或硝基，R2和R3各自为氢，卤素，低级烷基，低级烷氧基或低级卤代烷氧基，Q为未取代或取代的低级烷基，低级烯基，低级炔基或环烷基，低级烷酰基，可以被取代或未取代的脂族，脂环族，芳族或杂环酰基，羰基或硫代羰基，芳基或芳烷基，酰亚胺基甲基，苯二甲酰亚氨基甲基或杂环基。这些化合物能够用作解毒剂或安全剂，以保护栽培植物免受侵蚀性除草剂的植物毒性作用。优选的作物是高粱，谷物，玉米和大米，除草剂主要是氯乙酰苯胺和硫代氨基甲酸盐。

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