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1. 发明申请

US20130025649A1 BLUE LIGHT EMITTER WITH SINGLET HARVESTING EFFECT FOR USE IN OLEDS AND OTHER ORGANIC-ELECTRONIC DEVICES 失效
标题翻译：蓝光发光体，具有采用OLED和其他有机电子设备的单张收集效果
公开(公告)号：US20130025649A1
公开(公告)日：2013-01-31
申请号：US13574329
申请日：2011-01-19
申请人： Hartmut Yersin , Rafal Czerwieniec , Tobias Fischer
发明人： Hartmut Yersin , Rafal Czerwieniec , Tobias Fischer
IPC分类号： C07F15/00 , C09K11/06 , H01L31/042
CPC分类号： H01L51/0087 , C09K11/06 , C09K2211/185 , H01L51/5012 , H01L51/5016 , H05B33/14 , Y02E10/549
摘要： The invention relates to the use of a platinum-dicyano-bisisocyanide complex cluster, having a small ΔE distance, in particular between 500 cm−1 and 3000 cm−1, between the lowest triplet state and the overlying singlet state that is populated by means of thermal repopulation from the triplet, in an organic-electronic device for emission of blue light and for absorption in the ultraviolet and blue spectral range. The invention also relates to the use of the singlet harvesting method. Furthermore, the invention relates to the use of the high degrees of absorption of such platinum-dicyano-bisisocyanide complex clusters.
摘要翻译：本发明涉及使用铂 - 二氰基 - 二异氰酸酯复合物簇，其具有小的Dgr.E距离，特别是在500cm -1和3000cm -1之间，在最低三重态和上覆的单重态之间，其被填充通过来自三联体的热再生，在用于发射蓝光的有机电子装置中并在紫外和蓝光谱范围内进行吸收。本发明还涉及单线收割方法的应用。此外，本发明涉及使用这种铂 - 二氰基 - 二异氰酸酯复合物簇的高吸收度。

2. 发明授权

US08716510B2 Blue light emitter with singlet harvesting effect for use in OLEDs and other organic-electronic devices 失效
标题翻译：具有单线收集效果的蓝光发射器用于OLED和其他有机电子器件
公开(公告)号：US08716510B2
公开(公告)日：2014-05-06
申请号：US13574329
申请日：2011-01-19
申请人： Hartmut Yersin , Rafal Czerwieniec , Tobias Fischer
发明人： Hartmut Yersin , Rafal Czerwieniec , Tobias Fischer
IPC分类号： C07F15/00 , C09K11/06 , H01L31/042
CPC分类号： H01L51/0087 , C09K11/06 , C09K2211/185 , H01L51/5012 , H01L51/5016 , H05B33/14 , Y02E10/549
摘要： The invention relates to the use of a platinum-dicyano-bisisocyanide complex cluster, having a small ΔE distance, in particular between 500 cm−1 and 3000 cm−1, between the lowest triplet state and the overlying singlet state that is populated by means of thermal repopulation from the triplet, in an organic-electronic device for emission of blue light and for absorption in the ultraviolet and blue spectral range. The invention also relates to the use of the singlet harvesting method. Furthermore, the invention relates to the use of the high degrees of absorption of such platinum-dicyano-bisisocyanide complex clusters.
摘要翻译：本发明涉及使用铂 - 二氰基 - 二异氰酸酯复合物簇，其具有小的Dgr.E距离，特别是在500cm -1和3000cm -1之间，在最低三重态和上覆的单重态之间，其被填充通过来自三联体的热再生，在用于发射蓝光的有机电子装置中并在紫外和蓝光谱范围内进行吸收。本发明还涉及单线收割方法的应用。此外，本发明涉及使用这种铂 - 二氰基 - 二异氰酸酯复合物簇的高吸收度。

3. 发明申请

US20100141120A1 Oligomers of Isonitrile-Metal Complexes as Triplett Emitters for OLED Applications 有权
标题翻译：作为用于OLED应用的三重发射体的异腈 - 金属络合物的低聚物
公开(公告)号：US20100141120A1
公开(公告)日：2010-06-10
申请号：US12306957
申请日：2007-07-03
申请人： Hartmut Yersin , Uwe Monkowius , Tobias Fischer , Walter Finkenzeller , Rafal Czerwieniec
发明人： Hartmut Yersin , Uwe Monkowius , Tobias Fischer , Walter Finkenzeller , Rafal Czerwieniec
IPC分类号： H01L51/54 , H01L51/56 , C07F15/00
CPC分类号： H01L51/0087 , C07F15/0066 , C07F15/0093 , C09K11/06 , C09K2211/185 , H01L51/0081 , H01L51/0094 , H01L51/5016 , H05B33/14 , Y02E10/549
摘要： The present invention relates to light-emitting devices and in particular organic light-emitting devices (OLEDs). In particular, the invention relates to the use of luminescent isonitrile/metal complexes as oligomer emitters in devices of this type.
摘要翻译：本发明涉及发光器件，特别是有机发光器件（OLED）。特别地，本发明涉及发光异腈/金属络合物作为这种装置中的低聚物发射体的用途。

