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1. 发明授权

US3993710A Polymerizable organic dispersions 失效
标题翻译：可聚合的有机分散体
公开(公告)号：US3993710A
公开(公告)日：1976-11-23
申请号：US589949
申请日：1975-06-24
申请人： Heinrich Alberts , Klaus Schuster , Herbert Bartl , Hansjochen Schulz-Walz
发明人： Heinrich Alberts , Klaus Schuster , Herbert Bartl , Hansjochen Schulz-Walz
IPC分类号： C08L23/00 , C08F210/00 , C08J5/24 , C08L33/00 , C08L33/02 , C08L67/00 , C08L67/06 , C08L101/00 , C08L23/08
CPC分类号： C08L67/06
摘要： Dispersions suitable for the manufacture of moulding compositions which can be cured with low shrinkage to give mouldings with excellent surfaces can be obtained by the addition of finely divided ethylene copolymers manufactured in aqueous emulsion to unsaturated polyester resins.
摘要翻译：可以通过向不饱和聚酯树脂中加入以水性乳液制造的精细分散的乙烯共聚物来获得适于制造可以以低收缩率固化以得到具有优异表面的模制品的模塑组合物的分散体。

2. 发明授权

US3988388A Polymerizable organic dispersion of unsaturated polyester vinyl monomer and EVA copolymers 失效
标题翻译：不饱和聚酯乙烯基单体和EVA共聚物的可聚合有机分散体
公开(公告)号：US3988388A
公开(公告)日：1976-10-26
申请号：US552860
申请日：1975-02-25
申请人： Heinrich Alberts , Hansjochen Schulz-Walz , Herbert Bartl , Leonhard Goerden , Klaus Schuster
发明人： Heinrich Alberts , Hansjochen Schulz-Walz , Herbert Bartl , Leonhard Goerden , Klaus Schuster
IPC分类号： C08L67/00 , C08J3/09 , C08J5/24 , C08L23/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L67/06 , C08L77/00 , C08L101/00
CPC分类号： C08J5/24 , C08J3/09 , C08L67/06 , C08J2367/06
摘要： Pourable and pumpable, storage-stable organic dispersions which can be cured with little shrinkage comprising unsaturated polyesters, copolymerizable vinyl monomers, ethylene vinyl ester copolymers and optionally dispersing agents.
摘要翻译：可浇注和可泵送的储存稳定的有机分散体，其可以几乎不收缩而固化，包括不饱和聚酯，可共聚乙烯基单体，乙烯乙烯基酯共聚物和任选的分散剂。

3. 发明授权

US4501871A Process for the production of anhydride-group- or carboxyl-group-containing graft copolymers of polysaccharide esters 失效
标题翻译：制备含多酸酯类的含酸酐基或含羧基的接枝共聚物的方法
公开(公告)号：US4501871A
公开(公告)日：1985-02-26
申请号：US563660
申请日：1983-12-20
申请人： Herbert Bartl , Heinrich Alberts , Klaus Schuster
发明人： Herbert Bartl , Heinrich Alberts , Klaus Schuster
IPC分类号： C08F251/00 , C08G63/00 , C08L1/10 , C08L3/06 , C08L5/00
CPC分类号： C08F251/00
摘要： Anhydride-group- or carboxyl-group-containing graft copolymers of vinyl esters and other suitable monomers on polysaccharide esters of (A) a polysaccharide ester of aliphatic C.sub.1 -C.sub.5 -mono-carboxylic acids as the graft substrate and (B) a grafted-on monomer mixture of (a) a vinyl ester of a C.sub.1 -C.sub.18 -monocarboxylic acid and (b) maleic acid anhydride and/or semiesters of maleic acid and/or fumaric acid with aliphatic C.sub.1 -C.sub.14 -monoalcohols, the ratio by weight of (A) to (B) being from 1:0.1 to 1:2 and the molar ratio of (a) to (b) being from 1:0.5 to 1:3, and a process for producing these graft copolymers.
摘要翻译：（A）脂肪族C1-C5-单羧酸多糖酯作为接枝基质的多糖酯上的乙烯基酯和其它合适的单体的含酸基 - 或羧基接枝共聚物和（B）接枝 - 在（a）C1-C18-一元羧酸的乙烯基酯和（b）马来酸酐和/或马来酸和/或富马酸与脂肪族C 1 -C 14 - 一元醇的混合物的单体混合物上，（A）〜（B）为1:0.1〜1:2，（a）〜（b）的摩尔比为1:0.5〜1:3，以及这些接枝共聚物的制造方法。

