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1. 发明授权

US09024026B2 Copper (I) complexes for optoelectronic devices 有权
标题翻译：铜（I）配合物用于光电器件
公开(公告)号：US09024026B2
公开(公告)日：2015-05-05
申请号：US13810848
申请日：2011-07-20
申请人： Hartmut Yersin , Rafal Czerwieniec , Uwe Monkowius
发明人： Hartmut Yersin , Rafal Czerwieniec , Uwe Monkowius
IPC分类号： C09K11/06 , C07D471/04 , C07F5/02 , C07F9/50 , C07F9/6561 , H01L51/00 , H01L51/50
CPC分类号： C09K11/06 , C07D471/04 , C07F5/027 , C07F9/5027 , C07F9/5045 , C07F9/6561 , C09B57/00 , C09B57/008 , C09B57/10 , C09B69/109 , C09K2211/1007 , C09K2211/1011 , C09K2211/1029 , C09K2211/188 , H01L51/0072 , H01L51/008 , H01L51/009 , H01L51/0091 , H01L51/5012 , Y02E10/549 , Y02P70/521
摘要： The invention relates to neutral mononuclear copper (I) complexes for emitting light and with a structure according to formula (A) in which: M represents: Cu(I); L∩L represents: a single, negatively charged, bidentate ligand; N∩N represents: a diimine ligand (substituted with R and FG), in particular a substituted 2,2′-bipyridine derivative (bpy) or a substituted 1,10-phenanthroline derivative (phen); R represents: at least one sterically demanding substituent for preventing the planarization of the complex in the excited state; FG=functional group, and represents: at least one second substituent for increasing solubility in organic solvents. The substituent can also be used for electron transport or alternatively for hole transport, said functional group being bound to the diimine ligands either directly or by means of suitable bridges; and the copper (I) complex: having a ΔE(S1−T1) value of less than 2500 cm−1 between the lowest excited singlet state (S1) and the triplet state (T1) which lies below; having an emission lifespan of at most 20 μs; having an emission quantum yield of greater than 40%, and a solubility of at least 1 g/L in organic solvents, in particular polar organic hydrocarbons such as acetone, methyl ethyl ketone, benzene, toluene, chlorobenzene, dichlorobenzene, dichloromethane, chloroform, dichloroethane, tetrachloroethylene, alcohols, acetonitrile or water.
摘要翻译：本发明涉及用于发光并具有式（A）结构的中性单核铜（I）配合物，其中：M表示：Cu（I）; L∩L表示：单个带负电荷的二齿配体; N∩N表示：二亚胺配体（被R和FG取代），特别是取代的2,2'-联吡啶衍生物（bpy）或取代的1,10-菲咯啉衍生物（phen）; R表示：至少一个空间要求的取代基，用于防止复合物在激发态下的平面化; FG =官能团，并且表示：用于增加在有机溶剂中的溶解度的至少一个第二取代基。该取代基也可以用于电子传输或者可以用于空穴传输，所述官能团直接或通过合适的桥结合到二亚氨配体; 和铜（I）配合物：在最低激发单态（S1）和位于下面的三重态（T1）之间具有小于2500cm -1的＆Dgr; E（S1-T1）值; 排放寿命至多为20μs; 具有大于40％的发光量子产率和至少1g / L的溶解度在有机溶剂中，特别是极性有机烃如丙酮，甲基乙基酮，苯，甲苯，氯苯，二氯苯，二氯甲烷，氯仿，二氯乙烷，四氯乙烯，醇，乙腈或水。

