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1. 发明授权

US5082527A Nitrogen-containing polymeric compounds 失效
标题翻译：含氮的聚合物
公开(公告)号：US5082527A
公开(公告)日：1992-01-21
申请号：US323457
申请日：1989-03-14
申请人： Henning Bachem , Georg Schroder , Carlhans Suling , Jurgen Reiners , Janos Muszik , Dieter Arlt , Manfred Jautelat , Wolf-Dieter Schroer
发明人： Henning Bachem , Georg Schroder , Carlhans Suling , Jurgen Reiners , Janos Muszik , Dieter Arlt , Manfred Jautelat , Wolf-Dieter Schroer
IPC分类号： C08G73/00 , C08G59/10 , C08G69/48 , C08G73/02 , D21H17/54 , D21H17/55
CPC分类号： C08G73/0253 , C08G69/48 , C08G73/022 , D21H17/54
摘要： Crosslinkable compounds obtainable by reaction of water-soluble mono- or polyamines with 2,3-epoxypropyl sulphonates or 2-hydroxypropyl 1,3-bis-sulphonates or their mixtures with up to 15 mol % of an epihalogenohydrin or dihalogenohydrin are used for imparting wet strength to paper.
摘要翻译：可通过水溶性单胺或多胺与2,3-环氧丙基磺酸盐或2-羟丙基1,3-双磺酸盐或其与至多15mol％表卤代醇或二卤代醇的混合物的反应获得的可交联化合物用于赋予湿力量到纸。

2. 发明授权

US5093470A Nitrogen-containing polymeric compounds 失效
标题翻译：含氮的聚合物
公开(公告)号：US5093470A
公开(公告)日：1992-03-03
申请号：US745043
申请日：1991-08-14
申请人： Henning Bachem , Georg Schroder , Carlhans Suling , Jurgen Reiners , Janos Muszik , Dieter Arlt , Manfred Jautelat , Wolf-Dieter Schroer
发明人： Henning Bachem , Georg Schroder , Carlhans Suling , Jurgen Reiners , Janos Muszik , Dieter Arlt , Manfred Jautelat , Wolf-Dieter Schroer
IPC分类号： C08G73/00 , C08G59/10 , C08G69/48 , C08G73/02 , D21H17/54 , D21H17/55
CPC分类号： C08G73/0253 , C08G69/48 , C08G73/022 , D21H17/54
摘要： Crosslinkable compounds obtainable by reaction of water-soluble mono- or polyamines with 2,3-epoxypropyl sulphonates or 2-hydroxypropyl 1,3-bis-sulphonates or their mixtures with up to 15 mol % of an epihalogenohydrin or diyhalogenohydrin are used for imparting wet strength to paper.

3. 发明授权

US4992577A Preparation of 3-vinyl-substituted 2,2-dimethylcyclopropane-1-carboxylic acids and esters and intermediates therefor 失效
标题翻译：制备3-乙烯基取代的2,2-二甲基环丙烷-1-羧酸及其酯及其中间体
公开(公告)号：US4992577A
公开(公告)日：1991-02-12
申请号：US355578
申请日：1989-05-22
申请人： Reinhard Lantzsch , Dieter Arlt , Manfred Jautelat
发明人： Reinhard Lantzsch , Dieter Arlt , Manfred Jautelat
IPC分类号： C07C45/63 , C07C45/72 , C07C49/227 , C07C49/235 , C07C51/00
CPC分类号： C07C45/72 , C07C45/63 , C07C49/227 , C07C49/235 , C07C51/00
摘要： A process for preparing a compound of the formula ##STR1## in which Y is halogen, alkyl or cycloalkyl optionally substituted by halogen or C.sub.1-4 -alkoxy, alkenyl optionally substituted by halogen, aryl, heteroaryl or alkoxycarbonyl,X is hydrogen, halogen or optionally halogen-substituted alkyl, orX and Y, together with the adjacent C atom, form a saturated cycloalkphatic ring having up to 6 C atoms, andR is hydrogen or C.sub.1 -C.sub.4 -alkyl, comprising reacting an aldehyde of the formula ##STR2## with 2-methylbutan-3-one of the formula ##STR3## in the presence of a hydrohalic acid thereby to form a 4,4-dimethyl-3-halogeno-1-hexen-5-one of the formula ##STR4## in which Hal is halogen, halogenating said compound to produce a compound of the formula ##STR5## and reacting said compound with a base of the formulaR--OM (VI)in whichM is one equivalent of an alkali or alkaline earth metal ion.Compounds IV and V are new. By suitable conditions the trans isomer is selectively produced.
摘要翻译：制备式（I）化合物的方法，其中Y为卤素，任选被卤素或C 1-4 - 烷氧基取代的烷基或环烷基，任选被卤素，芳基，杂芳基或烷氧基羰基取代的链烯基，X为氢，卤素或任选的卤素取代的烷基，或X和Y与相邻的C原子一起形成具有至多6个C原子的饱和环烷基环，R是氢或C 1 -C 4烷基，包括使式（II）化合物与式（III）的2-甲基丁-3-酮在氢卤酸存在下反应，从而形成4,4-二甲基-3-卤代-1-己烯-5 其中Hal是卤素的式（Ⅳ）化合物，卤化所述化合物以制备下式化合物（Ⅴ），并使所述化合物与式R-OM（Ⅵ）的碱反应在其中M为1当量碱金属或碱土金属离子。化合物IV和V是新的。通过合适的条件选择性地制备反式异构体。