4. 发明授权

US4056671A Styrene acrylonitrile copolymers with high dimensional stability under heat 失效
标题翻译：加热下具有高尺寸稳定性的苯乙烯丙烯腈共聚物
公开(公告)号：US4056671A
公开(公告)日：1977-11-01
申请号：US574950
申请日：1975-05-06
申请人： Heinrich Alberts , Herbert Bartl , Richard Prinz
发明人： Heinrich Alberts , Herbert Bartl , Richard Prinz
IPC分类号： C08F210/00 , C08F212/10 , C08F220/44 , C08F212/00
CPC分类号： C08F212/10 , C08F210/00 , C08F220/44 , Y10S526/916
摘要： Copolymers with improved dimensional stability under heat consisting essentially of (meth)acrylonitrile, styrene and at least one aliphatic monoolefin with 2 to 8 carbon atoms.
摘要翻译：基本上由（甲基）丙烯腈，苯乙烯和至少一种具有2至8个碳原子的脂肪族单烯烃组成的加热下具有改进的尺寸稳定性的共聚物。

5. 发明授权

US4794142A Use of special ethylene-vinyl acetate-copolymers for the modification of PVC 失效
标题翻译：使用特殊的乙烯 - 醋酸乙烯酯共聚物改性PVC
公开(公告)号：US4794142A
公开(公告)日：1988-12-27
申请号：US83230
申请日：1987-08-10
申请人： Heinrich Alberts , Herbert Bartl , Otto Billinger , Fritz Mietzsch
发明人： Heinrich Alberts , Herbert Bartl , Otto Billinger , Fritz Mietzsch
IPC分类号： C08L23/04 , C08L23/08 , C08L27/06 , C08L31/00 , C08L31/04 , C08L33/02
CPC分类号： C08L27/06 , C08L23/08 , C08L31/04
摘要： The object of the invention is the use of ethylene-vinyl acetate-copolymers produced by emulsion polymerization and containing unipolymerized acids, for the modification of polyvinyl chloride.
摘要翻译：本发明的目的是使用通过乳液聚合制备的乙烯 - 乙酸乙烯酯共聚物并含有未聚合的酸来改性聚氯乙烯。

6. 发明授权

US3962371A Weather-resistant thermoplasts 失效
标题翻译：耐候热塑性塑料
公开(公告)号：US3962371A
公开(公告)日：1976-06-08
申请号：US530171
申请日：1974-12-06
申请人： Heinrich Alberts , Herbert Bartl , Richard Prinz , Salah Elabd Elghani , Winfried Fischer
发明人： Heinrich Alberts , Herbert Bartl , Richard Prinz , Salah Elabd Elghani , Winfried Fischer
IPC分类号： C08L33/00 , C08L23/00 , C08L25/00 , C08L25/12 , C08L33/02 , C08L33/18 , C08L51/00 , C08L51/02 , C08L51/06 , C08L101/00 , C08L51/04 , C08L23/08 , C08L23/14
CPC分类号： C08L25/12 , C08L33/18 , C08L51/003 , C08L51/06
摘要： Weather-resistant thermoplastic moulding compounds of mixtures ofA. copolymers of (meth)acrylonitrile, of at least one aromatic vinyl compound and of optionally at least one monoolefin, andB. a graft copolymer of an ethylene/vinyl ester copolymer as graft substrate and grafted polymerized units of (meth)acrylonitrile of at least one aromatic monovinyl compound and of optionally at least one aliphatic monoolefin.
摘要翻译：（甲基）丙烯腈，至少一种芳族乙烯基化合物和任选的至少一种单烯烃的A.共聚物的混合物的耐候性热塑性成型化合物和B.作为接枝基材的乙烯/乙烯基酯共聚物的接枝共聚物和至少一种芳族单乙烯基化合物和任选的至少一种脂肪族单烯烃的（甲基）丙烯腈的接枝聚合单元。