2. 发明申请

US20130299744A1 METAL COMPLEXES HAVING ADAPTABLE EMISSION COLORS FOR OPTOELECTRONIC DEVICES 审中-公开
标题翻译：具有用于光电器件的适应性排放颜色的金属复合物
公开(公告)号：US20130299744A1
公开(公告)日：2013-11-14
申请号：US13981111
申请日：2012-01-23
申请人： Hartmut Yersin , Rafal Czerwieniec , Uwe Monkowius , Thomas Baumann
发明人： Hartmut Yersin , Rafal Czerwieniec , Uwe Monkowius , Thomas Baumann
IPC分类号： H01L51/00
CPC分类号： H01L51/0091 , C07F9/5045 , C07F9/58 , H01L51/0034 , H01L51/004 , H01L51/009 , H01L51/5016 , Y02E10/549
摘要： The invention relates to a method for increasing the Stokes shift of an emitting metal complex having a given geometry in the region of the metal center in the electronic ground state, wherein said geometry is changing as a result of an optical excitation or an excitation by a hole-electron recombination, and to a polymeric matrix by means of which it is possible to influence the change in geometry in the excited state.
摘要翻译：本发明涉及一种用于在电子基态中增加金属中心区域中具有给定几何形状的发射金属络合物的斯托克斯位移的方法，其中所述几何形状由于光学激发或由空穴电子复合，以及聚合物基体，通过它们可以影响激发态的几何形状的变化。

3. 发明申请

US20130020560A1 BIPHENYL-METAL COMPLEXES-MONOMERIC AND OLIGOMERIC TRIPLET EMITTERS FOR OLED APPLICATIONS 有权
公开(公告)号：US20130020560A1
公开(公告)日：2013-01-24
申请号：US13540219
申请日：2012-07-02
申请人： Hartmut Yersin , Uwe Monkowius , Rafal Czerwieniec
发明人： Hartmut Yersin , Uwe Monkowius , Rafal Czerwieniec
IPC分类号： H01L51/54 , C07F19/00 , H01L51/56 , C07F15/00
CPC分类号： H01L51/0087 , H01L51/0035 , H01L51/004 , H01L51/0043 , H01L51/0084 , H01L51/0085 , H01L51/5016 , Y10S428/917
摘要： The present invention relates to light-emitting devices and novel emitter materials as well as emitter systems and, in particular, organic light-emitting devices (OLEDs). In particular, the invention relates to the use of luminescent complexes as emitters in such devices.

4. 发明申请

US20100141120A1 Oligomers of Isonitrile-Metal Complexes as Triplett Emitters for OLED Applications 有权
标题翻译：作为用于OLED应用的三重发射体的异腈 - 金属络合物的低聚物
公开(公告)号：US20100141120A1
公开(公告)日：2010-06-10
申请号：US12306957
申请日：2007-07-03
申请人： Hartmut Yersin , Uwe Monkowius , Tobias Fischer , Walter Finkenzeller , Rafal Czerwieniec
发明人： Hartmut Yersin , Uwe Monkowius , Tobias Fischer , Walter Finkenzeller , Rafal Czerwieniec
IPC分类号： H01L51/54 , H01L51/56 , C07F15/00
CPC分类号： H01L51/0087 , C07F15/0066 , C07F15/0093 , C09K11/06 , C09K2211/185 , H01L51/0081 , H01L51/0094 , H01L51/5016 , H05B33/14 , Y02E10/549
摘要： The present invention relates to light-emitting devices and in particular organic light-emitting devices (OLEDs). In particular, the invention relates to the use of luminescent isonitrile/metal complexes as oligomer emitters in devices of this type.
摘要翻译：本发明涉及发光器件，特别是有机发光器件（OLED）。特别地，本发明涉及发光异腈/金属络合物作为这种装置中的低聚物发射体的用途。

5. 发明授权

US08835021B2 Materials for organic electroluminescence devices 有权
标题翻译：有机电致发光器件材料
公开(公告)号：US08835021B2
公开(公告)日：2014-09-16
申请号：US13001719
申请日：2009-08-25
申请人： Hartmut Yersin , Uwe Monkowius , Rafal Czerwieniec , Jiangbo Yu
发明人： Hartmut Yersin , Uwe Monkowius , Rafal Czerwieniec , Jiangbo Yu
IPC分类号： H01L51/54 , C09K11/06 , H01L51/00 , C07F5/02 , C09B57/10 , H01L51/50
CPC分类号： H01L51/0091 , C07F5/02 , C07F9/5045 , C09B57/10 , C09K11/06 , C09K2211/1044 , C09K2211/1085 , C09K2211/188 , H01L51/0037 , H01L51/008 , H01L51/0094 , H01L51/5012 , H01L2251/5384 , Y02E10/549 , Y10S428/917
摘要： The invention relates to mononuclear, neutral copper (1) complexes having a bidentate ligand that binds via nitrogen, and two phosphane or arsane ligands, to the use thereof for producing electronic components, and to electronic devices comprising said complexes.
摘要翻译：本发明涉及具有通过氮键合的双齿配体的单核中性铜（1）络合物，以及其用于制备电子元件的两种膦或者阿烷配体，以及包含该络合物的电子器件。

