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1. 发明授权

US4186012A Light sensitive color photographic material containing development inhibitor releasing coupler 失效
标题翻译：含有显影抑制剂释放成色剂的感光彩色照相材料
公开(公告)号：US4186012A
公开(公告)日：1980-01-29
申请号：US882631
申请日：1978-03-02
申请人： Heinrich Odenwalder , Walter Puschel , Robert J. Pollet , Erwin Ranz
发明人： Heinrich Odenwalder , Walter Puschel , Robert J. Pollet , Erwin Ranz
IPC分类号： G03C7/26 , C07D257/04 , G03C1/06 , G03C7/305 , G03C1/48 , G03C1/40 , G03C5/30
CPC分类号： C07D257/04 , G03C7/30511 , Y10S430/158
摘要： Non-diffusible thioether compounds capable of releasing, on reaction with color developer oxidation compounds, a diffusible silver halide development inhibitor without at the same time forming permanent dyes to any substantial extent are characterized by containing a group of the formula ##STR1## or its tautomeric form, wherein Z.sup.1 represents an electron attracting substituent and X represents an aliphatic, aromatic or heterocyclic group that if released together with the sulfur atom, forms a diffusible silver halide development inhibiting mercaptane.
摘要翻译：能够与着色显影剂氧化化合物反应释放扩散性卤化银显影抑制剂而不同时在任何实质上形成永久性染料的非扩散性硫醚化合物的特征在于含有下式的基团或其互变异构体形式，其中Z1表示吸电子取代基，X表示如果与硫原子一起释放的脂族，芳族或杂环基形成抑制硫化烷的扩散性卤化银显影剂。

2. 发明授权

US4046574A Color photographic material with homophthalimide thioether development inhibitor 失效
标题翻译：含有邻苯二甲酰亚胺衍生物抑制剂的彩色摄影材料
公开(公告)号：US4046574A
公开(公告)日：1977-09-06
申请号：US650676
申请日：1976-01-20
申请人： Heinrich Odenwalder , Erwin Ranz , Walter Puschel , Hans Vetter
发明人： Heinrich Odenwalder , Erwin Ranz , Walter Puschel , Hans Vetter
IPC分类号： G03C7/26 , G03C1/10 , G03C7/305 , G03C1/40 , G03C1/48 , G03C7/00
CPC分类号： G03C7/30511 , Y10S430/158
摘要： A color photographic material having a silver halide emulsion layer and containing a thioether compound which is reactable on chromogenic development thereby releasing a diffusible substance which inhibits the development of the silver halide.The thioether compound is a homophthalimide containing a removable mercapto group containing moiety in the 4-position and its nitrogen in the 2-position atom being a tertiary nitrogen.

3. 发明授权

US4301243A Photographic recording material 失效
标题翻译：摄影记录材料
公开(公告)号：US4301243A
公开(公告)日：1981-11-17
申请号：US103000
申请日：1979-12-12
申请人： Walter Puschel , Heinrich Odenwalder , Erwin Ranz
发明人： Walter Puschel , Heinrich Odenwalder , Erwin Ranz
IPC分类号： G03C7/00 , C07C45/00 , C07C46/06 , C07C50/02 , C07C67/00 , C07C69/734 , C07C233/09 , C07C233/31 , C07C235/48 , C07C235/60 , C07C253/00 , C07C255/41 , C07D207/44 , C07D207/448 , C07D207/452 , C07D311/22 , G03C1/06 , G03C7/392 , G03C1/40 , G03C1/10 , G03C1/48
CPC分类号： C07D207/448 , C07C46/06 , C07C50/02 , G03C7/39208 , Y10S430/158
摘要： Traces of free inhibitors for the development of silver halide which might be present as impurities of inhibitor releasing compounds or which might be prematurely released therefrom because of insufficient stability thereof during storage of the photographic material are scavenged by compounds which are capable of binding free inhibitors at pH values below 7 but to a much less extent at pH values higher than 9.
摘要翻译：用于开发可能作为抑制剂释放化合物的杂质存在或可能由于其在照相材料储存期间的稳定性不足而可能过早释放的卤化银的游离抑制剂痕迹由能够结合游离抑制剂的化合物清除 pH值低于7，但在pH值高于9的情况下，其程度要小得多。