4. 发明申请

US20110012099A1 OPTOELECTRONIC COMPONENT COMPRISING NEUTRAL TRANSITION METAL COMPLEXES 有权
标题翻译：包含中性过渡金属复合材料的光电组件
公开(公告)号：US20110012099A1
公开(公告)日：2011-01-20
申请号：US12921849
申请日：2009-02-25
申请人： Hartmut Yersin , Tobias Fischer , Rafal Czerwieniec , Uwe Monkowius
发明人： Hartmut Yersin , Tobias Fischer , Rafal Czerwieniec , Uwe Monkowius
IPC分类号： H01L51/30 , H01L51/40 , H01B1/00
CPC分类号： H01L51/0084 , C09K11/06 , C09K2211/1007 , C09K2211/1029 , C09K2211/185 , H01L51/0081 , H01L51/0085 , H01L51/0087 , H01L51/009 , H01L51/0091 , H01L51/424 , H01L51/5016 , Y02E10/549
摘要： The invention relates to the use of compositions as emitters or absorbers in an electronic component, wherein the compositions have a first neutral transition metal complex and a second neutral transition metal complex. According to the invention, the first transition metal complex and the second transition metal complex together form a column structure. The invention further relates to a method for the production of electronic components having such compositions.
摘要翻译：本发明涉及组合物在电子部件中作为发射体或吸收剂的用途，其中组合物具有第一中性过渡金属络合物和第二中性过渡金属络合物。根据本发明，第一过渡金属络合物和第二过渡金属络合物一起形成柱结构。本发明还涉及一种用于生产具有这种组合物的电子部件的方法。

5. 发明授权

US09130178B2 Oligomers of isonitrile-metal complexes as triplet emitters for OLED applications 有权
标题翻译：异腈 - 金属络合物的低聚物作为OLED应用的三重发射体
公开(公告)号：US09130178B2
公开(公告)日：2015-09-08
申请号：US12306957
申请日：2007-07-03
申请人： Hartmut Yersin , Uwe Monkowius , Tobias Fischer , Walter Finkenzeller , Rafal Czerwieniec
发明人： Hartmut Yersin , Uwe Monkowius , Tobias Fischer , Walter Finkenzeller , Rafal Czerwieniec
IPC分类号： H01L51/54 , C09K11/06 , H01L51/00 , C07F15/00 , H05B33/14 , H01L51/50
CPC分类号： H01L51/0087 , C07F15/0066 , C07F15/0093 , C09K11/06 , C09K2211/185 , H01L51/0081 , H01L51/0094 , H01L51/5016 , H05B33/14 , Y02E10/549
摘要： The present invention relates to light-emitting devices and in particular organic light-emitting devices (OLEDs). In particular, the invention relates to the use of luminescent isonitrile/metal complexes as oligomer emitters in devices of this type.
摘要翻译：本发明涉及发光器件，特别是有机发光器件（OLED）。特别地，本发明涉及发光异腈/金属络合物作为这种装置中的低聚物发射体的用途。

6. 发明授权

US08610110B2 Optoelectronic component comprising neutral transition metal complexes 有权
标题翻译：包含中性过渡金属络合物的光电元件
公开(公告)号：US08610110B2
公开(公告)日：2013-12-17
申请号：US12921849
申请日：2009-02-25
申请人： Hartmut Yersin , Tobias Fischer , Rafal Czerwieniec , Uwe Monkowius
发明人： Hartmut Yersin , Tobias Fischer , Rafal Czerwieniec , Uwe Monkowius
IPC分类号： H01L35/24
CPC分类号： H01L51/0084 , C09K11/06 , C09K2211/1007 , C09K2211/1029 , C09K2211/185 , H01L51/0081 , H01L51/0085 , H01L51/0087 , H01L51/009 , H01L51/0091 , H01L51/424 , H01L51/5016 , Y02E10/549
摘要： The invention relates to the use of compositions as emitters or absorbers in an electronic component, wherein the compositions have a first neutral transition metal complex and a second neutral transition metal complex. According to the invention, the first transition metal complex and the second transition metal complex together form a column structure. The invention further relates to a method for the production of electronic components having such compositions.
摘要翻译：本发明涉及组合物在电子部件中作为发射体或吸收剂的用途，其中组合物具有第一中性过渡金属络合物和第二中性过渡金属络合物。根据本发明，第一过渡金属络合物和第二过渡金属络合物一起形成柱结构。本发明还涉及一种用于生产具有这种组合物的电子部件的方法。