6. 发明授权

US08828560B2 Biphenyl-metal complexes—monomeric and oligomeric triplet emitters for OLED applications 有权
标题翻译：联苯 - 金属络合物 - 用于OLED应用的单体和低聚三线态发射体
公开(公告)号：US08828560B2
公开(公告)日：2014-09-09
申请号：US13540219
申请日：2012-07-02
申请人： Hartmut Yersin , Uwe Monkowius , Rafal Czerwieniec
发明人： Hartmut Yersin , Uwe Monkowius , Rafal Czerwieniec
IPC分类号： H01L51/54 , C09K11/06 , H01L51/00 , H01L51/50
CPC分类号： H01L51/0087 , H01L51/0035 , H01L51/004 , H01L51/0043 , H01L51/0084 , H01L51/0085 , H01L51/5016 , Y10S428/917
摘要： The present invention relates to light-emitting devices and novel emitter materials as well as emitter systems and, in particular, organic light-emitting devices (OLEDs). In particular, the invention relates to the use of luminescent complexes as emitters in such devices.
摘要翻译：本发明涉及发光器件和新颖的发射极材料以及发射体系，特别涉及有机发光器件（OLED）。特别地，本发明涉及在这种装置中使用发光配合物作为发射体。

7. 发明申请

US20110012099A1 OPTOELECTRONIC COMPONENT COMPRISING NEUTRAL TRANSITION METAL COMPLEXES 有权
标题翻译：包含中性过渡金属复合材料的光电组件
公开(公告)号：US20110012099A1
公开(公告)日：2011-01-20
申请号：US12921849
申请日：2009-02-25
申请人： Hartmut Yersin , Tobias Fischer , Rafal Czerwieniec , Uwe Monkowius
发明人： Hartmut Yersin , Tobias Fischer , Rafal Czerwieniec , Uwe Monkowius
IPC分类号： H01L51/30 , H01L51/40 , H01B1/00
CPC分类号： H01L51/0084 , C09K11/06 , C09K2211/1007 , C09K2211/1029 , C09K2211/185 , H01L51/0081 , H01L51/0085 , H01L51/0087 , H01L51/009 , H01L51/0091 , H01L51/424 , H01L51/5016 , Y02E10/549
摘要： The invention relates to the use of compositions as emitters or absorbers in an electronic component, wherein the compositions have a first neutral transition metal complex and a second neutral transition metal complex. According to the invention, the first transition metal complex and the second transition metal complex together form a column structure. The invention further relates to a method for the production of electronic components having such compositions.
摘要翻译：本发明涉及组合物在电子部件中作为发射体或吸收剂的用途，其中组合物具有第一中性过渡金属络合物和第二中性过渡金属络合物。根据本发明，第一过渡金属络合物和第二过渡金属络合物一起形成柱结构。本发明还涉及一种用于生产具有这种组合物的电子部件的方法。