7. 发明授权

US4071580A Graft polymers 失效
标题翻译：接枝聚合物
公开(公告)号：US4071580A
公开(公告)日：1978-01-31
申请号：US662263
申请日：1976-02-27
申请人： Heinrich Alberts , Herbert Bartl
发明人： Heinrich Alberts , Herbert Bartl
IPC分类号： C08F255/00 , C08F255/02 , C08F291/06 , C08F263/02 , C08F263/04
CPC分类号： C08F255/02 , C08F291/06
摘要： A process for the preparation of graft polymers from ethylene homopolymers or copolymers and olefinically unsaturated monomers, especially from ethylene/vinyl ester copolymers, in the presence of a radical forming agent in homogenous or heterogeneous phase, in which a mixture of (meth)acrylonitrile, at least one aromatic vinyl compound and vinylchloride are polymerized in the presence of an ethylene homopolymer or copolymer. The products obtained contain no ungrafted styrene/acrylonitrile copolymer and more than 80% by weight of the graft polymer is chemically almost uniform in structure. The products obtained according to the invention are eminently suitable for use as coating materials and as materials which can be thermoplastically processed.
摘要翻译：一种在乙烯均聚物或共聚物和烯属不饱和单体，特别是乙烯/乙烯基酯共聚物的自由基形成剂存在下在均相或非均相中制备接枝聚合物的方法，其中（甲基）丙烯腈，在乙烯均聚物或共聚物存在下聚合至少一种芳族乙烯基化合物和氯乙烯。获得的产品不含未接枝的苯乙烯/丙烯腈共聚物，并且大于80重量％的接枝聚合物在结构上化学上几乎均匀。根据本发明获得的产品非常适合用作涂料和作为可热塑化处理的材料。

8. 发明授权

US3968184A Impact-resistant polyvinyl chloride grafted ethylene-vinyl esters 失效
标题翻译：耐冲击聚氯乙烯接枝乙烯 - 乙烯基酯
公开(公告)号：US3968184A
公开(公告)日：1976-07-06
申请号：US457259
申请日：1974-04-02
申请人： Dietrich Hardt , Heinrich Alberts , Herbert Bartl
发明人： Dietrich Hardt , Heinrich Alberts , Herbert Bartl
IPC分类号： C08L27/00 , C08L1/00 , C08L23/00 , C08L27/06 , C08L51/00 , C08L51/02 , C08L51/06 , C08L101/00 , C08J9/16 , C08L33/18
CPC分类号： C08L27/06 , C08L51/003 , C08L51/06
摘要： Moulding compounds with improved impact strength and weather resistance comprising mixtures of polyvinylchloride and graft polymers prepared from ethylene/vinyl ester copolymers on which have been grafted units of monomer mixtures of aromatic vinyl compounds, (meth)acrylonitrile and aliphatic monoolefins.
摘要翻译：具有改进的冲击强度和耐候性的成型化合物包括由乙烯/乙烯基酯共聚物制备的聚氯乙烯和接枝聚合物的混合物，其上已经接枝了芳族乙烯基化合物，（甲基）丙烯腈和脂族单烯烃的单体混合物。

