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1. 发明授权

US5693718A Block copolymers having improved combinations of properties 失效
标题翻译：具有改进的性能组合的嵌段共聚物
公开(公告)号：US5693718A
公开(公告)日：1997-12-02
申请号：US553947
申请日：1995-11-06
申请人： Hendrik De Groot , Karel Hendrik Leffelaar , Jacqueline Margaretha Veurink , Jeroen Van Westrenen
发明人： Hendrik De Groot , Karel Hendrik Leffelaar , Jacqueline Margaretha Veurink , Jeroen Van Westrenen
IPC分类号： C08F297/04 , C08F297/08 , C08L53/00 , C08L53/02
CPC分类号： C08F297/04 , C08L53/02
摘要： Block copolymer compositions, comprising for a major part of linear triblock copolymers, comprising two terminal predominantly poly(monovinylaromatic) blocks having a real molecular weight in the range of from 5,000 to 25,000 and one predominantly poly(boutadiene) midblock, said triblock copolymer having a monovinylaromafic content in the range of from 10 to 55 wt %, an apparent total molecular weight in the range of from 15,000 to 300,000, and an amount of from 0 to 40 wt % of a diblock copolymer relative to the total block copolymer composition weight, containing a predominantly poly(monovinylaromatic) block and a predominantly poly(boutadiene) block similar to those of the triblock copolymer component; said block copolymer composition having a free poly(vinylaromatic) content of at most 7 wt %, and shaped articles derived from said block copolymer composition.
摘要翻译：嵌段共聚物组合物，其包含主要部分的线性三嵌段共聚物，其包含两个主要为聚合（单乙烯基芳族）嵌段，其实际分子量为5,000至25,000，一个主要为聚（丁二烯）中间嵌段，所述三嵌段共聚物具有相对于总嵌段共聚物组合物重量，二嵌段共聚物的单乙酰基木香糖含量范围为10-55重量％，表观总分子量为15,000至300,000，量为0至40重量％含有主要为聚（单乙烯基芳族）嵌段和主要为聚（丁二烯）嵌段的嵌段共聚物组分; 所述嵌段共聚物组合物的游离聚（乙烯基芳族化合物）含量至多为7重量％，以及衍生自所述嵌段共聚物组合物的成型制品。

2. 发明申请

US20090247689A1 ELASTIC FILM GRADE THERMOPLASTIC POLYMER COMPOSITIONS HAVING IMPROVED ELASTIC PERFORMANCE 审中-公开
标题翻译：具有改进的弹性性能的弹性薄膜级热塑性聚合物组合物
公开(公告)号：US20090247689A1
公开(公告)日：2009-10-01
申请号：US12441791
申请日：2007-09-19
申请人： Holger Wickel , Hendrik De Groot , Markus Beitzel
发明人： Holger Wickel , Hendrik De Groot , Markus Beitzel
IPC分类号： C08L53/02
CPC分类号： C08L53/025 , C08K3/013 , C08K5/0016 , C08L25/04 , C08L2666/04
摘要： The present invention provides an improved block copolymer composition for extruding films having excellent stress relaxation and increased retained tension or load at elevated temperatures, as well as a film cast from this composition. The composition is comprised of (a) 100 parts by weight of a mixture of two or more hydrogenated styrenic block copolymers (HSBC's) having at least two polystyrene end-blocks and a mid-block of a polymerized diene wherein at least 80 mol % of the residual unsaturation has been hydrogenated, wherein HSBC #1 has an apparent number average molecular weight between 35,000 and 90,000 and a polystyrene content between 15 and 40 percent by weight, wherein HSBC #2 has an apparent number average molecular weight between 95,000 and 150,000 and a polystyrene content between 15 and 40 percent by weight, wherein the ration w/w of HSBC #1 versus HSBC #2 is in the range of from 8:1 to 1:8, (b) from 10 to 50 parts by weight per 100 parts by weight of polymer (phr) of a a medium molecular weight polystyrene (2) or a mixture of a low molecular weight polystyrene (1) and a medium molecular weight polystyrene (2), wherein PS (1) has a molecular weight in the range of 500 to 4,000 and PS(2) has a molecular weight in the range of 20,000 to 150,000 and wherein PS(1) and PS(2) are used in a weight ratio of 1:5 to 5:1, (c) from 3 to 50 phr of a filler, and (d) from 30 to 70 phr of a softening agent.
摘要翻译：本发明提供了一种用于挤出膜的改进的嵌段共聚物组合物，其具有优异的应力松弛和在升高的温度下增加的保持张力或载荷，以及由该组合物制成的薄膜。该组合物包含（a）100重量份的具有至少两个聚苯乙烯端嵌段的两个或更多个氢化苯乙烯嵌段共聚物（HSBC）的混合物和聚合二烯的中间嵌段，其中至少80mol％残余不饱和度被氢化，其中HSBC＃1的表观数均分子量在35,000和90,000之间，聚苯乙烯含量在15-40重量％之间，其中HSBC＃2的表观数均分子量在95,000和150,000之间，聚苯乙烯含量在15-40重量％之间，其中HSBC＃1与HSBC＃2的配比w / w在8:1至1:8的范围内，（b）10至50重量份/ 100重量份的中等分子量聚苯乙烯（2）或低分子量聚苯乙烯（1）和中等分子量聚苯乙烯（2）的混合物的聚合物（phr），其中PS（1）的分子量为 500至4000的范围和PS（2）具有分子重量在20,000至150,000范围内，并且其中PS（1）和PS（2）以1:5至5:1的重量比，（c）3至50phr的填料使用，和（d） 30至70phr的软化剂。

3. 发明授权

US06846535B2 Kink resistant medical tubes 有权
标题翻译：耐扭结医用管
公开(公告)号：US06846535B2
公开(公告)日：2005-01-25
申请号：US10130371
申请日：2001-06-07
申请人： Hendrik De Groot , Freddy Maria Armand Vervoort
发明人： Hendrik De Groot , Freddy Maria Armand Vervoort
IPC分类号： A61L29/04 , A61L29/14 , C08L23/10 , C08L53/02
CPC分类号： C08L53/025 , A61L29/049 , C08L23/10 , C08L53/02 , Y10T428/139 , C08L2666/24 , C08L2666/04 , C08L2666/02
摘要： Kink resistant medical tube is manufactured from a polymer composition comprising: a) a random polypropylene copolymer; and b) a block copolymer comprising at least two vinyl aromatic polymer blocks and at least one hydrogenated conjugated diene polymer block, wherein the hydrogenated conjugated diene polymer block has a vinyl content before hydrogenation of at least 50%.
摘要翻译：抗弯绞医用管由聚合物组合物制成，该聚合物组合物包含：a）无规聚丙烯共聚物; 和b）包含至少两个乙烯基芳族聚合物嵌段和至少一种氢化共轭二烯聚合物嵌段的嵌段共聚物，其中所述氢化共轭二烯聚合物嵌段在氢化之前具有至少50％的乙烯基含量。

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