7. 发明申请

US20120184738A1 COPPER COMPLEXES FOR OPTOELECTRONIC APPLICATIONS 有权
标题翻译：用于光电应用的铜复合材料
公开(公告)号：US20120184738A1
公开(公告)日：2012-07-19
申请号：US13380361
申请日：2010-06-24
申请人： Hartmut Yersin , Uwe Monkowius , Tobias Fischer , Thomas Hofbeck , Thomas Baumann , Tobias Grab
发明人： Hartmut Yersin , Uwe Monkowius , Tobias Fischer , Thomas Hofbeck , Thomas Baumann , Tobias Grab
IPC分类号： C07F9/28
CPC分类号： H01L51/0091 , C07F1/005 , C07F9/58 , C07F9/62 , C07F9/6512 , H01L51/009 , H01L51/4253 , H01L51/5012 , H01L51/5072 , Y02E10/52 , Y02E10/549 , Y02P70/521
摘要： The invention relates to copper(I) complexes of the formula (A) with X═Cl, Br or I (independently of one another) N*∩E=bidentate ligand, with E=phosphinyl/arsenyl radical of the form R2E (where R=alkyl, aryl, alkoxy, phenoxy, amide); N*=imine function. Which is part of an aromatic group selected from pyridyl, pyrimidyl, pyridazinyl, triazinyl, oxazolyl, thiazolyl and imidazolyl, the aromatic group optionally having at least one substituent for increasing the solubility of the copper(I) complex in an organic solvent, and “∩”=at least one carbon atom, which is likewise part of the aromatic group, the carbon atom being located both directly adjacent to the imine nitrogen atom and to the phosphorus or arsenic atom, and also to the use thereof in optoelectronic assemblies, especially in OLEDs.
摘要翻译：本发明涉及式（A）与X = Cl，Br或I（彼此独立）N（∩E）=二齿配体的式（A）的铜（I）络合物，其中E = R2E形式的氧化基/ R =烷基，芳基，烷氧基，苯氧基，酰胺）; N * =亚胺功能。哪个是选自吡啶基，嘧啶基，哒嗪基，三嗪基，恶唑基，噻唑基和咪唑基的芳族基团的一部分，芳族基团任选具有至少一个用于增加铜（I）络合物在有机溶剂中的溶解度的取代基， ∩“=至少一个碳原子，其同样是芳族基团的一部分，碳原子位于与亚胺氮原子直接相邻的位置以及磷或砷原子，以及其在光电子组件中的用途，特别是在OLED中。

8. 发明申请

US20140364611A1 FUNCTIONALIZED TRIPLET EMITTERS FOR ELECTRO-LUMINESCENT DEVICES 审中-公开
标题翻译：用于电致发光器件的功能性三极管发射体
公开(公告)号：US20140364611A1
公开(公告)日：2014-12-11
申请号：US14465333
申请日：2014-08-21
申请人： Shuk K. Mak , Wai K. Chan , Tobias Fischer , Hartmut Yersin
发明人： Shuk K. Mak , Wai K. Chan , Tobias Fischer , Hartmut Yersin
IPC分类号： C07F15/00
CPC分类号： C07F15/0033 , C09K11/06 , C09K2211/185 , H01L51/0061 , H01L51/0085 , H01L51/0095 , H01L51/5016 , H05B33/14 , Y02E10/549
摘要： Organo-metallic complexes for opto-electronic and sensory devices and their use in such devices are provided. The organo-metallic complex (triplet emitter) consists of a metal center and chelate ligands. At least one of chelate ligands comprises an aromatic or fused aromatic ring(s). Each ligand is covalently substituted with at least one, preferably two charge transport groups (ctg). The metal center can be coordinated by a spectator ligand. Presence of two ctgs at each ligand is advantageous for applications in organic light emitting diodes (OLEDs). Charge transport units facilitate hole and/or electron transport to the molecular center and allow for efficient exciton formation directly on the complex. Presence of ctgs on each ligand provides a good shielding with respect to interactions with the environment. Emission quenching is strongly reduced and materials with high emission quantum yields are obtained. Presence of ctgs on each ligand reduces undesired quenching by triplet-triplet annihilation or self-quenching effects.
摘要翻译：提供了用于光电和感官装置的有机金属配合物及其在这些装置中的应用。有机金属络合物（三线态发射体）由金属中心和螯合配体构成。至少一种螯合配体包括芳族或稠合芳环。每个配体被至少一个，优选两个电荷转运基团（ctg）共价取代。金属中心可由旁观者配体协调。在每个配体上存在两个ctg对于在有机发光二极管（OLED）中的应用是有利的。电荷传输单元促进空穴和/或电子传递到分子中心，并允许在复合物上直接形成有效的激子。每个配体上的ctgs的存在为与环境的相互作用提供了良好的屏蔽。发射猝灭强烈降低，并获得具有高发射量子产率的材料。每个配体上的ctgs存在通过三重态三重态湮灭或自熄效应减少不期望的猝灭。