4. 发明授权

US4826865A Novel azolyl-aroxymethyl-dimethylpentinol fungicides 失效
标题翻译：新型唑基 - 羟基甲基 - 二甲基辛醇杀菌剂
公开(公告)号：US4826865A
公开(公告)日：1989-05-02
申请号：US175467
申请日：1988-03-30
申请人： Gerhard Jager , Manfred Jautelat , Dieter Arlt , Paul Reinecke , Wilhelm Brandes , Gerd Hanssler
发明人： Gerhard Jager , Manfred Jautelat , Dieter Arlt , Paul Reinecke , Wilhelm Brandes , Gerd Hanssler
IPC分类号： A01N43/50 , A01N43/64 , A01N43/653 , C07D233/60 , C07D249/08 , C07D521/00 , C07D233/54
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08
摘要： Novel fungicidally active compounds of the formula ##STR1## in which X is nitrogen or the CH group,Y is hydrogen, bromine or iodine,Z is oxygen, sulphur, the --SO-- group or the --SO.sub.2 -- group, andAr is optionally substituted aryl,or physiologically tolerated addition products thereof with acids or metal salts.
摘要翻译：新型杀真菌活性化合物，其中X是氮或CH基，Y是氢，溴或碘，Z是氧，硫，-SO-基或-SO 2 - 基，Ar是任选的取代的芳基或其与酸或金属盐的生理上耐受的加成产物。

5. 发明授权

US4460793A Preparation of monochloromethyl ketones 失效
标题翻译：单氯甲基酮的制备
公开(公告)号：US4460793A
公开(公告)日：1984-07-17
申请号：US329959
申请日：1981-12-11
申请人： Manfred Jautelat , Dieter Arlt , Gerhard Jager
发明人： Manfred Jautelat , Dieter Arlt , Gerhard Jager
IPC分类号： C07C17/25 , C07C17/26 , C07C41/00 , C07C43/225 , C07C45/00 , C07C45/51 , C07C49/16 , C07C49/175 , C07C49/223 , C07C49/227 , C07C49/255 , C07C49/327 , C07C67/00 , C07C69/757 , C07C45/42
CPC分类号： C07C49/327 , C07C17/25 , C07C17/269 , C07C43/225 , C07C45/513 , C07C49/16 , C07C49/223 , C07C49/227 , C07C49/255
摘要： A process for the production of a monochloromethyl ketone of the formula ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 each independently is a hydrogen atom or an optionally substituted alkyl, alkenyl, alkinyl or aryl radical, orR.sup.1 and R.sup.2 together with the carbon atom to which they are attached form an optionally substituted carbocyclic ring,comprising reacting a 1,1-dichloroalkene of the formula ##STR2## with a phenolate of the formula ##STR3## in which R.sup.4 each independently is a halogen atom, a nitro group, or an optionally substituted alkyl, alkoxy or aryl radical,n is 0, 1, 2 or 3, andM is one equivalent of an alkali metal ion or alkaline earth metal ion,thereby to obtain a phenyl ether intermediate, and then subjecting the phenyl ether intermediate to an acid hydrolysis. The products are useful as intermediates in the synthesis of fungicides.
摘要翻译：制备式“IMAGE”的单氯甲基酮的方法，其中R 1，R 2和R 3各自独立地为氢原子或任选取代的烷基，烯基，炔基或芳基，或R 1和R 2与碳原子一起它们所连接的化合物形成任选取代的碳环，包括使式IMAMA的1,1-二氯链烯与式（Ⅰa）的酚盐反应，其中R 4各自独立地为卤原子，硝基或任选取代的烷基，烷氧基或芳基，n为0,1,2或3，M为1当量碱金属离子或碱土金属离子，从而得到苯基醚中间体，然后使苯基醚中间体进行酸水解。该产品可用作合成杀真菌剂的中间体。

