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    • 5. 发明授权
      US4187100A 4,5-Dichloro-imidazole-1-carboxylic acid aryl esters and their use as herbicides 失效
    • 4,5-Dichloro-imidazole-1-carboxylic acid aryl esters and their use as herbicides
    • 4,5-二氯 - 咪唑-1-羧酸芳基酯及其作为除草剂的用途
    • US4187100A
    • 1980-02-05
    • US948185
    • 1978-10-02
    • Klaus Sasse , Gunther Beck , Ludwig Eue , Robert R. Schmidt
    • Klaus Sasse , Gunther Beck , Ludwig Eue , Robert R. Schmidt
    • A01N47/22 , C07D233/68 , C07D233/90 , C07D487/14 , A01N9/22
    • C07D487/14 , A01N47/22 , C07D233/68 , C07D233/90
    • A 4,5-dichloro-imidazole-1-carboxylic acid aryl ester of the formula ##STR1## in which X represents trifluoromethyl, cyano or a group ##STR2## in which R.sup.1 represents a saturated or unsaturated aliphatic radical, which can be carrying one or more substituents selected from halogen, alkoxy with 1 to 6 carbon atoms and alkylmercapto with 1 to 6 carbon atoms, R.sup.2 represents hydrogen, alkyl with 1 to 8 carbon atoms, alkenyl with up to 8 carbon atoms or the formyl group, R.sup.3 represents alkyl with 1 to 8 carbon atoms or alkenyl or alkynyl each with up to 8 carbon atoms, it being possible for each of these alkyl, alkenyl and alkynyl radicals to carry one or more substituents selected from alkoxy with 1 to 4 carbon atoms, alkylmercapto with 1 to 4 carbon atoms, phenyl (which may optionally carry one or more substituents selected from halogen, alkyl with 1 to 4 carbon atoms, trifluoromethyl and alkoxy with 1 to 4 carbon atoms), furyl or thienyl, or represents cycloalkyl with 5 to 7 carbon atoms in the ring which is optionally substituted by alkyl with 1 to 6 carbon atoms, or represents phenyl which may optionally carry one or more substituents selected from halogen, alkyl with 1 to 4 carbon atoms, alkoxy with 1 to 4 carbon atoms, alkylmercapto with 1 to 4 carbon atoms and trifluoromethyl, or R.sup.2 and R.sup.3 conjointly with the adjoining nitrogen atom form an optionally substituted 5-membered to 7-membered heterocyclic radical in which 1 to 3 ring members may be selected from oxygen, sulfur and nitrogen, Y represents halogen, alkyl with 1 to 6 carbon atoms, trifluoromethyl, alkoxy with 1 to 6 carbon atoms, nitro, cyano or a ##STR3## group, in which R.sup.4 represents alkyl with 1 to 6 carbon atoms and n represents 0, 1, 2, 3, 4 or 5 which possesses plant protection properties especially herbicidal and plant growth regulant properties.
    • 其中X表示三氟甲基，氰基或其中R 1表示饱和或不饱和脂肪族基团的基团的4,5-二氯 - 咪唑-1-羧酸芳基酯，其中X表示三氟甲基，氰基或基团， 携带一个或多个选自卤素，具有1至6个碳原子的烷氧基和1至6个碳原子的烷基巯基的取代基，R 2表示氢，具有1至8个碳原子的烷基，具有至多8个碳原子的烯基或甲酰基， R3表示具有1至8个碳原子的烷基或各自具有至多8个碳原子的烯基或炔基，这些烷基，烯基和炔基中的每一个可以携带一个或多个选自具有1至4个碳原子的烷氧基的取代基， 具有1至4个碳原子的烷基巯基，苯基（其可任选地携带一个或多个选自卤素，具有1至4个碳原子的烷基，三氟甲基和具有1至4个碳原子的烷氧基）的取代基，呋喃基或噻吩基，或代表具有5个 至7个碳原子 在任选被具有1至6个碳原子的烷基取代的环中，或表示可任选地携带一个或多个选自卤素，具有1至4个碳原子的烷基，具有1至4个碳原子的烷氧基，具有1个碳原子的烷基巯基， 至4个碳原子和三氟甲基，或R2和R3与相邻的氮原子结合形成任选取代的5元至7元杂环基，其中1至3个环成员可以选自氧，硫和氮，Y代表卤素 ，具有1至6个碳原子的烷基，三氟甲基，具有1至6个碳原子的烷氧基，硝基，氰基或者IMAGE基团，其中R 4表示具有1至6个碳原子的烷基，n表示0,1,2,3 ，4或5，其具有植物保护性，特别是除草和植物生长调节性质。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 7. 发明授权
      US4268681A Novel 4,5-dichloro-imidazole derivatives and their use as plant protection agents 失效
    • Novel 4,5-dichloro-imidazole derivatives and their use as plant protection agents
    • 新型4,5-二氯 - 咪唑衍生物及其作为植物保护剂的用途
    • US4268681A
    • 1981-05-19
    • US34712
    • 1979-04-30
    • Klaus Sasse , Gunther Beck , Ludwig Eue , Robert R. Schmidt
    • Klaus Sasse , Gunther Beck , Ludwig Eue , Robert R. Schmidt
    • A01N43/50 , A01P13/00 , C07D233/68 , C07D233/90 , C07D487/14 , A01N9/22
    • C07D487/14 , A01N43/50 , C07D233/68 , C07D233/90
    • A 4,5-dichloro-imidazole derivative of the formula ##STR1## in which X represents a ##STR2## in which R.sup.1 represents hydrogen, alkyl with 1 to 8 carbon atoms, alkenyl with up to 8 carbon atoms or the formyl group,R.sup.3 represents cycloalkyl with 5 to 7 carbon atoms in the ring which is optionally substituted by alkyl with 1 to 6 carbon atoms or represents phenyl which may optionally carry one or more substituents selected from halogen, alkyl with 1 to 4 carbon atoms, alkoxy with 1 to 4 carbon atoms, alkylmercapto with 1 to 4 carbon atoms and trifluoromethyl, andR represents alkyl with 1 to 12 carbon atoms or alkenyl or alkynyl each with up to 12 carbon atoms, it being possible for each of these alkyl, alkenyl and alkynyl radicals to carry one or more substituents, or represents cycloalkyl with 5 to 7 carbon atoms in the ring or represents a phenyl radical which is at least disubstituted;and the use of such novel 4,5-dichloro-imidazole derivatives as plant growth protection agents especially as a herbicide, plant growth regulant, insecticide or acaricide.
