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1. 发明授权

US06734257B2 Block copolymer based on conjugated diolefins and polar monomers 有权
标题翻译：基于共轭二烯烃和极性单体的嵌段共聚物
公开(公告)号：US06734257B2
公开(公告)日：2004-05-11
申请号：US10102761
申请日：2002-03-21
申请人： Heike Windisch , Werner Obrecht , Cristina Stere , Thomas Scholl , Oskar Nuyken , Lars Friebe , Mario Vierle
发明人： Heike Windisch , Werner Obrecht , Cristina Stere , Thomas Scholl , Oskar Nuyken , Lars Friebe , Mario Vierle
IPC分类号： C08L5300
CPC分类号： C08F297/06
摘要： The block copolymers according to the invention which are based on conjugated diolefins and polar monomers and are prepared in the presence of catalysts based on the rare earth metals have a high cis-1,4 content in the polydiene block and, because of their polar polymer part and their non-polar diene polymer part, can be used as agents which impart compatibility in the preparation of vulcanizates with a filler content for the production of tires and tire component in the preparation of thermoplastic elastomers or in the modification of thermoplastics.
摘要翻译：根据本发明的基于共轭二烯烃和极性单体并且在基于稀土金属的催化剂存在下制备的嵌段共聚物在聚二烯嵌段中具有高顺式-1,4的含量，并且由于它们的极性聚合物部分和它们的非极性二烯聚合物部分可以用作在制备热塑性弹性体或在热塑性塑料的改性中赋予轮胎和轮胎组分的制备中的填料含量的硫化橡胶制剂相容性的试剂。

2. 发明授权

US06566465B1 Method for polymerizing conjugated diolefins (dienes) with catalysts based on vanadium compounds in the presence of vinylaromatic solvents 失效
标题翻译：在乙烯基芳族溶剂存在下，使用基于钒化合物的催化剂聚合共轭二烯烃（二烯）的方法
公开(公告)号：US06566465B1
公开(公告)日：2003-05-20
申请号：US09743535
申请日：2001-01-11
申请人： Heike Windisch , Werner Obrecht , Gisbert Michels , Norbert Steinhauser
发明人： Heike Windisch , Werner Obrecht , Gisbert Michels , Norbert Steinhauser
IPC分类号： C08F468
CPC分类号： C08F36/04 , C08F4/68
摘要： Conjugated diolefins, optionally in combination with other unsaturated compounds which may be copolymerized with the diolefins, are polymerized by performing the polymerization of the diolefins in the presence of catalysts based on monocyclopentadienyl compounds of vanadium and alumoxanes in the presence of aromatic vinyl compounds as the solvent at temperatures of −30 C. to +80 C. By means of the process according to the invention, it is possible to straightforwardly produce solutions of polydiolefins, such as polybutadiene, having 1,2 unit contents of 10 to 30% in aromatic vinyl compounds, which solutions may then, for example, be further processed to yield ABS or HIPS.
摘要翻译：任选与可与二烯烃共聚的其它不饱和化合物组合的共轭二烯烃通过在芳族乙烯基化合物作为溶剂存在下，在基于钒和铝氧烷的单环戊二烯基化合物的催化剂存在下进行二烯烃的聚合而聚合在-30℃至+ 80℃的温度下进行。通过本发明的方法，可以直接生产聚二烯烃如聚丁二烯的溶液，其中1,2-单体含量为10-30％，芳族乙烯基化合物，然后可以将该溶液进一步加工以产生ABS或HIPS。