4. 发明授权

US4250252A Light-sensitive color photographic material 失效
标题翻译：感光彩色照相材料
公开(公告)号：US4250252A
公开(公告)日：1981-02-10
申请号：US619301
申请日：1975-10-03
申请人： Heinrich Odenwalder , Hans Vetter , Walter Puschel , Erwin Ranz
发明人： Heinrich Odenwalder , Hans Vetter , Walter Puschel , Erwin Ranz
IPC分类号： G03C7/26 , C07D257/04 , G03C7/30 , G03C7/305 , G03C8/00 , G03C1/76
CPC分类号： C07D257/04 , C07C309/00 , G03C7/30511 , Y10S430/158
摘要： In a color photographic material wherein by color development there are produced either non-diffusing image dyes or diffusing image dyes (the latter being transferred to an image-receiving layer) the color development is controlled by means of non-diffusing thioether compounds which on color development release a diffusing mercapto compound but do not themselves form a dye. The mercapto compound inhibits the development of the silver halide and the thioether compound has the formula ##STR1## R.sub.1 =hydrogen or alkyl with 1-3 carbon atoms R.sub.2 =alkyl with up to 22 carbon atoms the group --S--Y is split off during color development and forms a mercaptane, e.g. 5-mercapto-1-phenyltetrazole, which inhibits the development.
摘要翻译：在通过彩色显影的彩色照相材料中，产生非漫射图像染料或漫射图像染料（后者转移到图像接收层），通过非扩散性硫醚化合物控制着色显色显影释放扩散巯基化合物，但本身不形成染料。巯基化合物抑制卤化银的发展，硫醚化合物具有下式R1 =氢或具有1-3个碳原子的烷基R2 =具有多达22个碳原子的烷基，-SY在显色期间分裂并形成硫醇，例如 5-巯基-1-苯基四唑，其抑制发育。

5. 发明授权

US4171223A Light-sensitive color photographic material 失效
标题翻译：感光彩色照相材料
公开(公告)号：US4171223A
公开(公告)日：1979-10-16
申请号：US918390
申请日：1978-06-23
申请人： Heinrich Odenwalder , Walter Puschel , Erwin Ranz
发明人： Heinrich Odenwalder , Walter Puschel , Erwin Ranz
IPC分类号： G03C7/26 , C07D285/06 , C07D285/10 , C07D417/12 , G03C7/305 , G03C1/48 , G03C1/06 , G03C1/40 , G03C5/30
CPC分类号： C07D285/10 , G03C7/30511 , Y10S430/158
摘要： Non-diffusible silver halide development inhibitor releasing thioether compounds in which a color development does not give rise to a substantial formation of permanent dyes are 1,2,5'-.DELTA..sup.2 -thiadiazoline-1,1-dioxide derivatives of the following formula or its tautomeric (.DELTA..sup.3) form: ##STR1## in which X represents an aliphatic, aromatic or heterocyclic group such that when it is split off together with the sulphur atom of the thioether bridge, it forms a diffusible mercapto compound capable of inhibiting the development of the silver halide;R.sup.1 represents hydrogen, alkyl, aryl or a heterocyclic group andR.sup.2 represents hydrogen, alkyl, aryl, a heterocyclic group or preferably acyl.
摘要翻译：不扩散卤化银显影抑制剂释放的硫醚化合物，其中显色不会引起永久性染料的大量形成是下式的1,2,5'-三（2,3-二 - 噻二唑啉-1,1-二氧化物）衍生物或其互变异构体（DELTA 3）形式：其中X表示脂族，芳族或杂环基团，使得当其与硫醚桥的硫原子一起分离时，其形成可扩散的巯基化合物，其能够抑制开发卤化银; R 1表示氢，烷基，芳基或杂环基，R 2表示氢，烷基，芳基，杂环基或优选酰基。