9. 发明申请

US20120326103A1 FUNCTIONALIZED TRIPLET EMITTERS FOR ELECTRO-LUMINESCENT DEVICES 审中-公开
标题翻译：用于电致发光器件的功能性三极管发射体
公开(公告)号：US20120326103A1
公开(公告)日：2012-12-27
申请号：US13512111
申请日：2010-11-26
申请人： Shuk Kwan Mak , Wai Kin Chan , Tobias Fischer , Hartmut Yersin
发明人： Shuk Kwan Mak , Wai Kin Chan , Tobias Fischer , Hartmut Yersin
IPC分类号： C07F15/00 , F21V9/00 , C09K11/06
CPC分类号： C07F15/0033 , C09K11/06 , C09K2211/185 , H01L51/0061 , H01L51/0085 , H01L51/0095 , H01L51/5016 , H05B33/14 , Y02E10/549
摘要： Organo-metallic complexes for opto-electronic and sensory devices and their use in such devices are provided. The organo-metallic complex (triplet emitter) consists of a metal center and chelate ligands. At least one of chelate ligands comprises an aromatic or fused aromatic ring(s). Each ligand is covalently substituted with at least one, preferably two charge transport groups (ctg). The metal center can be coordinated by a spectator ligand. Presence of two ctgs at each ligand is advantageous for applications in organic light emitting diodes (OLEDs). Charge transport units facilitate hole and/or electron transport to the molecular center and allow for efficient exciton formation directly on the complex. Presence of ctgs on each ligand provides good shielding with respect to interactions with the environment. Emission quenching is strongly reduced and materials with high emission quantum yields are obtained. Presence of ctgs on each ligand reduces undesired quenching by triplet-triplet annihilation or self-quenching effects.
摘要翻译：提供了用于光电和感官装置的有机金属配合物及其在这些装置中的应用。有机金属络合物（三线态发射体）由金属中心和螯合配体构成。至少一种螯合配体包括芳族或稠合芳环。每个配体被至少一个，优选两个电荷转运基团（ctg）共价取代。金属中心可由旁观者配体协调。在每个配体上存在两个ctg对于在有机发光二极管（OLED）中的应用是有利的。电荷传输单元促进空穴和/或电子传递到分子中心，并允许在复合物上直接形成有效的激子。每个配体上的ctgs的存在在与环境的相互作用方面提供良好的屏蔽。发射猝灭强烈降低，并获得具有高发射量子产率的材料。每个配体上的ctgs存在通过三重态三重态湮灭或自熄效应减少不期望的猝灭。

10. 发明授权

US09543531B2 Organic electroluminescent device 有权
标题翻译：有机电致发光器件
公开(公告)号：US09543531B2
公开(公告)日：2017-01-10
申请号：US13001664
申请日：2009-09-25
申请人： Hartmut Yersin , Uwe Monkowius , Tobias Fischer
发明人： Hartmut Yersin , Uwe Monkowius , Tobias Fischer
IPC分类号： H01L51/54 , C09K11/06 , H01L51/00 , C07F15/00 , H01L51/50
CPC分类号： H01L51/0085 , C07F15/0086 , C07F15/0093 , C09K11/06 , C09K2211/1029 , C09K2211/185 , H01L51/0042 , H01L51/0084 , H01L51/0087 , H01L51/5016 , H01L2251/5384
摘要： The present invention relates to the use of double-complex salts in electronic devices, in particular in organic electroluminescent devices, and oligomers formed from charged metal complexes.
摘要翻译：本发明涉及双配盐在电子器件中的用途，特别是有机电致发光器件以及由带电金属络合物形成的低聚物。

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