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1. 发明申请

US20090312581A1 METHOD FOR DEHYDROGENATING ALCOHOLS 失效
标题翻译：脱水醇的方法
公开(公告)号：US20090312581A1
公开(公告)日：2009-12-17
申请号：US12307925
申请日：2007-07-09
申请人： Heiko Urtel , Soo Yin Chin , Thorsten Johann
发明人： Heiko Urtel , Soo Yin Chin , Thorsten Johann
IPC分类号： C07C45/00
CPC分类号： C07C45/002 , B01J23/6447 , B01J23/8973 , C07C47/06 , C07C49/08 , C07C47/02 , C07C47/04
摘要： A method for dehydrogenating primary or secondary alcohols having 1 to 12 carbon atoms to give the corresponding aldehydes or ketones in which the alcohol is brought into contact with a catalytically active composition comprising an active component of the formula PdaBibYcZd, where Y is selected from the group consisting of Co, Rh, Pt, Ag, Au, and Z is selected from the group consisting of Na, Cs, Mg, Ca, Ba, V, Cr, W, Fe, Ni, Cu, Sb where the indices a, b, c and d give the mass ratios of the respective elements to one another, where a=0.1-3, b=0.1-3, c=0-3, d=0-1.
摘要翻译：一种使具有1至12个碳原子的伯醇或仲醇脱氢得到相应的醛或酮，其中醇与包含式PdaBibYcZd的活性组分的催化活性组合物接触，其中Y选自由Co，Rh，Pt，Ag，Au和Z组成的组分选自Na，Cs，Mg，Ca，Ba，V，Cr，W，Fe，Ni，Cu，Sb，，c和d给出各元素彼此的质量比，其中a = 0.1-3，b = 0.1-3，c = 0-3，d = 0-1。

2. 发明授权

US07847129B2 Method for dehydrogenating alcohols 失效
标题翻译：醇脱氢方法
公开(公告)号：US07847129B2
公开(公告)日：2010-12-07
申请号：US12307925
申请日：2007-07-09
申请人： Heiko Urtel , Soo Yin Chin , Thorsten Johann
发明人： Heiko Urtel , Soo Yin Chin , Thorsten Johann
IPC分类号： C07C45/27 , C07C45/29
CPC分类号： C07C45/002 , B01J23/6447 , B01J23/8973 , C07C47/06 , C07C49/08 , C07C47/02 , C07C47/04
摘要： A method for dehydrogenating primary or secondary alcohols having 1 to 12 carbon atoms to give the corresponding aldehydes or ketones in which the alcohol is brought into contact with a catalytically active composition comprising an active component of the formula PdaBibYcZd, where Y is selected from the group consisting of Co, Rh, Pt, Ag, Au, and Z is selected from the group consisting of Na, Cs, Mg, Ca, Ba, V, Cr, W, Fe, Ni, Cu, Sb where the indices a, b, c and d give the mass ratios of the respective elements to one another, where a=0.1-3, b=0.1-3, c=0-3, d=0-1.
摘要翻译：一种使具有1至12个碳原子的伯醇或仲醇脱氢得到相应的醛或酮，其中醇与包含式PdaBibYcZd的活性组分的催化活性组合物接触，其中Y选自由Co，Rh，Pt，Ag，Au和Z组成的组分选自Na，Cs，Mg，Ca，Ba，V，Cr，W，Fe，Ni，Cu，Sb，，c和d给出各元素彼此的质量比，其中a = 0.1-3，b = 0.1-3，c = 0-3，d = 0-1。

3. 发明授权

US08779212B2 Use of a supported catalyst containing precious metal for oxidative dehydrogenation 有权
标题翻译：使用含贵金属的载体催化剂进行氧化脱氢
公开(公告)号：US08779212B2
公开(公告)日：2014-07-15
申请号：US12933441
申请日：2009-03-16
申请人： Torsten Mäurer , Georg Seeber , Radwan Abdallah , Thorsten Johann , Günter Wegner
发明人： Torsten Mäurer , Georg Seeber , Radwan Abdallah , Thorsten Johann , Günter Wegner
IPC分类号： C07C45/29 , B01J23/50
CPC分类号： B01J31/1616 , B01J21/16 , B01J23/007 , B01J23/38 , B01J23/50 , B01J23/72 , B01J23/8926 , B01J37/0219 , B01J37/086 , B01J2231/763 , B01J2531/17 , C07C45/38 , C07C47/21
摘要： The use of a supported noble metal catalyst obtainable by applying a sparingly soluble noble metal compound to a support from solution or suspension, and subsequently treating thermally, for preparing olefinically unsaturated carbonyl compounds.
摘要翻译：使用负载的贵金属催化剂，其通过将溶于或悬浮液的微溶贵金属化合物施加到载体上，随后热处理，制备烯属不饱和羰基化合物。