6. 发明授权

US4358598A 2-(2,2-Dimethyl-3-buten-1-yl)-2-oxazolines 失效
标题翻译： 2-（2,2-二甲基-3-丁烯-1-基）-2-恶唑啉
公开(公告)号：US4358598A
公开(公告)日：1982-11-09
申请号：US212051
申请日：1980-12-01
申请人： Manfred Jautelat , Dieter Arlt
发明人： Manfred Jautelat , Dieter Arlt
IPC分类号： C07D263/04 , C07D263/12 , C07D263/10
CPC分类号： C07D263/04 , C07D263/12
摘要： A process comprising reacting a 2-methyloxazoline of the formula ##STR1## in which R.sup.1, R.sup.2, R.sup.3 and R.sup.4 each independently is hydrogen, alkyl, aralkyl, optionally substituted aryl or two of them together form a ring,with a 3-methyl-2-buten-1-yl derivative of the formula ##STR2## in which X is halide, sulphonate or phosphate, thereby to produce a 2-methyl-3-(3-methyl-2-butenyl)-2-oxazolinium salt of the formula ##STR3## reacting the oxazolinium salt with an alcoholate of the formulaR.sup.5 --O--M (V)in whichM is one equivalent of an alkali metal or alkaline earth metal cation,to produce an oxazolidine of the formula ##STR4## pyrolyzing the oxazolidine to produce a 2-methylene-3-(3-methyl-2-butenyl)-oxazolidine of the formula ##STR5## and heating the 2-methylene-3-(3-methyl-2-butenyl)-oxazolidine to produce a 2-(2,2-dimethyl-3-buten-1-yl)-2-oxazoline of the formula ##STR6## The compounds (II), (III) and (IV) are new.
摘要翻译：一种方法包括使式（VI）的2-甲基恶唑啉（其中R 1，R 2，R 3和R 4各自独立地为氢，烷基，芳烷基，任选取代的芳基或其中的两个一起形成环）与3 （VII）的2-甲基-2-丁烯-1-基衍生物，其中X是卤化物，磺酸盐或磷酸盐，从而产生2-甲基-3-（3-甲基-2-丁烯基） - 式（Ⅳ）的2-恶唑啉盐使恶唑啉盐与式为R5-OM（Ⅴ）的醇化物反应，其中M为1当量碱金属或碱土金属阳离子，得到（III）将式（III）热解得到式（II）的2-亚甲基-3-（3-甲基-2-丁烯基） - 恶唑烷并加热2-亚甲基-3-（ 3-甲基-2-丁烯基） - 恶唑烷以制备下式的2-（2,2-二甲基-3-丁烯-1-基）-2-恶唑啉（I）化合物（II），（ III）和（IV）是新的。