9. 发明授权

US4360635A Thermoplastic moulding compositions of cellulose ester graft copolymers or mixtures thereof with cellulose esters 失效
标题翻译：纤维素酯接枝共聚物或其与纤维素酯的混合物的热塑性模塑组合物
公开(公告)号：US4360635A
公开(公告)日：1982-11-23
申请号：US215939
申请日：1980-12-12
申请人： Heinrich Alberts , Winfried Fischer , Christian Leuschke , Herbert Bartl
发明人： Heinrich Alberts , Winfried Fischer , Christian Leuschke , Herbert Bartl
IPC分类号： C08F255/02 , C08F263/02 , C08L31/04 , C08L51/02 , C08L51/00 , C08F291/06
CPC分类号： C08F255/026 , C08F263/02 , C08L31/04 , C08L51/02
摘要： Transparent thermoplastic moulding compositions having improved mechanical properties consist of graft copolymers or mixtures thereof with a cellulose ester of aliphatic C.sub.1 -C.sub.5 carboxylic acids, wherein the graft copolymers consist of an ethylene vinyl ester copolymer and a cellulose ester of aliphatic C.sub.1 -C.sub.5 -carboxylic acids as the graft substrate, at least part of which being bridged with polymerized grafted units of vinyl esters and/or alkyl esters of acrylic and/or methacrylic acid, and, optionally, C.sub.2 -C.sub.4 -olefins.
摘要翻译：具有改进的机械性能的透明热塑性模塑组合物由接枝共聚物或其与脂族C 1 -C 5羧酸纤维素酯的混合物组成，其中接枝共聚物由乙烯乙烯基酯共聚物和脂族C 1 -C 5羧酸的纤维素酯组成作为接枝基材，其至少一部分与丙烯酸和/或甲基丙烯酸的乙烯基酯和/或烷基酯的聚合接枝单元和任选的C 2 -C 4 - 烯烃桥接。

10. 发明授权

US4329267A Process for the preparation of ethylene-vinyl ester graft polymer dispersions 失效
标题翻译：乙烯 - 乙烯基酯接枝聚合物分散体的制备方法
公开(公告)号：US4329267A
公开(公告)日：1982-05-11
申请号：US238996
申请日：1981-02-27
申请人： Klaus Riebel , Heinrich Alberts , Herbert Bartl , Fritz Mietzsch , Ulrich Steffen
发明人： Klaus Riebel , Heinrich Alberts , Herbert Bartl , Fritz Mietzsch , Ulrich Steffen
IPC分类号： C08F255/00 , C08F255/02 , C08F263/00 , C08F263/02 , C08F263/04 , C08L23/00 , C08L51/00 , C08L51/02 , C08L51/06 , C08L101/00
CPC分类号： C08F255/026 , C08F263/02
摘要： A process for the preparation of dispersions of optionally cross-linked ethylene-vinyl ester graft polymers wherein an ethylene-vinyl ester copolymer is used as graft substrate and a vinyl ester of a C.sub.1 -C.sub.18 carboxylic acid and/or a C.sub.1 -C.sub.10 -alkyl ester of acrylic and/or methacrylic acid are used as a graft monomer which is polymerized, optionally together with a cross-linking agent having two or more C--C double bonds, in organic solution until at least 25% by weight of the graft monomer has been reacted, the reaction product is converted into a stable finely divided dispersion by the addition of a precipitating agent under the action of shearing forces and polymerisation is completed before, during or after the formation of the dispersion.
摘要翻译：用于制备任选交联的乙烯 - 乙烯基酯接枝聚合物的分散体的方法，其中使用乙烯 - 乙烯基酯共聚物作为接枝基材和C1-C18羧酸和/或C1-C10-烷基的乙烯基酯使用丙烯酸和/或甲基丙烯酸的酯作为接枝单体，其在有机溶液中任选地与具有两个或更多个CC双键的交联剂一起聚合，直到至少25重量％的接枝单体已经被反应后，通过在剪切力的作用下加入沉淀剂将反应产物转化成稳定的细碎分散体，并且在形成分散体之前，期间或之后完成聚合。

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