4. 发明授权

US08563785B2 Method for isomerizing olefinically unsaturated alcohols 有权
标题翻译：异构化烯属不饱和醇的方法
公开(公告)号：US08563785B2
公开(公告)日：2013-10-22
申请号：US13608577
申请日：2012-09-10
申请人： Michael Limbach , Joaquim Henrique Teles , Radwan Abdallah , Torsten Mäurer , Thorsten Johann , Manuel Danz
发明人： Michael Limbach , Joaquim Henrique Teles , Radwan Abdallah , Torsten Mäurer , Thorsten Johann , Manuel Danz
IPC分类号： C07C29/56
CPC分类号： C07C29/56 , C07C45/38 , C07C33/03 , C07C47/21
摘要： A process for isomerizing olefinically unsaturated alcohols over supported noble metal catalysts with a support based on carbon in an oxygenous atmosphere.
摘要翻译：在含氧气氛中具有基于碳的载体的负载型贵金属催化剂上异构化烯属不饱和醇的方法。

5. 发明申请

US20130006021A1 METHOD FOR ISOMERIZING OLEFINICALLY UNSATURATED ALCOHOLS 有权
标题翻译：异构不饱和醇的异构化方法
公开(公告)号：US20130006021A1
公开(公告)日：2013-01-03
申请号：US13608577
申请日：2012-09-10
申请人： Michael Limbach , Joaquim Henrique Teles , Radwan Abdallah , Torsten Mäurer , Thorsten Johann , Manuel Danz
发明人： Michael Limbach , Joaquim Henrique Teles , Radwan Abdallah , Torsten Mäurer , Thorsten Johann , Manuel Danz
IPC分类号： C07C29/56
CPC分类号： C07C29/56 , C07C45/38 , C07C33/03 , C07C47/21
摘要： A process for isomerizing olefinically unsaturated alcohols over supported noble metal catalysts with a support based on carbon in an oxygenous atmosphere.
摘要翻译：在含氧气氛中具有基于碳的载体的负载型贵金属催化剂上异构化烯属不饱和醇的方法。

6. 发明授权

US08263813B2 Method for isomerizing olefinically unsaturated alcohols 有权
标题翻译：异构化烯属不饱和醇的方法
公开(公告)号：US08263813B2
公开(公告)日：2012-09-11
申请号：US12920150
申请日：2009-02-27
申请人： Michael Limbach , Joaquim Henrique Teles , Radwan Abdallah , Torsten Mäurer , Thorsten Johann , Manuel Danz
发明人： Michael Limbach , Joaquim Henrique Teles , Radwan Abdallah , Torsten Mäurer , Thorsten Johann , Manuel Danz
IPC分类号： C07C29/56 , C07C33/02
CPC分类号： C07C29/56 , C07C45/38 , C07C33/03 , C07C47/21
摘要： A process for isomerizing olefinically unsaturated alcohols over supported noble metal catalysts with a support based on carbon in an oxygenous atmosphere.
摘要翻译：在含氧气氛中具有基于碳的载体的负载型贵金属催化剂上异构化烯属不饱和醇的方法。

7. 发明授权

US07495132B2 Catalytically active composition and the use thereof in dehydration methods 失效
标题翻译：催化活性组合物及其在脱水方法中的应用
公开(公告)号：US07495132B2
公开(公告)日：2009-02-24
申请号：US10587191
申请日：2005-01-28
申请人： Christian Walsdorff , Thorsten Johann , Beatrice Roessler , Hartmut Hibst , Joaquim Henrique Teles , Sebastian Storck , Jens Klein
发明人： Christian Walsdorff , Thorsten Johann , Beatrice Roessler , Hartmut Hibst , Joaquim Henrique Teles , Sebastian Storck , Jens Klein
IPC分类号： C07C45/65 , B01J23/42
CPC分类号： C07C45/65 , B01J23/6445 , B01J23/6447 , B01J23/6522 , B01J23/681 , B01J23/8973 , B01J35/008 , B01J37/0201 , B01J37/0221 , B01J37/03 , C07C47/21 , C07C49/603
摘要： The present invention relates to a catalytically active composition comprising as active component Pd and Bi and at least one element selected from the group (a) consisting of Rh, Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Na, Cs and Ba, or Pd, Rh and Bi and optionally an element selected from the group (a′) consisting of Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Pt, Cu, Ag, Na, Cs, Mg, Ca and Ba. The present invention further provides a process for dehydrogenating hydrocarbons, preferably oxo-functionalized hydrocarbons such as cyclopentanone, cyclohexanone and isovaleraldehyde, using the catalytically active composition.
摘要翻译：本发明涉及包含作为活性成分Pd和Bi的至少一种元素的催化活性组合物和选自由Rh，Au，Sb，V，Cr，W，Mn，Fe，Co，Ni组成的组（a）中的至少一种元素， Na，Cs和Ba或Pd，Rh和Bi以及任选的选自Au，Sb，V，Cr，W，Mn，Fe，Co，Ni，Pt，Cu，Ag， Na，Cs，Mg，Ca和Ba。本发明还提供了一种使用催化活性组合物使烃优选氧化官能化烃如环戊酮，环己酮和异戊醛脱氢的方法。