7. 发明授权

US4267381A Preparation of side-chain fluorinated 3,3-dimethyl-butan-2-one 失效
标题翻译：侧链氟化3,3-二甲基 - 丁-2-酮的制备
公开(公告)号：US4267381A
公开(公告)日：1981-05-12
申请号：US77447
申请日：1979-09-20
申请人： Manfred Jautelat , Jorg Stetter , Dieter Arlt , Wolfgang Kramer
发明人： Manfred Jautelat , Jorg Stetter , Dieter Arlt , Wolfgang Kramer
IPC分类号： C07C45/63 , C07C45/64 , C07C45/67 , C07C45/71 , C07C47/14 , C07C49/16 , C07C49/167 , C07C49/255 , C07D521/00
CPC分类号： C07D231/12 , C07C45/63 , C07C45/64 , C07C45/673 , C07C45/71 , C07C49/16 , C07C49/255 , C07D233/56 , C07D249/08
摘要： A fluorine derivative of 3,3-dimethyl-butan-2-one, of the formula ##STR1## in which X is hydrogen or fluorine,is produced by reacting a metal fluoride in a diluent and at elevated temperature with a sulphonic acid ester of the formula ##STR2## in which R is optionally substituted alkyl or optionally substituted aryl, andY is hydrogen or O--SO.sub.2 --R.The product is useful in the synthesis of fungicides.
摘要翻译：通过使稀释剂中的金属氟化物与升高的温度下的金属氟化物与下列化合物的磺酸酯反应来制备其中X为氢或氟的式“IMAGE”的3,3-二甲基 - 丁-2-酮的氟衍生物其中R是任选取代的烷基或任选取代的芳基，Y是氢或O-SO 2 -R的式“IMAGE”。该产品可用于合成杀真菌剂。

8. 发明授权

US4440955A Process for the preparation of 2,2-dimethyl-3-vinyl-cyclopropanecarboxylic acids and esters 失效
标题翻译： 2,2-二甲基-3-乙烯基 - 环丙烷羧酸和酯的制备方法
公开(公告)号：US4440955A
公开(公告)日：1984-04-03
申请号：US443840
申请日：1982-11-22
申请人： Manfred Jautelat , Dieter Arlt
发明人： Manfred Jautelat , Dieter Arlt
IPC分类号： C07C49/16 , B01J23/72 , B01J23/74 , B01J27/02 , B01J27/08 , B01J27/24 , B01J31/02 , B01J31/04 , B01J31/22 , C07C43/225 , C07C45/51 , C07C45/69 , C07C51/00 , C07C61/40 , C07C69/747
CPC分类号： C07C45/69 , C07C43/225 , C07C45/513 , C07C51/00
摘要： A process for the production of 2,2-dimethyl-3-vinyl-cyclopropanecarboxylic acid derivative of the formula ##STR1## in which R.sup.1 is a hydrogen atom, an alkyl group or a radical of an alcohol which can be used in pyrethroids, andX.sup.1 and X.sup.2 each independently is a halogen atom or a fluorine-substituted alkyl radical,comprising adding (a) a polyhalogenoalkene of the formula ##STR2## in which X.sup.3 and X.sup.4 each independently is a halogen atom,to 1-chloro-3,3-dimethyl-pent-4-en-2-one of the formula ##STR3## in the presence of a catalyst which yields free radicals, or in the presence of a metal salt of the VIII main group or of the sub-group IVa, VIIa or Ib of the periodic system, thereby to obtain a mixture of compounds of the formula ##STR4## (b) reacting either or both of such compounds with a base of the formula(R.sup.1 --O.sup..crclbar.).sub.n M.sup.n+in whichM is an alkali metal or alkaline earth metal, andn is 1 or 2.The end products are known insecticides and intermediates therefor, while the intermediates produced by (a) are novel compounds.
摘要翻译：制备式“IMAGE”的2,2-二甲基-3-乙烯基 - 环丙烷羧酸衍生物的方法，其中R 1是可用于拟除虫菊酯的氢原子，烷基或醇基，以及 X 1和X 2各自独立地为卤素原子或氟取代的烷基，其包括将（X3）和X4各自独立地为卤素原子的式（a）的多卤代烯烃加入到1-氯-3,3 在产生自由基的催化剂的存在下，或在VIII主族或亚组IVa的金属盐存在下，式“IMAGE”的2-二甲基 - 戊-4-烯-2-酮， VIIa或Ib化合物，从而得到下式化合物的混合物：（b）使这些化合物中的一种或两者与式（R1-O（ - ））nMn +的碱反应，其中M为碱金属或碱土金属，n为1或2.最终产物为已知的杀虫剂及其中间体，而中间体（a）产生的是新化合物。