3. 发明授权

US06310151B1 Method for polymerizing conjugated diolefins (dienes) with catalysts based on cobalt compounds in the presence of vinylaromatic solvents 失效
标题翻译：在乙烯基芳烃溶剂存在下，使用基于钴化合物的催化剂聚合共轭二烯烃（二烯）的方法
公开(公告)号：US06310151B1
公开(公告)日：2001-10-30
申请号：US09743630
申请日：2001-01-12
申请人： Heike Windisch , Werner Obrecht , Gisbert Michels , Norbert Steinhauser
发明人： Heike Windisch , Werner Obrecht , Gisbert Michels , Norbert Steinhauser
IPC分类号： C08F470
CPC分类号： C08F36/04 , C08F4/7096
摘要： Conjugated diolefins, optionally in combination with other unsaturated compounds which may be copolymerized with the diolefins, are polymerized by performing the polymerization of the diolefins in the presence of catalysts based on cobalt compounds, organoaluminum compounds and modifiers in the presence of aromatic vinyl compounds at temperatures of −30° C. to +80° C. By means of the process according to the invention, it is possible straightforwardly to produce solutions of polydiolefins, such as polybutadiene, having different 1,2 unit contents in aromatic vinyl compounds, which solutions may then, for example, be further processed to yield ABS or HIPS.
摘要翻译：任选与可与二烯烃共聚的其它不饱和化合物组合的共轭二烯烃通过在芳族乙烯基化合物存在下，在芳族乙烯基化合物存在下，在基于钴化合物，有机铝化合物和改性剂的催化剂的存在下进行二烯烃的聚合， -30℃至+ 80℃。通过本发明的方法，可以直接在芳族乙烯基化合物中产生具有不同1,2-单元含量的聚二烯烃如聚丁二烯的溶液，该溶液然后可以例如进一步加工以产生ABS或HIPS。

4. 发明授权

US06284697B1 Compounds of the rare earths and their use as polymerization catalysts for unsaturated compounds 失效
标题翻译：稀土化合物及其作为不饱和化合物聚合催化剂的用途
公开(公告)号：US06284697B1
公开(公告)日：2001-09-04
申请号：US09073722
申请日：1998-05-07
申请人： Heike Windisch , Gerd Sylvester , Rudolf Taube , Steffen Maiwald
发明人： Heike Windisch , Gerd Sylvester , Rudolf Taube , Steffen Maiwald
IPC分类号： B01J3100
CPC分类号： B01J31/1616 , B01J31/122 , B01J31/143 , B01J31/2291 , B01J31/2295 , B01J2531/30 , B01J2531/35 , B01J2531/36 , B01J2531/37 , B01J2531/38 , B01J2540/22 , C08F4/52 , C08F36/04 , C08F4/54
摘要： The present invention relates to a new catalyst based on allyl complexes of the rare earths, of general formula [(C3R15)rM1(X)2−r(D)n]+[M2(X)p(C6H5−qR2q)4−p]− (I), to the preparation of this new catalyst, and to its use for the polymerization of unsaturated compounds, particularly of conjugated dienes, in solution and in the gas phase.
摘要翻译：本发明涉及一种基于稀土烯丙基络合物的新催化剂，通常是制备这种新催化剂，以及其用于在溶液和气相中不饱和化合物，特别是共轭二烯的聚合的用途。

5. 发明授权

US5958820A Gas-phase polymerisation of conjugated dienes in the presence of rare earth allyl compounds 失效
标题翻译：在稀土烯丙基化合物存在下，共轭二烯的气相聚合
公开(公告)号：US5958820A
公开(公告)日：1999-09-28
申请号：US930725
申请日：1997-10-02
申请人： Rudolf Taube , Steffen Maiwald , Thomas Ruhmer , Heike Windisch , Jurgen Giesemann , Gerd Sylvester
发明人： Rudolf Taube , Steffen Maiwald , Thomas Ruhmer , Heike Windisch , Jurgen Giesemann , Gerd Sylvester
IPC分类号： C08F2/34 , C08F4/02 , C08F4/54 , C08F4/60 , C08F36/00 , C08F36/04 , C08F36/06 , B01J31/00 , B01J37/00
CPC分类号： C08F36/04
摘要： A process for polymerizing a gaseous conjugated diene by bringing it in contact with a catalyst consisting of a rare earth allyl compound, an organic aluminum compound, an inorganic support and optionally, the same or a different conjugated diene. The resulting polymers possess elevated proportions of cis-1,4 units.
摘要翻译： PCT No.PCT / EP96 / 01276 Sec。 371 1997年10月2日第 102（e）日期1997年10月2日PCT 1996年3月22日PCT公布。出版物WO96 / 31544 PCT 日期：1996年10月10日通过使气态共轭二烯与由稀土烯丙基化合物，有机铝化合物，无机载体和任选相同或不同的共轭二烯组成的催化剂接触而使气态共聚二烯聚合的方法。所得聚合物具有升高的顺式-1,4单元比例。

