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    • 10. 发明申请
    • Non-aqueous electrolyte secondary battery
    • 非水电解质二次电池
    • US20060102472A1
    • 2006-05-18
    • US11174664
    • 2005-07-06
    • Yasuhiko BitoToshitada SatoTeruaki Yamamoto
    • Yasuhiko BitoToshitada SatoTeruaki Yamamoto
    • C25B11/04
    • H01M10/052H01M2/0222H01M4/134H01M4/38H01M4/386H01M10/058H01M2004/021
    • A non-aqueous electrolyte secondary battery that has a high electrical capacity and exhibits excellent cycle characteristics even when the battery is rapidly charged and discharged at a large current includes: a positive electrode capable of reversibly absorbing and desorbing Li; a negative electrode; and a non-aqueous electrolyte. The negative electrode includes an alloying material that is capable of electrochemically absorbing and desorbing Li, and includes an A phase composed mainly of Si and a B phase including an intermetallic compound of at least one transition metal element and Si. The transition metal element is selected from the group consisting of Ti, Zr, Ni, Cu, and Fe. The A phase and/or the B phase includes a microcrystalline or amorphous region. The weight percent of the A phase relative to the total weight of the A phase and the B phase is greater than 40% and not greater than 95%.
    • 即使电池以大电流快速充放电,具有高电容且显示优异的循环特性的非水电解质二次电池包括:能够可逆地吸收和解吸Li的正极; 负极; 和非水电解质。 负极包括能够电化学吸收和解吸Li的合金材料,并且包括主要由Si和包含至少一种过渡金属元素和Si的金属间化合物的B相组成的A相。 过渡金属元素选自Ti,Zr,Ni,Cu和Fe。 A相和/或B相包括微晶或非晶区。 A相的相对于A相和B相的总重量的重量百分比大于40%且不大于95%。