6. 发明授权

US4088491A Light sensitive photographic material 失效
标题翻译：感光感光材料
公开(公告)号：US4088491A
公开(公告)日：1978-05-09
申请号：US742139
申请日：1976-11-16
申请人： Heinrich Odenwalder , Walter Puschel , Erwin Ranz
发明人： Heinrich Odenwalder , Walter Puschel , Erwin Ranz
IPC分类号： G03C7/26 , C07D221/16 , C07D257/02 , C07D257/04 , C07D295/096 , C07D401/12 , C07D403/12 , C07D405/12 , G03C7/305 , G03C7/32 , G03C7/00 , G03C1/02 , G03C5/30
CPC分类号： C07D257/04 , C07C317/00 , C07D221/16 , C07D295/096 , G03C7/305
摘要： High edge effects and interimage effects are provided in a color-photographic material by the use of new DIR-compounds. These are of the formula ##STR1## wherein X represents together with the sulfur atom a development inhibiting group;Y represents --O--, ##STR2## methylene group which may be alkyl substituted or a methine group; Z represents a methylene or ethylene group which may be alkyl substituted, a methine group, a vinylene group, an o-phenylene group, a carbonyl group, an oxycarbonyl group or a carbonamide group;R.sup.1 and R.sup.2 represent aliphatic, araliphatic or aromatic groups, acyl, acyloxy, alkoxy, aryloxy, amino, halogen, cyano, thioether groups or arylsulfoxyl or alkylsulfoxyl or both R.sup.1 and R.sup.2 together complete an at least mono-unsaturated or aromatic ring.
摘要翻译：通过使用新的DIR化合物，在彩色照相材料中提供了高边缘效果和图像间效应。这些具有式“IMAGE”，其中X表示与硫原子一起显影抑制基团; Y表示可以被烷基取代的亚甲基或次甲基; Z表示可以被烷基取代的亚甲基或亚乙基，次甲基，亚乙烯基，邻亚苯基，羰基，氧羰基或碳酰胺基; R 1和R 2表示脂族，芳脂族或芳族基团，酰基，酰氧基，烷氧基，芳氧基，氨基，卤素，氰基，硫醚基或芳基亚砜基或烷基亚磺酰基，或者R 1和R 2两者一起完成至少单不饱和或芳环。

7. 发明授权

US4174969A Light sensitive photographic material 失效
标题翻译：感光感光材料
公开(公告)号：US4174969A
公开(公告)日：1979-11-20
申请号：US787970
申请日：1977-04-15
申请人： Heinrich Odenwalder , Erwin Ranz
发明人： Heinrich Odenwalder , Erwin Ranz
IPC分类号： G03C7/26 , C07D249/12 , C07D265/36 , C07D285/16 , C07D513/04 , G03C7/30 , G03C7/305 , G03C7/00 , G03C1/40
CPC分类号： C07D513/04 , C07D249/12 , G03C7/30511 , Y10S430/158
摘要： For controlling in a color photographic material the gradation, graininess, sharpness, edge and interimage effect and thus improving the overall color reproduction thioether DIR compounds of the following formula are particularly useful: ##STR1## in which X is a group that if split off together with the sulfur atom forms a diffusing development inhibiting mercaptan, Y represents --O--, ##STR2## or --S--, Z represents the ring members completing a 6-membered heterocyclic ring, R.sup.1 is an aliphatic, araliphatic or aromatic hydrocarbon group, a heterocyclic group or acyl, and R.sup.2 is the same as R.sup.1 or hydrogen.
摘要翻译：为了控制彩色照相材料，灰度，颗粒度，锐度，边缘和中间影响效应以及因此改善整体色彩还原的下列公式的硫醚DIR化合物特别有用：其中X是如果分开一起的组与硫原子形成抑制硫醇的扩散显影，Y表示-O-，-S-，Z表示完成6元杂环的环原子，R 1是脂族，芳脂族或芳族烃基，杂环基或酰基，R2与R1或氢相同。