6. 发明授权

US06399726B1 Method for the copolymerization of conjugated diolefins (dienes) and vinyl-aromatic monomers with rare-earth catalysts and use of the copolymers in rubber mixtures for tire applications 失效
标题翻译：共轭二烯烃（二烯）和乙烯基芳族单体与稀土催化剂共聚的方法和用于轮胎应用的橡胶混合物中的共聚物
公开(公告)号：US06399726B1
公开(公告)日：2002-06-04
申请号：US09638627
申请日：2000-08-15
申请人： Heike Windisch , Jürgen Trimbach , Peter Schertl , Ellen Giebeler , Rüdiger Engehausen
发明人： Heike Windisch , Jürgen Trimbach , Peter Schertl , Ellen Giebeler , Rüdiger Engehausen
IPC分类号： C08F472
CPC分类号： C08F212/04 , C08F4/545 , C08F236/10 , Y10S526/903
摘要： The present invention concerns a method for the copolymerization of conjugated diolefins and vinyl-aromatic monomers in the presence of rare-earth catalysts and the use of the copolymers in rubber mixtures for tire applications.
摘要翻译：本发明涉及在稀土催化剂存在下共轭二烯烃和乙烯基芳族单体共聚的方法以及用于轮胎应用的橡胶混合物中共聚物的用途。

7. 发明授权

US6093674A Supported cobalt catalyst, production thereof and use thereof for the polymerization of unsaturated compounds 失效
标题翻译：负载钴催化剂，其制备方法及其用途，用于不饱和化合物的聚合
公开(公告)号：US6093674A
公开(公告)日：2000-07-25
申请号：US132370
申请日：1998-08-11
申请人： Heike Windisch , Gerd Sylvester
发明人： Heike Windisch , Gerd Sylvester
IPC分类号： C08F4/02 , C08F4/602 , C08F4/70 , C08F36/04 , B01J31/00
CPC分类号： C08F36/04
摘要： The present invention relates to a supported cobalt catalyst consisting of(a) cobalt compounds,(b) organoaluminium compounds,(c) water or OH-acidic compounds,(d) inorganic or polymeric organic support materials and(e) modifiers selected from the group comprising tertiary phosphines,to the production thereof and to the use thereof for the polymerization of unsaturated compounds, in particular of conjugated dienes, in the gas phase. With the assistance of the catalysts according to the invention, it is possible to achieve gas phase polymerization of conjugated dienes with an elevated content of lateral double bonds in the polymers.
摘要翻译：本发明涉及由（a）钴化合物，（b）有机铝化合物，（c）水或OH-酸性化合物，（d）无机或聚合有机载体材料和（e）选自包括叔膦的组，其生产方法及其在气相中聚合不饱和化合物，特别是共轭二烯的用途。在本发明的催化剂的帮助下，可以实现聚合物中侧链双键含量升高的共轭二烯的气相聚合。

8. 发明授权

US06570031B1 Dendrimer compounds, method for the production thereof, use thereof as catalysts 失效
标题翻译：树枝状聚合物，其制备方法，其用途为催化剂
公开(公告)号：US06570031B1
公开(公告)日：2003-05-27
申请号：US09646839
申请日：2000-09-22
申请人： Sigurd Becke , Uwe Denninger , Michael Mager , Heike Windisch
发明人： Sigurd Becke , Uwe Denninger , Michael Mager , Heike Windisch
IPC分类号： C07F708
CPC分类号： C08G83/003 , C07F7/0838 , C08F4/61912 , C08F4/61927 , C08F4/65912 , C08F10/00 , C08F4/61908 , C08F4/44 , C08F4/65908 , C08F4/54 , C08F4/603
摘要： The present invention relates to a novel dendrimic compounds, to a method for the production thereof and to the use thereof as catalysts for the production of polymers, in particular to the use thereof as co-catalysts for metallocenes for polymerizing unsaturated compounds.
摘要翻译：本发明涉及一种新颖的树枝状化合物，其制备方法及其作为用于制备聚合物的催化剂的用途，特别涉及作为用于聚合不饱和化合物的金属茂的助催化剂的用途。