9. 发明授权

US4399309A Preparation of 1-aryloxy-methyl ketones 失效
标题翻译： 1-芳氧基 - 甲基酮的制备
公开(公告)号：US4399309A
公开(公告)日：1983-08-16
申请号：US335942
申请日：1981-12-30
申请人： Manfred Jautelat , Jorg Stetter , Dieter Arlt
发明人： Manfred Jautelat , Jorg Stetter , Dieter Arlt
IPC分类号： C07C49/175 , C07C43/225 , C07C45/00 , C07C45/42 , C07C49/255 , C07C49/35 , C07C67/00 , C07C201/00 , C07C205/37 , C07C205/39 , C07C45/51
CPC分类号： C07C41/16 , C07C45/42
摘要： A process for the preparation of a 1-aryloxy-methyl ketone of the formula ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 each independently is hydrogen, optionally substituted alkyl, alkenyl, alkynyl or optionally substituted aryl, orR.sup.1 and R.sup.2 together are an alkylene chain,R.sup.4 each independently is halogen, alkyl, alkoxy, optionally substituted aryl or nitro, andn is 0, 1, 2 or 3,comprising hydrolyzing a 1-halogeno-2-aryloxy-1-alkene of the formula ##STR2## in which Hal is chlorine or bromine, under acidic conditions at a temperature from about 20.degree. to 150.degree. C. until it is about 95 to 100% complete, adding a base, and then bringing the reaction to completion under weakly alkaline conditions at about 20.degree. to 150.degree. C. Advantageously all stages of the reaction are effected in a single vessel at a temperature from about 40.degree. to 100.degree. C. and in the presence of an inert organic solvent, optionally in admixture with water as a solution or as a two-phase system, about 1 mol of a monobasic acid and 2 mols of alkali metal carbonate being employed per mol of the 1-halogeno-2-aryloxy-1-alkene. The end products are known intermediates for fungicides.
摘要翻译：制备式“IMAGE”的1-芳氧基甲基酮的方法，其中R 1，R 2和R 3各自独立地为氢，任选取代的烷基，烯基，炔基或任选取代的芳基，或者R 1和R 2一起是亚烷基链，R4各自独立地为卤素，烷基，烷氧基，任选取代的芳基或硝基，n为0,1,2或3，包括水解式IMAMA的1-卤代-2-芳氧基-1-烯烃，其中Hal为氯或溴，在酸性条件下，在约20℃至150℃的温度下，直到其完全达到约95-100％，加入碱，然后使反应在弱碱性条件下在约有利的是，反应的所有阶段在单一容器中在约40℃至100℃的温度下进行，并且在惰性有机溶剂的存在下，任选与水作为溶液的混合物或作为两相体系，约1摩尔一元酸每摩尔1-卤代-2-芳氧基-1-烯烃使用2摩尔碱金属碳酸盐。最终产品是已知的杀真菌剂中间体。

10. 发明授权

US4871484A Process for the preparation of 2,2-bis-chloro-methylalkanecarboxylic acid chlorides 失效
标题翻译：制备2,2-双氯 - 甲基链烷羧酸氯化物的方法
公开(公告)号：US4871484A
公开(公告)日：1989-10-03
申请号：US50993
申请日：1987-05-15
申请人： Helmut Fiege , Manfred Jautelat , Dieter Arlt
发明人： Helmut Fiege , Manfred Jautelat , Dieter Arlt
IPC分类号： C07C53/50 , C07C51/00 , C07C51/58 , C07C51/60 , C07C51/62 , C07C67/00
CPC分类号： C07C51/58
摘要： A process for the preparation of a 2,2-bis-chloro-methyl-alkanecarboxylic acid of the formula ##STR1## in which R is hydrogen, alkyl, cycloalkyl or optionally substituted phenyl,which comprises reacting an oxetane-3-carboxylic acid of the formula ##STR2## or a salt thereof, with an inorganic acid chloride at a temperature between 20.degree. C. and the boiling point of the reaction mixture. The products are known intermediates for fungicides and herbicides.
摘要翻译：一种制备式“IMAGE”的2,2-双氯 - 甲基 - 链烷羧酸的方法，其中R是氢，烷基，环烷基或任选取代的苯基，其中包括使氧杂环丁烷-3-羧酸式中的“IMAGE”或其盐与无机酰氯在20℃和反应混合物的沸点之间。该产品是用于杀真菌剂和除草剂的已知中间体。

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