8. 发明授权

US4139383A Dye diffusion transfer employing pyridine azo dye 失效
标题翻译：使用吡啶偶氮染料的染料扩散转移
公开(公告)号：US4139383A
公开(公告)日：1979-02-13
申请号：US851107
申请日：1977-11-14
申请人： Heinrich Odenwalder , Walter Puschel , Rudolf Stolzenburg
发明人： Heinrich Odenwalder , Walter Puschel , Rudolf Stolzenburg
IPC分类号： G03C7/00 , C07D213/85 , C09B29/42 , G03C8/10 , G03C1/10 , G03C1/40 , G03C5/54
CPC分类号： G03C8/10 , C07D213/85 , C09B29/3621
摘要： Non-diffusible dye-providing compounds for the dye diffusion transfer process yielding yellow to red color images of wanted absorption characteristics and improved light fastness correspond to the formula(A.sup.1).sub.n -- D -- N .dbd. N -- Py -- (A.sup.1).sub.1-nin whichA.sup.1 represents an oxidizable organic carrier residue which may be attached through a connecting member X and containing a group which confers diffusion resistance, from which carrier residue, either in its oxidized or in its unoxidized form, a part is split off together with the group which confers diffusion resistance under alkaline photographic development conditions, a diffusible azo dye represented by the formula P--N.dbd.N--B being released imagewise at the same time;D represents a heterocyclic or carbocyclic aromatic group;Py represents a pyridine or 1,2-dihydropyridine group which is attached to the azo group through its 3-position and carries an amino or hydroxyl group in its 6-position;N = 0 or 1.
摘要翻译：用于染料扩散转移过程的非扩散染料提供化合物产生所需吸收特性和改善的耐光性的黄色至红色图像对应于式（A1）n-D-N = N-Py-（A1）1-n 其中A1表示可氧化的有机载体残余物，其可以通过连接构件X附着并且含有赋予扩散阻力的基团，以其氧化或未氧化形式的载体残余物与其一起分离，在碱性照相显影条件下赋予扩散阻力的组，由PN = NB表示的可扩散偶氮染料同时成像释放; D表示杂环或碳环芳基; Py表示吡啶或1,2-二氢吡啶基，其通过其3-位连接到偶氮基上，并在其6-位上带有氨基或羟基; N = 0或1。

9. 发明授权

US4139387A Process for the production of direct-positive photographic images 失效
标题翻译：生产直接摄影图像的过程
公开(公告)号：US4139387A
公开(公告)日：1979-02-13
申请号：US848095
申请日：1977-11-03
申请人： Anita von Konig , Heinrich Odenwalder , Manfred Peters , Walter Puschel
发明人： Anita von Konig , Heinrich Odenwalder , Manfred Peters , Walter Puschel
IPC分类号： C07D207/38 , C07D257/08 , C07D257/12 , C07D307/52 , C07D307/64 , C07D471/10 , G03C1/485 , G03C5/50 , G03C5/24 , G03C1/28
CPC分类号： C07D471/10 , C07D207/38 , C07D257/08 , C07D257/12 , C07D307/52 , C07D307/64 , G03C1/48561 , G03C5/50
摘要： Positive images including color images are obtained by imagewise exposure and development of a material which comprises at least one light-sensitive silver halide emulsion layer which contains an unfogged direct-positive silver halide emulsion, when the development is carried out in the presence of a fogging agent of the formula ##STR1## wherein the symbols are defined as hereinafter. The fogging agent is preferably contained in a layer of the material and more preferably in the unfogged direct-positive silver halide emulsion layer. For the production of color instant images the material may also contain non-diffusible color providing compounds capable in their oxidized form of being split under alkaline photographic development conditions to release diffusible dyes.
摘要翻译：通过成像曝光和显影包含至少一种含有未雾化的直接正性卤化银乳剂的感光卤化银乳剂层的材料获得包括彩色图像的正像，当显影在雾化其中符号定义如下。雾化剂优选包含在材料层中，更优选地包含在未雾化的直接正性卤化银乳剂层中。为了生产彩色瞬时图像，该材料还可以含有非扩散性颜色提供化合物，其能够在碱性照相显影条件下分解其氧化形式以释放可扩散染料。

10. 发明授权

US4310621A Photosensitive photographic material, a process for the production of photographic images, development baths and new hydroquinones 失效
标题翻译：感光照相材料，生产摄影图像的过程，开发浴和新的氢醌
公开(公告)号：US4310621A
公开(公告)日：1982-01-12
申请号：US217193
申请日：1980-12-16
申请人： Heinrich Odenwalder , Karl Frank , Reinhard Muller
发明人： Heinrich Odenwalder , Karl Frank , Reinhard Muller
IPC分类号： C07D249/12 , G03C5/30 , G03C7/305 , G03C1/06
CPC分类号： C07D249/12 , G03C5/3021 , G03C7/305 , G03C7/30541 , Y10S430/158 , Y10S430/16
摘要： New DIR-compounds of the formula ##STR1## are useful in photographic materials and processes.
摘要翻译：式（IMAGE）的新型DIR化合物在照相材料和方法中是有用的。

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