    • 式（I）的4,5-二氯 - 咪唑衍生物，其中X表示其中R 1表示氢，具有1至8个碳原子的烷基，具有至多8个碳原子的烯基或甲酰基 基团，R 3表示环中具有5至7个碳原子的环烷基，其任选被具有1至6个碳原子的烷基取代，或表示可任选地带有一个或多个选自卤素，具有1至4个碳原子的烷基，烷氧基， 具有1至4个碳原子，具有1至4个碳原子的烷基巯基和三氟甲基，R表示具有1至12个碳原子的烷基或各自具有12个碳原子的烯基或炔基，这些烷基，烯基和 炔基可携带一个或多个取代基，或表示环中具有5至7个碳原子的环烷基或代表至少二取代的苯基; 以及这些新型的4,5-二氯 - 咪唑衍生物作为植物生长保护剂，特别是作为除草剂，植物生长调节剂，杀虫剂或杀螨剂的用途。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 9. 发明授权
      US4187101A 1-Acyloxymethyl-4,5-dichloro-imidazole derivatives and their use as herbicides 失效
    • 1-Acyloxymethyl-4,5-dichloro-imidazole derivatives and their use as herbicides
    • 1-酰氧基甲基-4,5-二氯 - 咪唑衍生物及其作为除草剂的用途
    • US4187101A
    • 1980-02-05
    • US946252
    • 1978-09-27
    • Florin Seng , Klaus Sasse , Gunther Beck , Ludwig Eue , Robert R. Schmidt
    • Florin Seng , Klaus Sasse , Gunther Beck , Ludwig Eue , Robert R. Schmidt
    • A01N43/50 , C07D233/68 , C07D233/90 , C07D487/14 , A01N9/22
    • C07D487/14 , A01N43/50 , C07D233/68 , C07D233/90
    • 1-Acyloxymethyl-4,5-dichloro-imidazole-2-carboxylic acid derivatives of the formula ##STR1## in which X represents trifluoromethyl, cyano or a group ##STR2## in which R.sup.1 represents a saturated or unsaturated aliphatic radical, which can be carrying one or more substituents selected from halogen, alkoxy with 1 to 6 carbon atoms and alkylmercapto with 1 to 6 carbon atoms, R.sup.2 represents hydrogen, alkyl with 1 to 8 carbon atoms, alkenyl with up to 8 carbon atoms or the formyl group, R.sup.3 represents alkyl with 1 to 8 carbon atoms or alkenyl or alkynyl each with up to 8 carbon atoms, it being possible for each of these alkyl, alkenyl and alkynyl radicals to carry one or more substituents selected from alkoxy with 1 to 4 carbon atoms, alkylmercapto with 1 to 4 carbon atoms, phenyl (which may optionally carry one or more substituents selected from halogen, alkyl with 1 to 4 carbon atoms, trifluoromethyl and alkoxy with 1 to 4 carbon atoms), furyl or thienyl, or represents cycloalkyl with 5 to 7 carbon atoms in the ring which is optionally substituted by alkyl with 1 to 6 carbon atoms, or represents phenyl which may optionally carry one or more substituents selected from halogen, alkyl with 1 to 4 carbon atoms, alkoxy with 1 to 4 carbon atoms, alkylmercapto with 1 to 4 carbon atoms and trifluoromethyl or, R.sup.2 and R.sup.3 conjointly with the adjoining nitrogen atoms form an optionally substituted 5-membered to 7-membered heterocyclic ring in which 1 to 3 ring members may be selected from oxygen, sulfur and nitrogen, and R represents alkyl with 1 to 6 carbon atoms, plant protective compositions containing the same as active ingredients together with diluents, and methods for protecting plants by applying such novel 1-acyloxymethyl-4,5-dichloro-imidazole-2-carboxylic acid derivatives to a plant or its habitat.