9. 发明授权

US06365537B1 Two-component supported catalysts and their use for gas-phase polymerization 失效
标题翻译：双组分负载催化剂及其在气相聚合中的应用
公开(公告)号：US06365537B1
公开(公告)日：2002-04-02
申请号：US09151828
申请日：1998-09-11
申请人： Heike Windisch , Norbert Steinhauser
发明人： Heike Windisch , Norbert Steinhauser
IPC分类号： B01J3100
CPC分类号： C08F36/06 , C08F4/02 , C08F4/545 , C08F4/54 , C08F4/7096
摘要： The present invention relates to a two-component supported catalyst, consisting of a) at least one transition metal compound applied on to an inorganic or polymeric organic supporting material, the metal being selected from the group of the d and f elements of the periodic table according to Mendeleev, b) at least one organometallic compound applied on to an inorganic or polymeric organic supporting material, the metal being selected from the group of the IIa, IIb and IIIb elements of the periodic table (F. A. Cotton, G. Wilkinson, Anorganische Chemie, 4th edition, VCH Verlagsgesellschaft mbH, Weinheim, 1985) and c) optionally at least one modifier which is supported on a) and/or on b), the transition metal compound in component a) being used in quantities of 0.1 to 100 mmol, based on 100 g of the supporting material, and the organometallic compound in component b) being used in quantities of 0.1 to 100 mmol, based on 100 g of the supporting material, and component c) being used in quantities of 0.01 to 500 mmol, based on 100 g of the supporting material, and the supporting materials of components a) to b) being used in quantitative ratios by weight (g/g) of 1.10−3 to 1000, and at least one of components a) or b) having a supporting material with an average particle size before or during polymerisation of
摘要翻译：本发明涉及一种双组分负载型催化剂，由以下组成：a）至少一种应用于无机或聚合物有机支撑材料的过渡金属化合物，该金属选自周期表的d和f元素，根据至Mendeleev，b）至少一种应用于无机或聚合有机载体材料的有机金属化合物，该金属选自周期表IIa，IIb和IIIb族元素（FA Cotton，G.Wilkinson，Anorganische Chemie ，第4版，VCH Verlagsgesellschaft mbH，Weinheim，1985）和c）任选地至少一种负载在a）和/或b）上的改性剂，组分a）中的过渡金属化合物的用量为0.1至100mmol，基于100g支撑材料，组分b）中的有机金属化合物的用量为0.1至100mmol，基于100g支撑材料，组分c）用于定量 0.01至500mmol，基于100g支撑材料，组分a）至b）的支撑材料以1.10-3至1000的重量比（g / g）和至少一种的组分a）或b）在聚合<25μm之前或期间具有平均粒度的支撑材料。

10. 发明授权

US5965678A Catalyst system based on monoazadiene metal complexes 失效
标题翻译：基于单偶氮二烯金属络合物的催化剂体系
公开(公告)号：US5965678A
公开(公告)日：1999-10-12
申请号：US96654
申请日：1998-06-12
申请人： Sigurd Becke , Heike Windisch , Joachim Scholz , Steffen Kahlert
发明人： Sigurd Becke , Heike Windisch , Joachim Scholz , Steffen Kahlert
IPC分类号： C08F4/605 , C08F4/42 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/69 , C08F10/00 , C08F36/04 , C08F4/64 , C08F36/02
CPC分类号： C08F36/04 , C08F10/00 , C08F110/02 , C08F210/18 , C08F4/61908 , C08F4/61912 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65925 , C08F4/65927 , Y10S526/943
摘要： The present invention relates to a catalyst system based on monoazadiene metal complexes of the formula ##STR1## and a co-catalyst suitable for activating the metal complex, and to the use of the catalyst system for the polymerization of unsaturated compounds, especially for the polymerization and copolymerization of olefins and/or dienes.The novel catalyst system is characterised in particular by its ease of access, its lack of sensitivity to external influences and its ease of handling.
摘要翻译：本发明涉及一种基于下式的单偶氮二金属络合物和适用于活化金属络合物的助催化剂的催化剂体系，以及用于不饱和化合物聚合的催化剂体系的用途，特别是用于聚合和共聚烯烃和/或二烯。新型催化剂体系的特征在于其易于使用，其对外部影响的敏感性不足及其易于处理。

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