8. 发明申请

US20110015446A1 USE OF A SUPPORTED CATALYST CONTAINING PRECIOUS METAL FOR OXIDATIVE DEHYDROGENATION 有权
标题翻译：使用含有极性金属的负载型催化剂进行氧化脱氢
公开(公告)号：US20110015446A1
公开(公告)日：2011-01-20
申请号：US12933441
申请日：2009-03-16
申请人： Torsten Mäurer , Georg Seeber , Radwan Abdallah , Thorsten Johann , Günter Wegner
发明人： Torsten Mäurer , Georg Seeber , Radwan Abdallah , Thorsten Johann , Günter Wegner
IPC分类号： C07C45/29 , B01J23/50
CPC分类号： B01J31/1616 , B01J21/16 , B01J23/007 , B01J23/38 , B01J23/50 , B01J23/72 , B01J23/8926 , B01J37/0219 , B01J37/086 , B01J2231/763 , B01J2531/17 , C07C45/38 , C07C47/21
摘要： The use of a supported noble metal catalyst obtainable by applying a sparingly soluble noble metal compound to a support from solution or suspension, and subsequently treating thermally, for preparing olefinically unsaturated carbonyl compounds.
摘要翻译：使用负载的贵金属催化剂，其通过将溶于或悬浮液的微溶贵金属化合物施加到载体上，随后热处理，制备烯属不饱和羰基化合物。

9. 发明申请

US20090192335A1 TEMPERATURE-CONTROL IN THE PERFORMANCE OF OXIDATION REACTIONS OF HYDROCARBONS 审中-公开
标题翻译：氢气氧化反应性能的温度控制
公开(公告)号：US20090192335A1
公开(公告)日：2009-07-30
申请号：US12301184
申请日：2007-05-11
申请人： Jobst Rüdiger von Watzdorf , Gerhard Koppenhöfer , Wolfgang Kanther , Thomas Krug , Thorsten Johann
发明人： Jobst Rüdiger von Watzdorf , Gerhard Koppenhöfer , Wolfgang Kanther , Thomas Krug , Thorsten Johann
IPC分类号： C07C45/27 , B01J8/06
CPC分类号： C07C45/33 , B01J8/067 , B01J2208/00212 , B01J2208/00371 , C07C45/38 , C07C47/127
摘要： The present invention relates to a process for performing catalyzed oxidation reactions of hydrocarbons over a catalyst disposed in a reactor, which comprises cooling the product gas stream of the catalyzed oxidation reaction immediately after it leaves the reaction zone of the reactor by feeding in a temperature-controlled gas stream which is fed in through at least one feed device into the region between lower reactor plate and outlet of the product gas stream.
摘要翻译：本发明涉及一种在反应器中设置的催化剂上进行烃的催化氧化反应的方法，该方法包括在催化氧化反应产物的气流离开反应器的反应区之后，受控气流通过至少一个进料装置进入下反应器板和产物气流出口之间的区域。

10. 发明授权

US07518024B2 Process for preparing 1-butene 有权
标题翻译：制备1-丁烯的方法
公开(公告)号：US07518024B2
公开(公告)日：2009-04-14
申请号：US10577198
申请日：2004-10-27
申请人： Götz-Peter Schindler , Andreas Brodhagen , Thorsten Johann , Thomas Hill
发明人： Götz-Peter Schindler , Andreas Brodhagen , Thorsten Johann , Thomas Hill
IPC分类号： C07C5/327 , C07C5/32
CPC分类号： C07C5/333 , C07C5/05 , C07C11/08
摘要： A process for preparing 1-butene from 1-butane, which includes providing a n-butane-containing feed gas stream; introducing of the n-butane-containing feed gas stream into at least one dehydrogenation zone and nonoxidative catalytic dehydrogenation of n-butane; removing hydrogen, the low-boiling secondary constituents and optionally water vapor to give a C4 product gas stream containing 10-80% by volume of n-butane, 5-40% by volume of 1-butene, 10-50% by volume of 2-butene, 0-40% by volume of butadiene and 0-10% by volume of further gas constituents; introducing the C4 product gas stream containing 10-80% by volume of n-butane, 10-60% by volume of 1-butene, 15-60% by volume of 2-butene, 0-5% by volume of butadiene and 0-10% by volume of further gas constituents, into a selective hydrogenation zone and selective hydrogenation of butadiene to 1- and/or 2-butene to give stream consisting essentially of n-butane, 1-butene and 2-butene; and separating of the stream distillation into a desired product.
摘要翻译：一种从1-丁烷制备1-丁烯的方法，其包括提供含正丁烷的原料气流; 将含正丁烷的进料气流引入至少一个脱氢区和正丁烷的非氧化催化脱氢; 去除氢气，低沸点次级组分和任选的水蒸汽，得到含有10-80体积％正丁烷的C4产物气流，5-40体积％的1-丁烯，10-50体积％ 2-丁烯，0-40体积％的丁二烯和0-10体积％的其它气体组分; 引入含有10-80体积％正丁烷的C4产物气流，10-60体积％的1-丁烯，15-60体积％的2-丁烯，0-5体积％的丁二烯和0 -10％体积的进一步气体组分转化为选择性加氢区，并将丁二烯选择性氢化为1-和/或2-丁烯，得到基本上由正丁烷，1-丁烯和2-丁烯组成的物流; 并将料流蒸馏分离成所需产物。

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