8. 发明授权

US09130178B2 Oligomers of isonitrile-metal complexes as triplet emitters for OLED applications 有权
标题翻译：异腈 - 金属络合物的低聚物作为OLED应用的三重发射体
公开(公告)号：US09130178B2
公开(公告)日：2015-09-08
申请号：US12306957
申请日：2007-07-03
申请人： Hartmut Yersin , Uwe Monkowius , Tobias Fischer , Walter Finkenzeller , Rafal Czerwieniec
发明人： Hartmut Yersin , Uwe Monkowius , Tobias Fischer , Walter Finkenzeller , Rafal Czerwieniec
IPC分类号： H01L51/54 , C09K11/06 , H01L51/00 , C07F15/00 , H05B33/14 , H01L51/50
CPC分类号： H01L51/0087 , C07F15/0066 , C07F15/0093 , C09K11/06 , C09K2211/185 , H01L51/0081 , H01L51/0094 , H01L51/5016 , H05B33/14 , Y02E10/549
摘要： The present invention relates to light-emitting devices and in particular organic light-emitting devices (OLEDs). In particular, the invention relates to the use of luminescent isonitrile/metal complexes as oligomer emitters in devices of this type.
摘要翻译：本发明涉及发光器件，特别是有机发光器件（OLED）。特别地，本发明涉及发光异腈/金属络合物作为这种装置中的低聚物发射体的用途。

9. 发明授权

US09059415B2 Use of gold complexes in optoelectronic devices 有权
标题翻译：在光电器件中使用金络合物
公开(公告)号：US09059415B2
公开(公告)日：2015-06-16
申请号：US13578373
申请日：2011-02-10
申请人： Rafal Czerwieniec , Hartmut Yersin , Uwe Monkowius , Thomas Hofbeck , Antonio Laguna , Olga Crespo , Maria Conception Gimeno
发明人： Rafal Czerwieniec , Hartmut Yersin , Uwe Monkowius , Thomas Hofbeck , Antonio Laguna , Olga Crespo , Maria Conception Gimeno
IPC分类号： C07F1/12 , C07F9/6596 , H01L51/00 , C09K11/06 , H05B33/14 , H01L51/05 , H01L51/42 , H01L51/50 , H01S5/36
CPC分类号： H01L51/0091 , C09K11/06 , C09K2211/188 , H01L51/008 , H01L51/0081 , H01L51/009 , H01L51/0545 , H01L51/42 , H01L51/5012 , H01L2251/308 , H01S5/36 , H05B33/14 , Y02E10/549 , Y02P70/521
摘要： The invention relates to gold(I) complexes having a planar-trigonal coordination geometry and multivalent ligands for use in an optoelectronic device, in particular in organic light-emitting diodes (OLEDs) and in light-emitting electrochemical cells (LEECs).
摘要翻译：本发明涉及具有平面三角配位几何形状的金（I）配合物和用于光电器件（特别是有机发光二极管（OLED））和发光电化学电池（LEEC）中的多价配体。

10. 发明授权

US08658832B2 Luminescent metal complexes for organic electronic devices 失效
标题翻译：有机电子器件的发光金属络合物
公开(公告)号：US08658832B2
公开(公告)日：2014-02-25
申请号：US12667611
申请日：2008-07-03
申请人： Hartmut Yersin , Rafal Czerwieniec , Uwe Monkowius
发明人： Hartmut Yersin , Rafal Czerwieniec , Uwe Monkowius
IPC分类号： C07F15/00 , C07F9/02 , C07F5/02
CPC分类号： H01L51/5012 , C07F9/5045 , C07F13/005 , C07F15/002 , C07F15/0026 , C07F15/0046 , C07F15/0053 , C07F15/0073 , C07F15/008 , C07F15/0086 , C07F15/0093 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1029 , C09K2211/1092 , C09K2211/185 , C09K2211/188 , H01L51/0037 , H01L51/008 , H01L51/0081 , H01L51/0084 , H01L51/0087 , H01L51/5016 , Y02E10/549
摘要： The present invention relates to auxiliary ligands for luminescent metal complexes, particularly emitter complexes having such auxiliary ligands, and particularly light-emitting devices, and particularly organic light-emitting devices (OLED) having metal complexes, which have the auxiliary ligands according to the invention.
摘要翻译：本发明涉及用于发光金属络合物的辅助配体，特别是具有这种辅助配体的发光体配合物，特别是发光器件，特别是具有金属络合物的有机发光器件（OLED），其具有根据本发明的辅助配体。

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