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    • 5. 发明授权
    • Low viscosity, pregelable rubber-based adhesives
    • 低粘度,预胶化橡胶基粘合剂
    • US4824512A
    • 1989-04-25
    • US77258
    • 1987-07-24
    • Hans-Peter Kohlstadt
    • Hans-Peter Kohlstadt
    • C09J121/00C09J109/00C09J3/12C08C19/08B62D27/00
    • C09J109/00
    • Rubber based adhesives containing liquid stereospecific polybutadiene rubber, one or more hardeners or hardener systems, fillers and optionally primers, which contain one or more chemically irreversibly depolymerized solid rubbers of natural or synthetic origin in quantities of from 1.5 to 5% by weight, based on the sum of the constituents, to a process for the production of these low-viscosity rubber-based adhesives by chemically irreversible depolymerization of one or more solid rubbers of natural or synthetic origin, and to the use of these low-viscosity rubber-based adhesives in the bonding of metal components in automotive manufacturing.
    • 含有液体立体特异性聚丁二烯橡胶,一种或多种硬化剂或硬化剂体系的橡胶基粘合剂,填料和任选的底漆,其含有一种或多种天然或合成来源的化学不可逆解聚固体橡胶,其量为1.5至5重量%,基于 组分的总和,通过一种或多种天然或合成来源的固体橡胶的化学不可逆解聚制备这些低粘度橡胶基粘合剂的方法以及使用这些低粘度橡胶基粘合剂 在汽车制造中金属部件的粘合。
    • 10. 发明授权
    • Aqueous binder dispersion for producing vulcanization bonds between
rubber and a solid substrate
    • 用于在橡胶和固体基材之间生产硫化粘合剂的水性粘合剂分散体
    • US4336171A
    • 1982-06-22
    • US156130
    • 1980-06-03
    • Hans-Peter KohlstadtRiza N. zelliGerhard Gierenz
    • Hans-Peter KohlstadtRiza N. zelliGerhard Gierenz
    • C08L27/08C08J5/12C09J109/04C09J127/08C09J139/06C08L39/06
    • C08J5/127C09J109/04C09J127/08C08J2321/00
    • An aqueous binder dispersion for use in the production of composite bodies by vulcanizing a vulcanizable rubber composition on a substrate which is stable under vulcanization conditions comprising water and at least one emulsifier and a solids content of from 20% to 50% by weight of a solids composition of,(a) per 1000 parts by weight of a polymer selected from the group consisting of polyvinylidene chloride, vinylidene chloride/alkyl acrylate copolymers, butadiene/acrylonitrile copolymers and mixtures thereof,(b) from 100 to 500 parts by weight of at least one aromatic poly-C-nitroso compound,(c) from 50 to 300 parts by weight of masked polyfunctional isocyanates,(d) from 20 to 100 parts by weight of a water-soluble polymer selected from the group consisting of polyvinyl pyrrolidone and water-soluble copolymers of vinyl pyrrolidone, and(e) from 5 to 500 parts by weight of customary fillers and pigments, adhesion-improving resins based on formaldehyde condensation products, adhesion-improving condensation products based on epichlorohydrin condensation products; emulsifiers and antifoam agents; as well as the method of bonding rubbers to solid substrates employing said aqueous binder dispersion.
    • 一种用于生产复合体的水性粘合剂分散体,其通过在基材上硫化硫化橡胶组合物,所述硫化橡胶组合物在包含水和至少一种乳化剂的硫化条件下是稳定的,固体含量为20至50重量%的固体 (a)每1000重量份选自聚偏二氯乙烯,偏二氯乙烯/丙烯酸烷基酯共聚物,丁二烯/丙烯腈共聚物及其混合物的聚合物的组合物,(b)100至500重量份的 至少一种芳族聚C亚硝基化合物,(c)50至300重量份的掩蔽的多官能异氰酸酯,(d)20至100重量份的水溶性聚合物,其选自聚乙烯吡咯烷酮和 乙烯基吡咯烷酮的水溶性共聚物和(e)5至500重量份常规填料和颜料,基于甲醛缩合产物的粘合改进树脂,粘合剂 基于表氯醇缩合产物的改进型缩合产物; 乳化剂和消泡剂; 以及使用所述含水粘合剂分散体将橡胶粘合到固体基材的方法。