    • 其中X表示三氟甲基，氰基或其中R 1表示饱和或不饱和脂肪族基团的基团，其中X表示三氟甲基，氰基或者其中R 1表示饱和或不饱和脂肪族基团的基团的1-芳氧基甲基-4,5-二氯 - 咪唑-2-羧酸衍生物， 其可以携带一个或多个选自卤素，具有1至6个碳原子的烷氧基和具有1至6个碳原子的烷基巯基的取代基，R 2表示氢，具有1至8个碳原子的烷基，具有至多8个碳原子的烯基或甲酰基 基团，R 3表示具有1至8个碳原子的烷基或各自具有至多8个碳原子的烯基或炔基，这些烷基，烯基和炔基中的每一个可以携带一个或多个选自具有1至4个碳原子的烷氧基的取代基 原子，具有1至4个碳原子的烷基巯基，苯基（其可任选地携带一个或多个选自卤素，具有1至4个碳原子的烷基，三氟甲基和具有1至4个碳原子的烷氧基）的取代基，呋喃基或噻吩基，或表示环烷基 与5到 任选被具有1至6个碳原子的烷基取代的环中的7个碳原子，或表示可以任选携带一个或多个选自卤素，具有1至4个碳原子的烷基，具有1至4个碳原子的烷氧基的取代基的苯基， 具有1至4个碳原子的烷基巯基和三氟甲基，或者R 2和R 3与相邻的氮原子一起形成任选取代的5元至7元杂环，其中1至3个环成员可以选自氧，硫和氮， R表示具有1-6个碳原子的烷基，含有与活性成分一起含有稀释剂的植物保护组合物，以及通过应用这种新颖的1-酰氧基甲基-4,5-二氯 - 咪唑-2-羧酸衍生物保护植物的方法 到植物或其栖息地。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 10. 发明授权
      US4185991A 4,5-Dichloro-imidazole derivatives and their use as herbicides 失效
    • 4,5-Dichloro-imidazole derivatives and their use as herbicides
    • US4185991A
    • 1980-01-29
    • US945288
    • 1978-09-25
    • Klaus Sasse , Gunther Beck , Ludwig Eue , Robert R. Schmidt
    • Klaus Sasse , Gunther Beck , Ludwig Eue , Robert R. Schmidt
    • A01N43/50 , C07D233/68 , C07D233/90 , C07D487/14 , A01N9/22
    • C07D487/14 , A01N43/50 , C07D233/68 , C07D233/90
    • A 4,5-dichloro-imidazole derivative of the formula ##STR1## in which X represents trifluoromethyl, cyano or a ##STR2## or ##STR3## in which R.sup.1 represents a saturated or unsaturated aliphatic radical, which can be carrying one or more substituents selected from halogen, alkoxy with 1 to 6 carbon atoms and alkylmercapto with 1 to 6 carbon atoms,R.sup.2 represents hydrogen, alkyl with 1 to 8 carbon atoms, alkenyl with up to 8 carbon atoms or the formyl group,R.sup.3 represents hydrogen, alkyl with 1 to 8 carbon atoms or alkenyl or alkynyl each with up to 8 carbon atoms, it being possible for each of these alkyl, alkenyl and alkynyl radicals to carry one or more substituents selected from alkoxy with 1 to 4 carbon atoms, alkylmercapto with 1 to 4 carbon atoms, phenyl (which may optionally carry one or more substituents selected from halogen, alkyl with 1 to 4 carbon atoms, trifluoromethyl and alkoxy with 1 to 4 carbon atoms), furyl or thienyl, or represents cycloalkyl with 5 to 7 carbon atoms in the ring which is optionally substituted by alkyl with 1 to 6 carbon atoms, or represents phenyl which may optionally carry one or more substituents selected from halogen, alkyl with 1 to 4 carbon atoms, alkoxy with 1 to 4 carbon atoms, alkylmercapto with 1 to 4 carbon atoms and trifluoromethyl, orR.sup.2 and R.sup.3 conjointly with the adjoining nitrogen atom form an optionally substituted 5-membered to 7-membered heterocyclic ring in which 1 to 3 ring members may be selected from oxygen, sulphur and nitrogen, andR represents alkyl with 1 to 12 carbon atoms or alkenyl or alkynyl each with up to 12 carbon atoms, it being possible for each of these alkyl, alkenyl and alkynyl radicals to carry one or more substituents selected from halogen, alkoxy with 1 to 6 carbon atoms, alkylmercapto with 1 to 6 carbon atoms, cycloalkyl with 5 to 7 carbon atoms in the ring and phenyl (which itself optionally carries one or more substituents selected from alkyl with 1 to 6 carbon atoms, alkoxy with 1 to 6 carbon atoms, halogen and trifluoromethyl), or represents cycloalkyl with 5 to 7 carbon atoms in the ring or represents a phenyl radical which is at least disubstituted; and the use of such novel 4,5-dichloro-imidazole derivatives as plant protection agents especially as a herbicide, plant growth regulant, insecticide or acaricide.
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
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